Evelyn Del Carmen Figueroa Ribón

Método Ponchon- Savarit

 BENCENO-TOLUENO
 Determinar flujos destilado y residuo (
XD = 98% 𝑘𝑔
𝑦
𝑘𝑚𝑜𝑙
), composiciones % peso y %
ℎ𝑟 ℎ𝑟
mol
F= 10,000 Kg/hr  Determinar el Rm
XF = 45%
T= 50° C  Determinar etapas teóricas con 1.5
Rm
 Carga de calor, condensador y
XB = 2% rehervidor
 Determinar el diámetro de la
columna
Método Ponchon- Savarit
 Diseñar platos perforados tipo sieve
 A) Fmol ó Fpeso
0.45(78) 35.1
XF peso =0.45 = 35.1+50.6 = 0.4095
78 +(1−0.45)(92)

0.98(78) 76.44
XD peso = = = 0.9765
0.98 78 +(0.02)(92) 76.44+1.84

0.02(78) 1.56
XB peso =0.02 = 1.56+90.16 = 0.0170
78 +(0.98)(92)

Método Ponchon- Savarit

Balance General

 F= D + B
 FXF = DXD + BXB
 (10000Kg/hr)(0.4095)= (10000-B)(0.9765)+B(0.0170)
 4095kg/hr = 9765 -0.9765 B +0.0140 B
−5670 𝑘𝑔
 B = −0.959 = 5909.3277 ℎ𝑟

 F-B= D
𝑘𝑔 𝑘𝑔 𝑘𝑔
 D = 10000 ℎ𝑟 - 5909.3277 = 4090.6722
ℎ𝑟 ℎ𝑟

Método Ponchon- Savarit

 PM = 78(0.45) +92(0.55) = 85.7
𝐾𝑔 Formulas Liquido Frío
𝐾𝑚𝑜𝑙
 PM = 78(0.98) +92(0.02) =
𝐾𝑔
78.28
𝐾𝑚𝑜𝑙
 PM = 78(0.02) +92(0.98) =  q= 1 +
𝐶𝑝 (𝑇𝑏 −𝑇𝐹)
ℷ
Cp= 0.3941
𝐾𝑔
91.72  f=
𝐶𝑝 (𝑇𝑏 −𝑇𝐹)
ℷ = 93.3494
𝐾𝑚𝑜𝑙 ℷ
 Interpolar Temp @ x=0.4095
𝑘𝑔
10000 ℎ𝑟 𝑘𝑚𝑜𝑙 T= 93.2752 ° C
 F= 𝑘𝑔 = 116.6861
85.7 𝑚𝑜𝑙 ℎ𝑟
𝑘𝑔
4091.0986 ℎ𝑟 𝑘𝑚𝑜𝑙
X CP
 F= 𝑘𝑔 = 52.2624 92 0.453684
78.28 ℎ𝑟
𝑚𝑜𝑙
Cp= 0.4552 kcal/kg
𝑘𝑔
5908.9013 ℎ𝑟
96 0.458507
𝑘𝑚𝑜𝑙
 F= 𝑘𝑔 = 64.4232
91.72 𝑚𝑜𝑙 ℎ𝑟

Método Ponchon- Savarit

ℷ BENCENO 91.41882 Kcal / kg
B)
𝑄´ −𝐻𝐺 265−128.9675
ℷ TOLUENO 88.81359 kcal / kg Rmin=
𝐻𝐺 −𝐻𝐿
=
128.9675−35.2919
= 1.452
ℷ MEZCLA 91.4188(0.4096) +
(88.813594 x0.5905)
ℷ MEZCLA 89.8895 kcal/kg • Rop =1.452 x 1.5= 2.1783
𝐶𝑝 (𝑇𝑏 −𝑇𝐹)
 q= 1 + HG 0.98 128.4675Kcal/
ℷ
0.4552 (93.2752 −50°𝐶) Kg
 q= 1 + =1.219
89.8895 HL 0.98 35.2919
Kcal/Kg
𝑞 1.219
 M= = 1.219−1=5.5662
𝑞−1

 Tan θ = m
 Θ= tan –m =78.8097
# de etapas teóricas= 16
 x= 0.67 x=0.445
𝑘𝑐𝑎𝑙
 Qm= 265
𝑘𝑔

etapa de alimentación 8
Método Ponchon- Savarit
Datos de equilibrio vapor-líquido
del sistema
Benceno-Tolueno a 760
mm Hg.
cp
bencen cp cp mezcla
t x y o cp tolueno benceno cp tolueno x y PM f.liq PM f.vap f.liq Hliq. Hvap
J/g mol kcal/kg.
ºC frac. Mol frac. Mol °C J/g mol °C kcal/kg °C kcal/kg °C frac. Peso frac. Peso kg/k mol kg/k mol Sol. °C kcal/kg kcal/kg
80.1 1.0000 1.0000 142.86 171.76 0.4371 0.4456 1.0000 1.0000 78.11 78.11 0.43714 35.0146 129.1359
82.0 0.9067 0.9618 143.46 172.43 0.4390 0.4473 0.8918 0.9552 79.42 78.65 0.43988 36.0704 129.8253
84.0 0.8145 0.9187 144.10 173.14 0.4409 0.4492 0.7882 0.9055 80.71 79.25 0.44267 37.1847 130.5427
88.0 0.6466 0.8230 145.38 174.57 0.4449 0.4529 0.6080 0.7976 83.06 80.59 0.44800 39.4238 131.9513
92.0 0.4986 0.7142 146.68 176.00 0.4488 0.4566 0.4574 0.6793 85.14 82.12 0.45304 41.6794 133.3285
96.0 0.3678 0.5913 147.99 177.44 0.4528 0.4603 0.3303 0.5509 86.97 83.84 0.45785 43.9539 134.6765
100.0 0.2516 0.4529 149.32 178.89 0.4569 0.4641 0.2218 0.4124 88.60 85.78 0.46250 46.2496 135.9944
104.0 0.1480 0.2976 150.66 180.36 0.4610 0.4679 0.1284 0.2643 90.05 87.96 0.46700 48.5680 137.2837
108.0 0.0557 0.1241 152.01 181.83 0.4651 0.4717 0.0476 0.1073 91.35 90.39 0.47139 50.9102 138.5484
110.6 0.0000 0.0000 152.90 182.79 0.4679 0.4742 0.0000 0.0000 92.13 92.13 0.47420 52.4466 139.3531

Método Ponchon- Savarit

 Diagrama de equilibrio vapor líquido de la mezcla benceno
tolueno a 1 atm en fracción peso
1.00
y = -0.550612x4 + 1.815194x3 - 2.621921x2 + 2.356529x + 0.000485
R² = 0.999998
0.90

0.80

0.70

0.60

0.50

0.40

0.30

0.20

0.10

0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

Método Ponchon- Savarit

 Diagrama entalpía concentración del sistema benceno-tolueno a 1 atm. H en kcal/kg
y x-y en fración peso

300

y = -3.7562x2 - 6.3057x + 139.29

R² = 0.9997
200

100

0
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

-100
y = 11.1764x2 - 28.1037x + 52.1768
R² = 0.9990

-200
Método Ponchon- Savarit
Carga del condensador y rehervidor

𝑄𝐶
Q’=
𝐷+𝐻𝐷
• Qc=(Q’-HD)*D = 133241.01
kcal/h
• QB = D*HD+B*HB+Q –F*HF
• QB= 128548.96 kcal/hr

Método Ponchon- Savarit