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Fuel Cells
R. Shanthini
Source: http://parts.mit.edu/igem07/images/2/2d/Fuelcell.JPG
Microbial
Fuel Cells
anode
cathode
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Source: http://parts.mit.edu/igem07/images/2/2d/Fuelcell.JPG
and separated
internally by an ion
exchange membrane.
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Hydrogen generated is
reduced into hydrogen
ions (proton) and
electrons.
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The protons
move to the
cathodic
compartment
via the ion
exchange
channel and
complete the
circuit.
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An electrical current
is formed from the
potential difference
of the anode and
cathode, and power
is generated.
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Substrate concentration,
type, and feed rate can
greatly affect the
efficiency of a cell.
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Real-life MFC
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Real-life MFC
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Real-life MFC
Real-life MFC
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(http://microbialfuelcell.org).
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Conventional
Fuel Cells
Hydrogen is the fuel for
Proton Exchange
Membrane (PEM) fuel cells.
At the anode,
a platinum catalyst
causes the hydrogen
to split into
positive hydrogen ions
(protons) and
negatively charged
electrons.
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Conventional
Fuel Cells
The Proton Exchange
Membrane (PEM) allows
only the positively charged
hydrogen ions (protons) to
pass through it to the
cathode.
The negatively charged
electrons must travel along
an external circuit to the
cathode, creating an
electrical current.
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Conventional
Fuel Cells
At the cathode,
the electrons and
positively charged
hydrogen ions
combine with oxygen
to form water,
which flows out of the cell.
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Conventional
Fuel Cells
Power is produced by an electrochemical process not
by combustion
Noiseless operation
50% hydrogen energy content to electrical energy
conversion efficiency
Multi-fuel (hydrocarbon and alcohols) capability
Durability, reliability, scalability and ease of
maintenance
Only water and heat is emitted from a fuel cell (water
is in fact a greenhouse gas)
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Conventional
Fuel Cells
The electrodes are composed of platinum particles
uniformly supported on carbon particles. The platinum
acts as a catalyst.
Polymer Electrolyte Membrane (Proton Exchange
Membrane) is a thin, solid, organic compound.
Hydrogen for the fuel cell is produced from fossil fuel
at present (so CO2 emissions are part of hydrogen
energy).
Power-plant-to-wheel efficiency of 22% if the hydrogen
is stored as high-pressure gas, and 17% if it is stored as
liquid hydrogen
Hydrogen transportation and refuelling
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Conventional
Fuel Cells
Technological status Proton Exchange Membrane (PEM)
Fuel Cells): commercial in niche
markets
Solid Oxide Fuel Cells (SOFC): market
entering phase in niche markets;
Possible adverse
effects
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