Documente Academic
Documente Profesional
Documente Cultură
By
Prof.K.B.Krishna Kumar
PRESENTATION DETAILS
This presentation has been devided into:
INTRODUCTION ADVANTAGES OF MERCERIZATION CLASSIFICATION OF MERCERIZATION WHAT HAPPENS DURING MERCERIZATION PARAMETERS OF MERCERIZATION
EFFECT OF CONCENTRATION EFFECT OF DRYING EFFECT OF TEPARATURE EFFECT OF TENSION TEMPARATURE VS SHRINKAGE SHRINKAGE EFFECTS ON LUSTRE EFFECTS ON DYE ABSORPTION EFFECTS ON MOISTURE REGAIN
* IMPORTENCE OF WASHING
INTRODUCTION
Alakali treatments of COTTON has been found to be very advantageous to the processor. A number of alkali treatments like Desizing, Scouring, Caustic padding , Causticization, Mercerization etc. are being carried out on COTTON using NaOH by the processor. The effectiveness of these treatments depends on the penetration of the NaOH. However, the viscosity of NaOH poses, the problem of penetration to the processor.
INTRODUCTION cntd
Merecer observed that treatment OF COTTON with NaOH increases the Dye Exhaustion and fixation and Horace observed that treatment with NaOH by preventing shrinkage the fabric becomes more lustrous.
INTRODUCTION contd
Of all the treatments, treatment with NaOH of a specific concentration, for a specific period under control is known as Mercerization is of considerable importance, wherein the concentration is 48-52 Tw and the time is 30-40 sec. either under control or without control commonly referred as Tension Mercerization ( treatment under tension/ Control) Slack mercerization ( Treatment without tension/ Control)
Advantages of Mercerization
The mercerization has the following advantages: Improving luster Obtaining a silky look Improving the Tensile strength Retaining a greater proportion of tensile strength after easy care finishing Obtaining improved Dimensional Stability
Ability to cover & removal of Immature ( dead) fibres Improvement in cover factor
b)Tension Fixed-length mercerization Tension mercerization Tensionless mercerization c)Alkaline concentration Low-concentration alkaline mercerization High-concentration alkaline mercerization Two-step mercerization d)Temperature Ambient-temperature mercerization High-temperature mercerization Low-temperature mercerization
Modification of Crystalline net work ( The fibrils do not loose their identity but change in dimension and orientation ) The most important effect of mercerization on the fine structure of cellulose fibre consists of changing the crystal lattice from cellulose I to II
Temperature
Impurities of NaOH
PARAMETERS CONTD
Effect of Concentration
After swelling reaches its greatest point, NaOH thoroughly penetrates the interior of the micelle, and a reaction between the alkali and the micelle occurs, completing the generation of alkali cellulose I. From 18-22B, the range displaying the greatest degree of swelling, to around 24B, the cotton hair first contracts momentarily, and then swells again, and at 24B or above a second swelling peak was observed. These observations cannot be disregarded as baseless occurrences.
PARAMETERS CONTD
The longitudinal changes of a single scoured cotton hair in a single caustic soda solution (tensile force: 50mg) (Williams, Barratt and Parker)
PARAMETERS CONTD
Effect of Concentraton on Swelling According to the behavior observed for woven fabric and fibers of raw cotton exposed to alkali, woven fabric only displays around half the degree of swelling displayed by fibers if both are treated with the same concentration of alkaline solution, but no such difference exists between their respective degrees of alkali absorption.
The concentration at which yarn showed the greatest degree of swelling was determined to be 20% NaOH (26.5B).
PARAMETERS CONTD
Effect of Concentraton on Swelling contd.. The absorption of alkali solution by fibers & fabrics
PARAMETERS CONTD
PARAMETERS OF MERCERIZATION CONTD. The concentration of NaOH versus the shrinkage of cotton hairs and cotton fabrics
Cotton hair under physical restraint, that is, made into a yarn or a woven fabric that restrains the hair's freedom due to twisting and to crossing of twisted yarn, when treated with an alkali, displays different behavior because the shrinking and swelling displayed originally cannot occur due to the constraining forces. As an illustration reported by H. Flecken (Textil Praxis, Juni, 365, 1970) shows that even for the same type of yarn, the behavior of single, double and triple yarns display differences, as does the shrinkage of woven fabric and hairs. Cotton hair under physical restraint, when converted into a yarn or a woven fabric restrains the hair's freedom due to twisting and to crossing of twisted yarn, when treated with an alkali, displays different behavior because the shrinking and swelling displayed originally cannot occur due to the constraining forces. It is reported by H. Flecken that even for the same type of yarn, the behavior of single, double and triple yarns display differences, as does the shrinkage of woven fabric and hairs
The concentration of NaOH versus the shrinkage of cotton hairs and cotton fabrics
Fibers in their wet state at the conclusion of mercerization have a very high degree of swelling, and have large internal air gaps. But if the fibers are dried, these gaps will contract as the water evaporates. The final fixed sizes of the gaps inside the fibers are altered by different temperature and tension conditions during the drying. in comparison to untreated fiber, absorption of dyestuff is twice as high after mercerization, and 2.4 times as high after tensionless mercerization. Furthermore, the absorption of dyestuff is reduced by one third after natural drying in air, and by nearly one half after drying at 110C in comparison with non-dried fiber, which suggests the contraction of the air gaps inside the fiber.
PARAMETERS OF MERCERIZATION CONTD. EFFECT OF DRYING- DYE ABSORPTION a) Alkaline concentration versus the absorption of dyestuff b) Tension during mercerization versus the absorption of dyestuff
absorption of dyestuff
According to L.E. Hessler (Tex. Res. J., 24, p.822, 1954), the level of crystallization of cotton before mercerization was 89%, while after mercerization it was 64%, and that of viscose rayon was 45%. The results were particularly severe in cellulose having a low level of crystallization. Avoid drying on cylinders after mercerization. Dry at lowest possible temparature.
It can be concluded that the size of the air gaps in the cellulose's micelles, that is, the fiber's internal volumetric capacity, is altered by the tension and temperature conditions during the rinsing and drying at the end of the mercerization process which, in addition to altering the hygroscopic characteristics and producing variations in the absorption and reactivity of the dye, also significantly influence the hand of the fabric.
According to these results, regardless of the increase in the concentration of the alkali, above about 60C, complete mercerization does not take place. The concentration of around 30B in mercerization at room temperature, that is, around 20C, is in the middle of the chart for complete mercerization, and this, interestingly, is fairly consistent with stable conditions determined by experience in practical mercerization and with the results of all researchers.
The shrinkage of yarn in caustic soda solutions of different temperatures and concentrations
Beltzer in 1902, who investigated the relationship between shrinkage and the effects of temperature and alkaline concentration in the mercerization of cotton yarn, and the results show that the concentration of 20B represents a line beyond which behavior during mercerization changes.
The shrinkage of yarn in caustic soda solutions of different temperatures and concentrations
H. Flecken (Tex. Praxis., Juni, 365, 1970); measured the shrinkage of cotton yarn at concentrations of 30B and 38B for temperatures from 0C to 40C, and reported very small variations for temperatures in the range of 10-30C at a concentration of 30B, and this result can also be found in the center of Sisson's mercerization chart.
The relationship between the degree of stretching of a cotton hair during mercerization and the resulting luster.
WHAT ARE THE PARAMETERS OF MERCERIZATION ? Contd.. It is important to bear in mind that tension plays a key role which brings out not only luster, but also increases the Tenacity and Youngs modulus, however the Elongation at break decreases. As the concentration of NaOH increases from 150 to 350 gpl similar results as in the case of tension applied can be seen..
EFFECT OF TENSION
The luster of cotton fibers is decided by the ratio between the long and short axes of the cross section of the cellulose air, and it improves as the cross section becomes more circular. (See Fig. 19)
The axial ratio of the cross-section of single cotton fibers and their luster
WHAT ARE THE PARAMETERS OF MERCERIZATION ? Contd.. Fibre shrinkage in width and length direction is inversely proportional to the tension applied.
It is important to note that efficiency of mercerization is not dependent on swelling of cotton in alkali since swelling value of cotton is the least above 150 gpl conc. Of NaOH.
4. Luster increases
5. Stiffness increases
6. MR increases
7. Soiling decreases 8. % Exhaustion increases
WHEN MERCERIZATION CAN BE CARRIED OUT ? At Grey stage ( with the addition of alkali stable, low foaming, efficient Wetting agent) After Desizing After Scouring After Scouring and bleaching
Every stage of mercerizing has its own advantages and dis-advantages. It is suggested to carry out Mercerizing preferably after Scouring to get best of the best of the process.
CONDITIONS OF MERCERIZATION
Application of NaOH solution around 55-60TW ( 31-35% ) at a Temperature of 15 to 18C.
A dwell period of 55 sec on an average, to permit diffusion of alkali into the fibre. Warp tension during alkali treatment and stretching the weft ( width ) of the fabric during washing to prevent shrinkage. Finally washing off of the traces of alkali from the treated fibres.
Investigations reveal that with an impregnation concentration of 2830 Be or 250-300 Gpl of 100% NaOH or 215-240 Gpk (grams of 100% NaOH per Kg), there is no significant increase of Iodine absorption or dyestuff uptake. This means optimum mercerization is accomplished with a concentration of 220-240 grams of 100% NaOH per Kg of cloth on the fabric.
Chemical reactions lead to the formation of Alkali Cellulose. Physical reactions lead to a change in arrangement of units of cellulose. The surface of the of the nearly cylindrical cotton fibre after mercerizing reflects light more evenly to all sides than the kidney shaped cotton fibre and the fibre surface becomes more lustrous.
Mercerization reduces the axial ratio and increase the light scattering within the fibre ( transparency ) and thus increases the luster. Here it is important to bear in mind that short fibres on the surface decreases the luster which can avoided by singeing. It is also important to note that increase in luster can be seen from 180 gpl conc. Of NaOH to a maximum of 260-300 gpl NaOH conc. and then decreases slightly
Swelling and shrinkage are more when there is no tension in the fibre, but the alteration in cross section caused by swelling is more when mercerization is carried out under tension. Under optimum conditions each cotton fibre may contract nearly 9% in length and swell nearly 150%.
Swelling of the cotton fibre has also has a disadvantage. The fibre becomes more compact in its swollen condition. The compacting further diminishes the further penetration of Caustic.Soda into the fibre . In other words penetration slows down and the effect of mercerization in the fibres core is lower than on its surface giving rise to nonuniformity of mercerizing.
Mercerization also affects the size of crystallites and orientation of crystalline region and the extent of orientation depends on the tension during mercerization. Mercerization, both slack and with tension, increases the strength uniformity along the fibre length. The increase in TS is due to the elimination of weakest points in the fibre.
Mercerized fibre with tension shows greater gain in strength than that of without tension. Mercerization increases the cohesion between individual cotton hairs and this closer embedding of the hairs in the yarn not only increases the strength but makes it more uniform in strength and less in diameter. In practice, the improvements in strength are noticed mostly on mercerized yarn only, with fabric the major effect is only on the surface, along with dye fixation.
The properties of cellulose can be manipulated with the selection of Proper Concentration of Alkali,
Time,
Tension and Temperature during Mercerization. Washing conditions
Soda
Cellulose II follows an opposite course due to the better penetration of NaOH hydrates.
Cellulose III , IV and X can also be obtained on treatment of cotton with Ammonia at 35C , hot Glycerene and Phosphoric acid.
Mercerizing Machines.
Genarally a mercerizing machine consists of four sections which will have different tasks according to the process technique. Mercerizing Section : Impregnation with Caustic Intermediate sqeezing aggregate : Dividing of mercerizing section against stabilizing section. Here itself the required time factor is taken care to allow the Caustic to penetrate and mercerizing to take place. Stabilising Section : water treatment and thinning down concentration of the lye. At this zone structural modifications will take place. Intermediate sqeezing aggregate : Dividing of stabilising section against washing section Washing section : Washing off the alkali and nuetralisation
Hank Mercerizing
Yarn mercerizing generally entails rolling a 54-inch long (the length of one loop) hank weighing about 500g a number of times between two adjustable rollers. The yarn is moved by the turning of the rollers, with penetration of the alkali, application of tension and rinsing occurring automatically. In this, one cycle takes about three to five minutes, and four to eight kilograms can be treated at one time. In the latest machines, all operations are automated, including control of the alkaline solution's concentration and temperature and the addition and recovery of the alkali, along with application of tension on the yarn and rinsing.
CHEESE MERCERIZATION
Carrying out mercerization, scouring, bleaching, and, in some cases, dyeing, along with oiling or sizing, with the yarn in cheese form results in a major rationalization, which can raise productivity and reduce costs. However, mercerization in cheese form can only be expected to achieve half-mercerization, and not the same degree of evenness as hank mercerization or other types of mercerization. One problem is how to limit the difference in shrinkage between the inside and the outside of the cheese. Important factors in this are the adjustment of the twisting and the density of the winding of the yarn, the size of the take-up tube, the thickness of the layers during the winding, and the alkali concentration and temperature during the treatment.
In general, this method of treatment requires two-fold yarn with a yarn count less than 60, and it is unsuitable for the treatment of yarn with fine yarn counts higher than this. In general, this method of treatment requires two-fold yarn with a yarn count less than 60, and it is unsuitable for the treatment of yarn with fine yarn counts higher than this.
TOW MERCERIZATION
Normally, 400 or so yarns are wrapped around a beam or a ball with a warper and 8 to 10 of these beams or balls are set in a stand. Yarn is unreeled from the balls or the beams at the same time and lined up in ropes made with light twisting, which are mercerized continuously in a manner similar to that of roller mercerization of fabric. The equipment used in this method looks like a row of soapers, and each treatment bath is driven separately, tension on the yarn is controlled, and the shrinkage due to swelling during absorption of the alkali and the level of strain after this can be adjusted freely. This type of equipment can produce a large amount of yarn of consistent quality and so this method is suitable for the production of mercerized yarn for use in knits, and the treatment of fine yarn that is two-fold yarn with a yarn count of around 100-110 is also possible.
One problem concerning the type of equipment used is the separation of the yarns in the rope after it is dried at the conclusion of the mercerization process, and the way in which the yarns are unwound is very important for ensuring the smoothness of the operation.
WARP MERCERIZATION
While tow mercerization involves the treatment of a lot of yarn lined up in rope-form, in warp mercerization yarn is wound onto a beam and fed into a machine with the same system as in a slashersizing machine. Mercerization takes place with sheets of separate threads, and the machinery used can be exactly the same as that in tow mercerization. Thus, in the warp-beam method and the tow method, only the handling is different. problem, however, is that during treatment the breakage of a single thread can lead to major difficulties, and so if the yarn is not of very good even quality, industrial implementation of this method is difficult.
BATCH MERCERIZATION
In this method, an alkaline solution is padded onto fabric which is then rolled up, and when padding is completed the alkali is removed through continuous cold rinsing. Although the use of the method is not common in Japan, a certain degree of application, including in knits, can be found in in India & Western Europe. Despite costs for facilities being remarkably low, it is not an interesting method except for some special cases, as quality management and productivity remain problematic. Still, for the growing cases of carrying out alkali reduction for the polyester side of cotton/polyester blends to achieve both the mercerization of cotton and the alkali reduction of polyester in a single treatment, the application of this cold batch method is particularly interesting as a device that can combine the two separate stages which would otherwise raise facility problems.
The inherent disadvantage of chain mercerizing is; as the force for keeping the material under tension acts mainly on the outer edges and the line of force diminishes towards the middle, a greater elongation takes place at the edges than at the middle of the fabric.
The warp density, threads per cm are uniform before stentering and after stentering it is less at the edges than at the middle of the fabric. It is also note worthy to remember that the control over shrinkage in warp way is better when compared with weft way. In other words weft tension control is standard and not satisfactory.
IMPORTENCE OF WASHING
Many of the processors do not attach much importence to washing after mercerization. In fact it is very important and as important as mercerizing itself. The reorientation of the fibre takes place only at this stage. Effective and efficient washing only results in the strength gains, increased colour yield etc.
Washing
WASHING
HOT MERCERIZATION
Uniformity
Higher productivity Desired effect is achieved rapidly Contact time between fabric and NaOH is reduced by 50% When the fabric is impregnated in hot NaOH the fabric becomes highly plastic and less elastic and can be stretched to greater extent.
Higher Tensile strength can be anticipated. ( if stretching takes place while cooling ) Higher degree of Luster can be anticipated ( if streaching takes place while cooling ) Improved dye exhaustion Improved Colour Yield / dye-uptake Improvement in Easy-care finishing property.
1. Lower swelling 2. Conversion of Crystalline structure from Cellulose I to II is retarded 3. Cross sectional view reveals a skin-core appearance
A reasonable approach is to use hot caustic for better penetration and allow the impregnated material to cool to an adequate temperature in order to have good swelling Known as TWO STEP PROCEES
STEP 1 : Saturation of the cotton material with NaOH, preferably under relaxed conditions, at a temperature between 50oC and boiling temperature of NaOH. The immersion time ranges from 4-60 sec. STEP 2 : Controlled hot stretching following the saturation and cooling of the stretched material to less than 25oC. Tension controlled washing to a NaOH concentration of 60 gpl ( Stabilization), followed by final washing under normal conditions.
ANOTHER
METHOD
In another possible method of hot mercerization consists of wet-on-wet impregnation of the fabric immediately after washing at 95oC and a subsequent hot squeezing with high speed steam injection. The heated fabric is impregnated with NaOH solution at 30oC in the first step and at 20oC in the second step. Thereafter the stabilization sequence is normally carried out.
HOW IS IT
POSSIBLE
The above best While hot mercerization results are due to; appears to be advantages, it is Impregnation with hot important to remember alkali of 250-300 gpl that cotton fibers concentration leads to impregnated with Conc. the formation of only Soda cellulose I. Alkali solution are The transformation of subject to AKKALI DEGRADATION AND soda cellulose I to V THIS WILL BE HIGHER takes place only IN PRESENCE OF AIR during cooling step.
AND TEMPARATURE.
Yes, it is possible. Hot mercerization can permit an elimination of scouring or rather simplification or in other words combined process of scouring and mercerization, which can be carried out under the following conditions;
Cooling step and mercerization ( Chain or Chainless stabilization ) Furthermore the desizing step can be eliminated, since desizing will take place during this combined process. However the danger of alkali degradation chances increases which should be borne in mind while adopting this process.
Treatment of cotton fibre with liquid Ammonia produces similar effect that of Mercerization developed by Coats in 1960.
The liquid ammonia treatment is widely accepted for yarns used in sewing threads, and special fabrics like Denims, Corduroys, chmbays, Pillow material, linen, Jute and blends of cellulose with PET and/ or Nylon.
Prograde Process
in this process the yarn is treated with liquid ammonia at its boiling point of -33oC for less than a second, followed by immersion of yarn under tension in hot water for about 0.1 second to produce a 40% increase in tensile strength, improved luster etc. The yarn after ammonia treatment is streached and ammonia is removed by hot water washing.
Sanforset Process
This process represents a combination of exclusive liquid ammonia processing and controlled compressive shrinkage to provide Wash & wear characteristics with out strength loss on cotton denims along with an unusual soft and supple handle. Monforts, Germany has successfully developed Sanforset treatment range.
Sanforset Process
After entering process The material passes over 5 pre drying cylinders Then through a cooling station The drying cylinders reduce the moisture content of the material below the humidity, while the cooling station takes care of the cooling of the material.
Then the material pases into actual treatment chamber whre it is impregnated with liquid ammonia in a trough.
The treatment chamber is kept under slight vacuum to prevent ammonia from escaping. Finally it is squeezed off in a padder and the ammonia is driven off in two felt calanders. In this heat treatment 90-95% of ammonia is recovered. The rest which is chemically bound to the cellulose is removed in a steaming compartment consisting of a predwelling zone and a steaming zone. The entering and take off compartments are sealed by locks.
Sanforset Process
An after dwelling zone and take off zone complete the process. In this heat treatment 90-95% of ammonia is recovered. The rest which is chemically bound to the cellulose is removed in a steaming compartment consisting of a pre-dwelling zone and a steaming zone. The entering and take off compartments are sealed by locks. The evoparated ammonia is led to a recovery uni where it is compressed, cooled and liquefied to be led to a storage tank. The chemically bound ammonia is removed from the material separately, by dissolving in water and reusing it as chemical or manure. It can also be heated until it escapes and is oxidized. However, care must be taken to see that no pollution occurs.
Higher shrinkage
Lower luster Lower Colour yield Very costly Ammonia recovery even though not a problem with the machinery developed, leakages will do great harm to the personnel working.
Knitted fabrics are extremely sensitive to tension and therefore require careful handling during processing. This means that tensions exerted by the machinery on the fabric must be kept to a minimum. This is the reason for the special design of the entry to the range which consists of a centre driven unwinding arrangement. Due to its versatile design, the Benniger mercerizing machine BENDIMENSA masters the special structure, load and tension instability of knitted fabrics brilliantly, so much so that even single jersey fabrics can be run on the BEN-DIMENSA without any problems.
The machine has a specialized entry system. The low tension and gentle treatment is also ensured by the ratio metered AC drive. Each drive position can be adjusted up or down by 20%.
A minimum tension is exerted on the fabric during transportation in the chainless dwelling zone. The tension is controlled by the ratio metered AC drives located at the fabric transportation drums.
The dwelling zone is followed by a vertical return pin chain / stenter section, where the fabric is uniformly stretched during the gradual removal of the caustic content. This means an initial stabilization of the fabric already begins in the chain zone followed by further stabilization in the chainless section of the machine. Fabrics stabilized in this manner are subsequently washed and neutralised in Trikoflex washing compartment. The combination of the chain and chainless principles ensure the dimensional stability of the knitted fabric. The dimensions set during the processing are fixed and memorised permanently. The results after mercerising on the BEN -DIMENSA are representative of the final product and any deviation can be corrected immediately in the stenter frame.
CONCLUSIONS
Thanking you
OPEN WIDTH KNIT FABRIC PRETREATMENT RANGE Knitted fabrics are extremely sensitive to tension and therefore require careful handling during processing. This means that tensions exerted by the machinery on the fabric must be kept to a minimum. This is the reason for the special design of the entry to the range which consists of a centre driven unwinding arrangement. The unwinding tension on the fabric is independent to the size of the batch. The fabric enters the pre-washing zone with a constant low tension which is maintained throughout the process.
The impregnation with scouring and bleaching chemicals is carried out in a small Trikoflex LTS impregnation chamber followed by steaming in a specially designed steamer containing a roller bed dwelling zone. The fabric is passed, in a so-called free run, through a steam lock into the steamer and is immediately brought up to the reaction temperature. A folding mechanism plaits the fabric onto the roller bed. Depositing and draw off during the entire process occurs under stable pre-defined conditions.
Each chemical has a station consisting of a feed pump, inductive flow meter and control valve. This ensures the reproducibility of chemical quantities. The concentrated chemicals are fed into the circulation pipe of the Trikoflex LT-S, where by thorough mixing is effected. The set point is calculated according to the recipe entered (ml chemicals / kg fabric) and depends on the fabric flow (running meter weight x speed).
A dwell unit for soaping and other processes follows the initial washing compartments. Final rinsing and neutralisation are repeated in the subsequent Trikoflex washing compartments. This machine can be successfully utilised for washing of reactive dyed/ printed open width knitted fabrics too.