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Materials
Safety: Layer of Protection
Design with
Basic flowsheet
LC
1
Operability
FC
1
HAZARD IDENTIFICATION
1. Check lists
2. Dow Relative Ranking
3. HAZOP - Hazard and Operability
HAZARD ASSESSMENT
- Fault Tree
More
- Event Tree
accurat
- Consequence analysis
- Human Error Analysis e
Semi-quantitative
analysis to give orderof-magnitude estimate
We will use our group
skills and knowledge of
safety layers in applicat
Activity
Chemical Industry
Steel Industry
Coal Mining
Construction
Uranium
Asbestos (old data?)
FAR
4
8
40
67
70
620
Staying home
Traveling by automobile
Traveling by airplane
Cigarette smoking
3
57
240
???
Question:
Chemical Industry
Cigarette smoking
4
???
fatalities/time period
.001 = (.0000001)(100,000)
fatalities/time period
Probability or Frequency, F
(events/year)
1.00E-07
Unacceptable risk
1.00E-08
Acceptable risk
1.00E-09
10
100
Choosing Appropriate Quantitative Safety Risk Criteria Applications from the New CCPS Guidelines by Walt Frank (Frank Risk
Solutions, Inc.) and Dave Jones (Chevron Energy Technology Company)
Lees, F. (1996) Loss Prevention in the Process Industries 2nd Ed., Vol. 1, page 9/83.
Failure,
PFD2
Failure,
PFD1
I nitiating
event, f I
Unsafe!
I
P
L
n
I
P
L
3
I
P
L
2
I
P
L
1
Safe/
tolerable
Failure,
PFD2
Failure,
PFD1
I nitiating
event, f I
Unsafe!
I
P
L
n
I
P
L
3
I
P
L
2
I
P
L
1
Safe/
tolerable
The probability that the unsafe consequence will occur is the product
of the individual probabilities.
n
C
I
f i f i (PFD)ij
j 1
where
i=
j=
f Ii =
f Ci =
PFDij =
scenario or event
IPL layer
frequency of initiating event I for scenario i
frequency of consequence for scenario i
frequency of failure on demand of layer j in scenario i
HAZOP
Company, industry
experience
Company, industry
experience
Data
The maximum frequency or
probability of an accident,
fi max = F
Source
The F-N plot or similar analysis.
(A sample F-N plot is given in
Figure 5.16.)
HAZOP study
10-1
10-1 to 1.0 (depends on stress and time)
10-1 to 10-4
(depends strongly on details of design and maintenance)
10-2
10-2 for dike that will reduce consequences of spill
10-2 for drainage system that will reduce consequences of
spill
-2
10 for fireproofing
10-2 for blast wall
* These layers reduce only the major consequences of an accident. When doing a LOPA, the PFD would
be 1.0 for many consequences; for example, a dike would not prevent a fire. The tabular values would be
applied for only the worst consequences, e.g., for a dike, a spill flowing into the entire facility or the local
community.
PFD
1.0
10-1
10-2
*Based on Kletz(1999)
Event Severity
extensive
serious
minor
Medium
2
Minimal
1
Minimal
1
Major
3
Medium
2
Minimal
1
low
Major
3
Major
3
Medium
2
moderate
high
Event Likelihood
Table entries
word = qualitative risk description
number = required safety integrity
level (SIL)
Selection
documented for
legal
requirements
Additional
mitigation
(safety valves,
dykes, restricted
access, etc.)
Mitigated
event
likelihood
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Cause
likelihood
Likelihood
Mitigated likelihood =
Process
design
BPCS
Alarm
SIS
Probability of failure on
demand
f i f i ( PFD)ij f i max
j 1
Notes
Split range
Feed
Methane
Ethane (LK)
Propane
Butane
Pentane
T1
PC-1
T5
T2
LAL
LAH
FC-1
F2
TC-6
Vapor
product
T3
LC-1
F3
AC-1
Process
fluid
Steam
L. Key
Liquid
product
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Cause
likelihood
High
pressure
Connection
(tap) for
pressure
sensor P1
becomes
plugged
Process
design
BPCS
Alarm
SIS
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
Mitigated
event
likelihood
Notes
Pressure sensor
does not
measure the
drum pressure
Process examples
Class Exercise 1: Solution: Original design.
cascade
PAH
Split range
Feed
Methane
Ethane (LK)
Propane
Butane
Pentane
T1
PC-1
T5
T2
LAL
LAH
FC-1
F2
TC-6
Vapor
product
T3
LC-1
F3
AC-1
Process
fluid
Steam
L. Key
Liquid
product
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Cause
likelihood
Process
design
BPCS
Alarm
SIS
High
pressure
Connection
(tap) for
pressure
sensor P1
becomes
plugged
0.10
0.10
1.
1.0
1.0
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
1.0
Mitigated
event
likelihood
Notes
.01
Pressure sensor
does not
measure the
drum pressure
Split range
TC-6
PC-1
P-2
Feed
Methane
Ethane (LK)
Propane
Butane
Pentane
T1
PAHH
T5
T2
LAL
LAH
FC-1
F2
Vapor
product
T3
LC-1
F3
AC-1
Process
fluid
Steam
L. Key
Liquid
product
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Cause
likelihood
Process
design
BPCS
Alarm
SIS
High
pressure
Connection
(tap) for
pressure
sensor P1
becomes
plugged
0.10
0.10
1.0
0.10
1.0
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
PRV 0.01
Mitigated
event
likelihood
Notes
.00001
Pressure sensor
does not
measure the
drum pressure
Independent
Dependent
AT
1
FT
1
PI
4
TI
1
PI
5
TI
5
TI
2
feed
TI
6
PT
1
TI
3
TI
7
TI
4
TI
8
FT
2
PI
2
air
PI
3
TI
9
TI
10
FI
3
TI
11
PI
6
Fuel gas
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Combustibles
in stack, fire
or explosion
Limited air
supply
because air
fan/motor
fails
Cause
likelihood
Process
design
BPCS
Alarm
SIS
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
Mitigated
event
likelihood
Notes
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Cause
likelihood
Process
design
BPCS
Alarm
SIS
No/low air
flow to
heater
burners
Failure of
the air
fan/blower
0.10
0.10
1.0
1.0
1.0
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
------
Mitigated
event
likelihood
Notes
0.01
Alarm
PIC
1
AT
1
FT
1
PI
4
TI
1
PI
5
TI
5
TI
2
feed
TI
6
PT
1
TI
3
Flow
control
TI
7
TI
4
TI
9
TI
8
FT
2
PI
2
TI
10
FI
3
PI
3
TI
11
PI
6
air
Fuel gas
Alarms
SIS
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Cause
likelihood
Process
design
BPCS
Alarm
SIS
No/low air
flow to
heater
burners
Limited air
supply
because air
fan/motor
fails
1.0
0.10
1.0
0.10
0.01
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
Mitigated
event
likelihood
0.0001
Notes
AT
1
FT
1
PI
4
TI
1
PI
5
TI
5
TI
2
feed
TI
6
PT
1
TI
3
TI
7
TI
4
TI
8
FT
2
PI
2
air
PI
3
TI
9
TI
10
FI
3
TI
11
PI
6
Fuel gas
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
No process
flow,
equipment
damage,
tube rupture
and fire,
loss of
production
Feed
pump/motor
fauls
Cause
likelihood
Process
design
BPCS
Alarm
SIS
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
Mitigated
event
likelihood
Notes
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Cause
likelihood
Process
design
BPCS
Alarm
SIS
Low feed
flow rate to
tubes in
fired heater
Failure of
feed pump
0.010
0.10
1.0
1.0
1.0
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
------
Mitigated
event
likelihood
Notes
0.001
To SIS
AT
1
FS
FT
1
FAH
PI
4
TI
1
PI
5
TI
5
TI
2
feed
TI
6
PT
1
TI
3
TI
7
TI
4
TI
9
TI
8
FT
2
PI
2
TI
10
FI
3
PI
3
TI
11
PI
6
air
Fuel gas
SIS
10
Protection Layers
#
Initial
Event
Description
Initiating
cause
Cause
likelihood
Process
design
BPCS
Alarm
SIS
Low feed
flow rate to
tubes in
fired heater
Failure of
feed pump
0.010
0.10
1.0
0.10
0.01
Additional
mitigation
(safety valves,
dykes,
restricted
access, etc.)
------
Mitigated
event
likelihood
Notes
0.000001
Set Goals
Boss
Assemble Resources
See Section 5.14
Hazard Identification
Dow Preliminary Methods
Check list/ What-if
HAZOP
LOPA Analyst