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Documente Profesional
Documente Cultură
SUPRAJA RANI
I MDS
CONTENTS
INTRODUCTION
HIISTORY
CLASSIFICATION OF DENTURE BASE RESINS
PHYSICAL PROPERTIES
HEAT ACTIVATED RESINS
CHEMICALLY ACTIVATED RESINS
MANIPULATION AND ACRYLIZATION TECHNIQUES
LIGHT ACTIVATED RESINS
MICROWAVE CURED RESINS
TRAY MATERIALS
DENTURE LINERS
RECENT ADVANCES
CONCLUSION
REFERENCES
INTRODUCTION
a sound foundation,
similarly for fabricating long lasting,
esthetically and biologically acceptable dentures
Disadvantages –
-esthetic and
hygienic challenges
-degradation in oral
environment
believed to be carved out of
box wood in 1538 by
Nakoka Tei a Buddhist priest
bone
Fauchard fabricated dentures by
measuring individual arches with a
compass and cutting bone to fit the
arches
ADVANTAGES :
better dimensional stability than
wood, esthetic and hygienic
concerns remained
IVORY
Denture bases and prosthetic teeth were
carved in this material to desired shape
ADVANTAGES :
• Relatively stable in the oral
environment
• Esthetic and Hygienic
DISADVANTAGES:
• Not available readily
• Relatively expensive.
PORCELAIN
1788 A.D.
development of porcelain
dentures by De Chemant
1864
NELSON GOODYEAR (brother of
Charles Goodyear) got the patent for
vulcanite dentures
Vulcanite dentures were very
popular until the 1940s
BAKELITE
1909
Dr. Leo Backeland formed BAKELITE by heating and
compressing a mixture of phenol and formaldehyde
Disadvantages:
Lack of uniform quality
Variable strength & color
Dimensional instability
POLYVINYL CHLORIDE
1930
Flexible
Mouth guards and denture liners
Drawbacks – distortion , discoloration
Polymethyl methacrylate
1937
By Dr. Walter Wright and Vernon brothers
CLASSIFICATION OF DENTURE BASE POLYMERS
According to ISO 1567
TYPE CLASS DESCRIPTION
4 - Light-activated materials
5 - Microwave-cured material
Applied dental materials, 9th Edition, John .F.Mc Cable & Angus W.G. Walls
CLASSIFICATION
According to mode of polymerization:
Location :
likley to develop in thicker portions of a denture base
4. Air inclusions :
Most commonly associated with fluid resins
Due to air inclusions incorporated during mixing and pouring
HOW TO PREVENT :
careful mixing, spruing and venting
Water absorption
Water sorption of polymethyl methacrylate : 0.69 mg/sq.cm
Resaon :
Stress relaxation
Dissolution by a solvent ( prolonged contact with ethyl alcohol)
Tensile stresses
HOW TO PREVENT : use of cross linked resins and cross linked resin
teeth
HEAT ACTIVATED RESINS
COMPOSITION :
COMPONENTS FUNCTION
Pre polymerized Poly Methyl
Methacrylate ( PMMA) polymer
POWDER
Benzoyl Peroxide (0.5%) Initiator
5 distinct stages :
STRINGY STAGE :
Monomer attacks the surface of polymer beads
Polymer chains uncoil , increasing viscosity of the mix
CONSISTENCY : STRINGY or STICKY
DOUGH STAGE :
More no of polymer chains are dissolved in monomer
Large no of undissolved polymer also remains
Therefore, behaves as a pliable dough
STIFF STAGE :
Upon standing for longer period , monomer evaporates and the mass
becomes stiff
The mix appears very dry, and is resistant to mechanical deformation
TYPES OF POLYMERIZATION
CONDENSATION POLYMERIZATION
ADDITION POLYMERIZATION or STEP-GROWTH
INDUCTION • ACTIVATION
• INITIATION
PROPAGATION
CHAIN TRANSFER
TERMINATION
INDUCTION
ACTIVATION INITIATION
Free radicals are produced by The free radicals bond to one side of
activation of a chemical activator, the monomer molecule and forms a
heat, visible light, UV light new free radical site at the other end
Termination
Ivocap flask
Pressure apparatus
IVOCAP predosed Injection of resin & flask placed Placing into water bath
into clamping press
capsules
ADVANTAGES : DISADVANTAGES :
COMPONENT FUNCTION
PolyMethyl polymer
POWDER Methacrylate
DIMETHYL-
PARA- ACTIVATOR HEAT
TOLUIDINE
+
BENZOYL
PEROXIDE BENZOYL
PEROXIDE
DISADVANTAGES
ADVANTAGES
Sprinkle-on method
Finger adaptation dough method
Fluid resin technique
sprinkle-on method
FINGER ADAPTATION METHOD
FLUID RESIN TECHNIQUE
FLUID RESIN TECHNIQUE
ADVANTAGES: DISADVANTAGES:
Camphorquinone - initiator
commercially available light cure denture base resins
GC ACRON MC
Nature-cryl MC
FLASKS – not made of metal
INVESTING MATERIAL :
Denture liner
Heat polymerized
silicone
Acrylic
Auto polmerized Permanent soft temporary soft
acrylic resin
liner liner (tissue
Heat polymerized
conditioner)
acrylic resin
TISSUE CONDITIONERS
POLYMER ( powder) :
polyethyl methacrylate, polymethyl metacrylate,
sillicone rubber, poly ‘n’ propyl-methacrylate, poly’n’ butyl methacrylate
MONOMER (liquid):
Mixture of aromatic ester and ethyl alcohol
Based on composition:
Silicone elastomers
Soft acrylic compounds
Phthalate ester free compounds
Polyolefin liners
Fluoride containing liners
Based on durability :
Temporary or short term liners
Definitive or long term liners
Based on consistency:
Hard denture liners – Ufigel hard C
Soft denture liners - silicone based/
resin based
-self cured/
heat cured
Based on availability :
Home liners
Tissue conditioners
2. Hypoallergenic resins
4. Thermoplastic resins
CLINICAL APPLICATION:
DISADVANTAGES:
1.UNESTHETIC
2.EXPENSIVE
3.POOR BONDING WITH ACRYLIC( PMMA)
4.CORROSION PRONE
CARBON/GRAPHITE FIBRE REINFORCEMENT:
DISADVANTAGES:
Unesthetic because of black colour but this can be covered by an
opaquer.
The polishing is difficult & also weakens the finished prosthesis
POLYETHYLENE FIBER
REINFORCED
DISADVANTAGE :
decreased transverse strength
finishing and polishing is difficult
does not bond well to resins
HIGHLY DRAWN LINEAR POLYETHYLENE FIBERS (HDLPF) :
Thus mandibular bases are reinforced with fibers at right angle to ridge
located close to polished & fitting surface
ADVANTAGES :
high tensile stiffness & strength
cracks do not propagate through array of fibers.
The coherence is maintained even after a large number of
testing cycles
GLASS FIBRES (HAVE BEST
AESTHETICS)
MATERIALS USED:
THERMOPLASTIC NYLON
THERMOPLASTIC ACETAL
THERMOPLASTIC ACRYLIC
THERMOPLASTIC
POLYCARBONATE
ADVANTAGES:
• excellent esthetics
• unbreakable ,flexible, light weight
• stable ,high fatigue endurance
• increased creep & wear resistance
• non porous: no bacterial growth but retains enough moisture to
keep it comfortable for gums
• can be relined and repaired
THERMOPLASTIC NYLON
polyamide(valplast,flexiplast)
translucent
tissue colored clasps instead of
metal clasps
unbreakable & lightweight
flexible in nature
difficult to polish and adjust
not strong enough for normal
tooth borne rest seats
eg: VALPLAST,
LUCITONE FRS(more impact
resistance)
THERMOPLASTIC ACETAL - POLYOXYMETHYLENE
APPLICATION :
preformed clasp for RPDs
partial denture framework
provisional bridge
occlusal splints
THERMOPLASTIC ACRYLIC
EXCEPTION:
FLEXITE AND MP-a –highest impact resistance among acrylics
very popular in bruxism and parkinsonism patients
THERMOPLASTIC POLYCARBONATE:
POLYMER OF BISPHENOL- A
CLINICAL ADVANTAGE :
minimal residual monomer------can be used in allergic patients
very little water absorption---------less smell and bacterial growth
good adherence and coherence
ENIGMA GUM TONING
ACCUDENT SYATEM:
• EDENTULOUS TRAYS
• SYRINGE MATERIAL
• TRAY MATERIAL
Centric tray
final impression and jaw relations:
Inraoral tracers
Final impressions
Bite registration
Special features of BPS denture material:
New materials and techniques help clinicians to provide quality care for
the patients
references
PHILLIPS’ science of dental materials- 11th edition – ANUSVICE
Applied dental materials, 9th Edition, John .F.Mc Cable & Angus W.G. Walls
Evolution of denture base materials- S. K. Khindria, Sanjeev Mittal, Urvashi Sukhija, The Journal of
Indian Prosthodontic Society / April 2009 / Vol 9 / Issue 2
COMPLETE DENTURES - THE BPS WAY- Dr. Abby Abraham Dr. Deepika Lakshmi R.