SPECTROSCOPY.

Jeet Kansagara.
Pranav Wagh.
Dijvijay Pawar.
Harshal Humne.
Use of
Spectroscopy in
Minimizing Air
Pollution.
 Need Of The Research.
As now-a-days there is rapid increase of
v e h i c l e s o n I n d i a n Ro a d s .
The present number of four-wheelers in
Pune is 6,45,683 , two-wheelers 2,73,147,
a u t o - r i c k s h a w s 5 3 , 227 , t a x i - c a b s 2 8 , 3 4 4 , a n d
o t h e r h e a v y v e h i c l e s l i ke t r u c k s , b u s e s ,
tempos, etc., at 38,598.
So these is creating lot of AIR -
POLLUTION and making the air of Pune unfit
a n d u n s o u n d d a y - b y - d a y.
To m i n i m i z e t h e s e w e a r e t a k i n g a b a b y
step through our research.
OBJECTIVES.

▪ To Minimize the Air pollution.

▪ To learn In deep study of Air pollution.
▪ To Implement some logic in Electronics.
 What is AIR-POLLUTION?

The presence in or introduction into the air of a

substance which has harmful or poisonous effects.
OR
Air pollution occurs when harmful or excessive
quantities of substances including gases, particulates,
and biological molecules are introduced into Earth's
atmosphere.
 How is Air Pollution Caused?
Main Cause of Air Pollution is Pollutants.
 Pollutants :-
An air pollutant is a material in the air that
can have adverse effects on humans and the ecosystem.
The substance can be solid particles, liquid droplets, or
gases. A pollutant can be of natural origin or man-made.
Pollutants are classified as primary or secondary.
 Pollutants.
▪ Primary Pollutants :-
Primary pollutants are usually produced
by processes such as ash from a volcanic eruption. Other
examples include carbon monoxide gas from motor vehicle
exhausts or sulphur dioxide released from the factories.
▪ Secondary Pollutants :-
Secondary pollutants are not emitted
directly. Rather, they form in the air when primary
pollutants react or interact. Ground level ozone is a
prominent example of secondary pollutants.
Substances emitted into the
atmosphere by human activity include:
▪ Carbon dioxide (CO2).
▪ Sulphur oxides (SOx).
▪ Nitrogen oxides (NOx).
▪ Carbon monoxide (CO).
▪ Volatile organic compounds (VOC).
▪ Particulates.
▪ Chlorofluorocarbons (CFCs).
▪ Ammonia (NH3)
▪ Radioactive pollutants, etc.
Secondary pollutants include:

▪ Particulate Smog.
▪ Ground Level Ozone.
▪ Peroxyacetyl nitrate (C2H3NO5).
 Carbon Dioxide(CO2).
Because of its role as a greenhouse gas it has
been described as "the leading pollutant" and "the
worst climate pollution". Carbon dioxide is a natural
component of the atmosphere, essential for plant
life and given off by the human respiratory
system. This question of terminology has practical
effects.
CO2 currently forms about 410 parts per
million (ppm) of earth's atmosphere, compared to
about 280 ppm in pre-industrial times and billions of
metric tons of CO2 are emitted annually by burning
of fossil fuels. CO2increase in earth's atmosphere
has been accelerating.
 Sulphur oxides(SOx).

Particularly sulphur dioxide, a chemical

compound with the formula SO2. SO2 is produced
by volcanoes and in various industrial processes.
Coal and petroleum often contain sulphur
compounds, and their combustion generates
sulphur dioxide. Further oxidation of SO2, usually in
the presence of a catalyst such as NO2, forms
H2SO4, and thus acid rain. This is one of the causes
for concern over the environmental impact of the
use of these fuels as power sources.
 Nitrogen oxides(NOx)
Nitrogen oxides, particularly nitrogen dioxide,
are expelled from high temperature combustion, and
are also produced during thunderstorms by electric
discharge. They can be seen as a brown haze dome
above or a plume downwind of cities. Nitrogen
dioxide is a chemical compound with the formula
NO2. It is one of several nitrogen oxides. One of the
most prominent air pollutants, this reddish-brown
toxic gas has a characteristic sharp, biting odour.
 Carbon monoxide(CO).
CO is a colourless, odourless, toxic yet non-irritating gas. It
is a product of combustion of fuel such as natural gas, coal or
wood. Vehicular exhaust contributes to the majority of carbon
monoxide let into our atmosphere. It creates a smog type
formation in the air that has been linked to many lung diseases and
disruptions to the natural environment and animals. In 2013, more
than half of the carbon monoxide emitted into our atmosphere
was from vehicle traffic and burning one gallon of gas will often
emit over 20 pounds of carbon monoxide into the air.
Volatile organic compounds(VOC)
VOCs are a well-known outdoor air pollutant. They
are categorized as either methane (CH4) or non-methane
(NMVOCs). Methane is an extremely efficient greenhouse
gas which contributes to enhanced global warming.
Other hydrocarbon VOCs are also significant greenhouse
gases because of their role in creating ozone and
prolonging the life of methane in the atmosphere. This
effect varies depending on local air quality. The aromatic
NMVOCs benzene, toluene and xylene are suspected
carcinogens and may lead to leukemia with prolonged
exposure. 1,3-butadiene is another dangerous compound
often associated with industrial use.
 Particulates.
Alternatively referred to as particulate matter (PM),
atmospheric particulate matter, or fine particles, are tiny particles of
solid or liquid suspended in a gas. In contrast, aerosol refers to
combined particles and gas. Some particulates occur naturally,
originating from volcanoes, dust storms, forest and grassland fires,
living vegetation, and sea spray. Human activities, such as the
burning of fossil fuels in vehicles, power plants and various industrial
processes also generate significant amounts of aerosols. Averaged
worldwide, anthropogenic aerosols—those made by human
activities—currently account for approximately 10 percent of our
atmosphere. Increased levels of fine particles in the air are linked to
health hazards such as heart disease, altered lung function and lung
cancer. Particulates are related to respiratory infections and can be
particularly harmful to those already suffering from conditions
like asthma.
 Chlorofluorocarbons(CFCs).
Harmful to the ozone layer; emitted from
products are currently banned from use. These are
gases which are released from air conditioners,
refrigerators, aerosol sprays, etc. On release into the
air, CFCs rise to the stratosphere. Here they come in
contact with other gases and damage the ozone layer.
This allows harmful ultraviolet rays to reach the earth's
surface. This can lead to skin cancer, eye disease and
can even cause damage to plants.
 Ammonia(NH3).
Emitted from agricultural processes. Ammonia is
a compound with the formula NH3. It is normally
encountered as a gas with a characteristic pungent
odour. Ammonia contributes significantly to the
nutritional needs of terrestrial organisms by serving as a
precursor to foodstuffs and fertilizers. Ammonia, either
directly or indirectly, is also a building block for the
synthesis of many pharmaceuticals. Although in wide
use, ammonia is both caustic and hazardous. In the
atmosphere, ammonia reacts with oxides of nitrogen
and sulphur to form secondary particles.
Radioactive Pollutants.

Produced by nuclear explosions, nuclear

events, war explosives, and natural processes
such as the radioactive decay of radon.
 Particulate Smog.
Particulates created from gaseous primary
pollutants and compounds in photochemical
smog. Smog is a kind of air pollution. Classic smog
results from large amounts of coal burning in an area
caused by a mixture of smoke and sulphur dioxide.
Modern smog does not usually come from coal but
from vehicular and industrial emissions that are acted
on in the atmosphere by ultraviolet light from the sun
to form secondary pollutants that also combine with
the primary emissions to form photochemical smog.
 Ground Level Ozone.
Ground level ozone (O3) formed from NOx and
VOCs. Ozone (O3) is a key constituent of the
troposphere. It is also an important constituent of
certain regions of the stratosphere commonly known
as the Ozone layer. Photochemical and chemical
reactions involving it drive many of the chemical
processes that occur in the atmosphere by day and by
night. At abnormally high concentrations brought
about by human activities (largely the combustion of
fossil fuel), it is a pollutant and a constituent of smog.
Effects of Air Pollution.

▪ Health Effects.
▪ Agricultural Effects.
▪ Economic Effects.
Health Effects

▪ Mortality.
▪ Cardiovascular Disease.
▪ Lung Disease.
▪ Cancer(Lung Cancer).
▪ Infants.
▪ Central Nervous System.
 Mortality.
The World Health Organization estimated in 2014 that
every year air pollution causes the premature death of some 7
million people worldwide. India has the highest death rate due to
air pollution. India also has more deaths from asthma than any
other nation according to the World Health Organization.
Urban outdoor air pollution is estimated to cause 1.3
million deaths worldwide per year. Children are particularly at
risk due to the immaturity of their respiratory organ systems.
Diesel exhaust (DE) is a major contributor to combustion-
derived particulate matter air pollution. In several human
experimental studies, using a well-validated exposure chamber
setup, DE has been linked to acute vascular dysfunction and
increased thrombus formation.
 Cardiovascular Disease.
▪ A 2007 review of evidence found ambient air pollution
exposure is a risk factor correlating with increased total
mortality from cardiovascular events (range: 12% to 14% per 10
microg/m3 increase).
Air pollution is also emerging as a risk factor for stroke,
particularly in developing countries where pollutant levels are
highest. A 2007 study found that in women, air pollution is not
associated with haemorrhagic but with ischemic stroke. Air
pollution was also found to be associated with increased
incidence and mortality from coronary stroke in a cohort study in
2011. Associations are believed to be causal and effects may be
mediated by vasoconstriction, low-grade inflammation
and atherosclerosis Other mechanisms such as autonomic
nervous system imbalance have also been suggested.
 Lung Disease.
Research has demonstrated increased risk of developing
asthma and COPD from increased exposure to traffic-related air
pollution. Additionally, air pollution has been associated with
increased hospitalization and mortality from asthma and COPD.
Chronic obstructive pulmonary disease (COPD) includes diseases
such as chronic bronchitis and emphysema.
It is believed that much like cystic fibrosis, by living in a
more urban environment serious health hazards become more
apparent. Studies have shown that in urban areas patients
suffer mucus hyper secretion, lower levels of lung function, and
more self-diagnosis of chronic bronchitis and emphysema.
 Cancer(Lung Cancer).
A review of evidence regarding whether ambient air pollution
exposure is a risk factor for cancer in 2007 found solid data to conclude that
long-term exposure to PM2.5 (fine particulates) increases the overall risk of
non-accidental mortality by 6% per a 10 microg/m3 increase. Exposure to
PM2.5 was also associated with an increased risk of mortality from lung
cancer (range: 15% to 21% per 10 microg/m3 increase) and total
cardiovascular mortality (range: 12% to 14% per a 10 microg/m3 increase).
The review further noted that living close to busy traffic appears to be
associated with elevated risks of these three outcomes – increase in lung
cancer deaths, cardiovascular deaths, and overall non-accidental deaths.
The reviewers also found suggestive evidence that exposure to PM2.5 is
positively associated with mortality from coronary heart diseases and
exposure to SO2 increases mortality from lung cancer, but the data was
insufficient to provide solid conclusions. Another investigation showed that
higher activity level increases deposition fraction of aerosol particles in
human lung and recommended avoiding heavy activities like running in
outdoor space at polluted areas.
 Infants.
Ambient levels of air pollution have been associated with
preterm birth and low birth weight. A 2014 WHO worldwide
survey on maternal and perinatal health found a statistically
significant association between low birth weights (LBW) and
increased levels of exposure to PM2.5. Women in regions with
greater than average PM2.5 levels had statistically significant
higher odds of pregnancy resulting in a low-birth weight infant
even when adjusted for country-related variables. The effect is
thought to be from stimulating inflammation and increasing
oxidative stress.
 Central Nervous System.
In a June 2014 study conducted by researchers at
the University of Rochester Medical Center, published in the
journal Environmental Health Perspectives, it was discovered that
early exposure to air pollution causes the same damaging changes
in the brain as autism and schizophrenia. The study also shows that
air pollution also affected short-term memory, learning ability,
and impulsivity. Lead researcher Professor Deborah Cory-Slechta
said that "When we looked closely at the ventricles, we could see
that the white matter that normally surrounds them hadn't fully
developed. It appears that inflammation had damaged those brain
cells and prevented that region of the brain from developing, and
the ventricles simply expanded to fill the space. Our findings add to
the growing body of evidence that air pollution may play a role
in autism, as well as in other neurodevelopmental disorders." Air
pollution has a more significant negative effect on males than on
females.
In 2015, experimental studies reported the detection of significant
episodic (situational) cognitive impairment from impurities in indoor air
breathed by test subjects who were not informed about changes in the
air quality. Researchers at the Harvard University and SUNY Upstate
Medical University and Syracuse University measured the cognitive
performance of 24 participants in three different controlled laboratory
atmospheres that simulated those found in "conventional" and "green"
buildings, as well as green buildings with enhanced ventilation.
Performance was evaluated objectively using the widely used Strategic
Management Simulation software simulation tool, which is a well-
validated assessment test for executive decision-making in an
unconstrained situation allowing initiative and improvisation. Significant
deficits were observed in the performance scores achieved in increasing
concentrations of either volatile organic compounds (VOCs) or carbon
dioxide, while keeping other factors constant. The highest impurity levels
reached are not uncommon in some classroom or office
environments. Air pollution increases the risk of dementia in people over
50 years old.
Agricultural Effects.

In India in 2014, it was reported that air

pollution by black carbon and ground level
ozone had reduced crop yields in the most
affected areas by almost half in 2011 when
compared to 1980 levels.
 Economic Effects.
Air pollution costs the world economy $5 trillion per year as a
result of productivity losses and degraded quality of life, according
to a joint study by the World Bank and the Institute for Health
Metrics and Evaluation (IHME) at the University of Washington.
These productivity losses are caused by deaths due to diseases
caused by air pollution. One out of ten deaths in 2013 was caused by
diseases associated with air pollution and the problem is getting
worse. The problem is even more acute in the developing world.
"Children under age 5 in lower-income countries are more than 60
times as likely to die from exposure to air pollution as children in
high-income countries.“ The report states that additional economic
losses caused by air pollution, including health costs and the adverse
effect on agricultural and other productivity were not calculated in
the report, and thus the actual costs to the world economy are far
higher than $5 trillion.
 Reduction Efforts.
s Various air pollution control technologies and strategies are available
to reduce air pollution. At its most basic level, land-use planning is likely to
involve zoning and transport infrastructure planning. In most developed
countries, land-use planning is an important part of social policy, ensuring
that land is used efficiently for the benefit of the wider economy and
population, as well as to protect the environment.
Because a large share of air pollution is caused by combustion
of fossil fuels such as coal and oil, the reduction of these fuels can reduce air
pollution drastically. Most effective is the switch to clean power sources such
as wind power, solar power, hydro power which don't cause air
pollution. Efforts to reduce pollution from mobile sources includes primary
regulation (many developing countries have permissive
regulations), expanding regulation to new sources (such as cruise and
transport ships, farm equipment, and small gas-powered equipment such
as string trimmers, chainsaws, and snowmobiles), increased fuel efficiency
(such as through the use of hybrid vehicles), conversion to cleaner fuels or
conversion to electric vehicles.
 Titanium dioxide has been researched for its ability to reduce
air pollution. Ultraviolet light will release free electrons from
material, thereby creating free radicals, which break up VOCs and
NOx gases. One form is super hydrophilic.
In 2014, Prof. Tony Ryan and Prof. Simon
Armitage of University of Sheffield prepared a 10 meter by 20
meter-sized poster coated with microscopic, pollution-eating
nanoparticles of titanium dioxide. Placed on a building, this giant
poster can absorb the toxic emission from around 20 cars each day.
A very effective means to reduce air pollution is
the transition to renewable energy. According to a study published
in Energy and Environmental Science in 2015 the switch to 100%
renewable energy in the United States would eliminate about 62,000
premature mortalities per year and about 42,000 in 2050, if no
biomass were used. This would save about $600 billion in health
costs a year due to reduced air pollution in 2050, or about 3.6% of
the 2014 U.S. gross domestic product.
 Air Quality Index.

Think of the AQI as a yardstick that runs from 0 to 500.

The higher the AQI value, the greater the level of air pollution
and the greater the health concern. For example, an AQI value of
50 represents good air quality with little potential to affect public
health, while an AQI value over 300 represents hazardous air
quality.
An AQI value of 100 generally corresponds to the national
air quality standard for the pollutant, which is the level EPA has
set to protect public health. AQI values below 100 are generally
thought of as satisfactory. When AQI values are above 100, air
quality is considered to be unhealthy-at first for certain sensitive
groups of people, then for everyone as AQI values get higher.
Gases Expelled from Vehicles.

▪ Particulate Matter(PM).
▪ Hydrocarbons(HC).
▪ Nitrogen Oxides(NOx).
▪ Carbon Monoxide(CO).
▪ Hazardous Air Pollutants.
▪ Green House Gases.
▪ Sulphur Dioxide(SO2).
Ambient Air Quality Standard.

Conc g/m3
Category
SPM SOx CO NOx
Industrial and
500 120 5,000 120
mixed-use
Residential
200 80 2,000 80
and rural
Sensitive 100 30 1,000 30
Our Thought on Minimizing Air
Pollution.
We are Focusing on the Air Pollution by
Vehicles and to Minimize it.
What we are Thinking Is We will Build Such a
circuit Such that It will be inside the Vehicle Itself.
What we will do is whenever a Vehicle is
Stopped or Its Speed is 0 km/hr. at that time we will
directly check the levels of constituents or gases
which are directly coming from Engine as the
Standard Levels as shown in Above table and if the
Levels are Been Exceeded then the device is Having
such a Circuit that it will turn off the vehicle.
 We are Skipping the first Part that is
Detection of Levels of Gases We are Post ponding it
And we have Focussed on the Second Part of
Switching Off the Vehicle.
 Our Circuit.
At Present we are thinking that we will keep a
filter paper at the exhaust of the Vehicle for a limited
amount of time then we will cover a LDR using that
Filter paper.
As filter paper will absorb the particles and
eventually become black so when we cover LDR by it if
the intensity of Blackness is more it will block the light
and the resistance along the LDR will increase and at
present we are glowing the LED but in Actual it will
Turn Off the Vehicle.
THANK YOU!