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Unit 7
Chemistry
Langley
*Corresponds to Chapter 13 (pgs. 384-409) in Prentice Hall Chemistry
textbook
KINETIC THEORY
Kinetic Theory states that the tiny
particles in all forms of matter are in
constant motion.
Kinetic refers to motion
Helps you understand the behavior of solid,
liquid, and gas atoms/molecules as well as
the physical properties
Provides a model behavior based off three
principals
KINETIC THEORY
STATES OF MATTER
5 States of Matter
Solid
Liquid
Gas
Plasma
Bose-Einstein
Condensates
http://www.plasmas.org/E-4phases2.jpg
SOLIDS
Particles are tightly packed and close together
Particles do move but not very much
Definite shape and definite volume (because
particles are packed closely and do not move)
Most solids are crystals
Crystals are made of unit cells (repeating
patterns)
The shape of a crystal reflects the arrangement of
the particles within the solid
SOLIDS
Unit cells put together make a crystal
lattice (skeleton for the crystal)
Crystals are classified into seven crystal
systems: cubic, tetragonal,
orthorhombic, monoclinic, triclinic,
hexagonal, rhombohedral
Unit cell crystal lattice solid
SOLIDS
Amorphous Solid:
A solid with no defined shape (not a crystal)
A solid that lacks an ordered internal structure
Examples: Clay, PlayDoh, Rubber, Glass, Plastic,
Asphalt
Allotropes:
Solids that appear in more than one form
2 or more different molecular forms of the same
element in the same physical state (have different
properties)
Example: Carbon
Powder = Graphite
Pencil lead = graphite
Hard solid = diamond
SOLIDS
www.ohsu.edu/research/sbh/resultsimages/crystalvsglass.gif
SOLIDS
Allotropes of
Carbon: a)
diamond, b)
graphite, c)
lonsdaleite,
d)buckminsterfull
erene (buckyball),
e) C540, f) C70, g)
amorphous
carbon, and h)
single-walled
(buckytube)
www.wikipedia.org
LIQUIDS
Particles are spread apart
Particles move slowly through a container
No definite shape but do have a definite
volume
Flow from one container to another
Viscosity resistance of a liquid to flowing
Honey high viscosity
Water low viscosity
chemed.chem.purdue.edu/.../graphics
GASES
Particles are very far apart
Particles move very fast
No definite shape and No definite volume
http://www.phy.cuhk.edu.hk/contextual/heat/tep/
trans/kinetic_theory.gif
PLASMA
BOSE-EINSTEIN CONDENSATE
Particles extremely close together
Particles barely move
Only found at extremely cold
temperatures
Basically Bose-Einstein is a cold solid
Lowest energy of the 5 states/phases of
matter
TEMPERATURE
Temperature is the measure of the average
kinetic energy of the particles.
3 Units for Temperature:
Celsius
Farenheit
Kelvin
Has an absolute zero
Absolute lowest possible temperature
All particles would completely stop moving
Temperature Conversions:
Example 1: Convert 35C to F
Example 2: Convert 300 Kelvin to C
MEASURING PRESSURE
Manometers:
Measure pressure
2 kinds: open and closed
Open Manometers:
Compare gas pressure to air pressure
Example: tire gauge
Closed Manometer:
Directly measure the pressure (no
comparison)
Example: barometer
Energy of motion
Energy of a moving object
Matter is made of particles in motion
Particles have kinetic energy
KE = (mv2)/2
OR
KE = (ma)/2
Kinetic Energy is measured in Joules
1 J = 1kgm2/s2
Speed of Gases:
If two gases have the same temperature (particles
moving at the same speed) how can you tell which
gas has a greater speed?
The only difference is mass!
To find mass, use the periodic table
ENTROPY
A measure of the disorder of a system
Systems tend to go from a state of order (low
entropy) to a state of maximum disorder (high
entropy)
Entropy of a gas is greater than that of a liquid;
entropy of a liquid is greater than that of a solid
Solids=low entropy; plasma=high entropy
Le CHATELIERS PRINCIPLE
Anytime stress is placed on a system, the
sytem will readjust to accommodate that stress
If a chemical system at equilibrium experiences
a change in concentration, temperature,
volume, or total pressure, then the equilibrium
shifts to partially counteract the imposed
change
Can be used to predict the effect of a change
in conditions on a chemical equilibrium
Is used by chemists in order to manipulate the
outcomes of reversible reactions, often to
increase the yield of reactions
Le CHATELIERS PRINCIPLE
When liquids are heated (stress) they
produce vapor particles (adjust)
When liquids are cooled (stress) the
particles inside tighten to form a solid
(adjust)
Le CHATELIERS PRINCIPLE
Le Chateliers Principle explaining boiling and
condensation using covered beaker partially filled with
water
At a given temperature the covered beaker constitutes a
system in which the liquid water is in equilibrium with the water
vapor that forms above the surface of the liquid.
While some molecules of liquid are absorbing heat and
evaporating to become vapor, an equal number of vapor
molecules are giving up heat and condensing to become
liquid.
If stress is put on the system by raising the temperature, then
according to Le Chtelier's principle the rate of evaporation will
exceed the rate of condensation until a new equilibrium is
established
PHASE DIAGRAMS
A diagram showing the conditions at
which substance exists as a solid, liquid,
or vapor
Shows the temperature and pressure
required for the 3 states of matter to exist
Conditions of pressure and temperature
at which two phases exist in equilibrium
are indicated on a phase diagram by a
line separating the phases
Draw the phase diagram for water
PHASE DIAGRAM-WATER
PHASE DIAGRAM-WATER
Explanation of Phase Diagram:
X axis-Temperature (C)
Y axis- Pressure (kPa)
Line AB line of sublimation
Line BD boiling point line
Line BC melting point line
Point B triple point (all 3 states of matter
exist at the same time)
Tm melting point at standard pressure
Tb boiling point at standard pressure
HEAT in CHANGES of
STATE
Energy Diagrams (also referred to as
Heating Curves)
Graphically describes the enthalpy (the heat
content of a system at sonstant pressure)
changes that take place during phase
changes
X axis is Energy (Heat supplied)
Y axis is Temperature
HEAT in CHANGES of
STATE
Constructing Energy Diagrams
Step 1: Determine/Identify the melting and boiling
points for the specified substance
Step 2: Draw x and y axis (energy vs temp)
Step 3: Calculations