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Problem solving
Flexible
Rigid
Effect of Side Chain Substitution,
Crosslinking and Branching on PE
Which has a greater volume and a lower Tg
a) HDPE b) LDPE, Why?
LDPE
Which will be more flexible
a) PMMA b) PMA, Why?
PMA
The PMA chains are
more flexible than
PMMA chains due to PMMA PMA
the reason that bulkier
methyl groups on
Flexible low Tm
PMMA hinder packing Rigid high Tm
Aramid
If you want to produce nylon 6,6 by condensation
polymerization using hexamethylene diamine and
adipic acid, what masses of these two components
will be needed to yield 20 kg of completely linear
nylon 6, 6?
We write down the molecular weights of the three substances and
calculate their masses in the ratio of their molecular weights:
MW(adipic acid) = 146 g/mol
MW(hexamethylene diamine) = 116.21 g/mol
MW of Nylon 6,6 Repeat unit = 226 g/mol
Weight of polymer produced = 20 kg = 20000g
n = m/MM = 20000/226 = 88.5 moles
Hence mass of adipic acid needed = 88.5 x 146 = 12921 g = 12.9 kg
and mass of hexamethylene diamine needed = 88.5 x 116 = 10266
g = 10.26 kg
Carothers Equation
For a second order reaction, If the initial
concentration of monomers and the specific
rate constant are 10 mol/liter and 10-3 liter
mol-1 sec-1, respectively, how long would it
take to obtain an average degree of
polymerization of 37?
Ao = 10 mol/liter
K = 10-3 liter mol-1 sec-1
DP = 37
DP = 1 + kAot
t = 1 DP / kAo
= 3600 sec = 1 hr
Using the Arrhenius equation, show that the
value of the rate constant (k) increases as
the temperature increases?
k = A e(-Ea/RT )
since k e(-Ea/RT ),
as e(-Ea/RT ) increases so does k proportionally.
What is the functionality (f) of the following
monomers (a-c) in polymerization with
(A) HOOC(CH2)8COOH and (B)
CH2=CHCl:
a. CH2=CHC6H5 b.
H2N(CH2)6NH2
c.HO-CH=CH-OH
CH2=CHC6H5 (A) f = 0 (B)
f=2
H2N(CH2)6NH2 (A) f = 2 (B)
f=0
HO-CH=CH-OH (A) f = 2 (B) f =
2
Dr. Saima Shabbir, MS&E
If you are using 4.72843 kg of ethylene glycol and
12.660 kg of terephthalic acid in a condensation
polymerization to yield Polyethylene terephthalate
(PET), what will be the mass in kg of completely
linear PET produced through this polymerization?
OH OH O O O O H2 H2
n H2C CH2 + n HO C C OH C C O C C O
n
[-OC-( CH2)8-CO-NH-(CH2)6-NH-]
Nylon 6,10
[-CF2-CF2-]
Polytetrafluoroethylene (Teflon)
[NH(CH2)6NHCO(CH2)10CO-]
Nylon 6,12
[-NH-(CH2)3-CO-]
Nylon 4
Dr. Saima Shabbir, MS&E
Which would be higher melting and
why? (A) a Polyamide (B) a Polyester,
with same number of methylene groups
in the repeat unit?
(c) AnBn-
(B) O
C
O
C O
CH3
C O
CH3 n