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D. Jim Livingston
Asst. Professor of Chemistry
St. John’s College.
Infrared spectroscopy
• Infrared spectroscopy (IR spectroscopy or vibrational
spectroscopy) involves the interaction of infrared radiation
with matter.
• This can be analyzed in three ways by measuring absorption,
emission and reflection.
• mostly based on absorption spectroscopy to identify solid,
liquid, or gas samples.
• IR Spectroscopy measures the vibrations of atoms -
determine the functional groups
• An IR spectrum can be visualized in a graph of infrared light
absorbance (or transmittance) on the vertical axis (x) vs.
frequency or wavelength on the horizontal axis (y).
• Units - reciprocal centimeters (wave numbers),cm−1.
• Generally, stronger bonds will vibrate at a high stretching
frequency (wavenumber)
Vibrations of molecules
• A common
laboratory
FT - IR Instrument instrument -
Fourier transform
infrared (FTIR)
spectrometer.
An IR spectrum
Effect of electron density on metal
Π- back bonding
increases
Answers
Mn(CO)6]+ > Fe(CO)5 >V(CO)6]- > Fe(CO)3]4-
axial
1.80 Å
Equatorial
1.84 Å
diamagnetic
hexacarbonylchromium
octahedral
1.92 Å
diamagnetic
Mn2(CO)10, Dimanganese decacarbonyl
Square pyramidal
-Thank You