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Technical Seminar
Explosion
Bang or Muffled Whoosh
No Ignition
Typical Consequences of Accidental releases of Combustible Gas or Evaporating Liquid into the Atmosphere
Immediate Ignition
Fire No Damage
Release of Gas and/or Liquid Formation of Combustible Fuel-Air Cloud (premixed) Ignition Delayed Gas Explosion
Fire
Detonation
A detonation wave is a supersonic (relative to the speed of sound in the unburned gas ahead of the wave) combustion wave. The shock wave and the combustion wave are in this case coupled. In a fuel-air cloud a detonation wave will propagate at a velocity of 1500-2000 m/s and the peak pressure is typically 15 to 20 bar.
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Deflagration
The deflagration mode of flame propagation is the most common. A deflagration propagates at subsonic speed relative to the unburned gas, typical flame speeds (I.e. relative to a stationary observer) are from the order of 1 to 1000 m/s.The explosion pressure may reach values of several barg, depending on the flame speed.
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A 1.5% drop in Oxygen means that a whopping 7.5% of something else has gotten into that space.
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Effects
110
19.0
689
145
135
95
2,500
16.0
581
121
114
70
7,500
Increased pulse and breathing rate. Impaired thinking and attention. Reduced coordination.
14.0
532
110
100
60
10,000
Abnormal fatigue upon exertion. Emotional upset. Faulty coordination. Poor judgment.
12.5
450
96
85
48
14,000
Very poor judgment and coordination. Impaired respiration that may cause permanent heart damage. Nausea and vomiting.
<10
<367
<81
<71
<33
<18,000
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Solid Materials
Phosphorus (white) Peat Sulphur Spruce Wood Brown Coal Hard Coal Sugar Tar Rye Flour 60C 230 C 250 C 280 C 250280 C 330440 C 410 C 500 C 500 C
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Boiling Point
The Boiling Point of a liquid at a pressure of 14.7 pounds/Square inch absolute (psia.) 760mm of Hg. At temperatures above the boiling point, the pressure of the atmosphere can no longer hold the liquid in the liquid state and bubbles begin to form. The lower the boiling point, the greater the vapour pressure at normal ambient temperatures and consequently the greater the fire risk.
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Flash Point
The minimum temperature at which a liquid gives off vapour within a test vessel in sufficient concentration to form an ignitable mixture with air near the surface of the liquid. The flash point is normally an indication of susceptibility to ignition. The expression low flash-high hazard applies.
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Combustible Liquid
Any liquid having a flash point at or above 100F (37.8C.)
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Flammable Liquid
Any liquid having a flash point below 100F (37.8C) or higher , the total of which make up 99% or more the total volume of the mixture.
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Flash Point of a Few Common Liquids Liquid Propane Butane Ethyl Ether Gasoline Carbon Disulphide Acetone Benzene Methyl Ethyl Keytone (MEK) Heptane Toluene Methyl Alcohol Ethyl Alcohol Propyl Alcohol Jet Fuel (JP4) Turpentine Polyester Resin Diesel Fuel Kerosene Fuel Oil Ethyl Glycol Lubricating Oil Corn Oil Flash Point (rC) -104 -60 -45 -43 -30 -18 -11 -9 -4 4 11 12 15 18 35 38 40 51.6 80 111 149 254
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Classes
Classes of Flammable and Combustible Liquids as Defined in 29CFR 1910.106
F L A S H P O I N T (F) 200
IIIA
140
COMBUSTIBLE
(Flash Point =100F)
II
100
IC
73
FLAMMABLE
(Flash Point <100F)
IA
IB
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Vapour Pressure
Measure of a liquids propensity to evaporate. The higher the vapour pressure, the more volatile the liquid and, thus, the more readily the liquid gives off vapours.
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Types of Reaction
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Types of Reaction
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IR
100
lo s iv e tm o s h e r e
$
IT I
!
u e l/ a t io
T h e a m i
r m ist o r st) a th e a ir to g e th e r fo r m a o te tia lly o r tio o f th e f e l a a ir is et ee c e r ta i lim its th e y fo r m e ig ite y a ig itio so rce. tsi e th e lim its, th e te tia l to o s o if th e r o o r tio ca cha ge.
$#
"
ir
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Explosive Limits
The explosive range ill iden hen the initial temperature is increasing. hanges in initial pressure ill or hydrocarbons in air not change the LEL signi icantly, but the EL ill increase.
100
&
LEL
&
25C
Temperature
) 0
uel Concentration
Explosive
2 '
EL
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Gas Explosion
Process where combustion of a premixed gas cloud, i.e. fuel-air or fuel/oxidizer is causing a rapid increase in pressure.
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27
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Pressure Piling
ot Tur ule t ases Emerge ast r e ases Ig itio Flame Fro t arge ressure rop Causi g Cooli g
she hea
nclosure
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100
150
2nd Enclosure
80
60
Pressure Piling can increase the explosion pressure by up to 3 times in an explosionproof enclosure
40 20
0.2
0.4
0.6
0.8
1.0
Time-Seconds Pressure Traces for Two enclosure connected by Conduit Gas or Vapour
Acetylene Ethylene Propane Methane Hydrogen
EP (PSI)
149 129 125 104 102
TPP (MS)
14 25 46 70 7
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Testing at low temperature found that Pressure increased in direct proportion to the decrease in temperature. As temperature decreases, there is more gas and air in a given volume.
800
700
Temperature (C)
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Inertization
Means to reduce the oxygen concentration to a safe level LOC, Cmax(O2)
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Inertization
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Propane
1.0
0.1 MIE
Hydrogen
Flammable Range
10 20
30
40
50
60
70 80 90
100
Concentration in Volume (%) Increasing the initial temperature of a flammable or combustible mixture will decrease the amount of energy required to cause an ignition. Temperature variation can also change the concentration of flammable materials in the mixture. Oxygen enrichment decreases the energy necessary for an ignition. MIE is inversely proportional to pressure squared. When examining a situation where the gas mixture is not at atmospheric pressure, one must consider whether a flammable mixture exists under higher-pressure conditions. When the mixture is at high pressure many flammable materials condense.
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10-2
Atmospheric Air
10-3
10-4
10-5
10-6 0 10 20 30 40 Ether Vapour (%) The curve corresponding to atmospheric air is very narrow. This means that as soon as you move slightly outside the most easily ignited mixture (6% ether), the necessary energy is much higher. It is therefore possible only in a very small region to cause the vapour to ignite by a 0.2 mJ spark. On the other hand, somewhere between the surface of the mixture, where the mixture is to rich, to perhaps a couple of feet away, where the mixture is too lean, well find the most volatile mixture. However, for a concentration of approximately 16% ether vapour in pure oxygen, it takes only about 1 QJ to start an explosion.
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Causes of explosions
Heavy concentrations of fuel. Highly heated flammable gas mixture. Presence of a strong oxidizer. Increase in pressure. Detonation charge. Catalyst near reactive substance.
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Ignition Sources
Electrical arcs Electrical sparks Flames Hot surfaces Static electricity Mechanical impact Mechanical friction Compression ignition Ionizing radiation Acoustic energy Electromagnetic radiation including optical frequencies
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Classification Considerations
The likelihood that the explosive gas atmosphere is present when the equipment is operating. The ignition-related properties of the explosive gas atmosphere. The maximum surface temperature of the equipment under normal operating conditions; and The protection method(s) used by the equipment to prevent ignition of the surrounding atmosphere.
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Classes
Hazardous Location
Hazardous location means premises, buildings, or parts thereof in which there exists the hazard of fire or explosion due to the fact that: (a) Highly flammable gases, flammable liquids, mixtures, or other highly flammable substances are manufactured or used or stored in other than original containers; (b) Combustible dust or flyings are likely to be present in quantities sufficient to produce an explosive or combustible mixture or it is impracticable to prevent such dust or flyings from collecting in or upon motors or other electrical equipment in such quantities as to produce overheating through normal radiation being prevented, or from being deposited upon incandescent lamps; (c) Easily ignitable fibres or materials producing combustible flyings are manufactured, handled, or used in a free open state; or (d) Easily ignitable fibres or materials producing combustible flyings are stored in bales or containers but are not manufactured or handled in a free open state. In both Canada and the United States, there are three classes of hazardous locations. They are as follows: Class I- A location where there is a danger of explosion due to the presence of a flammable gas or vapour. Class II- A location where there is a danger of explosion due to the presence of a flammable dust. Class III- A location where there is a danger of explosion or flash fire due to the presence of flammable fibres or flyings.
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Divisions/Zones
CEC/NEC Division Classification Class I, Division 1: Where ignitable concentrations can exist under normal operating conditions; may exist frequently because of repair, maintenance or leakage; or may exist due to breakdown of equipment in conjunction with an electrical failure. IEC Zone Classification Class I, Zone 0: Where ignitable concentrations are present continuously or for long periods of time. Class I, Zone 1: Where ignitable concentrations are likely to exist under normal operations; may exist frequently because of repair, maintenance or leakage; may exists due to breakdown of equipment in conjunction with an electrical failure; or adjacent to Class I, Zone 0 locations. Class I, Zone 2: Where ignitable concentrations are not likely to exist in normal operation or may exist for a short time only; where volatile flammable liquids are stored, etc. in closed containers; where ignitable concentrations are normally prevented by positive pressure ventilation; or adjacent to Class I, Zone 1 locations.
Class I, Division 2: Where volatile flammable liquids are stored, etc. in closed containers; where ignitable concentrations are normally prevented by positive pressure ventilation; or adjacent to Class I, Division 1 locations.
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Ignition-related Properties
Maximum Experimental safe Gap. Minimum Igniting Current or Ratio. Minimum Ignition Energy. Test or estimate using the Le Chateliers Principle. Results found in NFPA 497.
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3 4
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Temperature Code
IEC Temperature Co e T1 T2 Temperature, C 450 300 280 260 230 215 200 180 165 160 135 120 100 85 North merica Temperature Co e T1 T2 T2 T2 T2C T2 T3 T3 T3 T3C T4 T4A T5 T6
9 A 9 @ @
T3
T4 T5 T6
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Hazardous Dust
The classi ication o areas containing dusts, ibres, and lyings is some hat di erent rom that o r gases and vapours. In orth America the classi ication o r Hazardous Dust, Class II, and Hazardous ibres, Class III, is urther divide into t o Divisions. Hazardous Dust has material roups assigned, as ell. Classificatio
H F C E B B BB F B B B B C B D E B B
ivisio s Co itio s Dust or ibres and lyings in u spension etal Dust in uspension or ettled on ur aces ther Dusts or ibres and lyings ettled on Horizontal ur aces
B P P P E P B P E E P E
aterial etal Dust Coal Dust rain and lastic Dust ibres and lyings
E I G
Category Class II, roup Class II, roup Class II, roup Class III
F Q G
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Methods of Protection
Type of Protection Flameproof (Explosion-Proof) Intrinsic Safety ( 2-fault) Intrinsic Safety (1-fault) Pressurization Increased Safety Oil Immersed Powder Filled Encapsulated Zone 2 Apparatus Special Protection Identification d ia ib p e o q m n s
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Conduit or Approved Hazardous Location Cable must have approved Sealing Fittings within 18 (450 mm) of an arcing device, and at Boundaries. Hazardous Location Cable and Sealing Fittings must be approved for the Hazardous Location where it is to be installed. Only use the Manufactures approved Epoxy.
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Non-hazardous Location
Remote Sensor
Non-incendive Barrier
Approved Sealing Fitting
Ex n Barriers
Non-Incendive for installation in Division 2 Locations when both the input power and relay outputs are connected to Non-Incendive sources not to exceed 32V dc (Power Input) and 24V dc (Relay Output.)
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56
I.S. Transmitter
57
Transmitter
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Safety Barriers
Intrinsically Safe [Ex I] method of protection
I.S. Barrier
Required
Ex ia [2 fault]
Class I, Division 1,Zone 0, Zone 1 [I.S. Plant Rat needs 1, RigRat II needs 8.] Class I, Division 2, Zone 2
Ex ib [1 fault]
Class I, Zone 1
Not Required
1. 2. 3. 4. 5. 6. 7.
Protection Method Ex ib is not allowed in a Class I, Division 1 or Zone 0 Area. BW Technologies Intrinsically safe detectors are approved Ex ia method. Barriers are usually mounted in Control Rooms outside industrial areas. In cases of installation of barriers in a hazardous area, they must be mounted in an enclosure which is suitability certified for the degree of hazard encountered. European Standards do not allow I.S. Barrier installation in Zone 0. Sealing Fittings are required where I.S. wiring crosses Divisions, Zones, or Non-hazardous locations. Sealing Fittings are required within 18 inches of all ports of a Flameproof Enclosure.
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I.S. Barrier
Two types of certified systems: Loop Approval and Entity Approval. Three types of I.S. Barriers: Grounded Safety Barrier, Grounded Repeater and Ungrounded Repeater. The wiring method must meet the requirement for ordinary locations for the class of circuit defined.
Limiting Energy
I.S. Barrier Open Circuit Voltage, Voc Short Circuit Current, Isc Allowed Capacitance, Ca Capacitance Allowed Inductance, La Inductance Field Device Vmax, Maximum Voltage Allowed Imax, Maximum Current Allowed Ci, Internal Li, Internal
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Class I Protection
Protection Techniques Vs Zones and Divisions for Class I (Gases and Vapours) Equipment CSA/UL/IEC Standard CSA/UL National Standard Permissible Protection Techniques Permissible Protection Techniques Zone 0: Division 1: Ex ia (Intrinsic Safety, 2-fault) Intrinsic Safety (Ex ia) Zone 1: Explosion-Proof Ex ib (Intrinsic Safety, 1-fault) Purged and Pressurized Ex d (Flameproof) Ex e (Increased Safety) Ex o (Oil Immersed) All Division 1 Ex p (Purged and Pressurized) Ex q (Power Filled) Ex m (Encapsulated)
All Zone 1
Those permitted for Division 1 Zone 2: Ex n (non-sparking/non-ignition-capable) Division 2: Non-ignition-capable arcing parts Non-ignition-capable heating parts Non-incendive
Notes: 1. Equipment suitable for Zone 0 is also suitable for Zone 1 and Zone 2. 2. Equipment suitable for Zone 1 is also suitable for Zone 2.
Those permitted for Zone 1 and 2, except Ex d that contains incendive normally arcing and sparking, or heated parts. Note: Equipment suitable for Division 1 is also suitable for Division 2.
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Approved Nipple Fitting Approved Sealing Fitting Installed within 18' (450mm) of the Ex d or Arcing Device.
Approved Ex e Fitting
Approved Sealing Fitting required where any Cable crosses into another Classification Boundary.
Notes:
1. Hazardous Location Cable and Sealing Fittings must be approved for the Hazardous Zone where it is installed. 2. Flameproof Sealing Fittings are required on the Increased Safety [Ex e] Enclosure if there are normally arcing parts inside the box. Otherwise approved Compression fittings that maintain the Ingress Protection rating of the Ex e Enclosure must be used to seal the Cable. 3. Ex d and Ex e protection methods are not to be used in a Zone 0 area.
Approved Ex e Fitting
Approved Ex e Fitting
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II 1 G
Equipment Marking
EEx ia d s IIC T6 T amb. -40C Ta 50C Class I, Gr. A, B, C, D Max. Amb: 50C. EEx d IIB H2 T3 T amb. -40C Ta 50C AEx d IIB H2 T3 T amb. -40C Ta 50C Class I, Div. 1, Gr. B, C, D T3C Max. Amb. 50C Class I, Zone 1, Gr. IIB H2 T3C Max. Amb. : 50C
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II 1 G
ATEX Directive
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Equipment Marking
Ta
50C
66
Equipment Marking
Ta Ta
50C 50C
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Equipment Marking
Class I, Div. 1, Gr. B, C, D T3C Max. Amb.; 50C Class I, Zone 1, Gr. IIB H2 T3 Max. Amb.; 50C
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The purpose of electrical apparatus designed to minimize the risk of ignition is to allow industry to handle situations where electrical power and signals can be used in hazardous atmospheres. The risk posed is never considered to be eliminated as this would be impossible to guarantee. The risk must be lowered to levels that are deemed acceptable by the law, and all interested parties in Safety. It is the consequences of an industrial explosion that are potentially catastrophic and therefore cannot be ignored.
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