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HAZARDS
Quiz
WRITE YOUR STUDENT SECTION IN YOUR ANSWER!
1. What are the basic steps that should be taken in
order to ensure a safe and healthy workplace and
prevent accidents?
(3 marks)
INTRODUCTION
SIGNIFICANT DISASTERS
1. Gases
CLASSIFICATION of chemical
hazards
2. Flammable liquids
3. Explosive substances
In forms of solid, liquid or mixture which is capable by
chemical reaction
Contain both fuel & oxidant can function
independently of the nature of their surrounding
Eg. : dynamite & carbide
4. Corrosive substances
Will attack skin & materials such as wood or metals
Eg. : sulphuric acid, caustic soda etc
Supply oxygen - readily support & maintain
combustion that increase the rate at which the fire
will develop
Eg. : Sodium chlorate
5. Oxidising agent
6. Flammable solids
7. Toxic substances
2. UN numbering
UN committee also came out with a numbering system
for each hazardous chemical
More specific to identify similar chemical with
different name
Only applied to hazardous chemicals
Eg. : - sodium hydroxide = caustic soda 1823
- acetone 1090
- sulphuric acid 1830
- acetylene 1001 etc
Developed by health & safety executive of United
Kingdom is address to the emergency and fire brigade
personnel
It gives them a ready method of controlling a spillage
or fire arising from hazardous chemicals
3. HAZCHEM scale
PROPANE
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SECTION I - Product Identification
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PRODUCT NAME:
PROPANE
FORMULA:
N/A
FORMULA WT:
N/A
COMMON SYNONYMS:
N/A
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SECTION II - Hazardous Components
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PROPANE
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SECTION III - Physical Data
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BOILING POINT:
-44F
VAPOR PRESSURE(MM HG):
N/A
MELTING POINT:
N/A
VAPOR DENSITY(AIR=1):
1.55
SPECIFIC GRAVITY:
N/A
EVAPORATION RATE:
NA
(H20=1)
(BUTYL ACETATE=1)
SOLUBILITY(H20):
N/A
% VOLATILES BY VOLUME:
100
APPEARANCE & ODOR:
COLORLESS-ROTTEN EGG ODOR.
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SECTION IV - Fire and Explosion Hazard Data
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FLAMMABILITY CLASSIFICATION:
UNK
FLASH POINT:
-156F
FLAMMABLE LIMITS:
UPPER - 9.5 %
LOWER - 2.1 %
FIRE EXTINGUISHING MEDIA:
STOP FLOW OF GAS OR OXYGEN
SPECIAL FIRE-FIGHTING PROCEDURES:
USE WATER TO COOL TANK
UNUSUAL FIRE AND EXPLOSION HAZARDS:
AUTO IGNIT TEMP 874F;HEAVIER THAN AIR
(VAPOR DENSITY 1.5) MAY TRAVEL A
CONSIDERABLE DISTANCE TO AN IGNITION
SOURCE AND FLASHBACK
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SECTION V - Health Hazard Data
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EFFECTS OF OVEREXPOSURE: POSS FREEZ BURN;MOD CONCENTRATION
W/AIR CAUSES UNCON
MEDICAL CONDITIONS PRONE
TO AGGRAVATION BY EXPOSURE:
UNK
PRIMARY ROUTE(S) OF ENTRY: INHALE
EMERGENCY AND FIRST AID PROCEDURES:
INHALE/FRESH AIR
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M AT E R I AL S AF E TY D ATA S H E E T
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SECTION VI - Reactivity Data
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STABILITY:
STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID:
NA
INCOMPATIBLES:
NONE
DECOMPOSITION PRODUCTS: NONE
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SECTION VII - Spill and Disposal Procedures
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DISPOSAL PROCEDURE:
VENT TO ATMOSPHERE IN FLAME FREE, SPARK FREE AREA OUTDOORS
OTHER PRECAUTIONS:
NONE
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SECTION VIII - Protective Equipment
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VENTILATION:
NA
RESPIRATORY PROTECTION: NONE W/NORMAL USE
EYE PROTECTION:
NONE
SKIN PROTECTION:
NONE
OTHER EQUIPMENT:
NONE
HYGIENIC PRACTICES:
NONE
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SECTION IX - Storage and Handling Precautions
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SPECIAL PRECAUTIONS:
TEMPS <120F IN WELL VENTED AREA AWAY FROM SPARK AND FLAME
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SECTION X - Transportation Data and Additional Information
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N/A
-------------------------------------------------------------------------------(TM) and (R) : Registered Trademarks
N/A = Not Applicable OR Not Available
The information published in this Material Safety Data Sheet has been compiled from our experience and data presented
in various technical publications. It is the user's responsibility to determine the suitability of this information for adoption
of necessary safety precautions. We reserve the right to revise
Material Safety Data Sheets periodically as new information becomes available.
Copyright by Manufacturer
LICENSE GRANTED TO MAKE UNLIMITED COPIES FOR INTERNAL USE ONLY
by OREGON STATE UNIVERSITY
Acute
Short term period between exposure and onset of
symptoms
Chronic
Long time period between exposure to an agent and the
onset of symptoms
Unit of concentration;
ppm - parts per million
mg/m3 -milligrams per cubic meter
Mppcf -millions or a particle per cubic foot
f/cc - fibers per cubic centimeter
Exposure limits;
TWA -takes into account variable exposure through a
full shift, 8 hour work day
STEL - limit of exposure for a short period, 15 mins
CEILING - absolute maximum level of exposure
0.5
Formaldehyde
Carbon Monoxide
25
Turpentine
100
Methyl Alcohol
200
Acetone
1000
TLV-TWA (ppm)
Important features
SYNONIMS
PEL
(ppm)
PHY. DESC.
INCOMP.
Ammonia
Ammonia
anhydrous
50
Colourless
liquid
Strong
oxidizers, gold,
halogens
Benzene
Colourless
liquid
Strong
oxidizers,
chlorine
bromine
Chloroform
Trichloromethane
50
Colourless
liquid
Active metals,
caustic soda
Potassium
cyanide
Sodium cyanide
White solid
Strong
oxidizers
Such as nitrates
chlorates, acids
acid salts
Oil of vitriol
Dark brown,
odorless
Organics,
chlorates
carbides
Phenyl methane
methyl benzene
200
Colourless
liquid
Strong
oxidizers
Cyanide
Sulfuric acid
Toluene
FIRST AID
CHEMICAL
NAME
Method of prevention
Inhalation
mouth, nose
Absorption
skin
Protective clothing
Ingestion
Type
DO
DONT
Corrosive
Will destroy or irreversibly damage another substance with
which it comes in contact. The main hazards include damage to
eyes, skin and tissue under the skin, but inhalation or ingestion
are also very risky. Avoid contact, and bear in mind that these
can (under some ciurcumstances) rust chemical cupboards.
Oxidising chemical
Oxidising chemicals are materials that spontaneously evolve
oxygen at room temperature or with slight heating, or that
promote combustion. To be kept away from flammable
chemicals at all costs!
Environmental hazard
Relatively rare with laboratory chemicals (most of which pose
some environmental hazard if not got rid of correctly), these
require particular care to be taken on disposal.
Explosive
Again, fairly self-explanatory, though fairly seldom seen in the
average lab. Bear in mind that noise and movement can also
trigger explosion (not just sparks/flames!).
THE END