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Engineering Course
7. Gas Handling
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 1
Units and Standard Conditions
Common Gas Units
mmscf, MMSCF, MMCF - one million standard cubic feet
BE CAREFUL!
In English units MM means million
In metric units M means “mega” or 10^6
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 2
Gas Handling
• Gas Management
1st Stage 2nd Stage Export
Compression Compression Compression
– compress to export gas to market Export
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 3
Compressors
Axial Compressor
Centrifugal Compressor
Reciprocating Compressors
Screw Compressor
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 4
Centrifugal Compressor
Vertical Split
Horizontal Split
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 5
Flow through Centrifugal Compressor
Discharge
Diffuser
Minimum width of
suctio last impeller passage
n is ~ 4mm
Inlet guide
vane
Seal Chamber
• Reciprocating: • Centrifugal:
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 7
Centrifugal Compressors
• Operation and Control – Compressor Operation Characteristics:
– Variable speed
– (Inter) cooling
– Blowdown Inlet Volumetric Flowrate
“Stonewall” or choked flow occurs when sonic velocity is reached at any point in
the compressor. When this point is reached for a given gas, the flow through the
compressor cannot be increased further without internal modifications.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 9
Anti-Surge Control
• Anti-Surge Control Systems 100
Head
50
at differing speeds gives surge control line 45
40
of the form y = mx + c. Recycle valve 35
30
modulated to ensure operating point is not 25 SOL RTL
Minim um Flow
20 Control Line
to the left of this line. Simple and robust. 15 Surge Lim it
Surge Control Line
10 Line
– CCC control. Uses two additional lines 5
0
Allows more efficient (closer to surge limit 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90
Flow
line (SLL)) and responsive control
• Surge Control Line (SCL). Uses PI control to manage normal load changes.
• Recycle Trip Line (RTL). Aggressive control, acts as flow approaches surge line. Recycle valve opened in
steps by timer delay until RTL is re-crossed when PI control is reactivated. Should never be re-set.
• Safety On Line (SOL). If SOL is crossed surge is assumed to have occurred. Incident is logged and the
controller moves all control lines to the right. Can be re-set (after investigation into incident cause).
– CCC uses deviation (DEV) between operating point and SCL to determine compressor status.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 10
Centrifugal Compressors
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 11
Reciprocating Compressors
Piston reciprocating compressors are the most common type of positive displacement
compressors. They are available both in single and double-acting design in various
configurations.
Gas is drawn into the cylinder usually through a self-acting valve which is opened and
closed by pressure difference. After compression, the gas leaves via a self-acting
discharge valve. The valve is comprised of a seat, valve guard, plates and springs. The
plate moves between the guard and seat aided by the springs which help to accelerate
closure. The valve is fully open when held against the guard and fully closed when held
against the seat. Some less common designs have cam-controlled or rotary slide valves.
More detail on valves is given later.
Other types of positive displacement compressor are oil-free labyrinth piston compressors
(no piston rings are fitted, the cylinder wall to piston seal is achieved by labyrinth seals)
and diaphragm compressors.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 12
Reciprocating Compressors
Single-acting Double-acting
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 13
Reciprocating Compressors
Single-acting
Compression occurs only on one side of the piston and only once per revolution of the
crankshaft. These machines are normally referred to as trunk type compressors.
Examples of cylinder layouts are shown on the next slide. Single-acting compressors
are usually of the enclosed type where the piston is directly driven by a connecting rod
working off a crankshaft, both of which are enclosed in an externally pressure-tight
crankcase.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 14
Reciprocating Compressors
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 15
Reciprocating Compressors
Double-acting
Compression occurs alternately on both sides of the piston, twice during each revolution
of the crankshaft. These machines are normally referred to as crosshead type
compressors. Examples of cylinder layouts are shown on the next slide.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 16
Reciprocating Compressors
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 17
Reciprocating Compressors
Compressor Construction • The three most common suction and
discharge valves in reciprocating
• Number of cylinders ranges from 1 – 16 compressors are
– The poppet valve, a cage serves as both
• Where 4 or more cylinders are used a V, a valve seat, stem guide and spring
W or radial arrangement is used. retainer. A spring, dashpot or bleeder
• Compressor cylinders are normally cast arrangement is used to limit and damp
in close-grained iron. Larger valve travel. These are slow response
valves and only used on slow speed
compressors will usually be fitted with compressors.
a replaceable cylinder liner.
– The ring plate valve was described
• Two types of piston are commonly earlier.
used, automotive and double-trunk. – Flexing valves vary in design but
Automotive type pistons are used where typically would consist of a seat, ribbon
the suction valves are located on the strips and a valve guard. This type of
cylinder head and double-trunk where valve is the feather valve. The ribbon
the suction gas enters through ports in strips or reeds flex under pressure and
the cylinder walls. as for the ring plate Valve operates
under pressure difference
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 18
Reciprocating Compressors
• Crankshafts in larger compressors are of the
crank-throw type. These are mainly
fabricated from forged steel or alloy cast iron.
Smaller compressors tend to use an eccentric
shaft.
• Bearing journals are highly polished and case
hardened where aluminium or brass bearings
are used. Usually plain bearings are found on
crankshafts, however, main bearings can be
of the roller or ball anti-friction type.
• In order to prevent leakage of gas (and oil)
from the crankcase or air into the crankcase it
is common to fit a self adjusting seal. The
spring loaded seal nose is held hard against
the polished seal plate. An oil film between
the two provides a gas-tight seal. The nose is
sealed to the crankshaft by the rubber gasket
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 19
Reciprocating Compressors
Compressor capacity control
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 20
Reciprocating Compressors
Compressor Performance
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 21
Reciprocating Compressors
The compression cycle
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 22
Reciprocating Compressors
The cycle is shown on the theoretical
time-pressure diagram. At point A the
piston is at top dead centre. The
pressure is maintained by the gas in the
clearance space holding the valves
closed. On the suction stroke from A-B
the pressure is reduced as the gas
expands to point B. Here, the gas in the
suction line is at a higher pressure than
the cylinder and the suction valves
open. From B-C the cylinder is filled
with gas at suction pressure until point
C when the suction valves close usually
under spring action. Compression takes
place from C-D. At point D the
pressure in the cylinder is higher than
the gas in the head of the compressor
and the discharge valves open. Gas
flows until the piston reaches point A
again and the cycle is complete with the
crankshaft having completed one full
revolution
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 23
Reciprocating Compressors
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 24
Reciprocating Compressors
Volumetric efficiency
ηv= Volumetric efficiency (%)
The actual volume of gas transferred Vact = actual volume of suction gas
from the suction line is the actual compressed per unit time
displacement of the cylinder. The ratio Vp = compressor piston displacement
of this actual displacement to piston
displacement is known as the total
volumetric efficiency of the compressor
Vact
V x 100
Vp
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 25
Reciprocating Compressors
Effects of clearance
When the piston has reached the end of the compression stroke, some gas is retained in the
clearance space in the cylinder after the discharge valves have closed. When the
compression cycle restarts, there is already a volume of gas in the cylinder which re-
expands and reduces the available volume for suction gas. Referring back to the pressure-
volume diagram, the clearance volume and re-expanded gas volume are shown as Va and Vb
respectively. Obviously, as the clearance volume increases, the volumetric efficiency
reduces.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 26
Reciprocating Compressors
Wiredrawing
As gas passes through the suction valves a mild throttling takes place which means that
the cylinder is at a slightly lower pressure than the suction line and thus less volume of
suction gas is transferred than if the gas was at suction line pressure. This reduces the
volumetric efficiency of the compressor as the actual volume of suction vapour
transferred is reduced. Wiredrawing is independent of compression ratio being a
function of gas velocity through the valves and passages of the compressor. As velocity
increase the effects of wiredrawing increase. The gas velocity is dependent upon valve
characteristics, the gas and the speed of the compressor. As the compressor rpm
increases so does the piston displacement and velocity of the gas passing through the
valves. This in turn amplifies the effects of wiredrawing.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 27
Reciprocating Compressors
Cylinder heating Piston and valve leakage
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 28
Reciprocating Compressors
Isothermal versus isentropic compression
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 29
Reciprocating Compressor
Suction
Con-rod Distance
Valves
Piece
Crank
Piston
Discharg
Crosshead Wiper Packing e Valves
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 30
Screw Compressors
Screw compressors are positive
displacement compressors. Twin screw
machines compress gas between two
meshing helically grooved rotors.
Single screw machines have a single
screw which meshes with two gate
rotors.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 31
Screw Compressors
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 32
Screw Compressors
Single screw compressors consist of a
single screw with two gaterotors. Gas
flows through the suction port into the
exposed grooves at each end. With
rotation, gaterotor teeth enter and seal
the grooves in the screw sequentially
trapping gas in the chambers. The gas
is continually compressed until the
leading edge of the screw passes the
discharge port. Gas is then discharged
until the gaterotor reduces the effective
volume to zero. Since there are two
gaterotors, the compression process
occurs twice per revolution thus
doubling the capacity of the machine.
1- gaterotor
2- screw rotor
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 33
Screw Compressors
Capacity Control Mechanism
Capacity control is accomplished by a slide valve which moves parallel to the rotor axis and
changes the area of the opening in the bottom of the rotor casing. This, in effect, lengthens or
shortens the region of compression of the rotor and further acts to return gas to the suction side,
while bypassing compressed gas. Variable speed drives can also control the capacity.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 34
Screw Compressors
Compressor Performance
Dynamic compressors use terms such as polytrophic head and temperature lift to describe their
performance capabilities. These are not normally applied to positive displacement machines, screw
compressors are usually described in terms of pressure ratio.
This may be a fixed ratio or a variable ratio where a slide valve is installed as described above fro capacity
control.
P2 Pressure at discharge
Pressure ratio i
P1 Pressure at suction
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 35
Screw Compressors
The isentropic relationship between the volume and pressure ratios described in
equation 2 of the section on Compression Thermodynamics.
Screw compressors are normally high speed rotating machines and as such due to the
short residence time of the gas during compression, the process is generally regarded as
reversible adiabatic.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 36
Compressor Selection
• Recip.-multi stage:
– Gas export / reinjection
• Recip.-single stage:
– Fuel gas compression
• Diaphragm:
– Oil free (air) compression
• Rotary compressors:
– Air (vacuum) systems
• Centr. Single stage:
– Gas pipeline boosting
• Centr. Multi stage:
– Gas export / reinjection
• Axial:
– Pilpeline boosting
– Air separation
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 37
Compressor Selection
Is the discharge volume flow
greater than 300m3/h
YES NO
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 38
Compression Thermodynamics
• The basic thermodynamic
H Enthalpy change (kJ)
equation for compression is: H VdP Wtheor [1] V Gas volume (m3)
P Pressure (kPa)
WtheorTheoretical work done (kJ)
• For the isentropic
P V k const P1 V1
k [2] k Ratio of specific heats (Cp/Cv)
compression process: m Mass (kg)
Z Compressibility factor (-)
P2
1 R Gas constant
• Substitution of [2] into [1] H P1 k V1 P
1
k
dP [3] (=8.314 kJ/kmol.K)
yields: P1 T Temperature (K)
1 MW Molweight (kg/kmol)
P k V1 k 1
P2 k P2 k
k 1
• or (solving): H 1 [4]
k 1
k
k 1
P1 V1
P2 k
• Equation [4] is rewritten as: H 1 [5]
k 1 P1
k
k 1
m Z1 R T1
P2 k
• Substitution of the ideal gas H 1 [6]
k 1
MW 1
P
law into [5] yields:
k
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 39
Compression Thermodynamics
k 1
Z a R T1 P2 k
• Equation [6] (previous slide) is usually written as: H isen 1 [7]
k 1
MW 1
P
k
which is the basic “head” equation for compressors, in which Z a is the average compressibility
((Z1+Z2/2)) and Hisen is the isentropic head (in kJ/kg). For the isentropic head in meters:
1000 H isen kJ / kg
H isen meters
g 9.81
• In a steady state situation the entropy change in a system is written as: S = Q/Tb + Sp [8]
in which Q is the heat exchanged with surroundings, T is the absolute temperature of the system
boundaries and Sp is the entropy production, reflecting the irreversibility of the process.
• P n m h poly
Centrifugal Compressors T2 T1 2 W
– cover a wide operating range P1 E poly
– n 1 k 1
extensive use in upstream oil & gas
industry n k E poly
– main suppliers For paraffin gases k may be estimated from:
• Dresser
k = 1.3 - 0.31 ( - 0.55)
• Nuovo Pignone
• Sulzer hpoly Polytropic head (kJ/kg)
T Temperature (K)
– good reliability compared to Za Average compressibility (Z1 + Z2)/2
reciprocating machines R Gas constant (8.314 kJ/kmol.K)
– not suitable for high head low flow P Pressure (Pa)
n Polytropic coefficient
applications
k Ratio of specific heats (Cp/Cv)
– compression ratio limited by discharge MW Molweight (kg/kmol)
temperature, in turn defined by materials W Gas power (kW)
m Mass flow (kg/s)
– Head equation:
n 1
Epoly Polytropic efficiency - Function of
T1 Z a R P
2 1
n volumetric inlet flow varying from approx.
h poly
n 1 P1 0.6 to 0.8 (compressor specific)
MW Gas relative density (-)
n 1/2 Suction/Discharge
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 41
Calculation Example
• 10 MMscfd of hydrocarbon gas (MW = 22.0 kg/kmol) is or Hpoly = 175.5 * 1000 / 9.81 = 17890 m
compressed from 4 bara to 15 bara. Calculate the required
3.0 175.5
compressor power and discharge temperature. The W 700 kW
polytropic efficiency of the compressor is 75%. Za = 0.98. 0.75
1.331
T1 = 30oC
15 1.33
T2 303 421 K 148o C
4
• Rule of thumb: 1 MMsm3/day = 1739 kmol/hr
10 MMscfd = 0.283 MMsm3/day = 492 kmol/hr • If the same compressor were to compress a heavier gas, e.g.
MW = 30, what would be the discharge pressure?
Mass flow: 492 * 22 / 3600 = 3.0 kg/s
• The head is unaffected, because the head is only dependent
on impeller (tip) speed:
Specific gravity: 22.0 / 28.96 = 0.76 1.33 1
1.331 175.5 30
P2 1.33
1.33
Ratio of specific heats (estimated): 1 P2 22 bara
4 303 0.98 8.314
k = 1.3 - 0.31* (0.76 - 0.55) = 1.23
• The required power would be: 700 * (30/22) = 955 kW
Polytropic coefficient:
• Note that the compression ratio is usually limited to 4
n 1 1.23 1 (although can be higher for high MW gases). If the
0.25 n 1.33
n 1.23 0.75 compression ratio is higher then 4, more stages are required
(with intercooling). The number of compression stages (r) can
1.331
303 0.98 8.314 15 1.33
1 175.5 kJ / kg
be estimated from:
h poly
1.33 1 ln P2
1
4 P2 r
22.0
r
4 or P1
1.33 1
P ln 4
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 42
Centrifugal Compressor
Design
• Mechanical design undertaken by machine supplier
• Design will account for;
– Thermodynamics • Specific speed:
– Aerodynamics
N q 0.5
– Rotor Dynamics Ns
– Stress/loads H 0.75
• Process engineer will specify;
N speed (rpm)
– Number of stages
q volumetric flowrate ft3/s)
– Flowrate
H head (ft)
– Gas Composition
– Inlet Pressure and Temperature
– Discharge Pressure • Specific diameter:
– Range in volumetric rate
d H
0.25
– Range in molecular weights
ds 0 .5
• Major Design Variables q
– Speed
d impeller diameter (ft)
– Impeller Diameter
– Number of impellers
– Impeller Design
– Head per impeller
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 43
Centrifugal Compressor
Train Design
1st Stage 2nd Stage Export
Compression Compression Compression
Export
Gas Lift
Re-injection
Gas from Lean Glycol
Separators
Dehydration
Column
Rich Glycol
Suction 60 80 80 Dehydration
Temperature Column
(DegF)
NGLs NGLs NGLs
Discharge 275 638 2500
Pressure (psia)
Rich Glycol
Compression 5 2.5 4.2
Ratio
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 45
Centrifugal Compressor
Train Design Sensitivity study at three speeds – 5000, 8000 and 14000 rpm .
Compressor 1st Stage 2nd Stage Export Compressor 1st Stage 2nd Stage Export
5000 rpm 8000 rpm
No Impellers 4 3 8 No Impellers 4 3 8
Impeller Diameter 2.94 2.68 2.49 Impeller Diameter 1.95 1.68 1.548
(Ft) (Ft)
Head (Ft) 40200 25690 57729 Head (Ft) 40200 25690 57729
Specific Speed 87.3 49.3 30.1 Specific Speed 139.6 78.9 48.1
Power (KW) 7800 5930 8700 Power (KW) 7860 4800 7550
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 48
Driver Selection
Is gas fuel
Yes available on
site?
No
Is dual fuel
capability
required? No
Yes
No No No
No No No
Consider gas Consider dual fuel Consider gas Consider gas Consider gas Consider diesel
turbine engine turbine engine turbine engine
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 49
Cooling / Scrubbing / Compression
Cooler Compressor
NGLs to separation
Scrubber
• Compression will heat the gas and therefore requires (interstage/after) cooling to reduce power and
also to avoid exceeding discharge temperature limits
• Cooling of the saturated vapour to compressor inlet conditions causes condensation of heavier
components and water
• Leaner gas from scrubber with reduced cricondenbar
• Cooler outlet temperature typically 25-30 DegC set by hydrates, cooling medium temperature, and
heat of compression from upstream compressor
• NGL recycle can significantly affect system heat and mass balance
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 50
BP Amoco North Sea Assets
Compressor Inventory
BP Amoco North Sea Assets– Compressor Inventory
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 51
BP Amoco North Sea Assets
Compressor Inventory
Harding LP (1st) 1 x 100% Demag 8B22 D? EM
HP Gas Lift/Reinj 1 x 100% Demag 6B22 D? Same shaft
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 52
BP Amoco North Sea Assets
Compressor Inventory
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 53
Hydrate Formation
• Presence of water in gas transportation system may result in Pressure-Temperature Curves For
hydrate formation and/or corrosion Predicting Hydrate Formation
• Hydrate Formation
– presence of free water
– low temperature
– high pressure
– C1-C4 parrafins
• Corrosion
– partial pressure H2S/CO2
– temperature
– water pH
• Formation boundary estimated by;
– charts (on right)
– Katz K Values
– equations of state
• modules within most commercial simulators
Note that this figure should only be used for first
approximations of hydrate formation conditions
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 54
Hydrate Curves
120
100
80
Pressure (bara)
60
40
20
0
-50 -40 -30 -20 -10 0 10 20 30
Temperature (deg C)
0% Methanol 10% Methanol 20% Methanol
30% Methanol 40% Methanol
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 55
Hydrate Inhibition
• Formation boundary suppression • Hammerschmidt gives good results at low
– methanol inhibitor concentrations (but errs on the
– glycol conservative side):
– threshold hydrate inhibitors – MeOH < 25 wt%
– MEG < 15 wt%
• Empirical Hammerschmidt equation for
prediction of the necessary inhibitor • The total inhibitor injection rate is found
concentration: d Mi from:
X 100
Ki d M i
XR
• X Weight percent of inhibitor in the mI mW
liquid water phase (wt%) XL XR
d Depression of hydrate point (oC)
mI mass of inhibitor solution (kg)
Mi Molweight of inhibitor
mW mass of liquid water (kg)
Ki Constant: XR rich inhibitor concentration (out) (wt%)
1297 for methanol XL lean inhibitor concentration (in) (wt%)
2220 for glycols
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 56
Equilibrium Charts
Vapour-Liquid Equilibrium of Methanol over Water Water Content of Sweet Lean Natural Gas
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 57
Inhibition Worked Example
• 10 MMscfd (2.83*105 stm3/d) of natural gas ( = 0.65) • Calculate the required mass of methanol in water:
having a hydrate formation temperature of 21.1oC cools to
4.4oC in a buried pipeline (pressure is 6.2 MPa). How 29.2
mMeOH 181 75 kg / day
much methanol ( = 800 kg/m3, MW = 32) must be added 100 29.2
if the gas enters the line saturated at 32.2oC and what is
the rate of injection ? • Calculate the methanol loss to the vapour phase using the
vapour-liquid equilibrium chart (4.4oC, 6.2 MPa):
X MeOH 100
16.7 32 29.2 wt % 215 / 0.8 = 269 liter/day
1297 16.7 32
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 58
Hydrate Inhibition
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 59
Gas Dehydration Technologies
Dehydration Method Dewpoint BP Amoco Assets Typical Equipment Cost
Depression (not installed)
o
C $k/MMscfd
Glycol Injection 35 – 40 Cleeton 3.2
Glycol Absorption 35 – 55
Forties Bravo, Gyda,
Glycol Absorption 55 – 78
Magnus 5.8
(with stripping gas)
DRIZO 70 – 85 Bruce
Adsorption 50 – 90 Ula, Miller, Clyde,
8.4
Wytch Farm
Membranes 80 – 90 cheaper than DRIZO; ETAP
Endicott (small unit)
study; 30% cost & weight
Easington (test rig)
savings
IFPEX-1 90 East Gilby Gas Plant ETAP-study; cost savings of
(Petro-Canada), over 60% over conventional gas
Markham Gas Plant processing (glycol, turbo-
(Marathon) expander)
Vortex Tubes 25 – 60 Erskine-study; 10-20% overall
topsides cost saving over
conventional processes
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 60
Gas Dehydration
• Glycol/Methanol Injection Comparison of Dehydration Methods
Method Gas Specification Gas Specification Remarks
(ppm v/v) (lb/MMscf)
• Glycol Contacting TEG Contacting 20 1
Atmospheric regeneration
Min. contact temp 15-26oC
– simple 5 0.25
Vacuum regeneration and
gas stripping
• Membranes
– new technology
Membrane Separator for Natural Gas Dehydration
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 61
Glycol Injection
Glycol injection (usually MEG) can be used either to protect against hydrate
formation in transmission lines from offshore facilities or upstream of gas
refrigeration systems on onshore treatment plants. Glycol injection is
possibly the simplest method of dehydrating natural gas, as in its simplest
format it consists of an injection pump and injection point(s). If required,
the injected glycol can be recovered in a glycol still where the absorbed
water is driven off from the glycol. It is always economic to recover glycol
from a continuous process.
The glycol can be injected into the pipeline or into various sections of the
unit upstream of the chilling facilities. Spray nozzles are used to ensure
good dispersion into the gas the chilling facilities. Spray nozzles are used
to ensure good dispersion into the gas phase. As the gas is cooled and
water condenses, the glycol dissolves in the water phase. The gas and
liquid phases are separated downstream in one or more separators as the
gas is processed further. The glycol water mixture is drawn off and sent to
the glycol regeneration unit. The flow description and facilities are very
similar to the glycol regeneration unit described in the conventional glycol
absorption system.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 62
Glycol Injection
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 63
TEG Dehydration/Regeneration
Water Vapour
PC (+ some HC, BTX) Drizo® (aromatic, naphtenic, paraffin mixture) Vent
Stripping Gas
low HC/BTX
Rich TEG Cooler (Air/Water)
Dry Gas
Still
Column
Flue Glycol/Glycol
dehydrati gas Exchangers
on.exe Reboiler
Water
LC
Drizo®
Wet Gas
Coldfinger®
LC
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 64
Drizo Refit on Ekofisk
Prosernat France
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 65
Glycol Contacting
• Water is absorbed into glycol in a bubble tray • Contactor design:
or packed counter current contactor 0.5
G
vmax K s L
G
• For tray type contactors a minimum spacing of
24” is recommended to prevent the formation vmax Maximum allowable superficial gas velocity (m/s)
Ks Constant (m/s)
of stable foams between trays and to allow for
0.0488 for 24” tray spacing and 2” seal
a suitable liquid level in the downcomers over bubble cap slots
0.1 for structured packing
L Density of TEG (kg/m3)
• Structured packing types:
G Density of gas (kg/m3)
– Mellapak, Montzpak, Flexipak, Gempak
– Advantages of structured packing:
• smaller diameter tower (cheaper) • Contactor designs available form key suppliers
• better mass transfer
– Natco
• no leak problems on trays
• not very sensitive to motion – Robert Jenkins
– BS&B
• Number of actual trays usually between 4 - 8 – Kvaerner Paladon
– Latoka
• TEG circulation rate (rule of thumb): – KCC
20-40 liter TEG / kg H20 absorbed – Allen Tank
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 66
Absorption
Glycol rate
Water content
Glycol purity Multiple variables
Know gas rate and required outlet water content
Outlet water quality sets inlet (lean) glycol purity
Glycol circulation rate set by equilibrium calculations
Tower diameter normally established by entrainment
limits
Vessel Packing height from packing characteristics
Diameter
Reboiler duty from heat balance - latent and sensible.
Packing
height
..\..\Simulations\GLYCOL
MODEL.HSC
Gas rate
Glycol purity
Water content
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Packing Characteristics
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 68
Trays
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Packings
Random Packing
Sulzer Mellapak® Koch-Glitsch
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Distributors / Collectors
Distributors
Collectors
Sulzer Type SLMT Sulzer Type SLR
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Upthrust Damage
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Water Dewpoint /
Lean TEG Concentration
• The achievable water dewpoint from the glycol
contactor depends on the inlet lean TEG Minimum Lean TEG Concentration
concentration (equilibrium)
• It is normal practice to take the desired dewpoint
5-10oC below the equilibrium dewpoint (approach)
as equilibrium will not be reached in a contactor.
• Problem:
What should be the concentration of a lean TEG
solution achieving an equilibrium dewpoint of
-15oC in a contactor operating at 30oC ?
• Solution:
To be on the safe side, an approach of 10oC is
subtracted Equilibrium dewpoint is -25oC
From the chart on the right, read the lean TEG
concentration at the intersection of the dewpoint
line and the contactor temperature line:
Lean TEG concentration: 99.4 wt%
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 73
Gas Dehydration
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 74
Glycol Dehydration / Regeneration
• Glycol Regeneration Methods:
– Coldfinger® using a cooling element in the surge tank to condense water, thus
reducing the water partial pressure in the vapour space and increasing the lean glycol
concentration
• glycol concentrations of > 99.4 wt% can be achieved without the use of a stripping gas
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 75
Glycol System Operating Issues
Hydrocarbon Content - If hydrocarbons are present, the unit may be subject to foaming and the formation of gummy or tarry
deposits in the reboiler, heat exchangers, and absorber.
Corrosion - A glycol pH of less than 6 indicates a potentially serious corrosion problem with the system.
A simple visual inspection of the glycol can provide clues for identifying many glycol problems. The following conditions can
indicate major problems:
The presence of a finely divided black precipitate is the result of iron corrosion.
A black viscous glycol solution may be the result of heavy hydrocarbon contamination or glycol
polymerization due to thermal breakdown or interaction with hydrocarbons.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 76
Adsorption - Molecular Sieves
• Adsorption of water onto solid molecular • An adsorbent material should have the
sieve dessicant following characteristics:
• Material categories (alumino-silicates): – large surface area
– bauxite – “activity” for components to be removed
– alumina – high mass transfer rate
– silica gel – easily and economically regenerated
– molecular sieves – good activity retention with time
• Batch process on timed cycle – small resistance to gas flow
– high mechanical strength
• One bed on stream other under regeneration
– cheap, non-corrosive, non-toxic, chemically
• Key vendors: inert, high bulk density
– UOP (Alumina, Molecular Sieves) – no appreciable change in volume during
– W R Grace (Silica Gel, Molecular Sieves) adsorption desorption
– Rhone-Poulenc (Alumina, Molecular Sieves)
– Solvay (Silica Gel)
– Kvaerner Process Systems (Equipment)
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 77
Molecular Sieve System
PC
FC Sequence Condensate
Controller Separator
Cooler
Heater
LC
Cooling
Heat
TC Cool
Regeneration
Molecular Molecular
Drying
Sieve Sieve
Cooling adsorber adsorber
Drain
Heating
Cool
Heat
Dry Gas Outlet
Filter
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 78
Operating Characteristics
Dry Desiccant Dehydration
• Recommended Operating Range:
– T < 50oC
– T > Hydrate point
• Desiccant Service:
– 3 - 5 years in absence of poisoning. Limited by loss of capacity, dusting and
breakage
• Dehydration Obtained:
– Essentially bone dry gas. Dewpoint: -75 to -125oC (Silica Gel: -60oC)
• Length of Cycle:
– Varies with water loading and gas rate: 4 - 24 hours
• Regeneration:
– Temperature: 175 - 300oC. About 5 to 15% of the total gas stream is used for
regeneration. 8 hour cycle: 6 hours heating, 2 hours cooling
• Advantages: • Disadvantages:
– Low exit dewpoint – High initial investment
– Effective dewpoint depression over a wide range of – Desiccant sensitive to poisoning
operating conditions – Rated capacity declines with pressure
– Compact – Pressure drop is higher than liquid desiccant systems
– Relatively low initial investment for small amounts – Regeneration heat load can be high in relation to the
of gas (batch or semi-batch operation) amount of gas processed
– Rated capacity may be increased by by-passing some
wet gas
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 79
Molecular Sieve - Design Rules
• Preliminary sizing rules: Maximum Superficial Velocity
– Sieve bed quantity: 10 kg sieve/kg water adsorbed
– Bulk density (average): 722 kg/m3
– The bed height is calculated from the quantity of
sieve bed required (above)
– The bed diameter is calculated from the gas
maximum superficial velocity (chart on the right)
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 80
IFPEX
Gas dehydration can be achieved by chilling a gas stream to low temperatures in order to remove water down to a level which
is equivalent to the specified water dewpoint. One complication of such a process is the need for a hydrate inhibitor to prevent
hydrates forming at low temperatures. Institut Francais du Petrole (IFP) has developed a scheme which uses methanol for such
a duty and overcomes the traditional regeneration problems associated with methanol.
The novel regeneration process consists of a packed column to enable a slipstream of the wet gas stream, to be contacted
with the water/methanol stream from the Low Temperature Separator. The gas effectively strips the methanol out of the water
stream producing a discharge water stream containing as low as 50 ppm of methanol (suitable for offshore
disposal). Methanol losses from the Low Temperature Separator to the vapour and liquid hydrocarbon streams are accounted
for by means of a methanol make-up which is added to the inlet gas stream prior to chilling. The main benefits of the process
are the simple, environmentally friendly regeneration (minimal losses) process, small footprint area over conventional
dehydration schemes, suitability for unmanned platforms and the ability to dewpoint the gas at the same time as it is being
dehydrated. The main drawbacks are the methanol losses to the hydrocarbon phases and the dual dehydration and dewpointing
function. This is a drawback, as well as an advantage, as if the water specification is severe whilst the hydrocarbon dewpoint is
not, IFPex-1 will essentially overtreat the gas and produce large amounts of unwanted condensate.
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 81
Dehydration Technologies
Comparison
Actual Outlet Gas Specification Calibration is 1lb/MMscf = 20ppmv
1.50 30
A A Example Applications
Glycol Absorption
(A) Forties Bravo
1.25 25 (B) Gyda
C A (C) Frigg (Elf)
(D) Magnus
(E) Bruce
1.00 20 A B B
20ppm Glycol Injection
(A) Cleeton
Silica Gel
0.75 15 (A) Dimlington Terminal
D (B) Q8 Terminal
Netherlands
Cold
Finger
0.50 10 Molecular Sieve
10ppm
Stripping
Gas
(A) Ula
(B) Miller
7ppm
(C) Wytch Farm
0.25 5 E Membrane
Drizo (A) Easington Test Rig
C
2ppm 2ppm 2ppm
1ppm
0 0
Ib/MMscf Pppm Glycol Glycol Methanol Molecular
IFPEXOL Injection Silica Gel Membranes
Absorption Injection Sieve
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 82
Shell Twister - Dehydration Technology
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 84
Shell Twister - Dehydration Technology
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Shell Twister - Dehydration Technology
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Fiscal Gas Metering
• Fiscal Gas Metering:
– Gas is metered for accounting and to
meet the requirements of the
Department of Energy (DoE) for
reporting and taxation
– The basis of metering is mass flow
by on line density measurement
– The recognised principle of
measurement is use of orifice plates,
with corrections for pressure,
temperature, density, and relative
density variations
– Ultrasonic technology become more
accepted Gas Metering Skid
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 87
Ultrasonic Flow Metering
One transducer transmits a signal downstream the flow. A second
transducer transmits a signal upstream against the flow along the same
path. A sound wave going with the flow travels faster than one
propagated against the flow. The time the acoustic pulses take to travel
across, with and against the flow, is measured very accurately. The
difference in transit times is directly proportional to the medium's mean
flow velocity.
The volumetric flow rate is the product of the mean velocity multiplied
with the cross section of the pipe.
KROHNE Meter
Upstream Process Engineering Course Prepared by Genesis Oil and Gas Consultants Ltd Gas Handling 88