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activation energy
temperature
concentration
catalysts
Symbol: S
A measure of randomness or disorder
The natural progression is from order to disorder
It is natural for disorder to increase
Entropy is a thermodynamic function
Describes the number of arrangements that are
available to a system in a given state
+
+
(remember, - H = Ssurr )
T
T
T
G = Ssurr + Ssys (remember, Ssurr + Ssys = Suniv)
T
-G = Suniv
T
So(J/K.mol)
248
NiO
O2
38
205
NiS
53
So (J/K.mol)
51
H2
131
Al
H2O
28
189
Hof(kJ/mol)
So (J/K.mol)
SO2(g)
-297
248
SO3
-396
257
O2
205
Go = -394 kJ
Gof(kJ/mol)
CH3OH
-163
O2
CO2
-394
H2O
-229
G = Go + RT ln Q
Q is the reaction quotient (from the law of mass action)
T is the temperature in K
R is the gas constant, 8.3145 J/mol.K
Substance
Hof (kJ/mol)
So(J/K.mol)
Fe2O3
-826
90
Fe
O2
0
0
27
205