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Degradation
and Durability
Locwaza Pideksa
Introduction
– The fact
– damage to bridge decks in North America due to corrosion caused by de-icing salts
– severe wear of concrete structures in the Arabian Gulf Area caused by chloride-
initiated corrosion
– degradation of sewers due to sulphuric acid attack and deterioration caused by
alkali–silica reactions
Chemical degradation
mechanisms
– Degradation of cement stone by acids
– Degradation of cement stone by salts
– Degradation by expansive salts
– Degradation by expansive silica
Degradation by acids
Degradation by acids
– The slime layer in particular is biogenically active.This layer can be divided into
various zones as shown in Fig.3.1.In the case where the oxygen content of the
sewage water is greater than 1mg/l,three layers can be distinguished. The outer
layer in contact with water is aerobic.The middle and inner layers are anaerobic.
Reduction of sulphur compounds can take place in the middle layer.These sulphur
compounds diffuse from the waste water into the slime layer. When reduced, the
sulphide diffuses backwards into the waste water, but is oxidized again in the
aerobic slime layer. There will, therefore, be no net reaction. However, if the waste
water itself is anaerobic,i.e.if the oxygen concentration is lower than 0.1mg/l,the
aerobic slime layer will not be present so that sulphide will enter the waste water by
backward diffusion. Here it can form hydrogen sulphide that can escape as a gas.The
rate of escape is especially high in areas of turbulence.
Rate of deterioration caused by
acid
– the rate of degradation appears to depend mainly on the lime content of the
concrete
Manure Silos
– Concrete attack by the highly acid extracts of corn has also attracted much
attention over the past years. The general pattern of this acid degradation of
concrete is that it slowly dissolves the cement paste starting from the surface.
The aggregates usually degrade less quickly than the cement paste. .Which
happens,for instance,when limestone or dolomite aggregates are used.In this
case degradation initially looks more severe,but when degradation
proceeds,the situation reverses because lime or dolomite provides an additional
alkaline buffer that can neutralize the acid.
Degradation of cements
by salts
Ammonium salts
– In the latter case it was considered likely that cement paste degradation
occurred first,while ettringite formation took place later on. Ettringite formation
occurred when there was enough space to release the expansive ettringite
forces.
Degradation of cements
by expansive salts
Sulphate attack
– Sulphates are present in many natural waters such as ground water,but they can
also be found, occasionally in high concentrations, in industrial waste
water.When sulphate ions penetrate pore systems by absorption of water
containing sulphate or by diffusion,they can react with the free lime present in
the concrete and form gypsum
Foundations of high voltage poles
– Formation of this salt not only requires sulphate, but also calcium
carbonate.Calcium carbonate is not always present in concrete,but could be
there if the carbonation frontier advances
– During thaumasite formation, ettringite occurs as an intermediate salt.
Delayed sulphate degradation
– This reaction frequently takes place where the ground water is often very salty
and the evaporation rate high, for instance in the Gulf area.
Alkalis silica reaction
Reaction Mechanism
– Air Entrainment
– Surface treatment
– Low water/ cement ratio
Air-entrainment
– Frost–thaw (de-icing salt) damage of concrete only occurs if the concrete is wet.
It is therefore worth while considering ways of preventing the concrete from
becoming wet. By applying an organic coat to the surface the ingress of water
can be prevented.
– However,such a coat also prevents evaporation of the water already present in
the concrete or of water that enters from the soil beneath the concrete.In the
case of frost –thaw de-icing salt loading,e.g.at concrete bridge parapets,it
appears that water condenses behind the coating system.
Low water/
cement ratio
applying a water/cement ratio
lower than 0.45 in combination with
good curing is permitted. In such
cases the use of airentrainment is
not obligatory. Obviously, this
measure only applies to a country
with a moderate climate.
Reinforcement
Corrosion
Passivation
– Concrete in contact with air reacts with carbon dioxide and is neutralized. If the
carbonation frontier reaches the reinforcement,the steel is no longer
passivated. Subsequently, the reinforcement can corrode and the concrete can
crack.
– .Carbon dioxide reacts with the alkaline and earth alkaline constituents in the
concrete.The reaction occurs at the water–air frontier in the pores, just below
the water surface
Carbonation Mechanism
Qualified curing
The temperature
Corrosion propagation
– Once the passivation layer dissolves, corrosion occurs and the corrosion
propagation phase starts
– In reinforced concrete structures below sea level, for instance, critical corrosion
is often greatly exceeded, but the corrosion rate is very low.This is due to the
lack of oxygen.The underwater oxygen flow through concrete towards the
reinforcement is very small.
– Cement type
– with a powder coal fly ash content of at least 30% fly ash, silica fume or
other pozzolanic additions can show high resistance to chloride ingress.
Water/ cement ratio
Increasing the binder content is, of course, another possibility for
decreasing the water/cement ratio. This increase is restricted by the
Preventive
increase in hydration heat, hydration development,shrinkage and creep of
the concrete,
measures
Cover
In structures subject to chloride loading,the cover has to be at least
50mm thick.One has to be aware that the concrete skin is often of poorer
Curing
When concrete dries out, the cement stops reacting and the concrete
carbonates. The earlier drying out occurs during cement hydration giving a
more negative effect on concrete.
Prestressed concrete
Deterioration
– The failures observed in practice are due to stress corrosion cracking and
hydrogen embrittlement.Both can occur suddenly and without any warning as
discussed
– Corrosion can be initiated during the construction stage,during transport and on
the site when the tendons are left unprotected; even contact with water can
induce corrosion. Contact with salt water or salt-laden air in marine
environments can be especially detrimental.
Prevention of corrosion
– Inhibitors are chemical agents that discourage the formation of anodic regions
on the reinforcement. There is controversy about the medium- and long-term
effectiveness of this type of treatment. Coating the reinforcement with a
substance that is an electrical conductor with a lower electrode potential than
steel causes the cations of the coating material (rather than the steel) to
dissolve under corrosive conditions.
Repair Mortars
Repair Mortars
– In practice, hydrophobic
impregnation and coating are the
most important.
– Coatings are distinguished by
thickness :
– Thin coatings: layers less than
100μm thick.
– Thick coatings: layers between
100 and 500μm thick.
– Plasters both with an organic and
an inorganic basis that have
thicknesses of between 500μm
and 5 mm.
Durability of protection
Hydrophobic agents
Coatings
Hydrophobic Agents
– The hydrophobic agents most commonly applied are those that consists
of organo-silicon compounds. The right choice of organo-silicon
compounds will give concrete very good hydrophobic properties and
water-repellence should be maintained for at least 10 years.
– Agents that can bind chemically with concrete are:
• Siliconates
• Silicon resins
• Alkylalkoxy silanes
• Oligomeric alkylalkoxy siloxanes
• Polymeric alkylalkoxy siloxanes
Impegnation/ filling of pores
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