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Multilayer Films,
Polycrystalline,
Nanocomposites,
Patterned structures,
Bulk structures,
Liquid crystals,
Biological samples,
Fractals,
Gels,
and etc.
108 photon/s/mm2
Widely used flux, conventional x-rays
Different formed aggregats can be investigated Lamellar
Diluted -I Densed -I
|q|=2 k sin
q= 4 sin /
A(q) Fourier T. (r)
= Ae (r) exp(-iq.r) dr = [A(q)/Ae] exp(iq.r) dq
Scattered wave amplitude Radial electron density
q
P Particle Form Factor P(q)= F(q) 2
F(q)= 3V (1-2) [ sin(qR) qR cos(qR) ] / (qR)3
q
WAXS
sample: lactose powder
sample-detector distance: 29.5 cm
active length of detector ~ 5 cm
1024 pixels 50 m/pixel
2~18 2~26
4.8 3.2
d = 58.38 2~8
11
Diluted systems-I
Protein or polymer solutions, etc.
I Guinier
ln I Guinier line
region
I(q) =I(0) exp(-R2q2/3) tan = -R2/3
1/R . q(nm-1)
q2
Spherical nano crystals embeded SiO2
____________
Elipsoid R= (a2+b2+c2)/5 Guinier law
a,b,c elipsoid axes
(q0)
____
Sphere R= (3/5) r = 0.77 r
r, radius
I(q)q4
Porod law (q)
Porod region
lim I(q) q4 = constant
lim I(q)= 2 (1-2)2 S / q4
S, surface area
q (-1)
Kratky plots Q = V <2>
Fluctuation in the electron
densities
Invariant V Total volume causing the
I.q2 (nm) -2
scattering
The positions of
Bragg peaks for
h = 1, 2, 3 give
the lamellar
distance (1/d)
q
80 80 80
60 60 60
40 40 40
I(q)
I(q)
I(q)
20 20 20
0 0 0
0.0 0.1 0.2 0.3 0.4 0.5 0.0 0.1 0.2 0.3 0.4 0.5 0.0 0.1 0.2 0.3 0.4 0.5
q q q
?
I.
III.
II.
lam
hex
According to the observed q ratios PS-b-PEO Co-polymer phase transition
Blue Heating
Light blue
Spin-cap (rotating capillary)
300 s / Frame
45
WAXS
20
www.hecus.at 23
ln I(q) ln I(q)
Slope
Porod
Hydrophillic(repulsion)
Volume hight and base area
DEAn-b-DMAm diblock copoylmers are Hydrophobic (attraction) of the cone were determined
stable (n/m=1/2) in misellar forms at 23C beside of packing parameter
shell
ve pH=7,7. size distributions are narrow
and forms are spherical.
For T=22,0-25,5C, pH=7,6-8,0 and
n/m=0,25-0,73 values, misel numbers per
unit volume, misel sizes, shell thickness,
core radius and densities have been
determined by SAXS analysis.
core
13 nm
Y9,Y10
Y11, , Y20
Y9,Y10
liquid paraffin, non-ionic
surfactants (Brij 72 and Brij 721P)
and/or pure water
H3
Formulation Liquid Parafin Brij 721 P/ Brij 72 H2O (%)
(%w/w) (3/1) (%w/w)
A3 70 30 -
H3 - 30 70
L2 6 31 63
F1 40 10 50
AFM View
TEM View
[D.I. Svergun, Biophysics J.
1999, 76, 2879-2886]
Ferroelectric thin films, P.C. Photovoltaics, H. Kurz, Inst. of Multilayered Al-Si Porous
Mclntyre Res. Group, Semiconductor Elect. thin films, C. Orilall ,
Stanford Germany Cornel Univ.
65 55
400 24 24
55 45
27 30
400
n Ga As 45 40
400 i Al Ga As 33 35
n+ Ga As
GaAs , a= 5.65 , = 5.32 g/cm3
AlGaAs, a= 5.66 , = 3,76 g/cm3
k is decay constant (interfacial area) for a
two phase system.
It depends on the total inner surface (S) and
the mean-square electron density fluctuations
dc
dac da
Q
invariant
Volume fractions
It has the
dimention of a
resprocal volume
Total irradiated
volume
d()Sample I (7) d() Sample II (8)
330.00 202.70
184.73 116.40
136.59 80.24
104.70 61.00
82.67 49.87
70.59 42.16
60.41 37.40
52.79 30.35
Mean sizes of the planar aggregations in the content of the sample I and
II are 198.09 and 121.67 , respectively.
R( ) R( )
Sample I Sample II
5.32 6.44
30.77 35.42
56.41 62.79
79.48 83.72
100.02 122.36
125.64 161.10
184.63 194.81
217.94 223.79
258.97 262.43
317.95 281.75
371.80
425.64
453.85
Summary
2. BP
LS
Dzgn 1. BP
ynelmi
tabakalar SB zotropik
+ PB lipozom
W- tarama
www.hecus.at 42
SAXS ile alglanan nano-oluumlar (1-100 nm)
WAXS ile alglanan nano-oluum i yaplar ( 1-10 )
Lc : correlation
Lc SAXS ile elde edilen bilgiler:
distances
*Kesikli izgilerle gsterilen elektron younluk
farklarnn yksek olduu nano oluumlarn
ekli/ekilleri
* Nano-oluumlarn ortalama byklkleri
*Nano-oluumlar aras ortalama uzaklk ve uzaklk
dalmlar
*Birim hacimdeki nano-oluum saylar v.b. bilgiler.
I h 4 p r sin ( h r )
hr
dr
0
I(h)
p(r)