Documente Academic
Documente Profesional
Documente Cultură
L1-1
SOURCES
• Rain water
• River water
• Lake water
• Sea water
• Underground water-spring and well water
L1-2
Effect of water on rocks and
minerals:
• Dissolution: some mineral constituents of rocks
such as NaCl and CuSO4.2H2O readily dissolve
in water.
• Hydration: Some minerals are easily hydrated
with the consequent increase in volume leading
to disintegration of the rocks in which these
minerals are present. Eg.
• CaSO4 Hydration CaSO4.2H2O
(Gypsum)
• Mg2SiO4 Mg2SiO4.XH2O (Serpentine)
L1-3
Effect of water on rocks and minerals:
L1-5
They are mainly 3 types..
1. Physical impurities
2. Chemical impurities
3. Biological impurities
L1-6
PHYSICAL IMPURITIES:
1. Colour
2. Turbidity
3. Taste
4. odour
L1-7
Colour
Colour in water is
caused by metallic
substances like
salts.
L1-8
Turbidity
L1-9
Taste
In water is undesirable
for domestic as well as
industrial purpose.
L1-11
CHEMICAL IMPURITIES:
In-organic chemicals
Organic chemicals
L1-12
Inorganic chemicals:
L1-13
Organic chemicals
L1-14
Acidity
L1-16
Mineral matters
L1-17
BIOLOGICAL IMPURITES
L1-18
A. Micro-organisms: algae, fungi, viruses,
etc.
B. Water bodies in water include 1. Bacteria,
organisms’ inhabitating the bottom sludge,
and 2. Organisms and planktons
developed at the water surfaces. These
are inhibitated by different groups of
worms like flat worms, hair worms, tiny
roundworms, oligochetes, etc.
L1-19
HARDNESS
OF
WATER
L2-1
Definition
• Hardness of water defined as
which prevent the lathering of
soap.
L2-3
SODIUM STEAREATE
formulae is….
C17H35COONa
L2-4
POTASSIM STEARATE
formulae is….
C17H35COOK
L2-5
SOAP with HARDWATER
REACTIONS
2C17H35COONa+CaCl2
(C17H35COO)2Ca+2NaCl
L2-6
2C17H35COONa+MgSO4
(C17H35COO)2Mg+Na2SO4
L2-7
Types of Hardness
1.Temporary Hardness
2. Permanent Hardness
L2-8
Temporary Hardness
L2-9
Temporary Hardness mainly
caused by the presence of
dissolved Bicarbonates of
Calcium, Magnesium and
other Heavy metals and the
carbonate of Iron.
L2-10
Temporary hardness of water
mainly responsible salts are…
Calcium bicarbonate
Ca(HCO3)2
Magnesium bicarbonate
Mg(HCO3)2
L2-11
Temporary Hardness can be
largely removed by mere
Boiling of water.
L2-12
Equations
Ca(HCO3)2
Calcium bicarbonate
Heat
CaCO3+H2O+CO2
L2-13
When bicarbonates are
decomposed a, yielding
insoluble carbonates or
hydroxides, which are
deposited as a crust at the
bottom of vessel.
L2-14
Mg(HCO3)2
Magnesium bicarbonate
Heat
L2-15
Mg(OH)2+2CO2
Temporary Hardness is also
known as….
3.Carbonate Hardness
4. Alkaline Hardness
L2-16
Permanent hardness
• Non-Carbonate Hardness
• Non-Alkaline Hardness
L2-22
Differences between
Temporary
and
Permanent
Hardness
L2-23
Differences between Temporary
and Permanent Hardness
• Temporary • Permanent hardness
Hardness is mainly is due to the
caused by presence of
Bicarbonates of dissolved Chlorides
Calcium, and sulphates of
Magnesium and Calcium,
other heavy metals. Magnesium , Iron
and other metals
L2-24
Differences between Temporary
and Permanent Hardness
• Calcium bicarbonate
• CaCl2
• MgCl2
Ca(HCO3)2 • CaSO4
• Magnesium bicarbonate
• MgSO4
Mg(HCO3)2 • FeSO4
• Al2(SO4)3
L2-25
Differences between Temporary
and Permanent Hardness
L2-26
Differences between Temporary
and Permanent Hardness
• Temporary • Permanent
Hardness can be Hardness cannot
largely removed by removed by boiling
mere Boiling of but it can be
water. removed by the use
of chemical agents.
L2-27
Assignment work
• Distinguish between Temporary and Permanent
Hardness of water.
L2-28
L2-29
ES TIMA TION OF
HAR DNES S BY
EDT A M ET HOD
L3-1
T he har dne ss of water
is not a pol lu tion
par am eter but
indi ca te the ea ter
quali ty i n ter ms of
Cal ci um and
ma gnesi um expr essed
L3-2
in t er ms o f CaC O3.
T he a nal ysis is d one
by c omplex me tric
tit r atio n usin g
st andar d ED TA and
EBT a s an in dic ator.
L3-3
PRI NC IP LE:
In t his comp le x
metric Tit r ation, the
wate r sa mple i s
titr ated w ith
st andar d so lutio n o f
Di so diu m sa lt o f
L3-4
EDT A usin g EBT
PR OC EDUR E:
To 50 mL of sampl e ad d
10-15 mL buf fer sol uti ons
adj ust the pH about 10
and then war m the
sol uti on. A dd 2 dr ops o
Eri oc hrome Bl oc k- T and it
is tit r ated with 0. 01 M
EDT A sol uti on changes its
colour f rom r ed- wine to
L3-5
REA CT IO NS
INV OL VED :
EBT indica tor w hen ad ded
to har d w ater a t pH = 10,
for ms w eak comple xes
with calci um a nd
ma gnesi um pr esent in
har d w ater . It r esults in
the f or ma tion of Ca-EBT
or M g-E BT comple xes
w hic h is wine-r ed, these
L3-6
ar e u nsta ble.
Duri ng ti tr ati on with
ED TA, cal ci um fir st
reacts to f or m
rel ati vel y sta bl e
foll owed by ma gnesiu m
to gi ve Mg- EDTA +2
compl ex rel easi ng the
fr ee indi ca tor (bl ue) the
col our changes fr om
win e-r ed to bl ue at the
L3-7
EDTA COMPLEX
STRUCTURE
L3-8
Pr epar ation of st andar d
har d w ate r :
di ssol ve 1g of pur e, dr y
CaCO 3 i n mini mum
quan ti ty of di l.H Cl and
then eva por ate the
sol ution to dr yness on a
water ba th. Di ssol ve the
r esi due in di sti ll ed wate r
to mak e 1 Liter soluti on.
Eac h mL of thi s soluti on
L3-9
thus contain s 1mg of
CaCO 3 equal ent har dness.
1 mL h ar d w ater
so lu tio n = 1mg o f
Ca CO 3 e quale nt
har dness.
L3-10
Pr epar ation o f EDT A
so lu tion:
Disso lv e 4 g of pur e
EDT A cr ystals +
0.lg MgCl2 i n 1
Liter o f dist il le d
wate r.
L3-11
Pr epar ation o f EDT A
so lu tion:
Di ssol ve 4 g of
pur e EDTA
cr ystal s + 0.l g
MgCl 2 i n 1 Li ter
of di stilled water .
L3-12
EDTA STRUCTURE
L3-13
EDTA STRUCTURE
L3-14
EDTA STRUCTURE
L3-15
Pr epar ation o f
Indic ator (EB T):
Di ss ol ve 0. 5 g of
Erioc hr om e B lac k-
T in 100mL
alcohol .
L3-16
FORMULAE OF EBT
L3-17
Pr epar ation o f Bu f fer
so lu tion:
add 6 7.5g o f NH 4Cl
to 5 70 mL of Con.
Am mo nia so lu tio n
and th en d ilu te
wit h d ist il le d w ate r
to 1 Lit r e.
L3-18
Standar diza tion of EDT A
so lu tion:
Rinse and fill the burette with
EDTA solution. Pipette out 50
mL of standard hard water in a
conical flask. Add 10-15 mL of
buffer solution and 4 to 5 drops
indicator. Titrate with EDTA
solution till wine-red colour
changes to clear blue. Let
volume used by V1 mL.
L3-19
Titr atio n o f Un known
Ha r d w ate r :
Ti tr ate 50 mL of wate r
sampl e just in Step- 5.
let vol ume used be
V2 mL.
L3-20
Titr atio n o f
Per manent h ar dness:
take 250 mL o f t he w ater sample
in a l ar ge b eaker. B oil i t. T ill
the v olume is r educed to a bout
50 mL, filte r it , w ash th e
precip ita te wi th d ist il le d
water, colle cting f iltr ate and
washin g i n a 2 50 mL measuring
fla sk. F inall y ma keup the
volu me to 2 50 m L wi th d istil le d
wate r. T hen, titrate 50 mL o f
boil ed water s ample ju st a s i n
Ste p (5 ). L et volume u sed b y
L3-21 V3 mL.
Calculations
L3-22
V1 mL of EDTA is consumed by 50 mL
standard hard water.
50 * 1 mg of CaCO3 = V1 mL of EDTA
L3-23
Now 50 mL of given/ unknown hard
water =V2 mL of EDTA
V2*50/V1 mg of CaCO3
eq.
1 Lt or 1000 mL of given hard water
= 1000*V2/V1 mg of CaCO3
eq.
Total hardness of water
= 1000*V2/V1 mg/L
1 mg/L = 1ppm so,
= 1000*V2/V1 ppm
L3-24
Now 50 mL of boiled water
= V3 mL of EDTA
= V3*50/V1 mg of
CaCO3 eq.
1000 mL of boiled water
= 1000*V3/V1 mg of
CaCO3 eq.
= 1000*V3/V1 ppm
So,
Permanent hardness =
1000*V3/V1 ppm
L3-25
Temporary hardness =
[Total hardness – Permanent
hardness]
= 1000*V2/V1 – 1000*V3/V1
L3-26
• Total har dness of water
= 1000* V2/ V1 pp m
• Per manent har dness =
1000*V 3/ V1 ppm
• Temp or ar y har dness =
1000[( V2- V3)/ V1] ppm
L3-26
Ad va nta ges
of EDT A
me thod:
L3-27
T hi s method is def initel y
pr ep ar abl e to the other
me thods, b ec ause of
the
1. Gr ea ter accur ac y
2. C on ven ience and
3. Mor e r api d p rocedur e
L3-28
Assignment
L3-29
EDTA & HARDNESS
problems
L4-1
EDTA problems
• 1 g of CaCO3 was dissolved in dil.HCl and
diluted to 1000 mL. 50 mL of this solution
required 48 mL of EDTA solution for
titration. 50 mL of hard water sample
required 15 mL of EDTA solution for
titration. 50 mL of same water sample on
boiling, filtering etc, required 10 mL of
EDTA solution. Calculate the different
kinds of hardness in ppm.
L4-2
50 mL of standard hard water = V1 mL of
EDTA
V1= 48
50 mL of sample hard water = V2 mL of
EDTA
V2= 15
50 mL of after boiling sample hard water =
V3 mL of EDTA
V3= 10
L4-3
• Total hardness of water = 1000XV2/V1
= 1000 X 15/48
=312.5 ppm
• Permanent hardness = 1000XV3/V1
= 1000 X 10/48
= 208.3 ppm
• Temporary hardness = 1000[(V2-V3)/ V1]
= 1000 X (15-10)/48)
= 104.16 ppm
L4-4
EDTA problems
• 50 ml of a sample of hardwater was
titrated against 0.01 M EDTA, required 48
ml of EDTA for titration. 50 ml of the same
hardwater after boiling and filtering etc.
required 35ml of the EDTA for titration.
Calculate the total and temporary
hardness of water in degree clark.
L4-5
50 mL of standard hard water = V1 mL of
EDTA
V1= 50
50 mL of sample hard water = V2 mL of
EDTA
V2= 48
50 mL of after boiling sample hard water =
V3 mL of EDTA
V3= 35
L4-6
• Total hardness of water = 1000XV2/V1
= 1000 X 48/50
= 960 ppm
• Permanent hardness = 1000XV3/V1
= 1000 X 35/50
= 700 ppm
• Temporary hardness = 1000[(V2-V3)/ V1]
= 1000 X (15-10)/48)
= 260 ppm
L4-7
• Total hardness of water = 960 ppm
In Clarks 960 X 0.07 =67.2 0Cl
L4-8
Hardness problems
• Calculate the temporary, permanent and
total hardness in mg/litre of a sample of
water containing the following salts :-
Mg(HCO3)2 = 14.6mg/litre; Ca(HCO3)2
=16.2 mg/litre MgCl2 = 9.5mg/litre; CaSO4
= 13.6 mg/litre ( Assume the atomic mass
of Ca to be 40 and that of Mg to be 24).
L4-9
S.No. Constituent Amount MF CaCO3
mg/lit equivale
nt
1 CaSO4 13.6 100/136 10
L4-10
• Temporary Hardness = Ca(HCO3)2 +
Mg(HCO3)2
= 10 + 10 = 20 ppm
= 20 ppm = 20 mg/L
• Permanent Hardness = CaSO4 + MgCl2
= 10 +10 = 20 ppm
= 20 ppm = 20 mg/L
Total hardness = Temporary + permanent
hardness
= 20 + 20 = 40 ppm
= 40 ppm = 40 mg/L
L4-11
Hardness problems
• 2 litres of water obtained from a borewell in
Patancheru near Hyderabad gave the following
analysis for salts :- FeSO4 = 30.4 mg; CaSO4 =
13.6mg; MgCl2 = 38 mg;Ca(HCO3)2 = 32.4 mg;
Mg(HCO3)2 = 14.6mg; NaCl = 11.7 mg. Find out
the total hardness of water in ppm units, giving
temporary and permanent hardness assuming
the atomic mass of Fe to be 56, that of Ca to be
40, that of Mg to be 24 and that of Na to be 23.
L4-12
S.No. Constituent Amount MF CaCO3
mg/lit equivale
nt
1 FeSO4 30.4 100/152 20
3 MgCl2 38 100/95 40
L4-14
Hardness problems
• Determine the total hardness of a
sample of water in 0Fr and 0Clarke which
showed the following analysis :-
Suspended matter = 100 mg; Ca(NO3)2
= 16.4 mg/litre; MgSO4 = 24 mg/litre;
MgCl2 = 19 mg/litre; NaOH = 40 mg/litre;
KOH = 56 mg/litre ( At. Masses of Na =
23, Mg = 24, K = 39 and Ca = 40.)
L4-15
S.No. Constituent Amount MF CaCO3
mg/lit equivalent
2 MgSO4 24 100/120 20
3 MgCl2 19 100/95 20
4 NaOH 40 - -
5 KOH 56 - -
L4-16
• Temporary Hardness = Ca(NO3)2 = 10
ppm
L4-17
• Total hardness of water = 50 ppm
In Clarks 50 X 0.07 = 3.5 0Cl
In French 50 X 0.1 = 5 0Fr
• Permanent hardness = 40 pp
In Clarks 40 X 0.07 = 2.8 0Cl
In French 40 X 0.1 = 4 0Fr
• Temporary hardness = 10 ppm
In Clarks 10 X 0.07 = 0.7 0Cl
In French 10 X 0.1 = 1 0Fr
L4-18
ANALYSIS OF WATER
Alkalinity
Estimation of Chlorides
Estimation of Dissolved Oxygen
L5-1
1. ALKALINITY:
Alkalinity of water is due to the presence of
carbonates and bicarbonates of calcium and
magnesium. So the carbonate and bicarbonates in
water can be determined by titrating the solution
with standard acid like N/50 H2SO4 using first
Phenolphthalein and later methyl orange as an
indicator conversion of carbonates into
bicarbonates occur.
In the II step to the solution using methyl orange as
indicator (pH 4.2 to 5.4) bicarbonates present in the
water and bicarbonates formed from carbonates
gets neutralized.
The alkalinity of water is attributed to the presence
of the 100 Caustic alkalinity (due to hydroxide &
carbonate ions)
Temporary hardness (due to Bicarbonate ions)
L5-2
Analysis of water
PROCEDURE: Pipette out 100 mL of
the water sample in a clean titration
flask. Add to it 2 to 3 drops of a
phenolphthalein indicator. Run in
N/50 H2SO4 from burette. Till the
pink colour is just dis-charged. Then
to the same pink colour reappears.
L5-3
Analysis of water
CALCULATION:
let volume of acid used to phenolphthalein endpoint
= V1 mL
And
Extra volume of acid used to Methyl orange endpoint
= V2 mL
Phenolphthalein alkalinity P= V1 x 50 x 1000000 =
10 V1 ppm
50 x 100 x 1000
Methyl orange alkalinity M = (V1+V2) x 50 x
1000000 = 10(V1+V2) ppm
50 x 100 x 1000
L5-4
ESTIMATION
OF
CHLORIDES
IN WATER
L5-5
The chloride ions are present in
water in the form of one or more of
the compounds like CaCl2, MgCl2,
NaCl etc.
The estimation of chloride ions
is generally made by titrating the
water sample against a standard
solution of silver nitrate using
potassiumchromate as indicator.
The added silvernitrate precipitate
chloride ions as white precipitate
of silverchoride,
L5-6
as per the following chemical
reactions..
L5-7
When all the chlorine ions are
removed as AgCl ppt, the excess
drop of silvernitrate reacts with
potassiumchromate forming
silverchromate, which is red in colour.
L5-8
The endpoint is therefore
the change in colour from
bright yellow due to brick
red colour due to
formation of Ag2CrO4
indicator. Then titrate it
against N/50 AgNO3
solution till the colour
changes from yellow to
L5-9
permanent brick-red.
Calculation:
Let volume of N/50 AgNO3 used = V
mL
L5-11
The oxidation of KI by dissolved
Oxygen determines the amount of
dissolved Oxygen in water. Iodine
is titrated with standard
sodiumthiosulphate solution using
starch as final indicator. The
dissolved molecular Oxygen in
water does not react with KI. So,
an oxygen carrier is used to bring
about the reaction between
Oxygen and KI. Hence manganese
hydroxide is produced as a result
L5-12
2KOH + MnSO4 Mn(OH)2 +
K2SO4
2Mn(OH)2 + O2 2 MnO(OH)2
MnO(OH)2 + H2SO4 MnSO4 +
2H2O + [O]
2KI + H2SO4 + [O] K2SO4 +
H2O + I2
2Na2S2O3 + I2 2NaI + Na2S4O6
L5-13
The presence of sulphates,
nitrates, etc.
in rain water gives wrong results
in determination of dissolved
Oxygen in water because these
ions also liberates Iodine from KI.
In order to prevent the liberation
of Iodine solution from nitrate, If
present in water, sodium-azide
(NaN3) is added to the alkaline
Iodide solution.
L5-14
This reacts with nitrates and
gives..
L5-15
PROCEDURE:
250 mL of water is taken in bottle preventing
it to contact with air.
2 mL of Manganoussulphate solution is added
by means of pipette, and also 2 mL of
alkalineiodine solution is also added.
Shake the bottle thoroughly, and repeat the
process thrice.
The ppt is allowed to settle half-way and mix
again.
L5-16
PROCEDURE:
Then add to it Conc. H2SO4 insert the stopper
and shake the bottle again allow the yellow
solution to stand for 5 min.
L5-17
When the volume of
Thiosulphate is V mL
then dissolved oxygen
content in water is 8 V
ppm.
L5-18
Assignment
Write a short notes on
b. Estimation of Chlorides
c. Estimation of Dissolved Oxygen
L5-19
Methods of Treatment
of
Water
for
Domestic Purposes
L6,7-1
Methods of Treatment of
Water for Domestic Purposes
is mainly 3 types,
they are..
SEDIMENTATION
Chemical coagulation
FILTRATION
L6,7-2
SEDIMENTATION
Sedimentation is the process of removing
large suspended particles at the bottom of
the reservoir. Which are collected due to
gravity.
L6,7-3
SEDIMENTATION
In order to carry out the sedimentation process
successfully, some of the chemicals are added to
water before sedimentation. These chemicals are
called Coagulants.
L6,7-4
SEDIMENTATION TANK
L6,7-5
SEDIMENTATION TANK
L6,7-6
SEDIMENTATION TANK
L6,7-7
SEDIMENTATION TANK
L6,7-8
Chemical coagulants:
L6,7-9
•Alum is the most widely used in water treatment plants.
L6,7-10
FILTRATION
L6,7-13
L6,7-14
L6,7-15
L6,7-16
Sand filter
L6,7-17
Sand filter
L6,7-18
SAND FILTER
L6,7-19
ULTRA SAND FILTER
L6,7-20
SAND FILTER
L6,7-21
OPERATION OF SAND
FILTER
In sand filtration process, water is passed
through different sized sand beds like fine,
coarse and gravel beds.
The suspended particles are unable to pass
through the gaps in the sand bed, because of
their size.
Water is first passed through a fine sand-bed.
The suspended particles are first collected
and gets clogged in fine sand and then
passed through sand-bed.
Here colloidal matter gets collected and the
water is free from sediments.
L6,7-22
OPERATION OF SAND
FILTER
After passing of water from coarse
sand bed it enters through a bed of
medium sized stones called gravel or
gravel-bed.
This is the last bed where water is
filtered completely and the filtered
wate is collected at the filter outlet.
During the filtration process the fine
pores of sand bed gets seized and
clogged.
In order to continue the filtration
process, 2-3 cm of fine sand at the top
L6,7-23
L6,7-24
Sand filter operation
L6,7-25
Disinfection:
The process of destroying/killing the
disease producing Bacteria,
microorganisms, etc. from the water
and making it safe for use, is called
disinfection.
Disinfectants: the chemicals or
substances which are added to eater
for killing the Bacteria.
L6,7-26
The disinfection of water can be
carried out by following
methods:
A) BOILING
B) BLEACHING POWER
C) CHLORINE
D) OZONISATION
L6,7-27
The disinfection of water can be
carried out by following methods:
A). BOILING: Water for 10-15 minutes, all the disease-
producing bacteria are killed and water becomes safe for
use.
L6,7-29
BREAK-POINT
CHLORINATION:
Break-point chlorination is a controlled process.
In this process suitable amount of Chlorine is added to water.
In order to kill all the bacteria present in water, to oxidize the
entire organic matter and to react with free ammonia the
chlorine required should be appropriate.
Break-point determines whether chlorine is further added or
not. By Chlorination, organic matter and disease producing
Bacteria are completely eliminated which are responsible for
bad taste and bad odour in water.
When certain amount of Chlorine is added to the water, it
leads to the formation of Chloro-organic compounds and
chloramines.
Addition of some more chlorine leads to destruction of
chloro-organic compounds and chloramines.
The point at which free residual chlorine begins to appear is
terms as “Break-point”.
L6,7-30
BREAK-POINT
CHLORINATION:
L6,7-31
OZONISATION:
Ozone is powerful disinfectant and is
readily dissolved in water.
Ozone being unstable decomposes by
giving Nascent Oxygen which is
capable of destroying the Bacteria.
This ascent Oxygen removes the
colour and taste of water and oxidizes
the organic matter present in water.
O3
O2 + [O]
L6,7-32
Assignment
1. Write short notes on the following
:(a) Break-point chlorination (b) Slow
sand filtration (c) Impurities in water
and their effects. [5+5+6]
2. What is meant by disinfection?
What is its significance? Explain the
different methods used for
disinfection of surface water.
L6,7-33