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WATERATTCK ON CONCRETE
C3A.3CaSO4.32H2O
3(C3A.CaSO4.12H2O)
Internal Attack
Delayed Ettringite Formation
(DEF):
1-Ettringite is not formed if concrete temperature exceeds 70C.
2- If curing is at elevated temperature, or if self heating in large pours
(or in hot weather) ettringite might not be formed.
3- Monosulphate is present and most of the sulphates are absorbed by
C-S-H.
4- When concrete cools down to ambient temperature, these phases are
not stable and ettringite crystals form with considerable expansion.
5- In many cases this delayed ettringite formation leads to cracking
through the paste and around the aggregate particles.
Internal Attack
Delayed Ettringite Formation
(DEF):
External Attack
1- Sulphates are present in ground water, and soil.
2- Common sulphate salts are: sodium, magnesium,
potassium, and calcium.
3- External sulphates react with C 3A and monosulphates
(Afm) to form ettringite (Aft)
4- Additional reaction takes place with CH to form
gypsum:
Ca(OH)2 + SO42- = CaSO4.2H2O +2OH-
External Attack
5-
6-
External Attack
Sulphate Solution
SO42-
Sulphate solution
SO42-
Un reacted zone
Ettringite Formation
C3A(CS)3 H32
C3A(CS) H12
Un reacted zone
C3A(CS) H12
External Attack
Sulphate Solution
SO42Gypsum Formation
C3A(CS)3 H32
And Ettringite
reduced Ca(OH)
Formation
2
C3A(CS)3 H32
Un reacted zone
Sulphate Solution
Gypsum Formation
SO42-
CSH2
C3A(CS) H12
C3A(CS)3 H32
And Decalcifi. of CSH
Gypsum Formation
CSH
C3A(CS)32 H32
And reduced Ca(OH)2
Ettringite Formation
C3A(CS)3 H32
Un reacted zone
SiO2 aq
CSH2
C3A(CS) H12
External Attack
Thaumasite Formation
1- Thaumasite has the composition:
Ca3Si(OH)6(SO4)(CO3).12H2O
2- It is formed through a combination of sulphate attack and
carbonation
3- Sulphates is usually from an external source but carbonate
may be derived from the aggregate or cement constituents.
4- It forms in wet conditions at temperatures below 15C.
5- The attack on C-S-H leads to complete destruction of the
cement paste.
External Attack
Thaumasite Formation