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HUBBLEs PRESENT HAIRLINDA ARINI AGUSTIN KARINA FRANSISKA
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HERMODYNAMIC ASPECT PRODUCE HYDROGEN H STEAM REFORMING OF NATURE GASES PROC

INTRODUCTION MATERIALS METHODS RESULTS AND DISCUSSION CONCLUTION

INTRODUCTION

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Nowdays many hydrogen gas applied in various chemical industry (amonia hydrochloric acid).

On the production processes of liquid coal, hydrogen is needed for hydrogenation

Hydrogen production requires heat energy and source of usable energy is heat energy that comes from nuclear power plants(NP

This study will discuss the thermodynamic aspects of an operating condition needs to be considered in the process of hydrogen production using steam reform

NPP (Nuclear Power Plant) Steam Reforming

NPP (Nuclear Power Plant)

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Steam Reforming

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MATERIALS

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ydrogen production by steam reforming of natural gas is the result of a reaction between natural gas (methane) and steam at high temperatures.

atural gas is a gaseous fossil fuel which is primarily consisting of methane (CH4), which is a short-chain and light hydrocarbon molecules. Natural gas also contains heavier hydrocarbon molecules such as methane (C2H6), propane (C3H8) and butane (C4H10 )

Natural gas

Natural gas

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METHODS

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steps of the steam reforming process consists of pretreatment of feed (natural g the process of reforming into synthesis gas (syngas), furthermore conversion into which is rich of hydrogen and hydrogen gas purification.

action takes place at a temperature 300-400oC and the pressure of 30-45 kg/cm Reforming process carried out in a primary reformer which is filled with nickel oxide (NiO) catalyst. The inlet temperature to primary reformer is 530-650oC and outlet temperature is 770-811oC, pressure 35-45 kg/cm2.

REACTIONTABLE

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A secondary reformer is needed to complete the reaction in the primary reformer ncorporating oxygen reacted with hydrogen gas to produce heat steam (exotherm Inlet temperature of secondary reformer is 520-560oC and outlet temperature is 920-1050oC, the pressure is 35 kg/cm2. Reaction conditions for the production of hydrogen from methane is determined by the thermodynamics of steam reforming from methane to CO and H2 and shift reaction to form CO2 and H2 .

REACTIONTABLE

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REACTION

H2 + RHS H2S + RH ZnO + H2S ZnS + H2O CH4 + H2O CO + 3H2 CO + H2O CO2 + H2 H2(g) + O2(g) H2O(g)

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TABLE

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RESULTS AND DISCUSSION

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This time, the process of hydrogen production by steam reforming of natural gas as a raw material is the most widely used is about 48% of world production.

this hydrogen production process occurs heat transfer in radiation and convectio Equilibrium of the reaction depends on the reaction temperature, pressure and steam to carbon ratio.

main product of the formation of carbon in the steam reforming is carbon whisk This type of whisker growth on the top of the nickel crystals.

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Carbon formation is also dependent on the kinetics of the reaction of hydrocarbons absorbed with oxygen and further dissociation of hydrocarbons into carbon atoms, which is soluble in nickel crystals

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CONCLUTION Utilization of heat energy from NPP for the production of hydrogen is one of the development of NPP heat recovery.

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Based on study of the thermodynamic aspects of formation process is as follows: ydrocarbons absorbed or carbon. hydrogen production by the steam reforming o natural gas, hydrogen production reaction is endothermic, an increase in temperature will increase the reaction conversion. he temperature rise is limited by the strength of the material and the catalyst u Viewed from equilibrium reaction, reforming reaction will be very well operated at low pressure, but will result in increased load (power) compressor in the refining and transportation of hydrogen product, so that the optimum pressure is 35-40 kg/cm2. NEXT

Steam to carbon ratio of 2.5 and temperature of 920oC will produce the maximum methane conversion. Phase in terms of the reaction, catalyst type and the heating medium suitable type of reactor used for the production of hydrogen by steam reforming is in coupling with the HTGR NPP is a fixed bed multitubes

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Katrya tifani Why kinetic reaction influence the carbon formation mirdA PRISMA THE PURPOSE OF THE JOURNAL SUCI AYU CAN EXPPLAIN PROCES IN THE STEAM PROCES..