CIBACRON H

The future of the industry

 Positioning of CIBACRON exhaust ranges
Warm dyeing
Cibacron FN
- For severe/special fastness requirements
- Very good shade reproducibility even in
difficult trichromy shades (beige, grey,etc..)
- Level dyeing performance
- Best washing off of all warm ranges
- Highly soluble, ideal for Ultra Short LR jets
- Favorable ecological properties
Warm dyeing
Cibacron S & Super Black G & R
- Very deep shades achievable
- Unique cost effectiveness in deep shades
- High degree of fixation
- Satisfies standard fastness requirements
- Outstanding washing-off properties in
deep shades
- Good shade reproducibility
TD 4.5
Low salt, hot dyeing
Cibacron LS
- Outstanding shade reproducibility
- Outstanding for ecological requirements
- Low sensitivity to liquor ratio variations
- Level dyeing performance
- Attractive process for PES/CEL dyeing:
LS-SuperFast
- Easier, cheaper automation (liquid salt adds)
Hot dyeing
Cibacron H
- Good washing-off (best of all hot ranges)
- Good shade reproducibility
- Best results on poor cotton qualities
- Excellent cost effectiveness
- Special, safe process for bright blue &
green (Smile green)
- Special, productive, Gray State Dyeing
02/98 all07.ppt
 POSITIONING OF CIBACRON H DYES
EXHAUST DYEING
Cibacron H (Hot dyeing 80 )
- for large volume shades,when economy is key
- for densely woven or poor quality cotton
- when customer prefers hot dyeing
- when washing off conditions are poor
- when chlorine fast shades are requested
- for difficult bright blue & green shades: smile green process
- for gray state dyeing GSD process

Polyreactive, high degree of fixation,

Very good wash-off
 CIBACRON H
New response to the needs of the HOT dyeing segment

Best washing off performance of all HOT dyes

Compatible trichromies:Ideal for high productivity and Right First Time dyeing

Meets requirements for productive Gray State Dyeing

Allows achieving of fastness superior to usual standard ( chlorine-, light- )

Special dye selection and process for reproducible and level dyeing of difficult
bright south sea shades : Smile Green

With CIBACRON Red HD- 200% Ciba offers a very economical

trichromy component with unique build-up in deep shades

Limited number of dyeing procedures allow an easy handling in production

 CIBACRON H range

Brill.Yellow H-4GN For brilliant combinations

Smile green concept Red H-BL For light fast combinations

Yellow H-G For chlorine and light fast combinations

Red H-F For chlorine fast combinations

Yellow H-RN 200% Trichromatic element

Blue H-RN-01 Trichromatic element

Orange H-R For chlorine fast and brilliant combinations For brilliant combinations
Brill. Blue H-GR
Smile green concept

Orange H-BR For light fast combinations

Navy H-2G For chlorine fast combinations
Red H-D 200% Economical trichromatic element
Turquoise H-GN For brilliant combinations
Smile green concept
Red H-B 150% Trichromatic element

CTS Exhaust CEL & CEL/PES 01/01

 CIBACRON
CIBACRON HHrange
Trichromatic systems

Standard Chlorine fast Light fast Special shades

Smile Green
Yellow H-RN 200% Yellow H-G Yellow H-G

Red H-D 200% Orange H-R Orange H-BR Brill.Yellow H-4GN

Red H-B 150% Red H-F Red H-BL Brill.Blue H-GR

Red H-F Navy H-2G Blue H-RN-01 Turquoise H-GN

Blue H- RN-01

Navy H-2G

YELLOW NP for shades without photochromism

 CIBACRON H
Improved washing - off properties
Conventional HOT dyes are known to be problematical s far as washing - off is concerned.
They never perform as well as ordinary warm dyes.
The difference is even bigger if you compare them with modern bi-reactive warm dyes.
Cibacron H constitute large improvement, nearly matching Cibacron FN performance.
Ciba now offers an entire range ( except Smile green concept ) with remarkably improved
washing - off properties,thus allowing increased productivity due to fewer washing - off baths.

Reasons :

High degree of Fixation An ideal washing-off Profile = Fewer baths

% of total dye in the washing-off
liquor
Hydrolized dye to be washed-off % of total
16
Yellow H-R 200% 12
Red H-D 300% 11 12
Red H-B 150% 8
8
Blue H-RN 12
Navy H-2G 3 4

0
bath 1 bath 2 bath 3 bath 4 bath 5 bath 6

= CIBACRON H = MCT dye

Dye in the wash bath WASHING-OFF HOT RED DYES (CO Tricot bleached, 10:1, 1.85 RD)
(spectral measure)

Conventional Conventional CIBACRON

Hot Red 1 Hot Red 2 Red H-F
1st. Bath 50C 2nd. Bath 70C 3rd. Bath 95C 4th. Bath 95C 5th. Bath 70C 6th. Bath 30C

CIBACRON H makes the wash-off easier and faster than with conventional hot dyes
 WASHING FASTNESS
C1S 60C, ISO 105 / C06

CA CO PA 6.6 PES PAN WO

Standard

Procion Red H-E7B

CIBACRON RED H-F

Procion Crimson H-EXL

Main hot competitors

 Other example of top washfastness
here achieved in a one-bath process, (GSD process see later)
Bulk trial results

Wash fastness: a 60C/140F ISO 105 C06-C2S

b 95C/203F ISO 105 C06-E2S

a
Red H-B 150% 1.430%
Red H-D 200% 2.850%
b Blue H-RN-01 0.020%

a Red H-D 200% 1.500%

Navy H-2G 3.500
b
 CIBACRON H
Orange H-BR

Cibacron Orange H-BR for highest light fastness

Even for pale shades or for special light fastness tests like
perspiration light fastness (sportswear)
We recommend a combination of

Orange H-BR

Yellow H-G Blue H-RN-01

 CIBACRON H
Ciba test
CIBACRON H process: Migration, soda ash Liquor ratio 10:1
0.07% CIBACRON Yellow H-G Fix. temp. 80C
0.05% CIBACRON Orange H-BR Fix. time 50 min
0.08% CIBACRON Blue H-RN-01 Exh. time 90 min

A 20% salt I 20% alkali

B + 20% salt J + 20% alkali
C 15 exh. time K 15 fix. time
Not credible D + 15 exh. time L + 15 fix. time
G 5C temp. M LR 8:1
H + 5C temp. N LR 12:1
 CIBACRON H

RED H-BL

A new Red for pale to medium shades with good lightfastness

A new standard for lightfastness in the hot dyeing field

A wide shade range can be covered with CIBACRON RED H-BL

Increase the overall performence of your trichromy dyeings

 Lightfast tricromy based on Red H BL: Good compatibility, good reproducibility

Ciba-Test 04.11.2003
Liquor ratio 1:10
CIBACRON H 0.070% Cibacron Yellow H-G Fix. temp. 80C
Process: Soda ash 0.070% Cibacron Red H-BL Fix. time 45 min
0.150% Cibacron Blue H-RN-01 Exh. time 45 min
30 g/ l Salt
10 g/ l Soda ash

Samples Standard -10% +10% 1.5

yellower
0.16
1.0

0.15

0.5
0.14 F
G
A D M
Strength (RD)

ILC

dH*
N J
0.0 K B
0.13

-0.5
0.12

0.11 -1.0

bluer
0.1
-1.5
A B C D F G I J K L M N
-1.5 -1.0 -0.5 0.0 0.5 1.0 1.5
dC* brighter
duller

A -20% Salt I -20% Alkali

B +20% Salt J +20% Alkali
C -15' Exh. time K -15' Fix. time
D +15' Exh. time L +15' Fix. time
M LR 1:8
F - 5C Temp. N LR 1:12
G + 5C Temp.
 CIBACRON H

Chlorine fast combinations

Yellow H-G

Orange H-R

Red H-F

Navy H-2G
Chlorinated water fastness ISO 105-E03, 20mg/Cl

Original Ch

Orange H-R 2.00%

Red H-F 2.00%

4-5

Orange H-R 3.00%

Red H-F 1.95%
Navy H-2G 1.05%
4-5

Yellow H-G 3.85%

Red H-F 0.34%
Navy H-2G 1.64%
4-5
 CIBACRON H

Yellow NP

CIBACRON Yellow NP a new, non-photochromic, bi-reactive

golden yellow dye.

with excellent chlorine, light, perspiration-light

and peroxide fastness

with a very high degree of fixation and outstanding

alkali stability good reproducibility of shades

with very good washing-off properties

reduced water/energy consumption
 CIBACRON H
Yellow NP
A new Yellow avoiding photochromic problems,: Useful in sensitive shades like khaki,
earth tones, yellowish brown,

Influence of reactive gold yellow types on photochromy

1.6

Olive/brown shade based on

1.4 Yellow photochromic

CIBACRON Yellow NP
1.2
Change of shade (dE)

1.0

0.8

0.6

0.4

0.2

0.0
0 22h 4 4h 6 8 10 12 14 16 18
Exposed 4 h to 0 2h 4h 6h 8h 10 h 12 h 14 h
the light then covered 14 h
 Standard M ethod
CIBACRON H
C
100

80

60

40

20

0
0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 min.

Dyestuff 1st add alkali 2nd add alkali

Salt
Auxiliaries

Salt and alkali recommendation / Soda ash alone :

Dye % up to 0.5 0.5- 1.0 1- 2 2- 3 3- 4 4- 6 above 6

Salt g/l 30 30-45 45-60 60-70 70-80 80-90 90
1.Soda ash g/l 3 5 5 5-7 7 7 7
2.Soda ash g/l 7 10 10 10-13 13 13 13

Salt and alkali recommendation / Mixed alkali :

Dye % up to 0.5 0.5- 1.0 1- 2 2- 3 3- 4 4- 6 above 6

Salt g/l 30 30-45 45-60 60-70 70-80 80-90 90
Soda ash g/l 10 5 5 5 5 5 5
NaOH 30% ml/l - 1.1 1.1 1.1-1.65 1.65-2.2 2.2-2.5 2.5
 Migration Method
CIBACRON H
Recommended method for mercerized cotton and viscose
C
100
90
80
70
60
50
40
30
20
10
0
0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180
min.
Dyestuff 1st add alkali 2nd add alkali
Salt
Auxiliaries

Salt and alkali recommendation / Soda ash alone :

Dye % up to 0.5 0.5- 1.0 1- 2 2- 3 3- 4 4- 6 above 6

Salt g/l 30 30-45 45-60 60-70 70-80 80-90 90
1.Soda ash g/l 3 5 5 5-7 7 7 7
2.Soda ash g/l 7 10 10 10-13 13 13 13

Reduced amount of salt for cotton merc. and viscose :

Salt g/l 5-20 20-30 30-40 40-45 45-55 55-65 65
 CIBACRON H

Wash-off procedure
Rinse 10 min 50C

Neutralize 10 min 70C with acetic acid, pH 5-6

Soap 10 min 95C with 2g/l CIBAPON R liq., pH 6-6.5

second soaping recommended for very dark shades

Rinse 10 min 70C

Rinse cold
 CIBACRON H, SMILE GREEN

The perfect solution to solve problems

with brilliant green and south sea blue shades

Better dyeing reproducibility, compared to existing process

Better substrate The
appearance
future and lessindustry
of the dichroism
Suitable for all kind of substrates
Specific migration dyeing process
A (strongly ) recommended auxiliary system
Short liquor ratio possible
Recommended procedures with and without dosing facilities
 CIBACRON H, SMILE GREEN

Turquoise H-GN

Brilliant Yellow H-4GN Brilliant Blue H-GN

The solution whenever unlevellness and reproducibility is an issue for brilliant green and royal blue shades
 CIBACRON H, SMILE GREEN
Dyeing procedure
C 100 212
F

90 90 194
194

80 80 176
176

70 70 158
158

60 60
The future of the industry 140
140

50 50 122
122

40 104

-5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 185 190 195 200

0 10 20 40 45 95 100 115 155 195 m in

A/ C B D

A/C = Auxiliaries , dyes

B = Salt( linear dispensing )
D = Soda ash ( progressive dispensing , 70% progression )

Salt addition: all salt can be added at the start if dyestuffs can be dosed linearly at 80 or 90C
Soda ash addition : if no dosing facilities are available, soda ash should be added in
portions : 1/10, 2/10, 7/10
 CIBACRON H, SMILE GREEN

Auxiliary system

CIBACEL DS (protective colloid)

Dyebath conditioner, prevents precipitation of Ca, Mg in the water and on the textile.
Improves the apperance of the dyed goods. Binds metal ions in the dyebath.
The future of the industry
CIBAFLUID CD (lubricant)
Lubricant to prevent creasing and wrinkling. Essential for good running properties on jets.
Improves levelness and apparence of the goods.

CIBAFLOW Jet / FFW (penetration accelerant)

Penetration accelerant with durable foam-inhibiting and de-aerating properties.
Promotes fiber and surface levelness in dyeing.

LYOPRINT RG (reduction inhibitor)

Prevents reduction of reactive dyes.
Washing-off procedure. Cibacron H . Smile Green process

Rinse 10 min 50C

Rinse 10 min 70C

Neutraliz 10 min 70C with acetic acid, pH 5-6

Soap 15 min 95C with 2g/l CIBAPON R liq., pH 6-6.5

Soap 15 min 95C with 2g/l CIBAPON R liq., pH 6-6.5

Rinse 10 min 80C

Rinse 10 min 50C

Cationic aftertreatment with CIBAFIX ECO or TINOFIX FRD

Smile green allows reproducible & level dyeing of
very difficult turquoise-based combinations !!
Ciba-Test 04.11.2003
Smile green Liquor ratio 1:10
CIBACRON H 0.150% Cibacron Brill.Yellow H-4GN Fix. temp. 80C
Soda ash 0.300% Cibacron Brill.blue H-GR Fix. time 60 min
1.700% Cibacron Turquoise H-GN Exh. time 45 min
60 g/ l Glauber's salt
15 g/ l Soda ash

Samples Standard -10% +10% 1.5

bluer
0.60
1.0

0.50

0.5
0.40 A
G
C
K D
Strength (RD)

dH*
J L
0.0 FI
0.30 M
B

-0.5
0.20

0.10 -1.0
yellower

0.00
-1.5
A B C D F G I J K L M N
-1.5 -1.0 -0.5 0.0 0.5 1.0 1.5
dC*
duller brighter

A -20% Salt I -20% Alkali

B +20% Salt J +20% Alkali
C -15' Exh. time K -15' Fix. time
D +15' Exh. time L +15' Fix. time
F - 5C Temp. M LR 1:8
G + 5C Temp. N LR 1:12
 Benefits of CIBACRON H DYES
SMILE GREEN
CIBACRON H smile green concept ...with the two new elements Yellow H-4GN and Brill. Blue H-GR we reach
a very good surface levelness with a minimum of dichroism
 Safe and Reproducible Gray State Dyeing

ADDED VALUE

WATER SAVING :

ENERGY SAVING ( Electricity, Steam) :

DECREASE COSTS

TIME SAVING / PRODUCTIVITY : Production

INCREASE PRODUCTIVITY
 CIBACRON H, Gray State Dyeing
PRODUCTIVITY

CIBACRON H Gray State Dyeing vs Conventional Hot dyeing process

Conv.hot dyes / week 17.5

Conv.hot dyes / week/target Week of 7 days

The future of the industry
21 Target optimal production
G S D process 2 ,100% cotton gray
CIBACRON H / week / G S 31.5
D

Conv.hot dyes / day

2.5

Conv.hot dyes / day / target 3

CIBACRON H / day / G S D 4.5

0 2.5 5 7.5 10 12.5 15 17.5 20 22.5 25 27.5 30 32.5

Number of batches per Jet dyeing machine

 CIBACRON H, Gray State Dyeing

WATER SAVINGS Conv. process Gray State Dyeing

process 2 ( 100% cotton gray )

Production / day 50.000 kg CO 50.000 kg CO

Water consumption
per kg of fabric 85 l/kg 45 l/kg
The future of the industry
Water consumption 4.250 m3 2.250 m3
per day
Water consumption 1.530.000 m3 810.000 m3
per year
Cost of water per day * .. ..

Cost of water per year .. ...

TOTAL YEARLY SAVINGS ON WATER

..

conv. process consumes 88 % more

* Provided cost of water is ...per liter
 CIBACRON H, Gray State Dyeing
Dyeing procedure
C100

90
B
80
C
70

60

A Wash off
50
pH 5.5
40

30

20
0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170

A Auxiliaries system, Ciba INVADINE DA

3.0 g/ l
common salt * CIBACEL DS 3.0 g/ l
Ciba LYOPRINT RG
3.0 g/ l
CIBAFLUID CD1.5 g/ l
common salt x g/ l
B CIBACRON H dyes, linear dispensing over 15 min
C Mixed alkali, soda ash + caustic soda progressive dispensing (70% progression) over
40 min. If no dosing facilities are available, soda ash should be added in 3 portions:
2/ 10, 3/ 10, 5/ 10 followed by an addition of caustic soda in 2 portions: 3/ 10, 7/ 10
* For the GSD process we recommend to use only common salt, to avoid precipitation problems

Common salt and alkali recommendation

Dye % 23 34 46 above 6
Salt (NaCl) g/ l 6070 7080 8090 90
Soda ash g/ l 5 5 5 5
NaOH 36B ml/ l 1.52.2 2.22.9 2.93.3 3.3
Very high productivity and excellent shade reproducibility, right-first-time dyeing
 Benefits of CIBACRON H DYES
GSD Process
CIBACRON H dyes dyed with the GSD process shorten up your dyeing process and increase imediately
your productivity.

Number of batches per day and week for one jet

PRODUCTIVITY

day
GSD
Conventional dyeing

week

0 3 6 9 12 15 18 21 24 27 30 33

ECOLOGY
Water Steam Electricity

consumption in l/kg fabric consumption in kg/kg fabric consumption in % (relative)

0 20 40 60 80 100
0 20 40 60 80 100 0 2 4 6 8 10

saves your time, water and energy consumption and has a great positive impact on the ecologycal system
 FN
CEL Exhaust
Warm Dyeing
- Range
LS
Profiles
Hot Dyeing
Top level for all modern fastness TS Top fastness level for all modern TS
requirements (repeated washing C10A, light, requirements (repeated washing C10A,
chlorine, PLF, ) washfastness 95, light, chlorine, PLF, ...)
Wide shade gamut incl. very brilliant shades TS Match environmental requirements all
Right-First-Time for critical shades (excellent Wide shade gamut (excl. turquoise and
Top compatibility, levelness) TOM green shades)
TOM

Excellent application properties (solubility, Right-First-Time for critical shades, even TOM
fixation rate, washing-off) TOM under varying liquor ratios
Special one-bath procedure for PES/CEL TOM
with excellent reproducibility (LS Superfast)

Medium fastness level fulfilling all common Technical solution for difficult fabrics (CO/EL, TS
S requirements (washing 60C, water severe,
Buy H CO merc., CV, etc.)
rubbing, light, ...) Medium fastness level fulfilling all common Buy
Economic offer for deep and very deep requirements incl. Chlorine
Value Buy
shades, competitive at medium shades Wide shade gamut incl. turquoise and green TS
in use Good technical performance (reproducibility shades
Buy/
and washing-off in medium to deep shades Good technical performance (reproducibility Buy/
TOM
and washing-off in medium to deep shades) TOM
State-of-the-art build-up all
Economic offer for medium to deep shades Buy