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Thermal decomposition
precipitation
Reversible reactions
Thermal Decomposition
A thermal decomposition is when heat causes a chemical to break down to simpler substances. Compounds but not elements - undergo thermal decomposition. For compounds that contain metals we usually find: the more reactive the metal, the harder it is to decompose its compounds. Eg.
Gets harder
Potassium carbonate is not thermally decomposed. Calcium carbonate decomposes on strong heating Silver carbonate decomposes on gentle heating
Thermal Decomposition
Generally, the more reactive the metal is, the more difficult it is to decompose its compounds. Fill in the last column: easy, medium or hard
Potassium sodium calcium magnesium aluminium zinc iron copper mercury silver gold
Compound
Mercury oxide Sodium oxide Iron oxide Silver oxide Zinc oxide
Increasing reactivity
Hot air
1500C
Calcium oxide
O O Hg Hg
O O Hg
Hg
Heat
Hg O Hg O O Hg O Hg Hg O Hg O
O Hg O Hg Hg O Hg O O Hg O Hg Hg O Hg O O Hg O Hg Mercury oxide decomposes
Mercury
oxygen
Exothermic reactions give out heat (get Endothermic reactions take in heat (get
cold.) hot.)
Many chemical reactions need some energy to get them started (activation energy) but then the majority of chemical reactions are exothermic.
Burning wood on a fire Burning petrol in a car Burning butane in a cigarette lighter Burning gas in a gas hob
Reacting an acid and alkali together Burning magnesium Rotting compost etc etc
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A more reactive metal (higher in the reactivity series) will displace a less reactive metal from its compound
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Increasing reactivity
magnesium
K Na Ca Mg Al Zn Fe Cu Ag Au
Magnesium
Copper sulphate
Magnesium sulphate
Copper
more reactive
less reactive
K Na Ca Mg Al Zn Fe Cu Ag Au
Magnesium +
Magnesium sulphate
Copper
more reactive
Magnesium fuse
Aluminium
Iron Oxide
Aluminium Oxide
Iron
more reactive
less reactive
Aluminium wins the competition. Iron is displaced and melts at the high temperatures produced.
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Magnesium fuse
Activity
Iron
Magnesium
Zinc
Copper
Yes
Yes
No
No
No
No
Yes
No
Yes
Yes
Yes
Chlorine
Bromine Iodine
We can often tell which halogen is present from the colour of the solution.
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Increasing reactivity
Chlorine
Sodium Bromide
Sodium Chloride
Bromine
more reactive
less reactive
Activity
Predict what colour these will be after mixing. (The compounds of the halogens with Group 1 metals are all colorless.)
Halogen Halide Potassium chloride Potassium bromide Potassium Iodide
Br2
Chlorine solution
Bromine solution
Br2
Iodine Solution
I2
I2
I2
I2
+ bromine
Activity
Predict whether or not a chemical reaction will occur, If no reaction - not write no reaction. Where there is a reaction write the names of the products and then write a chemical equation underneath..
1) iodine + sodium bromide solution
F Cl Br I At
No reaction
No reaction Sodium chloride + iodine
2NaCl(aq) + I2(aq)
Reversible Reactions
Although most chemical reactions are difficult to reverse it is possible to find reactions ranging from irreversible through to the fully reversible.
One of the best known reversible processes is heating copper sulphate. Note the double arrow symbol in the chemical equation
Heat
Hydrated copper sulphate
anhydrous copper sulphate steam
CuSO4.5H20
These decompose
CuSO4
5H2O
These combine
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Equilibrium Reactions.
There are some reactions in which both the forward and backward reactions occur to a substantial extent under the same conditions.
These lead to equilibrium mixtures of reactants and products. One of the most important of these reactions occurs in the Haber Process.
N2(g) + 3H2(g) 2 NH3(g)
However long you leave the reaction going you still get a mixture of nitrogen, hydrogen and ammonia.
3H2(g) + N2 (g)
Low temperature
Precipitation Reactions
A precipitation reaction is any reaction that produces an insoluble compound when two aqueous solutions are mixed. It is impossible to predict whether or not we will get precipitation reactions unless we know something about the physical states (especially solubility) of the various reactants and products. Here are the symbols that we use in chemical equations to say what the physical state is:
(s) (l) (g) (aq) solid liquid gas aqueous (dissolved in water)
liquid
gas
Copper hydroxide is insoluble and precipitates. A pale blue solid settles at the bottom of the test tube.
Iron hydroxide is insoluble and precipitates. A deep brown solid settles at the bottom of the test tube.
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1.
To work out whether a precipitate will be formed when many ionic compounds react there are four stages:
Write down the names of the reactants. Sodium chloride & lead nitrate Na+ ClPb2+ ClPb2+ NO3Na+ NO3-
2
3 4
Sodium + chloride
lead nitrate
lead chloride
sodium nitrate
aqueous
aqueous
solid solid
aqueous
Activity
2
3 4
Sodium + sulphate
magnesium nitrate
magnesium sulphate
+ sodium nitrate
aqueous
aqueous
aqueous
aqueous
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Activity
2
3 4
Sodium + sulphate
barium nitrate
barium sulphate
sodium nitrate
aqueous
aqueous
solid solid
aqueous
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Activity
Neutralisation Reactions
Acids are substances that: Turn litmus red. Turn universal indicator yellow, orange or red. Have a pH below 7. Form solutions containing H+ ions. Bases are substances that: Turn litmus blue. Turn universal indicator dark green, blue or purple. React with the H+ ions in acids. Are called alkalis if they dissolve in water.
10 11 12 13 14
Increasingly acid
Increasingly alkali
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Strong or Weak?
strong strong strong
Sulphuric
Hydrochloric
HCl
HNO3 CH3COOH
Nitric
Ethanoic (vinegar)
weak
Salts
Sulphuric acid Nitric acid Hydrochloric acid
Sulphates
Nitrates
Chlorides
Strong or Weak?
strong
strong
strong weak
Ca(OH)2
NH4OH
Metal Oxides
Metal Carbonates
O2CO32-
10 11 12 13 14
Increasingly acid
Increasingly alkali
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2 The acid gives the last part of the name of the salt.
So Sulphuric acid make sulphates Nitric acid makes nitrates Hydrochloric acid makes chlorides
Sodium nitrate calcium sulphate
Activity
Salt?
Calcium chloride
Magnesium nitrate Calcium sulphate Aluminium nitrate
Potassium sulphate
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2H2O +
Eg. Potassium + hydrochloric water + carbon + potassium carbonate acid dioxide chloride
K2CO3
Eg. calcium + carbonate
+ 2HCl
nitric acid
H2O + CO2
2KCl
CaCO3
+ 2HNO3
H2O
+ CO2
+Ca(NO3)2
Neutralisation Equations
Complete the word equation
Eg. Potassium + hydrochloric hydroxide acid +
water
Potassium chloride
KOH
+ HCl
H2O
KCl
Check that it balances (same number of each type of atom each side).
Eg.
KOH
+ HCl
Reactants 1*O 2*H
H2O + KCl
Products 1*O 1*K
1*Cl
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1*K
1*Cl
2*H
Neutralisation Equations
Complete the word equation
Eg. Magnesium + nitric oxide acid water + Magnesium nitrate
MgO
+ HNO3
H2O
Mg(NO3)2
Check that it balances (Same number of each type of atom each side.
Eg.
MgO
2 HNO3
2 H 2O
1*Mg
1*NO3
2*H
2*NO3
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Activity
Write balanced equations going through the same stages as the previous examples
1. word equation, 2. formulae, 3. Balance.
a) sodium hydroxide + hydrochloric acid b) magnesium oxide + hydrochloric acid c) sodium hydroxide + sulphuric acid d) ammonium hydroxide + hydrochloric acid
Activity
Insoluble salts can be separated by filtering. Soluble salts are obtained by evaporating.
Put these in the correct order A. Check the pH frequently by testing drops of the solution.
vapour
gauze Evaporating basin
tripod
Heat-proof mat
Bunsen burner
Redox Reactions:
Redox is a short way of saying:
Early on in chemistry these words had very straightforward meanings
Oxidation meant adding oxygen to a substance.
Rusting (iron becoming iron oxide) is an example of oxidation
Reduction and oxidation.
Reduction meant taking oxygen away. Extracting iron from iron oxide in the blast furnace is reduction
Mg
2 e-
to give
Mg2+
O2-
O
Mg2+
Mg
S
S2-
Cl
Cl- Mg2+ Cl-
Oxygen removed
loss
R Reduction I is
gain
Activity
calcium oxide
zinc + water
Copper chloride
reduced
copper + chlorine
Activity If the first substance is oxidised, what has been reduced or vice versa. (Use whichever definition of oxidation and reduction seems easier to apply.). Calcium + oxygen calcium oxide
oxidised
zinc + water
Copper chloride
reduced
copper + chlorine
Activity
Across: 5 tells us whether acid or alkali 11 reaction of an acid with a base 1 2 3 4 6 7 8 9 10 Down a solid forms in a solution loss of electrons competition reaction gives solutions containing H+ ions to break down into smaller particles removal of oxygen state of balance soluble base ionic compound formed in neutralisations
Activity
Match them up
Thermal decomposition Dehydrating copper sulphate
Endothermic Metal displacement Reversible reaction Precipitation Neutralisation Oxidation Reduction Soluble base Equilibrium
A solid forms within a solution A salt and water is formed Alkali Reaction in a state of balance Thermit reaction Removal of oxygen Breaking up with heat Takes in energy gets cold Loss of electrons
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When heated the orange powder erupted like a volcano producing a huge pile of green powder that had less mass than the orange material. Is this? 1. 2. 3. 4. Neutralisation Thermal decomposition Displacement Precipitation
When the two colourless solutions mixed a yellow solid formed which sank to the bottom of the test tube Is this? 1. 2. 3. 4. Neutralisation Thermal decomposition Displacement Precipitation
When the copper was placed in the silver nitrate solution snow like crystals of silver seemed to grow out from the copper. Is this? 1. 2. 3. 4. Equilibrium Thermal decomposition Displacement Precipitation
When the washing soda was added to the lemon juice it fizzed and the pH rose towards 7. Is this? 1. 2. 3. 4. Neutralisation Thermal decomposition Displacement Oxidation
Which of the oxides shown will thermally decompose most easily? 1. 2. 3. 4. Mercury oxide Potassium oxide Iron oxide Gold oxide
Which of the salts below might be formed when nitric acid neutralises a metal hydroxide? 1. 2. 3. 4. Potassium hydroxide Potassium nitrate Ammonium nitrate Calcium sulphate
Which of the mixtures below will result in a metal displacement reaction? 1.Potassium oxide and gold 2.Magnesium and sodium nitrate 3.Copper and gold nitrate 4.Aluminium and calcium sulphate
Which of the mixtures below will result in a nonmetal displacement reaction? 1.Potassium chloride and iodine 2.Potassium bromide and iodine 3.Potassium fluoride and chlorine 4.Potassium iodide and chlorine
Which of the elements in red (below) is oxidised in the reaction? (Oil Rig!)? 1.Ca + 2.2Li + 3.2Al + 4.HNO3 CuO CaO + Cu 2HCl 2LiCl + H2 Fe2O3 Al2O3 + 2Fe + CuO CuNO3 + H2O
Which compound can you be sure is soluble in water? 1. 2. 3. 4. Manganese nitrate Osmium iodide Thallium chloride Palladium sulphate