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Its Only Plastic

Introduction to Plastics

Outline
What is plastic? Where do they come from? Types of plastic

What is Plastic?
a group of synthetic or natural organic materials that may be shaped when soft and then hardenedused in place of other materials, as glass, wood, and metals
www.dictionary.com

What is Plastic?
Plastic is a polymer
Poly Greek for many Meros Greek for part Polymer = many parts

Made of monomers
Greek = one part

Linear chain of molecules

What is Plastic?
Homopolymer
Made up of one type of monomer (polycarbonate for example)

Copolymer
Made up of more than one type of monomer (ABS for example)

Where Does Plastic Come From?


Coal
Can be used to make polyethylene and polystyrene

Petroleum
Source of most plastics

Natural
Corn, trees, soybeans, etc.

Where Does Plastic Come From?


Starting material is reacted to form monomer Monomer is reacted to form polymer (plastic) Addition polymerization
The monomer comes from one molecule (polyethylene, polypropylene, polystyrene)

Condensation polymerization
Monomer is made from more than one molecule and a by-product is given off (polyester, polycarbonate)

Making Plastic
Addition Type

Ethylene

Polyethylene

Making Plastic
Condensation Type

Terephthalic Acid

Ethylene Glycol

PET

Types of Plastic
Thermoplastics
Material can be softened by heat and then formed into an article. The material can be repeatedly softened and formed.

Thermoset plastics
Material is hardened with heat, pressure, or chemical reaction. The material can not be resoftened.

Types of Plastic
Polyethylene Advantages
Low Temperature Impact Chemical Resistant

Disadvantages Features
Different densities Processed different ways

Stress Cracking High Mold Shrinkage

Types of Plastic
Polypropylene Advantages
Light Weight Chemical Resistant Heat Resistant

Disadvantages Features
Easy to process Easy to customize Low Temperature Impact Bonding

Types of Plastic
Polyvinyl Chloride Advantages
Rigid Low Cost

Disadvantages Features
Easily modified Rigid is flame retardant

Processing PVC

Types of Plastic
Polystyrene Advantages
Rigid Paintable

Disadvantages Features
Can increase impact (HIPS) Transparent (GPPS)

Weathering Chemical Resistance Brittleness (GPPS)

Types of Plastic
Styrene Acrylonitrile (SAN) Advantages
Chemical Resistance Weathering

Disadvantages Features
Improved properties vs. GPPS Transparent Heat Resistance

Types of Plastic
Acrylonitrile Butadiene Styrene (ABS) Advantages
Dimensional Stability Toughness

Disadvantages Features
Different gloss levels Alloys Weathering Solvent Resistance

Types of Plastic
Nylon 6 Advantages
Strength, Stiffness Chemical resistant

Disadvantages
Water absorption

Features
Abrasion resistant Creep resistant

Types of Plastic
Nylon 66 Advantages
Strength, Stiffness Chemical resistant Heat resistant

Disadvantages
Features
Abrasion resistant Versatile Water absorption

Types of Plastic
Polybutylene Terephthalate (PBT) Advantages
Water absorption High Strength

Disadvantages Features
Dimensional Stability Processing Boiling Water Chemical Resistance

Types of Plastic
Polyethylene Terephthalate (PET) Advantages
Heat Resistance Close Mold Tolerances

Disadvantages Features
Can be transparent Tricky to injection mold Warpage Must be Dried

Types of Plastic
Polycarbonate Advantages
Dimensional stability Toughness

Disadvantages Features
Transparent Creep resistant

Chemical resistance Fatigue resistance

Resources
www.omnexus.com www.rtpcompany.com www.pslc.ws/macrog/

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