Isomerization in a CSTR

with Aspen HYSYS®

Using Aspen HYSYS® V8.0

Revised: November 26, 2012

© 2012 Aspen Technology, Inc. All rights reserved

 Reaction Kinetics

 1st order reaction kinetics

 𝑟𝐴 = 𝑘𝐶𝐴
𝑁𝐴 𝑑𝐶𝐴
 𝐶𝐴 = ; = −𝑟𝐴
𝑉 𝑑𝑡
𝑑𝐶𝐴
 = −𝑘𝐶𝐴
𝑑𝑡
– Exponential shape

© 2012 Aspen Technology, Inc. All rights reserved | 2

 Residence Time

 rA is ‘moles of reactant becoming product per time, per

volume’
– Time until any given conversion of reactant is independent of
reactor size
 This time is called Residence Time, τ
– Can be solved for analytically
 Residence time and volumetric flow rate are used to size
reactors

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 Continuously Stirred Tank Reactor

 Assumes perfect mixing in

AB
the tank
CA0
 Effluent stream has same
composition as the tank
𝑑𝑁𝐴 0
 = 𝑞𝑖𝑛 𝐶𝐴 − 𝑞𝑜𝑢𝑡 𝐶𝐴 − 𝑉𝑟𝐴
𝑑𝑡
𝑑𝑉𝑖𝑛 𝑡𝑎𝑛𝑘
 = 𝑞𝑖𝑛 − 𝑞𝑜𝑢𝑡
𝑑𝑡

 Steady state so all time CA CA

derivatives are zero

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 Problem Statement

 Solve the ODE for 90% conversion in a CSTR

 Report the residence time required
– 𝑘 = 0.23𝑚𝑖𝑛−1 = 0.003833𝑠 −1
 Use Aspen HYSYS to verify answer

© 2012 Aspen Technology, Inc. All rights reserved | 5

 Copyright

 Copyright © 2012 by Aspen Technology, Inc. (“AspenTech”). All

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