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SOURCES OF FLUORIDES
Ê Fluorine is one of the physiologically essential elements for normal
growth and development. It is the 13th most frequently occurring
elements which represents 0.06%to 0.09% of the earth crust.
Ê Fluorine is a yellowish green diatomaceous gas. The highest fluoride
value has been recorded in the rift valley of Kenya.{2800mg per kg
-5600mg per kg in soil} fluoride in atmosphere is highest in the
vicinity of fertilizers factories and industry involved in production
of plants uranium and aluminum. Plants like tea also contain
fluoride.
Ê Fish have a high content of fluoride because oceans contain about
1 ppm of fluoride.
À À ÀÀ
À
À
èIR
èirborne fluoride exists in gaseous and particulate forms,
which are emitted from both natural and anthropogenic
sources. Fluoride released as gaseous and particulate matter
is deposited in the general vicinity of an emission source,
although some particulates may react with other
atmospheric constituents.
WèTER
Ê Fluoride levels in surface waters vary according to location
and proximity to emission sources. Surface water
concentrations generally range from 0.01 to 0.3 mg/litre.
Seawater contains more fluoride than fresh water, with
concentrations ranging from 1.2 to 1.5 mg/litre.
SOIL
Fluoride is a component of most types of soil, with total
fluoride concentrations ranging from 20 to 1000 µg/g in
areas without natural phosphate or fluoride deposits and up
to several thousand micrograms per gram in mineral soils
with deposits of fluoride.
TERRESTIèL BIOTè
Ê Fluorides can be taken up by aquatic organisms directly from
the water or to a lesser extent via food. Fluorides tend to
accumulate in the exoskeleton or bone tissue of aquatic
animals
Ê Mean fluoride concentrations of 150²250 mg/kg were
measured in lichens growing within 2²3 km of fluoride
emission sources, compared with a background level of <1
mg fluoride/kg.
FOOD STUFF
Ê Urine ,
Ê plasma,
Ê saliva,
Ê Teeth,Hair
Ê Nails
Ê Bones
Ê teeth
MECHèNISM OF èCTION
Fluorosis or
toxicity
F
FLUORIDE èDMINISTRèTION
Ê SYSTEMèTIC FLUORIDE
Fluoride after ingestion can get absorbed and incorporated into
developing enamel and can benefit teeth before eruption .It also
benefits the teeth eruption, when it returns to mouth in saliva and
gingival exudates.
Ê COMMUNITY WèTER FLUROIDèTION
Community water fluoridation in the process adjusting the amount of
fluoride in a community water supply to an optimum level for the
preventation of dental caries.
Studies have shown that adjustment of fluoride concentration in
drinking water to the optimum level of 1 ppm is associated with
marked decrease in dental caries.
Ê FLUORIDE COMPOUNDS USED IN WèTER
FLUORIDèTION
Fluorspar
Sodium fluoride
Silicofluoride
Sodium silicofluoride
Hydrofluosilicic
èmmonium silicofluoridr
Ê E UIPMENTS USED IN WèTER
FLUORIDèTION
There are three systems of water fluoridation
Saturated system
Dry feeder system
Solution feeder system
BENEFITS
This method is preferred since some tooth surfaces receive
greater protection against caries than other.
Water fluoridation has both pre-eruptive and post-eruptive
effects.
SCHOOL WèTER FLUORIDèTION
¦
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OTHER FORMS
Pastes
Key ingredients in TP:
1. F salt
2. èbrasive
Gels:
1. Better interdental
penetration
2. More acceptable
to children
DENTIFRICE
2. 0.76% sodium
monofluorophosphate (MFP)
3. 0.4% stannous F
4. èmine F
F F
Sn
F salt (all reach 1000-1500 ppm F) SnF2 exhibits less shelf life and may
cause dental staining
S F
P
High
salivary
T flow
F awake
Brush S
F F F
before
F bedtime P F Low
F T salivary
F F F
flow
asleep
F
Evidence shows that increased F
use and F concentration Rinsing after brushing
increases bioavailability in
reduces F effectiveness by 50%.
stagnation sites.
Recommendations: Do not rinse
(Note: be aware of fluorosis
after brushing or rinse with a F
susceptible patients.)
rinse.
HOME F RINSES
Indications:
1. High caries risk
2. Exposed roots
PHOS- 3. Prevention programs
FLOR
Topical F, 12,300
ppm F pH= 3.5
F F
Ca
F Ca
Divalent cations like
Ca cause Ca
Ca precipitation, of F
and prevent
absorbtion in the
F intestine. F
Ca Ca F Ca Ca F
F F Ca F F Ca
Ca Ca
TREèTMENT
Ê èll attempts must be made to eliminate the toxic dose of
fluoride from the body and
Minimize the further absorption
Support vital signs
èdministration of an emetic if patient possesses a gag reflex i.e. if
he is not vomiting he is not unconscious and not having
convulsions.
Investigations of blood should be done for pH,palsma fluoride
concentration and serum chemistry profiles.
èn intravenous line should be secured and glucose to be
reversed hyperkalemia and calcium gluconate to maintain
sodium and calcium levels must be given.
Sodium bicarbonate or ringer·s lactate must also be given to:
Increase urinary flow
Decrease acidosis
Increases Ph and thus
Increases excretion of fluoride
Continuously monitoring of the patient till the normalcy is
attained, is must.
CHRONIC FLUORIDE TOXICITY
Fluoride has been made the scapegoat for many accusations. It has
been reported to cause
èllergy
Carcinoma
Birth abnormalities
Mutation and other genetic disorders.
èfter an extensive research it is now thought there is no detectable
risk of cancer in humans associated with consumption of
optimally fluoridated water. Fluoride is not associated with
Down·s syndrome or any birth abnormality. èt present, there is
no indication ,which suggest that organ system are affected by
fluoride.
SKELETèL FLUOROSIS
This is also called osteofluorosis.è water fluoride level over
4ppm cause a mild variant but levels over 8ppm cause severe
skeletal fluorosis.
FEèTURES
Increase bone density
Change in bone contours
Irregular periosteal growth
Spinal column and pelvis show roughening and blurring of
trabeculae.
Bone appears as marble white shadow and the configuration is
woolly.The cortex of long bone is thick and dense and the
medullary cavity is diminished.
Ligamental and tendon calcification with vague pain in joints.
Stiffness and limitation of joint movements, immobilizing the
patient-crippling fluorisis.
èrthritic changes ,cataract,thyroid problems,tumors and
cysts,fractures,urinary and gallstones may be seen.
DENTèL FLUOROSIS
0 NORMèL-enamel appears translucent ,smooth and
glossy
1 UESTIONèBLE-enamel shows white flecks to an
occasional white spot.
2 VERY MILD-small opaque paper white areas
scattered irregularly over the tooth surface.
3 MILD-the white opaque areas are more extensive but
not involving greater than 50% of enamel
pitting severe
Ê Fluorosis occurs when teeth are developing. The most critical ages
are from 0 to 6 years. èfter 8 years, risk of fluorosis is essentially
past. During the critical ages F intake in excess of 0.1mg/kg body
weight/day can lead to fluorosis. This is roughly 1mg/day for a 1 to
2 year old or 1.5 to 2 mg for a 5 year old. Remember that all forms
of F intake comprise the daily consumption. This includes water
intake (up to 1.5mg/day), foods (0.3 to 1.0mg) and especially
significant in young children, swallowed toothpaste. Children under
2 years swallow 50% of toothpaste during tooth brushing and at
5years, 25%, both of which may amount to 1mg F/day.
POTENTIèL HèRM
DMFT FLUOROSIS
10
9 severe
8
moderate
7
6
mild
5
4 slight
3
2 0.0 0.5 1.0 2.0 3.0 4.0
Enamel prism
Excess F affects
mineralization of
developing teeth
0.5 ppm
water F
1.2 ppm
water F
supplements toothpaste
Maxium safe dose for a fluids food
5 year old = 2 mg F /
day
1 to 3 grams
Toothpaste = 1 mg F /
gram (1000 ppmF) ´pea size amount (0.5g) is
recommenred for fluorosis susceptible
children.
Ê TREèTMENT
Dental fluorosis presents an aesthetic concerns for the patient
and hence aesthetic restorative techniques have been advocated.
For milder forms of fluorosis,rubbing the teeth with 18%
hydrocholoric acid(with or without heat)and treatment with
30%hydrogen peroxide is used
Croll(1989)suggested that these techniques can be enhanced by
microabrasion or grinding of the surface layer.
Severe forms require composite restoration of full ceramic crowns
METHODS OF
MINIMIZING TOXICITY
Ê The danger of acute toxicity is high in cases of tropical
fluoride treatment where the teeth are treated with the high
F containing solution or gel at one time. Hence,
Upright position of patient, head incline forward
Use of custom made trays.
Use of saliva ejector
Use of minimum amount of gel required is recommended.
DEFLUORIDèTION
Defluoridation is a scientific means to improve the quality of water
with high fluoride concentration by adjusting the optimum level
in drinking water
METHODS
èDSORPTION èND ION EXCHèNGE METHOD
Some substances adsorb fluoride ion by the surface and it can
exchange its negative ion such as OH group for fluoride ion.
Thus the concentration of fluoride in water decreases for
eg.activated alumina, fluidized activated alumina.
PRECIPITèTION METHOD
In high pH condition,co-precipitation of several elements in with
fluoride ions forms fluoride salts.for eg.alum,alum and lime
METHODS BèSED ON MEMBRèME SEPERèTION
In the industrialized world·reverse osmosis·process is well know.
èll elements in water get diminished after filtration.
INDIèN TECHNOLOGY FOR
DEFLUORIDèTION
Ê NèLGONDè TECHNI UE
This technique first developed in India in 1975,is the simplest, the
least expensive and the easiest to operate of all the other method
of Defluoridation.
USING LIME èND èLUM
The first community plant for removal of fluoride from drinking
water was constructed in the district of nalgonda in èndhra
Pradesh, in the town of kathri,thus the name of technology.
Ê PROCEDURE
RèPID MIX: rapid mix is an operation by which the coagulant
is rapidly and uniformly dispersed though the single or multiple
phase system.This helps in the formation of microflocs and
results in proper utlization of chemical coagulant,preventing
localization of concentration and premature formation of
hydroxides which lead to less utilization of coagulants.
FLOCCULèTION:
flocculation is the second stage in the formation of settable
particles(FLOCS)from destabilized colloidal sized particles and is
achieved by gentle and prolonged mixing.
SEDIMENTèTION: it is the seperation from the water by
gravitational setting of suspended particles that are heavier than
water.
FILTERèTION: this is the final step. The water is allowed to
stand for about an half an hour and the water collected is
utilized for drinking.
DOMESTIC USE
In rural areas this method is advised for domestic use of
defluroidation of drinking water as required. This advise is given
to mix water,lime and alum in a close big vessel and leave it
overnight,so that next morning the clean supernatent is
decantedfor use and is safe for consumption
èDVèNTèGES OF NèLGONDè TECHNI UE
This method can be used both at domestic and community levels.
Operation are possible manually.
The chemical are same as those used in municipal urban water
supply.
It is cost effective.
Designs are flexible to use at different locations.
Defluoridation meets with standard laid down by the Bureau of
Indian Standard(fluoride content less than 1mg/l).
Other techniques used are
Combined Nalgonda and calcined Magnesite technique
Prasanti technology
Other materials tried in India
Fish bone charcoal
Drumstick plant
èskali-extract mycetial biomass
Clay minerals
Tricalcium phosphate
COMBINED NèLGONDè èND CèLCINED MèGNESITE
TECHNI E
In this plant the Nalgonda technique was passed through a filter
bed of calcined magnesite granules. Fluoride was absorbed by
the calcined magnesite granules, there was a rise in pH over 10.0
method is found impractical for rural regions .
PèRèSèNTI TECHNOLOGY:
In Indian villages this method of utilizing èctivated èlumina is
found to be most popularand cost effective material for
defluoridation.
!)
Was also used as an alternative to defluoridate drinking water as it is easily
accessible and it has been widely used to reduce water turbiditY because
of its excellent coagulating and clarifying properties.