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filmelor subtire de
P3HT:CuInSe2:TiO2 applicatii in
celule solare hibride
Yang-Yen Yu, Wen-Chen Chien, Yu-Hsin Ko, Si-Han Chen
Ce facem?
Pentru ca se apropie Energie nucleara
sfarsitul la:[1]
Biomasa
2052
Energie Solara
Wind turbine
2088
Energie geotermala
[1] https://www.ecotricity.co.uk/
Calcule energetice[2]
Anul 2001:
[4]
[3] Prabakaran Kumaresan, Sureshraju Vegiraju, Yamuna Ezhumalai, Shueh Lin Yau, Choongik Kim, Wen-Hsi Lee, Ming-Chou Chen, Polymers, 2014, 6(10), 2645-2669
[4] https://www.youtube.com/watch?v=j1jF3in2JUE
[5] [6]
PEDOT- poly(3,4-ethylenedioxythiophene) polystyrene sulfonate ITO- Indium tin oxide TCO- Transparent
Conductive Oxides
FTO- fluorine doped tin oxide
[5] Carsten Deibel, Vladimir Dyakonov, Rep. Prog. Phys., 73, 2010, 096401, 39
[6] Veluru Jagadeesh Babua, Sesha Vempatib, Subramanian Sundarrajan, Merum Sireesha, Seeram Ramakrishna, J.Sol.En, 106, 2014, 1-22
Bulk-heterojunction
polymer s.c
Polymer-fullorene s.c
Hybrid s.c
Hybrid thin-film solar cell based on P3HT-
poly-hexylthiophene and CuInSe2
Low price
Why CuInSe2?
Large absortion coefficient
Radiation stability
Metode de sinteza CuInSe2
De ce TiO2?
Synthesis of TOPO-capped
Characterization
CuInSe2 nanoparticles
TEM- for det.particle size of TiO2
Was realized by hot injection method, CISe 04 SEM-fracture surface of hybrid thin film
particles were shielded by TOPO 01 AFM- surface morphology of coated film
X ray for crystalline struct., PL, UV-Vis,
● A spin-coating process was used to fabricate the hybrid solar cell devices.
● Cleaning of ITO glass
● PEDOT/PSS was then mixed with DMSO solvent and spin-coated on the prepared ITO glass substrate
● The substrate was cured for 20 min at 120 °C under nitrogen to remove the solvent.
● Dichlorobenzene solutions composed of P3HT and CISe were then spin-coated over the PEDOT:PSS layer.
● Subsequently, the active layer was baked
● The cell was then heated.
● Calcium and aluminum were thermally deposited onto the device under vacuum
Results and discussions
XRD pattern