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Ion exchange
Boiling
• Temporary hardness is the one which can be removed by
boiling mainly because it is made up of a combination of
calcium and bicarbonate ions in the water.
• Boiling promotes the formation of carbonate from the
bicarbonate and precipitates solid calcium carbonate,
leaving water that is softer upon cooling.
Ca2+(aq) + 2HCO3-(aq) ↔ CaCO3(s) + CO2(aq) + H2O
• Upon heating, less CO2 is able to dissolve into the water.
Since there is a deficiency of CO2, the reaction cannot
proceed from right to left.
• Boiling the water will remove the hardness as long as the
precipitated CaCO3 is removed e.g. by decantation. After
cooling, if enough time passes, the water will re-absorb CO2
from the atmosphere and the reaction will again proceed
from right to left, allowing the CaCO3 to re-dissolve.
• The basic principle that works in ion exchange is
exchange of ions responsible for hardness mainly Ca2+
and Mg2+ for sodium or potassium, thereby effectively
reducing the concentration of hardness minerals to
tolerable levels and thus making the water softer.
• An ion exchange water softener unit with beads uses
sodium chloride (table salt) for ion exchange process.
• As the hard water passes through and around the
beads, the hardness mineral ions are preferentially
adsorbed, displacing the sodium ions.
Ca2+ - {Cat(s)}2 + 2Na+ + 2Cl- → 2Na+ - {Cat(s)} + Ca2+ +
2Cl-
• The beauty of ion exchange is that the softening of
water does not require the removal of all ionic solutes,
just those cations responsible for water hardness.
• Sodium ion at low concentrations is harmless in water
to be used for most purposes, and sodium chloride is a
cheap and convenient substance with which to
recharge the cation exchangers.
• When the bead or sodium zeolite has a low
concentration of sodium ions left, it is exhausted, and
can no longer soften water. The resin is recharged by
flushing (often back flushing) with salt water.
• Sodium chloride is not the only compound with ion-
exchange properties there are zeolites or aluminum
silicate minerals , potassium chloride and synthetic ion
exchange resins.
This process involves the addition of slaked
lime(Calcium Hydroxide –Ca(OH)2) to a hard
water supply to convert the hydrogen
carbonate hardness to carbonate which
precipitates and can be removed by filtration:
Ca(HCO3)2 + Ca(OH)2 → 2CaCO3 +2H2O.
The addition of sodium carbonate also
permanently softens hard water containing
Calcium Sulphate, as the Calcium ions form
Calcium Carbonate which precipitates out and
potassium sulphate is formed which is soluble.
The calcium carbonate that is formed sinks to
the bottom. Sodium sulphate has no effect on
the hardness of water.
CaSO4 + Na2CO3 → CaCO3 + Na2SO4
Calcium sulphate + → Calcium carbonate +sodium
sulphate
Mg(HCO3)2 + Ca(OH)2 → MgCO3 +2H2O
Magnesium bicarbonate + lime → Calcium carbonate
+ water
MgSO4 +Ca(OH)2 →CaSO4 + Mg(OH)2
Magnesium sulphate + Calcium Hydroxide→Calcium
sulphate+Magnesium hyroxide
CO2 + Ca(OH)2 → CaCO3 + H2O
Carbon dioxide + Calcium hydroxide → Calcium
Carbonate+water
Assuming the influent water sample contains
200mg/l of Total hardness as (Calcium carbonate)
and the effluent water contains a total hardness of
100mg/l as Calcium Carbonate. The water
treatment plant recieves 10Ml/d