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The Theory
Lecture outcome
2
Momentum Transport Balance
p pt
Molecular viscous
stresses stress
Static
pressure
4
Molecular Transport Expression
pij pdij tij
Recall!
Kronecker delta, d ij
If i = j , d=1
If i ≠ j, d=0
dxx = 1, dyy = 1, dzz = 1
dxy = 0, dxz = 0, dyz = 0 etc.
6
Molecular Transport Expression (1.2)
p pd t
7
Molecular Motion
Particle
Let’s imagine a molecule motion in
as a particle tornado
8
Molecular Motion
Let’s imagine a molecule as a particle
Floating
ball
9
Molecular Transport
Yes!
Split into 3D
components
y
z x
10
Molecular Transport Expression (1.2)
13
Viscous Stress
v j vi
t ij
d i d j
15
Viscous stress in Cartesian coordinates
v y vx
t xy
x y
Viscous force per unit area in the z-direction on a plane
perpendicular to x-direction
v z v x
t xz
x z 16
Viscous stress in cartesan coordinates
Viscous force per unit area in the x-direction on a plane
Area perpendicular to y-direction
perpendicular vx v y
to y t yx
y x
Viscous force per unit area in the y-direction on a plane
perpendicular to y-direction
v y v y v y
t yy 2
y y y
v y vz
t zy
z y
Viscous force per unit area in the z-direction on a plane
perpendicular to z-direction
v z v z v z
t zz 2
z z z 18
Viscous stress in cartesan coordinates
Direction!
19
Viscous stress in cartesian coordinates
20
Viscous stress in cartesan coordinates
Viscous Stress
Note that:
Shear Stress
txy =tyx
Look at the
direction! tzy =tyz
txz =tzx
22
Velocity gradient
dv
t
dx
What is velocity
gradient ?
23
Molecular Transport Expression -1D
vx=vx(y)
Recall! 1D
dv x
t yx
dy
24
Velocity gradient
dv
dx
25
Summary
v j vi
t ij
d i d j
27