TEKNIK REAKSI KIMIA I

By Haryanto
 PUSTAKA
• Levenspiel,O.,1999,”Chemical Reactor
Engineering”,3rd ed.,John Wiley & Sons,New York.
• Froment,GF.,1979,”Chemical Reactor and
Design”,John Wiley & Sons,New York.
• Hill,Charless G.,Jr.,1977,”An Introduction to Chemical
Engineering Kinetic & Reactor Design”,John Wiley &
Sons,New York.
• Smith,J.M.,1981,”Chemical Engineering Kinetics”, 3rd
ed.,Mc Graw Hill,Kogakhusha,Tokyo.
• Fougler,Scott.H.1999,”Elements of Chemical
Reaction Engineering”,3rd ed,Prentice-Hall,Inc,New
Jersey.
 Tujuan Instruksional Umum
• Setelah mengikuti kuliah diharapkan
mahasiswa mampu memahami mekanisme
reaksi serta memecahkan berbagai
persoalan yang berkaitan dengan kecepatan
reaksi untuk reaksi homogen.
 MATERI
TRK I

Kecepatan Mekanisme Kec

Reaksi Reaksi
SILABI

Pengertian kinetika kimia.

kec reaksi dan klasifikasi reaksi.
Kinetika reaksi homogen.
Mekanisme reaksi.
Pengaruh suhu terhadap kec reaksi.
Analisa data kinetika.
Kinetika reaksi berganda.
Kinetika reaksi fase cair.
 Pemahaman Tentang Teknik
Reaksi Kimia

Physical Chemical Physical Products

Raw Material
Treatment Treatment Treatment
Steps Steps Steps

Recycle
Unit
Operation Unit
Operation
Reaktor
 Penjelasan Bagan diatas
• Physical Treatment steps is studied
in the Unit Operation.
• Chemical Treatment steps is
studied in Chemical Engineering.
 Performance Equation

Input Out Put

Reaktor

Flow Pattern Kinetics

Out Put = f ( Input, Kinetics, Contacting )

 Klasifikasi Reaksi
Jenis Non Katalitik. Katalitik.

Homogen Reaksi fase gas. Reaksi fase cair.

Heterogen Absorpsi gas-cair. Sintesis Amonia

Cracking minyak
mentah.
Oksidasi SO2 mjd SO3
Variables Affecting The Rate Of
Reaction

Temperature
Homogenous System
Pressure
Composition

Temperature
Heterogenous System Pressure
Composition
Mass Tranfer
Heat Transfer
 Definition of Reaction Rate
1 dNi mole i formed
ri   Based on unit vol of reacting volume
v dt (vol of fluid)(tim e)

1 dNi mole i formed

ri  '
 Based on mass solid in fluid solid system
v dt ( mass of solid )(time)

1 dNi mole i formed

ri  
''
Based on unit vol of solid in gas solid system.
v dt (vol of solid)(tim e)
 SPEED OF CHEMICAL
REACTION

10-4 10-3 10-2 0,1 1 10

∫
Indutrial water Gases in porous katalyst particles
Treatment Plents
Working hard
Coal furnaces
Human at rest

103 104 109 1010

∫ •∫∫
Rocket engines Bimolekuler reaction
Jet engine
Kinetics of Homogeneous Reactions
• Ideal reactors have three ideal flow pattern :
1. Batch ; uniform composition everywhere in the
reactor, but of course the composition changes
with time.
2. Plug flow ; Fluid passes through the reactor with
no mixing of earlier and later entering fluid, and
with no overtaking. It is as if the fluid moved in
the fluid moved in single file through the reactor.
3. Mixed flow ; Uniformly mixed, same composition
everywhere, within the reactor and at the exit.
A. PENGARUH KONSENTRASI THD KEC REAKSI

1. Jenis –jenis Reaksi ;

Berdasar reaksi :
 Reaksi Tunggal
 Reaksi Ganda ; Seri dan Paralel , Kompleks
Berdasar pers kec reaksi :
 Reaksi Elementer
 Reaksi Non Elementer
2. Molekularitas dan Orde Reaksi
 Molekularitas adalah Jumlah molekul yang terlibat didalam reaksi.
 Orde Reaksi adalah power atau pengaruh konsentrasi terhadap
kecepatan reaksi
 II. Jenis-jenis Reaksi

 Jenis Reaksi Berdasar Arah Mekanisme ;

 Reaksi Irreversible
 Reaksi Reversible
 Penjelasan reaksi ganda ;

 Reaksi Paralel
 Reaksi berantai/konsekutif
 Reaksi berdasar jumlah
molekul ;
 Reaksi unimolekuler
 Reaksi Bimolekuler
 Reaksi Trimolekuler
 Reaksi berdasar tingkat reaksi
;
 Integral order reaction
 Fractional Order reaction
 Reaksi berdasar Jumlah Fase ;

 Reaksi fase homogen

 Reaksi fase heterogen
 Reaksi berdasar ada tidaknya
katalis ;
 Reaksi katalitik
 Reaksi non katalitik
 Reaksi berdasar cara
operasinya ;
 Batch
 Semi batch
 Kontinyu
 Reaksi berdasar kondisi
operasi ;
 Ishotermal
 Adiabatik
 III. KECEPATAN REAKSI
 III.1. Definisi
a. Utk reaksi homogen ;

a. Utk reaksi Heterogen ;