Documente Academic
Documente Profesional
Documente Cultură
and Equilibrium
Chapter 18
Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
18.2
spontaneous
nonspontaneous
18.2
H2O (s)
NH4NO3 (s)
18.2
disorder
S = Sf - Si
If the change from initial to final results in an increase in randomness
Sf > Si
S > 0
For any substance, the solid state is more ordered than the
liquid state and the liquid state is more ordered than gas state
Ssolid < Sliquid << Sgas
H2O (s)
H2O (l)
S > 0
18.3
Entropy
W=1
W = number of microstates
S = k ln W
S = Sf - Si
S = k ln
W=4
Wf
Wi
W=6
18.3
Processes that
lead to an
increase in
entropy (S > 0)
18.2
18.3
Entropy
State functions are properties that are determined by the state
of the system, regardless of how that condition was achieved.
energy, enthalpy, pressure, volume, temperature, entropy
Equilibrium process:
cC + dD
18.4
Exothermic Process
Ssurr > 0
Endothermic Process
Ssurr < 0
18.4
S = k ln W
W=1
S=0
18.3
Equilibrium process:
G = Hsys -TSsys
G < 0
G > 0
G = 0
The standard free-energy of reaction ( G0rxn) is the freeenergy change for a reaction when it occurs under standardstate conditions.
aA + bB
cC + dD
0
Grxn
= [ cG0f (C) + dG0f (D) ] - [ aG0f (A) + bG0f (B) ]
0
Grxn
= nG0f (products) - mG0f (reactants)
0
Grxn
= nG0f (products) - mG0f (reactants)
0
Grxn
= [ 12Gf0 (CO2) + 6Gf0 (H2O)] - [ 2Gf0 (C6H6)]
0
Grxn
= [ 12x394.4 + 6x237.2 ] [ 2x124.5 ] = -6405 kJ
G = H - TS
18.5
H0 = 177.8 kJ
S0 = 160.5 J/K
G0 = H0 TS0
At 25 0C, G0 = 130.0 kJ
G0 = 0 at 835 0C
18.5
G0 = 0 = H0 TS0
H2O (l)
S =
H2O (g)
H
40.79 kJ
=
T
373 K
= 109 J/K
18.5
Efficiency =
Th - Tc
X 100%
Tc
Q=K
0 = G0 + RT lnK
G0 = RT lnK
18.6
G0 < 0
G0 > 0
18.6
G0 = RT lnK
18.6
Alanine + Glycine
G0 = +29 kJ
ATP + H2O + Alanine + Glycine
G0 = -2 kJ
Alanylglycine
K<1
ADP + H3PO4 + Alanylglycine
K>1
18.7
18.7
High Entropy
Low Entropy