Documente Academic
Documente Profesional
Documente Cultură
ENGINEERING &
TECHNOLOGY
SUBMITTED BY : SUBMITTED TO :
1 PATEL ARMIN (160420105035) 1 PROF. VAISHALI UMRIGAR
2 PATEL BHAUMIN (160420105036) 2 PROF. BANSI KANSAGRA
3 PATEL CHINTAN (160420105037)
4 PATEL DHRUVIN (160420105038)
CONTENTS :
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INTRODUCTION :
• The adsorption operations exploit the ability of certain solids preferentially to concentrate specific
substances from solution onto their surfaces.
• In these operations the mixture to be separated is brought into contact with another insoluble phase,
the adsorbent solid.
• The unequal distribution of the original constituents between the adsorbed phase on the solid
surface and the bulk of the fluid then permits a separation to be made.
• The rigidity and immobility of a bed of solid adsorbent particles make possible useful application
of semi-continuous methods which are not at all practicable when two fluids are contacted.
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TYPES OF ADSORPTION :
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NATURE OF ADSORBENTS :
• Adsorbent solids are usually used in granular form, varying in size from 50 µm to 12 mm.
• They are used in a fixed bed through which a liquid or gas is to flow, they must not offer too great
a pressure drop for flow nor must they easily be carried away by the flowing stream.
• They must have adequate strength and hardness so as not to be reduced in size during handling.
• If they are to be transported frequently in and out of bins, they should be free-flowing.
• Adsorption of organic materials is increasing with pH is decreasing.
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• Large surface per unit weight seems essential to all useful adsorbents. Particularly in the case of
gas adsorption,
• The pores are usually very small, sometimes of the order of a few molecular diameters in width,
but their large number provides an enormous surface for adsorption.
• There are many other properties evidently of great importance which are not at all understood, and
we must depend largely on empirical observation for recognition of adsorptive ability.
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DIFFERENT ADSORBENTS USED :
1. Fuller's earths :
• These are natural clays.
• They are chiefly magnesium aluminum silicates in the form of the minerals attapulgite and
montmorillonite.
• Commercially available sizes range from coarse granules to fine powders.
• The clays are particularly useful in decolorizing, neutralizing, and drying such petroleum products
as lubricating oils, transformer oils, kerosenes, and gasolines, as well vegetable and animal oils.
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2. Activated clays :
• These are bentonite or other clays which show essentially no adsorptive ability unless activated by
treatment with sulfuric or hydrochloric acid.
• It is particularly useful for decolorizing petroleum products and is ordinarily discarded after a
single application.
3. Bauxite :
• This is a certain form of naturally occurring hydrated alumina which must be activated by heating
to temperatures varying from 230 to 815 °C in order to develop its adsorptive ability.
• It is used for decolorizing petroleum products and for drying gases and can be reactivated by
heating.
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4. Alumina :
• This is a hard, hydrated aluminum oxide which is activated by heating to drive off the moisture.
• It is used chiefly as a desiccant for gases and liquids.
5. Bone char :
• This is obtained by the destructive distillation of crushed, dried bones at temperature in the range
600 to 900 °C.
• It is used chiefly in the refining of sugar.
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6. Decolorizing carbons :
• These are variously made by:
Mixing vegetable matter with inorganic substances and leaching away the inorganic matter.
Mixing organic matter such as sawdust.
Carbonizing wood, sawdust, and the like, followed by activation with hot air or steam.
• They are used the decolorizing of solutions of sugar, industrial chemicals, drug, and dry-cleaning
liquids, water purification, refining of vegetable and animal oils, and in recovery of gold and silver
from cyanide ore-leach solutions.
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7. Gas-adsorbent carbon :
• This is made by carbonization of coconut shells, fruit pits, coal, lignite, and wood.
• It is used for recovery of solvent vapor from gas mixtures, gas masks, collection of gasoline
hydrocarbons from natural gas, and fractionation of hydrocarbon gases.
8. Molecular-screening activated carbon :
• This is a specially made form with pore openings controlled from 5 to 5.5 Å.
• The pores can admit paraffin hydrocarbons.
• It is useful in fractionating acetylene compounds, alcohols, organic acids, ketones, aldehydes, and
many others.
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APPLICATIONS :
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REFERENCES :
1. “ Mass Transfer Operations “ , Robert E. Treybal, McGraw Hill Education Pvt. Ltd., Third
Edition, Adsorption and Ion Exchange, Page no. 565-569.
2. www.slideshare.net/reddyas/adsorption.
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