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On the Celsius scale, an ice point of 0 C (0 degrees Celsius) and a steam point of 100 C were selected. On the Fahrenheit scale, an ice point of 32 F (32 degrees Fahrenheit) and a steam point of 212 F were chosen. The Celsius scale is used worldwide, while the Fahrenheit scale is used mostly in the United States. The temperature of the human body is about 37 C, where the symbol C stands for degrees Celsius. However, the change between two temperatures is specified in Celsius degrees (C)not in degrees Celsius. The separation between the ice and steam points on the Celsius scale is divided into 100 Celsius degrees, while on the Fahrenheit scale the separation is divided into 180 Fahrenheit degrees. Therefore, the size of the Celsius degree is larger than that of the Fahrenheit degree by a factor of 180 , or 9 . 2 100 5
Thus, the persons temperature is 37.0 Celsius degrees above the ice point. Adding 37.0 Celsius degrees to the ice point of 0 C on the Celsius scale gives a Celsius temperature of 3
The temperature, then, is 36.0 Fahrenheit degrees below the ice point. Subtracting 36.0 Fahrenheit degrees from the ice point of 32.0 F on the Fahrenheit scale gives a Fahrenheit temperature of
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Reasoning Strategy
Converting Between Different Temperature Scales 1. Determine the magnitude of the difference between the stated temperature and the ice point on the initial scale. 2. Convert this number of degrees from one scale to the other scale by using the fact that. 3.Add or subtract the number of degrees on the new scale to or from the ice point on the new scale.
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178 X
When a gas confined to a fixed volume is heated, its pressure increases. Conversely, when the gas is cooled, its pressure decreases. The change in gas pressure with temperature is the basis for the constant-volume gas thermometer.
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A plot of absolute pressure versus temperature for a low-density gas at constant volume. The graph is a straight line and, when extrapolated (dashed line), crosses the temperature axis at 273.15 C. Absolute zero means that temperatures lower than 273.15 C cannot be reached by continually cooling a gas or any other substance.
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Thermometers
A property that changes with temperature is called a thermometric property.
The thermocouple is a thermometer used extensively in scientific laboratories. It consists of thin wires of different metals, welded together at the ends to form two junctions.
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One of the junctions, called the hot junction, is placed in thermal contact with the object whose temperature is being measured. The other junction, termed the reference junction, is kept at a known constant temperature (usually an icewater mixture at 0 C). The thermocouple generates a voltage that depends on the difference in temperature between the two junctions. This voltage is the thermometric property and is measured by a voltmeter.
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Because this electrical resistance changes with temperature, electrical resistance is another thermometric property. Electrical resistance thermometers are often made from platinum wire, because platinum has excellent mechanical and electrical properties in the temperature range from 270 C to +700 C. The electrical resistance of platinum wire is known as a function of temperature. Thus, the temperature of a substance can be determined by placing the resistance thermometer in thermal contact with the substance and measuring the resistance of the platinum wire.
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Radiation emitted by an object can also be used to indicate temperature. At low to moderate temperatures, the predominant radiation emitted is infrared. As the temperature is raised, the intensity of the radiation increases substantially. Thermal painting is called a thermograph or thermogram. Thermography is an important diagnostic tool in medicine.
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For modest temperature changes, experiments show that the change in length is directly proportional to the change in temperature (L w (T In addition, the change in length is proportional to the initial length of the rod. (L
is proportional to both L0 and (T ( (L w L0 (T ) by using a proportionality constant E , which is called the coefficient of linear expansion.
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LINEAR THERMAL EXPANSION OF A SOLID The length L0 of an object changes by an amount ( L when its temperature changes by an amount ( T:
(L ! EL0 (T
where E is the coefficient of linear expansion. Common Unit for the Coefficient of Linear Expansion:
1 1 ! C r Cr
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Substance
Linear (a)
Solids Aluminium Brass Concrete Copper Glass (common) 23 106 19 106 12 106 17 106 8.5 106 69 106 57 106 36 106 51 106 26 106
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Liquidsb Benzene Carbon tetrachloride Ethyl alcohol Gasoline Mercury Methyl alcohol Water 1240 106 1240 106 1120 106 950 106 182 106 1200 106 207 106
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A concrete sidewalk is constructed between two buildings on a day when the temperature is 25 C. The sidewalk consists of two slabs, each three meters in length and of negligible thickness . As the temperature rises to 38 C, the slabs expand, but no space is provided for thermal expansion. The buildings do not move, so the slabs buckle upward. Determine the vertical distance y in part b of the drawing.
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Antiscalding device screws onto the end of a faucet and quickly shuts off the flow of water when it becomes too hot. As the water temperature rises, the actuator spring expands and pushes the plunger forward, shutting off the flow. When the water cools, the spring contracts and the water flow resumes.
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F (L Stress ! ! Y A L0
E = 12 106 (C) 1
(T = 19 C
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Bass
Steel
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Bimetallic strips are frequently used as adjustable automatic switches in electrical appliances.
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THE EXPANSION OF HOLES: Conceptual Example 5. Do Holes Expand or Contract When the Temperature Increases?
Eight square tiles that are arranged to form a square pattern with a hole in the center. If the tiles are heated, what happens to the size of the hole?
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The hole expands just as if it were made of the material of the surrounding tiles.
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32
b&d
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(V ! FV0 (T
where
F = 3E.
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(V ! F V0 (T ! 4.10 v10
6
4
C r
A15quarts
86C r
1
! 0.53quarts
F ! 51v 10
C r
6
1
(V ! F V0 (T ! 51v 10
C r
A15quarts
86C r
1
! 0.066quarts
The overflow volume is 0.53 quarts 0.066 quarts = 0.46 quarts.
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The fact that water has its greatest density at 4 C, rather than at 0 C, has important consequences for the way in which a lake freezes.
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The fact that the density of ice is smaller than the density of water has an important consequence for home owners, who have to contend with the possibility of bursting water pipes during severe winters.
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DEFINITION OF HEAT Heat is energy that flows from a higher-temperature object to a lower-temperature object because of the difference in temperatures. SI Unit of Heat: joule (J) The internal energy of a substance is the sum of the molecular kinetic energy (due to the random motion of the molecules), the molecular potential energy (due to forces that act between the atoms of a molecule and between molecules), and other kinds of molecular energy. When heat flows in circumstances where the work done is negligible, the internal energy of the hot substance decreases and the internal energy of the cold substance increases. 41
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Q ! cm(T
where c is the specific heat capacity of the substance. Common Unit for Specific Heat Capacity: J/(kgC)
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Substance
Solids Aluminum Copper Glass Human body (37 C, average) Ice (15 C) Iron or steel Lead Silver 9.00 102 387 840
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Liquids Benzene Ethyl alcohol Glycerin Mercury Water (15 C) 1740 2450 2410 139 4186
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(b)
At a cost of $0.10 per kWh, the bill for the heat is $0.64 or 64 cents.
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GASES
The value of the specific heat capacity depends on whether the pressure or volume is held constant while energy in the form of heat is added to or removed from a substance. The distinction between constant pressure and constant volume is usually not important for solids and liquids but is significant for gases.
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Joules experiments revealed that the performance of mechanical work, like rubbing your hands together, can make the temperature of a substance rise, just as the absorption of heat can.
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CALORIMETRY
The kind of heat transfer that occurs within a thermos of iced tea also occurs within a calorimeter, which is the experimental apparatus used in a technique known as calorimetry.
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cunknown
ater
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(T (C)
15 40 25 20
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c, b, d, a
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The graph shows the way the temperature of water changes as heat is added, starting with ice at 30 C. The pressure is atmospheric pressure.
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HEAT SUPPLIED OR REMOVED IN CHANGING THE PHASE OF A SUBSTANCE The heat Q that must be supplied or removed to change the phase of a mass m of a substance is
where L is the latent heat of the substance. SI Unit of Latent Heat: J/kg The latent heat of fusion Lf refers to the change between solid and liquid phases, the latent heat of vaporization Lv applies to the change between liquid and gas phases, and the latent heat of sublimation Ls refers to the change between solid and gas phases. 60
Substance
Latent Heat of Fusion, Lf (J/kg) 33.2 104 12.6 104 20.7 104 10.8 104 6.28 104 2.32 104 1.14 104 2.57 104 1.39 104 33.5 104
Latent Heat of Vaporization, Lv (J/kg) 13.7 105 3.94 105 47.3 105 8.55 105 17.2 105 8.59 105 2.96 105 2.00 105 2.13 105 22.6 105 61
Ammonia Benzene Copper Ethyl alcohol Gold Lead Mercury Nitrogen Oxygen Water
114.4
78.3
Q = mLf
Q = cm (T
mL
! cm (T
f ice
lemonade
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(a)
(b)
(c)
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(d)
(e)
.
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A dye-sublimation printer. As the plastic film passes in front of the print head, the heat from a given heating element causes one of three pigments or dyes on the film to sublime from a solid to a gas. The gaseous dye is absorbed onto the coated paper as a dot of color. The size of the dots on the paper has been exaggerated for clarity.
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c, a, b
6.0 C 12 C 3.0 C
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(b) (c)
The pressure of the vapor that coexists in equilibrium with the liquid is called the equilibrium vapor pressure of the liquid. 69
The equilibrium vapor pressure does not depend on the volume of space above the liquid. Only when the temperature and vapor pressure correspond to a point on the curved line, which is called the vapor pressure curve or the vaporization curve, do liquid and vapor phases coexist 70 in equilibrium.
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Water is boiling in an open flask. Shortly after the flask is removed from the burner, the boiling stops. A cork is then placed in the neck of the flask to seal it. To restart the boiling, should you pour hot (but not boiling) water or cold water over the neck of the flask, as in part b of the drawing?
It is possible to restart the boiling by pouring cold water over the neck of the flask.
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The operation of spray cans is based on the equilibrium between a liquid and its vapor.
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As is the case for liquid/vapor equilibrium, a solid can be in equilibrium with its liquid phase only at specific conditions of temperature and pressure. For each temperature, there is a single pressure at which the two phases can coexist in equilibrium. A plot of the equilibrium pressure versus equilibrium temperature is referred to as the fusion curve.
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Humidity
The partial pressure of a gas is the pressure it would exert if it alone occupied the entire volume at the same temperature as the mixture.
When the partial pressure of the water vapor equals the equilibrium vapor pressure of water at a given temperature, the relative humidity is 100%. In such a situation, the vapor is said to be saturated because it is present in the maximum amount, as it would be above a pool of liquid at equilibrium in a closed container. 75
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(a)
(b)
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When air containing a given amount of water vapor is cooled, a temperature is reached in which the partial pressure of the vapor equals the equilibrium vapor pressure. This temperature is known as the dew point.
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Concepts & Calculations Example 17. Linear and Volume Thermal Expansion
Three rectangular blocks are made from the same material. The initial dimensions of each are expressed as multiples of D, where D = 2.00 cm. They are heated and their temperatures increase by 35.0 C. 80
The coefficients of linear and volume expansion are and respectively. Determine the change in their (a) vertical heights and (b) volumes.
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(b)
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Objects A and B are made from copper, but the mass of B is three times that of A. Object C is made from glass and has the same mass as B. The same amount of heat Q is supplied to each one: Q = 14 J. Determine the rise in temperature for each.
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Conceptual Question 3
REASONING AND SOLUTION The plate is made of aluminum; the spherical ball is made of brass. The coefficient of linear expansion of aluminum is greater than the coefficient of linear expansion of brass. Therefore, if the plate and the ball are heated, both will expand; however, the diameter of the hole in the aluminum plate will expand more than the diameter of the brass ball. In order to prevent the ball from falling through the hole, the plate and the ball must be cooled. Both the diameter of the hole in the plate and the diameter of the ball will contract. The diameter of the hole will decrease more than the diameter of the ball, thereby preventing the ball from falling through the hole.
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Problem 12
REASONING AND SOLUTION a. The radius of the hole will be larger when the plate is heated, because the hole expands as if it were made of copper. b. The expansion of the radius is ( r = E r0 (T . Using the value for the coefficient of thermal expansion of copper given in Table 12.1, we find that the fractional change in the radius is
! 0.0017
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Problem 18
REASONING AND SOLUTION The initial diameter of the sphere, ds, is
ds = (5.0 * 104)dr + dr
where dr is the initial diameter of the ring. Applying to the diameter of the sphere gives
(L ! EL0 (T
(d s ! E s d s (T
and to the ring gives
(d r ! E r d r (T
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d s (d s ! d r (d r
(T !
d r ds E sd s E r d r
Substituting Equation (1) in this result and taking values for the coefficients of thermal expansion of steel and lead from Table 10.1 yield 4
(T !
5.0 v 10
! 29Cr
41 rC
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Problem 30
REASONING AND SOLUTION Both the water and pipe expand as the temperature increases.
(VW ! FW V0 (T
(VP ! F CV0 (T
V0 ! Tr L
2
(V ! (VW (V ! ( FW F C )V0 (T
(V !(207 10 Cr 51 10 Cr )T(9.5v10 m) ( 6 )(54 r) v v m C
! 1.8 v 10 m
4
6
1
6
1
3
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Problem 32
REASONING AND SOLUTION Both the coffee and beaker expand as the temperature increases.
(VC ! FW V0 (T
(Vb ! F bV0 (T
6
1
6
1
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Problem 46
REASONING AND SOLUTION We wish to convert 2.0% of the heat Q into gravitational potential energy, i.e., (0.020)Q = mgh. Thus
mg !
0.020
Q
h
! 4.4 v 10 3 N
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