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core/shell nanoparticles
Presented by
Minaketan Ray
(608CH601)
Under the guidance of
Dr. Santanu Paria
Outline
Introduction
Literature review
Methods
Objectives of the study
Result and discussion
Synthesis of AgBr nanoparticles
Synthesis Silica nanoparticles
Core/shell nanoparticles
Introduction
Many researcher has been prepared core/shell by micro emulsion, solgel, CVD and other methods.
Among them micro emulsion is used by many due to small size particle
formation. But the separation of particles is difficult.
Literature review
There
Continue..
Methods
Product
Finding
W/O/W
emulsion
Gold/silver
Nanospheres
Degradation of Basic
dye
Bardr et al.
2007
Sol-gel
Au/Au
Au is catalyst
Basic
R,emulsion
Gold/silica
biocompatible
Basic
Shimizu et al
2003
Kumar et al.
2006
R. emulsion
R. emulsion
Fe/Silica
Photo catalyst
Basic
TiO2/SiO2
Photo catalyst
Basic
Xu et al. 2006
Park et al 2005
Micelle
Ag/SiO2
Hollow Silica
basic
kim et al 2009
Complex
solution
Ni/SiO2
Flower, star
like structure
Basic
Libor et al.
2009
Liz-Marzan
Au/SiO2
Thermally
stable
Basic
Zhang et al.
2009
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Medium of reference
solution
Methodology
To
AgBr nanoparticles.
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Problems
Control
of particle size
Coating
Shape
Separation
and
Isolation
of
core/shell
materials
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nanomaterials
To study
To
Shell nanoparticles
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Surface
Coating
Core-shell
shell
+
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core
10
The
The
The
The
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Absorbance (a.u.)
0.6
0.4
0.2
0.0
0.1 mmol/L
0.05 mmol/L
0.01 mmol/L
0
50
100
Time (min)
150
The
13
14
Concentration
constant
effect
on
coarsening
350
400
200
0
0.00
Aqueous Sol.
TX-100
3 3 -3
Radius(nm ) r x10
Coarsening Constant(kc)
600
300
0.1 mmol/L
0.05 mmol/L
0.01 mmol/L
250
200
150
100
50
0
0
20
40
60
Time (min)
80
100
The plot of cube of the radius of AgBr particles vs. time prepared in aqueous media. (R)
The plot of coarsening constant with the increasing reactant concentration in the pure aqueous
and TX-100 media (L)
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15
r r kct
3
av
3
0
3
av and
Where r
r03 are the average and initial particle
radius respectively, kc is diffusion limited coarsening rate
constant, and t is time.
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16
17
0.9
Absorbance
Absorbance (a.u.)
1.0
0.8
0.7
0.6
1.0
0.1 mmol/L
0.8
0.05 mmol/L
120min
60min
0.6
0.01
mmol/L
30min
5min
0.4
0.2
0.1 mmol/L
0.0 250 300 350 400 450 500
W
avelength(nm)
0.5
0.4
50
100
Time (min)
150
200
140
120
Aqueous
TX-100
100
80
60
40
0.00
0.03
0.06
0.09
Concentration of reactant (mmol/L)
18
Effect of temperature
19
In ten sity (a .u .)
1500
200
220
1000
TX-100 222
500
Aqueous
0
20
30
40
2 (Degrees)
50
60
20
SEM images of AgBr nanoparticles (A) using 0.01 mmol AgNO3, (B) 0.1 mmol
AgNO3 (C) 0.01 mmol AgNO3 in the presence of TX-100.
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Conclusion
Lower
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The
molar
concentration
of
precursor
mixture
TEOS:
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Mechanism
nanoparticles
of
Silica
Formation
(ii)
The
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600
Size (nm)
550
500
450
400
350
300
250
10
20
30
40
50
Concentration (mmol)
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(b)
26
Effect of Time
180
160
140
120
S1
TEOS
S2
100
Absorbance
80
60
40
20
0
300
27
Effect of Surfactant
P artic le
S ize (nm )
700
600
Aq
CTAB
SDBS
TX-100
500
400
300
200
0
Concentration (mmol)
28
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(b)
(d)
(c)
The SEM images of silica nanoparticles in CTAB (a), TX-100 (b), aqueous
solution (c) and SDBS solution (d) at 0.1 mmol concentration
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Conclusion
The
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Core/shell nanoparticles
The
32
Intensity
1.5
5 min
20 min
30 min
60 min
120 min
1.0
0.5
0.0
The
240
270
300
330
Wavelength (nm)
33
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Effect of Concentration
400
300
200
100
0
0.1
0.2
0.3
0.4
0.5
TEOS Concentration (mmol)
35
Study of
spectra
4
core/shell
15
Intensity
Intensity (a.u)
fluorescence
20
AgBr@SiO2
AgBr + SiO2
by
AgBr
10
5
0
250 300 350 400 450 500 550 600
wavelength (nm)
0
400
450
500
550
Wavelength (nm)
600
36
The
size of core/shell NP is 98
nm.
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The
38
Conclusion
The
39
AgBr nanoparticles.
The
hydroaxide.
The
40
Thank you
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References
Kumar
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