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BONDING
OBJECTIVES
explain
list
explain
VALENCE
ELECTRONS:
The electrons in the outer most
shell take part in the bond
formation
and
determine
the
combining capacity or the valency
of the atom. Therefore, the outer
most shell of any atom is called its
valence shell and the electrons
present in the valence shell are
called the valence electrons.
There
Let
Cl + e Cl ; H = 379.5 kJ mol1
2,8,7
2,8,8
According to Kossels theory, there is a
transfer of one electron from sodium
atom to chlorine atom and both the atoms
attain noble gas configuration.
The positively charged sodium ion and
the negatively charged chloride ion are
held together by electrostatic attractions.
The
This
(b)
(d)
The
Thus
Born-Haber
Cycle
On
These
Secondly,
COVALENT BOND
Lewis
For
H:H
HH
This
Lewis Structure
Lewis
This
In
In
Characteristic properties of
Covalent Compounds
The
However,
Dipole moment
Dipole
Moment () = Magnitude of
charge (Q) Distance of Separation (r)
It is commonly measured in the unit
debye, symbol D.
The SI unit of dipole moment is
Coulomb-metre (Cm). The two units are
related as 1D = 3.336 1030 cm
Dipole
The
Ammonia,
NH3
NH3 has a pyramidal structure which
makes the arrangement of three NH
bonds unsymmetrical.
In each NH bond, nitrogen is the
negative centre and hydrogen is the
positive centre.
Fajans rules
Fajan
cations
order:
Bond order is the number of bonds
present between two atoms in a molecule
or ion. Generally, bond order has an
integral value.
For example, Bond order = 1.
Bond
Bond
Length:
Bond length is the distance between the
nuclei of the two bonded atoms. It is
expressed in picometer (pm).
Bond length depends upon the sizes of
the bonded atoms and the bond order of
the bond linking them.
The greater the bond order, the smaller is
the bond length.
Bond
Angle:
It is the angle between the two bonds in a
molecule. Since covalent bonds are
formed through overlapping of orbitals.
It may also be defined as the angle
between the two orbitals that contain
bonding electrons and overlap with
atomic orbitals of other atoms. Bond
Bond
Enthalpy aH
It is the amount of energy required for
breaking one mole of bonds of a
particular type in gaseous molecules.
It is also called bond dissociation
enthalpy, and is applicable to simple
molecules, containing only one bond of
the particular type.
For
In
HYDROGEN BONDING
It
In
There
Salicyldehyde
POSTULATE 1
The electron pairs (both bonding and
non-bonding) around the central atom in
a molecule arrange themselves in space
in such a way that they minimize their
mutual repulsion.
In other words, the chemical bonds in the
molecule will be energetically most
stable when they are as far apart from
each other as possible.
For
According
POSTULATE 2
Chemical Bonding The repulsion of a
lone pair of electrons for another lone
pair is greater than that between a bond
pair and a lone pair which in turn is
greater than between two bond pairs. The
order of repulsive force between different
possibilities is as under.
lone pair - lone pair > lone pair - bond
pair > bond pair - bond pair
Let
MODERN THEORIES OF
CHEMICAL BONDING
After
Valence
Bond Theory
Valence bond theory was proposed by
Heitler and London in 1927, to describe
the formation of hydrogen molecule from
its atoms.
Linus
Pauling and others further
developed it. In this approach the process
of chemical bond formation can be
visualised as the overlapping of atomic
orbitals of the two atoms as they
approach each other.
Hybridisation
Hybridisation
Let
In
Now
The
This
In
Resonance
Some
Similarly,
According
The
The
The
Here
Bond
Order:
we may define a new parameter called
bond order as
Bond order = (b.o.) = (nb - na)
Where, nb and na refer to the number of
electrons present in bonding and
antibonding
molecular
orbitals,
respectively.
For
An
Magnetic
nature:
Molecules magnetic behaviour depending
on their MO electronic configuration. If
all the MOs are doubly occupied the
substance shows diamagnetic behaviour.
In case one or more MOs are singly
occupied,
the
substance
shows
paramagnetic behaviour.
The
MO electronic configuration of O2
(with 12 valence electrons) is
Since
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