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Lecture 04
Structure of Ceramics: Part 3
That
Sulphur form the lattice structure with an sequence
AABB means two
S layers right on
top of each
other (AA)
Next layers sits
on the groove of
second layer
(AAB)
The fourth layer
follows the third
layer (AABB)
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MoS2 GROUP
B Right in between
two layers ( that
B are right on top of
A each other) there
are Mo ions at the
A center of trigonal
prism. However
only half the
trigonal prisms are
occupied
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Spinel and Inverse Spinel Structures
The bond strength is therefore 2/4 for A2+ and 3/6 for B3+. In order
to satisfy Pauling’s second rule, each oxygen must be coordinated
by three A2+ and one B3+.
The most commercially important spinel structure ceramics by far
are soft magnetic ferrite, which is used as inductors, transformer
cores, and read/write heads for magnetic storage media.
Types of spinel Ferrite
Normal spinel ferrites: (Me2+)A[Fe3+Fe3+]BO4 :where Me
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SPINEL GROUP
TTHDR
L voids
here
Find
the
OCT
void
n’ ( AC + AA )
r =
V C NA
2 (rNa+ rCl)
n’ = 4 in FCC lattice
S AC = ANa = 22.99
g/mol
S AA = ACl = 35.45
g/mol
VC = a3 = (2 rNa+ 2 rCl )3 rNa
= 1.911 x 10-22 cm3