Laborator 3

Lucrare de laborator privind prelucrarea statistic a datelor pentru apele uzate de la o

pstrvrie.
Mod de lucru:
Se vor reprezenta 8 grafice dupa cum urmeaz:
-

pH-ul pentru cele 12 puncte de lucru pentru data de 14 mai si 18 iunie;

oxigenul dizolvat pentru cele 12 puncte de lucru;
CBO5pentru cele 12 puncte de lucru;
reziduu fix;
azot total;
fosfor tota;l
CCO-Mn;
CCO-Cr.
Se calculeaza pentru fiecare indicator valoarea medie.
n fiecare punct de lucru se va face la rndul su o medie ntre valorile msurate la
cele 2 date.
Pentru fiecare din indicatori se va calcula abaterea standard i pentru indicatorii pH,
reziduu fix, coeficient de corectie respectiv ntre CBO5 i azot total respectiv CBO5 i fosfor
total.
Table nr. 1 Datele prelevate in data de 14 mai
indicato
r
proba 1
proba 2
proba 3
proba 4
proba 5
proba 6
proba 7
proba 8
proba 9
proba
10
proba
11
proba
12
proba
13
proba
14

Ph
7,06
7,14
7,17
7,02
7,06
7,09
7,03
7,07
7,42

Oxigen_dizolva
Reziduu_fix_105_
t
P_tot
CBO5
C
N_tot
CCO_Cr
10,95
0,02
1,59
50,81
0,382
3,13
9,34
0,027
1,72
55,1
0,446
3,33
10,12
0,012
1,62
98,24
0,391
3,04
9,74
0,035
1,56
58,47
0,372
3,36
9,4
0,023
1,61
56,77
0,578
3,38
10,14
0,011
1,64
52,15
0,291
3,26
9,86
0,015
1,66
55,46
0,226
3,19
9,51
0,017
1,6
55,75
0,22
3,16
9,88
0,021
1,87
62,19
0,435
3,15

7,09

9,77

0,042

1,7

57,01

0,473

3,24

7,06

9,31

0,035

1,66

59,08

0,346

4,2

7,11

10,2

0,022

1,53

59,21

0,573

7,18

9,79

0,018

1,55

56,45

0,479

3,12

7,16

9,56

0,02

1,5

66,28

0,359

3,03

Cu ajutorul programului MedCalc s-au calculate urmatoarele:

Variable

: REZIDUU_FIX

Sample size = 12
Lowest value = 44,7500
Highest value

= 98,2400

Arithmetic mean

= 57,8050

95% CI for the mean = 49,1757 to 66,4343

Median = 56,5900
95% CI for the median = 48,4363 to 58,9646
Variance = 184,4572
Standard deviation =

13,5815

Relative standard deviation = 0,2350 (23,50%)

Standard error of the mean

= 3,9206

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,052)

Percentiles : 2.5th = 44,7500 97.5th = 98,2400

5th =45,0990

Variable

95th = 94,3430

10th = 47,1930

90th =70,9610

25th = 50,1100

75th = 58,3000

: pH

Sample size = 12
Lowest value =
Highest value

6,5800
= 7,9600

Arithmetic mean =

7,2817

95% CI for the mean = 7,0095 to 7,5538

Median

= 7,3550

95% CI for the median = 6,7000 to 7,6245

Variance = 0,1834
Standard deviation

= 0,4283

Relative standard deviation = 0,0588 (5,88%)

Standard error of the mean

= 0,1236

Kolmogorov-Smirnov test
for Normal distribution: accept Normality (P=0,660)
Percentiles : 2.5th = 6,5800 97.5th =7,9600
5th = 6,5860

Variable

95th = 7,9270

10th = 6,6220

90th = 7,7290

25th = 6,9900

75th = 7,5950

: p_total

Sample size = 12
Lowest value
Highest value

0,0310

= 0,1200

Arithmetic mean = 0,0687

95% CI for the mean =
Median

0,0516 to 0,0858

= 0,0630

95% CI for the median = 0,0464 to 0,0953

Variance

= 0,0007

Standard deviation = 0,0269

Relative standard deviation = 0,3923 (39,23%)
Standard error of the mean

= 0,0078

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,861)

Percentiles : 2.5th = 0,0310 97.5th = 0,1200

Variable

5th = 0,0321

95th = 0,1190

10th = 0,0387

90th = 0,1130

25th = 0,0500

75th = 0,0825

: oxigen_dizolvat

Sample size = 12
Lowest value = 10,0800
Highest value = 11,4000
Arithmetic mean = 10,9083
95% CI for the mean
Median

= 10,6467 to 11,1700

= 10,9900

95% CI for the median = 10,5290 to 11,3273

Variance = 0,1696
Standard deviation = 0,4118
Relative standard deviation =0,0377 (3,77%)
Standard error of the mean

= 0,1189

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,795)

Percentiles : 2.5th = 10,0800 97.5th =

Variable

11,4000

5th = 10,1020

95th =11,3960

10th = 10,2340

90th = 11,3720

25th = 10,7200

75th = 11,2100

: n_total

Sample size = 12
Lowest value =0,2500
Highest value

= 0,5280

Arithmetic mean = 0,3642

95% CI for the mean

= 0,3072 to 0,4212

Median = 0,3460
95% CI for the median = 0,2772 to 0,4734
Variance

0,0080

Standard deviation

= 0,0897

Relative standard deviation = 0,2464 (24,64%)

Standard error of the mean

= 0,0259

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,761)

Percentiles : 2.5th = 0,2500 97.5th = 0,5280

Variable

5th = 0,2519

95th = 0,5239

10th = 0,2633

90th = 0,4993

25th = 0,2860

75th = 0,4335

: CCO_cr

Sample size = 12
Lowest value = 2,4800
Highest value = 4,2800
Arithmetic mean = 3,0733
95% CI for the mean = 2,7025 to 3,4442
Median

= 2,9250

95% CI for the median

Variance

= 2,5273 to 3,7482

= 0,3406

Standard deviation

= 0,5836

Relative standard deviation = 0,1899 (18,99%)

Standard error of the mean
Kolmogorov-Smirnov test

= 0,1685

for Normal distribution

: accept Normality (P=0,563)

Percentiles : 2.5th = 2,4800 97.5th = 4,2800

5th = 2,4820

Variable

95th = 4,2470

10th = 2,4940

90th = 4,0490

25th = 2,6200

75th = 3,3500

: CBO5

Sample size = 12
Lowest value = 1,2600
Highest value

= 2,0500

Arithmetic mean

= 1,5508

95% CI for the mean =

Median

1,3867 to 1,7150

= 1,4750

95% CI for the median

Variance

= 1,3127 to 1,8682

= 0,0668

Standard deviation

0,2584

Relative standard deviation =

0,1666 (16,66%)

Standard error of the mean

0,0746

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,586)

Percentiles : 2.5th = 1,2600 97.5th = 2,0500

5th = 1,2620

95th = 2,0400

10th = 1,2740

90th =1,9800

25th = 1,3700

75th = 1,7200

Variable Y : pH
Variable X : REZIDUU_FIX

Sample size = 12
Correlation coefficient r = 0,2393 P=0,4539
95% Confidence interval for r = -0,3879 to 0,7150
Variable Y : CBO5
Variable X : p_total
Sample size = 12
Correlation coefficient r = -0,0032 P=0,9921
95% Confidence interval for r = -0,5761 to 0,5717
Variable Y : CBO5
Variable X : n_total
Sample size = 12
Correlation coefficient r

= 0,7120 P=0,0094

95% Confidence interval for r = 0,2335 to 0,9129

Table. Nr. 2 Datele prelevate in data de 18. Iunie

indicato
r
proba 1
proba 2
proba 3
proba 4
proba 5
proba 6
proba 7
proba 8
proba 9
proba
10
proba
11
proba
12
proba
13
proba
14

Ph
7,06
7,14
7,17
7,02
7,06
7,09
7,03
7,07
7,42

Oxigen_dizolva
Reziduu_fix_105_
t
P_tot
CBO5
C
N_tot
CCO_Cr
10,95
0,02
1,59
50,81
0,382
3,13
9,34
0,027
1,72
55,1
0,446
3,33
10,12
0,012
1,62
53,2
0,391
3,04
9,74
0,035
1,56
58,47
0,372
3,36
9,4
0,023
1,61
56,77
0,578
3,38
10,14
0,011
1,64
52,15
0,291
3,26
9,86
0,015
1,66
55,46
0,226
3,19
9,51
0,017
1,6
55,75
0,22
3,16
9,88
0,021
1,87
62,19
0,435
3,15

7,09

9,77

0,042

1,7

57,01

0,473

3,24

7,06

9,31

0,035

1,66

59,08

0,346

4,2

7,11

10,2

0,022

1,53

59,21

0,573

7,18

9,79

0,018

1,55

56,45

0,479

3,12

7,16

9,56

0,02

1,5

66,28

0,359

3,03

Cu ajutorul programului MedCalc am calculate urmatoarele variabile:

Variable

: Ph

Sample size =

14

Lowest value = 7,0200

Highest value = 7,4200
Arithmetic mean

7,1186

95% CI for the mean

Median

= 7,0605 to 7,1766

= 7,0900

95% CI for the median = 7,0600 to 7,1676

Variance

= 0,0101

Standard deviation = 0,1005

Relative standard deviation = 0,0141 (1,41%)
Standard error of the mean

= 0,0269

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,585)

Percentiles : 2.5th = 7,0200 97.5th =

Variable

5th = 7,0220

95th 7,3720

10th =7,0290

90th = 7,2040

25th = 7,0600

75th = 7,1600

7,4200

: Oxigen_dizolvat

Sample size = 14
Lowest value =
Highest value

9,3100

= 10,9500

Arithmetic mean =

9,8264

95% CI for the mean = 9,5753 to 10,0775

Median = 9,7800
95% CI for the median

= 9,4260 to 10,1353

Variance = 0,1891
Standard deviation = 0,4349
Relative standard deviation = 0,0443 (4,43%)
Standard error of the mean

= 0,1162

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,803)

Percentiles : 2.5th = 9,3100 97.5th = 10,9500

5th = 9,3160

95th = 10,8000

10th = 9,3370

90th = 10,2750

25th = 9,5100
Variable

75th = 10,1200

: P_tot

Sample size = 14
Lowest value = 0,0110
Highest value = 0,0420
Arithmetic mean

= 0,0227

95% CI for the mean =

0,0175 to 0,0280

Median = 0,0205
95% CI for the median = 0,0155 to 0,0331
Variance = 0,0001
Standard deviation = 0,0091
Relative standard deviation = 0,4007 (40,07%)
Standard error of the mean

= 0,0024

Kolmogorov-Smirnov test
for Normal distribution
: accept Normality (P=0,569)
Percentiles : 2.5th = 0,0110 97.5th = 0,0420
5th = 0,0112 95th = 0,0406
10th = 0,0119 90th = 0,0357
25th = 0,0170 75th = 0,0270

Variable

: CBO5

Sample size = 14
Lowest value = 1,5000
Highest value = 1,8700
Arithmetic mean = 1,6293
95% CI for the mean
Median

= 1,5753 to 1,6833

= 1,6150

95% CI for the median = 1,5524 to 1,6905

Variance = 0,0087
Standard deviation

0,0935

Relative standard deviation = 0,0574 (5,74%)

Standard error of the mean

= 0,0250

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,849)

Percentiles : 2.5th = 1,5000 97.5th = 1,8700

5th = 1,5060

95th = 1,8400

10th = 1,5270

90th =1,7350

25th = 1,5600
Variable

75th = 1,6600

: Reziduu_fix_105_C

Sample size = 14
Lowest value = 50,8100
Highest value = 66,2800
Arithmetic mean= 56,9950
95% CI for the mean = 54,6821 to 59,3079
Median

= 56,6100

95% CI for the median = 53,6489 to 59,1793

Variance

16,0464

Standard deviation

4,0058

Relative standard deviation = 0,0703 (7,03%)

Standard error of the mean

= 1,0706

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,898)

Percentiles : 2.5th = 50,8100 97.5th = 66,2800

Variable

5th = 51,0780

95th = 65,4620

10th = 52,0160

90th = 62,5990

25th = 55,1000

75th = 59,0800

: N_tot

Sample size = 14
Lowest value = 0,2200
Highest value = 0,5780
Arithmetic mean = 0,3979
95% CI for the mean = 0,3345 to 0,4613
Median = 0,3865
95% CI for the median = 0,3040 to 0,4776
Variance = 0,0121
Standard deviation

0,1098

Relative standard deviation = 0,2760 (27,60%)

Standard error of the mean

= 0,0294

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,997)

Percentiles : 2.5th = 0,2200 97.5th = 0,5780

5th = 0,2212

95th = 0,5770

10th = 0,2254

90th = 0,5735

25th = 0,3460

75th = 0,4730

Variable

: CCO_Cr

Sample size

= 14

Lowest value = 3,0000

Highest value

= 4,2000

Arithmetic mean = 3,2564

95% CI for the mean = 3,0850 to 3,4278
Median

= 3,1750

95% CI for the median

= 3,0589 to 3,3529

Variance = 0,0881
Standard deviation = 0,2968
Relative standard deviation = 0,0912 (9,12%)
Standard error of the mean

0,0793

Kolmogorov-Smirnov test
for Normal distribution

: accept Normality (P=0,230)

Percentiles : 2.5th = 3,0000 97.5th = 4,2000

5th = 3,0060

95th = 4,0360

10th =3,0270

90th = 3,4620

25th 3,1200

75th = 3,3300

Variable Y : CBO5
Variable X : N_tot
Sample size = 14
Correlation coefficient r = -0,0298 P=0,9194
95% Confidence interval for r = -0,5517 to 0,5088
Variable Y : CBO5
Variable X : P_tot
Sample size = 14
Correlation coefficient r = 0,1507 P=0,6071

95% Confidence interval for r = -0,4129 to 0,6308

Variable Y : Ph
Variable X : Reziduu_fix_105_C
Sample size = 14
Correlation coefficient r = 0,4020 P=0,1541
95% Confidence interval for r = -0,1634 to 0,7687

6
5
Frequency

Frequency

4
3

2
1
0

40

45

50

55

60

65

70

75

80

85

90

95

REZIDUU_FIX

Fig.nr.1 Cantitatea de reziduu fix la 14.05

100 105

50

52

54

56

58

60

62

64

Reziduu_fix_105_C

Fig.nr.2 Cantitatea de reziduu fix la

18.06

Un al treilea indice studiat este cantitatea de reziduu fix. In data de 14 mai media
acestui indice a fost de 57,77mg/l, cu o abatere de 13,58%. Maximul masurat al acestui indice
a fost de 98,24 mg/l la proba3. Minimul a fost de 44.75mg/l, masurat la punctual de
prelevare1. In data de 18.06 valoarea medie a cantitatii de reziduu fix a fost de 66,49mg/l, cu
o abatere standard de 4,0%, deci mai mica decat in 14 mai. Cantitatea de reziduu fix in data
de 18.06 a atins maximul la proba 12 (66.28mg/l) si minimul la proba 1 (50,81mg/L).

66

68

Frequency

Frequency

0
6,4

6,6

6,8

7,0

7,2

7,4

7,6

7,8

8,0

7,00

8,2

7,05

7,10

7,15

7,20

7,25

7,30

7,35

7,40

7,45

Ph

pH

Fig.nr.3 Concentratia pH-ului la data de 14.05

Fig.nr.4 Concentratia pH-ului la data

de 18.06

Comparand pH-ul apei in ambele zile de preluare a probelor s-a constatat ca cel din
data de 14 mai prezinta fluctuatii mai mari. Maximul este de 7.196unitati la proba 13 in timp
ce minimul a fost de 6.58 unitati. Media a fost de 7.28 unitati de ph. In data de 18 iunie
valorile au fost mult mai liniare, incadrandu-se intre 7,02 si 7,42 unitati de ph. Valoarea
media pentru aceasta data a fost de 8,3 unitati.

Frequency

Frequency

1
1

0
0,03

0,04

0,05

0,06

0,07

0,08

0,09

0,10

0,11

0,12

0,13

p_total

Fig, nr 5 Concentratia de P total la data de 14.05

0,010

0,015

0,020

0,025

0,030

0,035

0,040

P_tot

Fig, nr 6 Concentratia de P total la data de

18.06

Cantitatea de P total este mult mai mare la data de 14 mai fata de 18 .06. valoarea
medie de P total in data de 14 mai este de 0,0268 mg/l, ci 0,0003 mg/l mai mare fata de cea
din data de 18.06 ( 0,0265 mg/l). Pe data de 14 mai valoarea maxima a fost de o,o31 mg/l in
timp ce valoarea minima a fost de 0,013 mg/l. Pe data de 18.06, valoarea maxima de 0.42
mg/l a fost masutata la proba 10, iar cea minima, de 0,11 mg/l, a fost masurata la proba 6.

0,045

Frequency

Frequency

10,0

10,2

10,4

10,6

10,8

11,0

11,2

9,2

11,4

9,4

9,6

9,8

10,0

10,2

10,4

10,6

10,8

11,0

11,2

Oxigen_dizolvat

oxigen_dizolvat

Fig.nr.7 Concentratia de oxigen dizolvat

la data de 14.05

Fig. Nr. 8 Concentratia de oxigen

dizolvat la data de 18.06

Frequency

Frequency

In ceea ce priveste cantitatea de oxigen dizolvat, media masurata in ziua de 14 mai

(10,95mg/l) a fost mai mica decat cea masurata in data de 18 iunie (11,46mg/l). Pe data de 14
mai valorile acestui indice s-au incadrat intre 10,8 mg/l la proba 10 si proba 12 si 11,4mg/,l
masurata in zona paraului Pascoaia. In data de 18 mai valorile au fost mult mai fluctuante,
acestea variind intre limite mult mai mari. Maximul a fost inregistrat la proba 1
(10.95mg/l)iar minimul de 9.31 mg/l a fost masurat la proba 11.

0
0,25

0,30

0,35

0,40

0,45

0,50

n_total

Fig.Nr.9 Concentratia de N total in data de 14.05

0,55

0,20

0,25

0,30

0,35

0,40

0,45

0,50

0,55

N_tot

Fig. Nr.10 Concentratia de N total in data

de 18.06

Conform histogramei, se poate observa ca in ceea ce priveste cantitatea de azot total,

valoarea lui este mult mai crescuta sim ult mai fluctuanta in data de 18.06, datorita procesului
de reproducere la aceasta specia de pesti. Astfel ca, in cea de-adoua data in care s-au efectuat
masuratori, valoarea maxima a fost de 0,578 mgN/l la punctual 5 de recoltare a apei, iar
valoarea minima masurata a fost de 0.025 mgN/l, la proba 8, in lateralul pastravariei, la 50
cm deasupra fundului lacului. Media cantitatii de N total la aceasta data a fost de
0.4642mgN/l. In data de 18 iunie, media cantitatii de N total a fost de 0.089 mgN/l, cu o
valoare maxima de 0,528 mgN/l la proba 2 si o minima de 0.22 mgN/l la proba 6, in lateralul
pastravariei.

0,60

Frequency

Frequency

2
3

1
1

0
2,4

2,6

2,8

3,0

3,2

3,4

3,6

3,8

4,0

4,2

3,0

4,4

3,1

3,2

3,3

3,4

3,5

3,6

3,7

3,8

3,9

4,0

4,1

4,2

4,3

CCO_Cr

CCO_cr

Fig.Nr.11 Concentratia de CCO-Cr la data de 14.05

Fig Nr.12 Concentratia de CCO-Cr la data

de 18.06

Cantitatea de CCO-Cr este mai mare in zona paraului si mai mica in amonte in data
de 14 mai, iar in data de 18.06 aceasta situatie este invers proportionala. In cazul indicelui
CCO-Cr, valoarea medie este de 0,5023 mgO2/l in data de 14.05. valoarea maxima masurata
a fost de 2,48 mgO2/l la proba 3. Valoarea minima a fost de 1,99 mgO2/l la proba 7. Pentru
acelasi indicator, valoarea medie a fost de 3,07 mgO2/l in data de 18.06. valoarea maxima in
aceasta data a fost de 4,20 mgO2/l la proba 11, iar cea minima de 2,45 mgO2/l
4

Frequency

Frequency

1
1

0
1,2

1,3

1,4

1,5

1,6

1,7

1,8

1,9

2,0

2,1

CBO5

Fig, nr, 13 Concentratia de CBO5 la data de 14.05

1,50

1,55

1,60

1,65

1,70

1,75

1,80

1,85

CBO5

Fig, nr, 14 Concentratia de CBO5 la data

de 18.06

In data de 14 mai , valoare medie de CBO5 este 1,5516 mgO2/l, mai mica decat la a-doua
masuratoare, din 18.06, de 1,901 mgO2/l. Pe data de 14 mai valorile au fluctuat intre 1,26
mgO2/l la proba a 7-a, ion lateralul pastravariei la 30 cm adancime, si 2.05 mgO2/l la punctual
3 de monitorizare. In data de 18.06, valoarea maxima este de 1,87mgO2/l la proba 9, si un
minim de 1.5 mgO2/l la proba13, in amonte de pastravarie la circa 30 cm adancime.

1,90