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BAS ES
A guide for A level students
KNOCKHARDY PUBLISHING
Acid & Bases
INTRODUCTION
This Powerpoint show is one of several produced to help students understand
selected topics at AS and A2 level Chemistry. It is based on the requirements of
the AQA and OCR specifications but is suitable for other examination boards.
Individual students may use the material at home for revision purposes or it
may be used for classroom teaching if an interactive white board is available.
Accompanying notes on this, and the full range of AS and A2 topics, are
available from the KNOCKHARDY SCIENCE WEBSITE at...
www.argonet.co.uk/users/hoptonj/sci.htm
CONTENTS
• Brønsted-Lowry theory of acids and bases
• Lewis theory of acids and bases
• Strong acids and bases
• Weak acids
• Weak bases
• Hydrogen ion concentration and pH
• Ionic product of water Kw
• Relation between pH and pOH
• Introduction to buffer solutions
• Check list
Acid & Bases
Conjugate systems
Acids are related to bases ACID PROTON + CONJUGATE BASE
Conjugate systems
Acids are related to bases ACID PROTON + CONJUGATE BASE
For an acid to behave as an acid, it must have a base present to accept a proton...
HA + B BH+ + A¯
acid base conjugate conjugate
acid base
LONE PAIR
LONE PAIR DONOR
ACCEPTOR
STRONG
ACIDS completely dissociate (split up) into ions in aqueous solution
STRONG
ACIDS completely dissociate (split up) into ions in aqueous solution
STRONG
BASES completely dissociate into ions in aqueous solution
The dissociation constant for the weak acid HA is Ka = [H+(aq)] [A¯(aq)] mol dm-3
[HA(aq)]
WEAK BASES
Partially react with water to give ions in aqueous solution e.g. ammonia
Partially react with water to give ions in aqueous solution e.g. ammonia
for strong acids and bases the concentration of ions is very much
larger than their weaker counterparts which only partially dissociate.
Hydrogen ion concentration [H+(aq)]
[H+] 100 10-1 10-2 10-3 10-4 10-5 10-6 10-7 10-8 10-9 10-10 10-11 10-12 10-13 10-14
OH¯ 10-14 10-13 10-12 10-11 10-10 10-9 10-8 10-7 10-6 10-5 10-4 10-3 10-2 10-1 10-0
pH 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
This is due to the slight ionisation ... H2O(l) + H2O(l) H3O+(aq) + OH¯(aq)
This is due to the slight ionisation ... H2O(l) + H2O(l) H3O+(aq) + OH¯(aq)
This is due to the slight ionisation ... H2O(l) + H2O(l) H3O+(aq) + OH¯(aq)
As the dissociation is small, the water concentration is very large compared with the
dissociated ions and any changes to its value are insignificant; its concentration can be
regarded as constant.
Temperature / °C 0 20 25 30 60
Kw / 1 x 10-14 mol2 dm-6 0.11 0.68 1.0 1.47 5.6
H+ / x 10-7 mol dm-3 0.33 0.82 1.0 1.27 2.37
pH 7.48 7.08 7 6.92 6.63
What does this tell you about the equation H2O(l) H+(aq) + OH¯(aq) ?
Ionic product of water - Kw
Temperature / °C 0 20 25 30 60
Kw / 1 x 10-14 mol2 dm-6 0.11 0.68 1.0 1.47 5.6
H+ / x 10-7 mol dm-3 0.33 0.82 1.0 1.27 2.37
pH 7.48 7.08 7 6.92 6.63
What does this tell you about the equation H2O(l) H+(aq) + OH¯(aq) ?
Temperature / °C 0 20 25 30 60
Kw / 1 x 10-14 mol2 dm-6 0.11 0.68 1.0 1.47 5.6
H+ / x 10-7 mol dm-3 0.33 0.82 1.0 1.27 2.37
pH 7.48 7.08 7 6.92 6.63
What does this tell you about the equation H2O(l) H+(aq) + OH¯(aq) ?
N.B. As they are based on the position of equilibrium and that varies with
temperature, the above values are only true if the temperature is 25°C (298K)
Acidic Buffer (pH < 7) made from a weak acid + its sodium or potassium salt
ethanoic acid sodium ethanoate
Alkaline Buffer (pH > 7) made from a weak base + its chloride
ammonia ammonium chloride