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Solubility Equilibria
Chapter 16
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CH3COOH (aq)
common
ion
16.2
HA (aq)
H+ (aq) + A- (aq)
Ka [HA]
[H ] =
[A-]
+
[HA]
[A-]
[A
]
-log [H ] = -log Ka + log
[HA]
+
[A
]
pH = pKa + log
[HA]
Ka =
[H+][A-]
[HA]
Henderson-Hasselbalch
equation
[conjugate base]
pH = pKa + log
[acid]
pKa = -log Ka
16.2
0.30
0.00
0.52
-x
+x
+x
0.30 - x
0.52 + x
[HCOO
]
pH = pKa + log
[HCOOH]
[0.52]
= 4.01
pH = 3.77 + log
[0.30]
CH3COOH (aq)
CH3COO- (aq) + H2O (l)
16.3
HCl
HCl + CH3COO-
H+ + ClCH3COOH + Cl-
16.3
16.3
pKa = 9.25
0.029
0.001
NH4+ (aq) + OH- (aq)
0.028
0.0
[0.30]
pH = 9.25 + log
= 9.17
[0.36]
0.024
H2O (l) + NH3 (aq)
0.025
[0.25]
pH = 9.25 + log
= 9.20
[0.28]
16.3
16.3
Titrations
In a titration a solution of accurately known concentration is
added gradually added to another solution of unknown
concentration until the chemical reaction between the two
solutions is complete.
Equivalence point the point at which the reaction is complete
Indicator substance that changes color at (or near) the
equivalence point
Slowly add base
to unknown acid
UNTIL
The indicator
changes color
(pink)
4.7
16.4
16.4
NH4Cl (aq)
NH4Cl (aq)
16.4
0.01
0.01
HNO2 (aq) + OH- (aq)
0.0
0.0
0.05
0.00
0.00
-x
+x
+x
Equilibrium (M)
0.05 - x
x2
[OH-][HNO2]
-11
=
2.2
x
10
Kb =
=
[NO2-]
0.05-x
pOH = 5.98
pH = 14 pOH = 8.02
Acid-Base Indicators
HIn (aq)
H+ (aq) + In- (aq)
[HIn]
10 Color of acid (HIn) predominates
[In ]
[HIn]
10
Color
of
conjugate
base
(In
) predominates
[In ]
16.5
pH
16.5
16.5
16.5
Solubility Equilibria
AgCl (s)
Ksp = [Ag+][Cl-]
MgF2 (s)
Ag2CO3 (s)
Ca3(PO4)2 (s)
Ksp = [Mg2+][F-]2
Ksp = [Ag+]2[CO32-]
Ksp = [Ca2+]3[PO43-]2
Unsaturated solution
Q = Ksp
Saturated solution
Q > Ksp
Supersaturated solution
No precipitate
Precipitate will form
16.6
16.6
16.6
Initial (M)
AgCl (s)
Change (M)
Equilibrium (M)
[Ag+] = 1.3 x 10-5 M
+s
s = 1.3 x 10-5
16.6
16.6
16.6
-13
K
7.7
x
10
sp
-11
=
=
3.9
x
10
M
[Ag+] =
0.020
[Br ]
AgCl (s)
-10
K
1.6
x
10
sp
-9
=
=
8.0
x
10
M
[Ag+] =
0.020
[Cl ]
[Br-] = 0.0010 M
AgBr (s)
Ag+ (aq) + Br- (aq)
[Ag+] = s
[Br-] = 0.0010 + s 0.0010
Ksp = 0.0010 x s
s = 7.7 x 10-10
16.8
pH and Solubility
Mg(OH)2 (s)
CoCl24
Kf =
[CoCl24 ]
[Co2+][Cl-]4
Kf
stability of
complex
16.10
16.10
16.11
Qualitative
Analysis of
Cations
16.11
lithium
sodium
potassium
copper
16.11
CaCO3 (s)
carbonic
H2CO3 (aq)
anhydrase
H2CO3 (aq)
HCO3- (aq)