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Editura Explorator - Chimie Anorganica - Elena Alexandrescu PDF
Editura Explorator - Chimie Anorganica - Elena Alexandrescu PDF
CHIMIE
ANORGANICĂ
şi FIZICĂ
pentru liceu şi gimnaziu
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tal
Sinteze
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se Probleme
Teste
Elena Alexandrescu
CHIMIE
ANORGANICĂ
și FIZICĂ
pentru liceu și gimnaziu
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Probleme
Teste
Autori: Elena Alexandrescu
prof. gr. I - Şcoala Internaţională „Spectrum”, Ploieşti
546
544
ISBN: 978-606-93525-7-1
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TABELUL PERIODIC AL ELEMENTELOR
Blocul s Blocul d Blocul p
GRUPE
Perioade
1 (IA) 18 (VIIIA)
1 1,00797 2 4,00260
1 H He
Hidrogen Numãr atomic ¾ 1 0,00797 ½ Masa atomicã Heliu
2,1 313 567
1s1 2 (IIA) ½ Simbol chimic 13 (IIIA) 14 (IVA) 15 (VA) 16 (VIA) 17 (VIIA) 1s2
3 6,941 4 9,01218 Denumire ¾ Hidrogen
H 5 10,81 6 12,01 7 14,00 8 15,99 9 18,99 10 20,179
Electronegativitate ¾ 2,1 313 ½ Energia primei
2 Li Be 1s1 ionizãri [kcal/g mol] B C N O F Ne
Litiu Beriliu ¿ Bor Carbon Azot Oxigen Fluor Neon
1,0 124 1,5 215 Configurația electronicã 2,0 191 2,5 260 3,0 336 3,5 314 4,0 402 - 497
1s22s1 1s22s2 1s22s22p1 1s22s22p2 1s22s22p3 1s22s22p4 1s22s22p5 1s22s22p6
11 22,98977 12 24,305 13 26,98 14 28,08 15 30,97 16 32,06 17 35,45 18 39,94
3 Na Mg Al Si P S Cl Ar
Sodiu Magneziu Aluminiu Siliciu Fosfor Sulf Clor Argon
0,9 119 1,2 176 1,5 138 1,8 188 2,1 254 2,5 239 3,0 300 - 363
[Ne]3s1 [Ne]3s2 3 (IIIB) 4 (IVB) 5 (VB) 6 (VIB) 7 (VIIB) 8 (VIIIB) 9 (VIIIB) 10 (VIIIB) 11 (IB) 12 (IIB) [Ne]3s23p1 [Ne]3s23p2 [Ne]3s23p3 [Ne]3s23p4 [Ne]3s23p5 [Ne]3s23p6
19 39,0983 20 40,08 21 44,9559 22 47,88 23 50,94 24 51,99 25 54,93 26 55,84 27 58,93 28 58,69 29 63,54 30 65,39 31 69,72 32 72,61 33 74,9216 34 78,96 35 79,904 36 83,80
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Potasiu Calciu Scandiu Titan Vanadiu Crom Mangan Fier Cobalt Nichel Cupru Zinc Galiu Germaniu Arsen Seleniu Brom Kripton
0,8 100 1,0 141 1,3 151 1,5 158 1,6 156 1,6 156 1,5 171 1,8 182 1,8 181 1,8 176 1,9 178 1,6 216 1,6 138 1,8 187 2,0 231 2,4 225 2,8 273 - 323
[Ar]4s1 [Ar]4s2 [Ar]3d14s2 [Ar]3d24s2 [Ar]3d34s2 [Ar]3d54s1 [Ar]3d54s2 [Ar]3d64s2 [Ar]3d74s2 [Ar]3d84s2 [Ar]3d104s1 [Ar]3d104s2 [Ar]3d104s24p1 [Ar]3d104s24p2 [Ar]3d104s24p3 [Ar]3d104s24p4 [Ar]3d104s24p5 [Ar]3d104s24p6
37 85,4678 38 87,62 39 88,9059 40 91,22 41 92,90 42 95,94 43 (98) 44 101,07 45 102,90 46 106,42 47 107,86 48 112,41 49 114,82 50 118,71 51 121,75 52 127,60 53 126,90 54 131,29
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Rubidiu Stronțiu Ytriu Zirconiu Niobiu Molibden Tecnețiu Ruteniu Rodiu Paladiu Argint Cadmiu Indiu Staniu Stibiu Telur Iod Xenon
0,8 96 1,0 131 1,3 152 1,4 160 1,6 156 1,8 166 1,9 167 2,2 173 2,2 178 2,2 192 1,9 175 1,7 207 1,7 133 1,8 169 1,9 199 2,1 208 2,5 241 - 280
[Kr]5s1 [Kr]5s2 [Kr]4d15s2 [Kr]4d25s2 [Kr]4d45s1 [Kr]4d55s1 [Kr]4d55s2 [Kr]4d75s1 [Kr]4d85s1 [Kr]4d105s0 [Kr]4d105s1 [Kr]4d105s2 [Kr]4d105s25p1 [Kr]4d105s25p2 [Kr]4d105s25p3 [Kr]4d105s25p4 [Kr]4d105s25p5 [Kr]4d105s25p6
55 132,9054 56 137,33 57-71 72 178,49 73 180,94 74 183,85 75 186,20 76 190,2 77 192,22 78 195,08 79 196,96 80 200,59 81 204,38 82 207,2 83 208,98 84 [209] 85 [210] 86 [222]
6 Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Cesiu Bariu Hafniu Tantal Wolfram Reniu Osmiu Iridiu Platinã Aur Mercur Taliu Plumb Bismut Poloniu Astatin Radon
0,7 90 0,9 120 1,3 127 1,5 138 1,7 184 1,9 182 2,2 201 2,2 212 2,2 207 2,4 213 1,9 241 1,8 141 1,8 171 1,9 185 2,0 - 2,2 - - 248
[Xe]6s1 [Xe]6s2
La-Lu [Xe]4f145d26s2 [Xe]4f145d36s2 [Xe]4f145d46s2 [Xe]4f145d56s2 [Xe]4f145d66s2 [Xe]4f145d76s2 [Xe]4f145d96s1 [Xe]4f145d106s1 [Xe]4f145d106s2 [Xe]4f145d106s26p1 [Xe]4f145d106s26p2 [Xe]4f145d106s26p3 [Xe]4f145d106s26p4 [Xe]4f145d106s26p5 [Xe]4f145d106s26p6
87 [223] 88 226,0254 89-103 104 [261] 105 [262] 106 [263] 107 [262] 108 [265] 109 [266]
7 Fr Ra Ac-Lr Rf Db Sg Bh Hs Mt
Franciu Radiu Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnérium
0,7 - 0,9 - - - - - - - - - - - - -
[Rn]7s1 [Rn]7s2 [Rn]5f146d27s2 [Rn]5f146d37s2 [Rn]5f146d47s2 [Rn]5f146d57s2 [Rn]5f146d67s2 [Rn]5f146d77s2
Blocul f
57 138,9055 58 140,12 59 140,90 60 144,24 61 [145] 62 150,36 63 151,96 64 157,25 65 158,92 66 6,941 67 164,93 68 167,26 69 168,93 70 173,04 71 174,96
Lantanide La
Lantan
Ce
Ceriu
Pr
Praseodim
Nd Pm Sm Eu
Neodim Promețiu Samariu Europiu
Gd
Gadoliniu
Tb
Terbiu
Dy
Disprosiu
Ho
Holmiu
Er
Erbiu
Tm Yb
Tuliu Yterbiu
Lu
Lutețiu
1,1 129 1,1 159 1,1 133 1,2 145 - 133 1,2 129 - 131 1,1 142 1,2 155 - 157 1,2 - 1,2 - 1,2 - 1,1 143 1,2
[Xe]5d16s2 [Xe]4f25d06s2 [Xe]4f35d06s2 [Xe]4f45d06s2 [Xe]4f55d06s2 [Xe]4f65d06s2 [Xe]4f75d06s2 [Xe]4f75d16s2 [Xe]4f95d06s2 [Xe]4f105d06s2 [Xe]4f115d06s2 [Xe]4f125d06s2 [Xe]4f135d06s2 [Xe]4f145d06s2 [Xe]4f145d16s2
89 [227] 90 232,03 91 231,03 92 238,02 93 237,04 94 [244] 95 [243] 96 [247] 97 [247] 98 [251] 99 [252] 100 [257] 101 [258] 102 [259] 103 [260]
Actinide Ac
Actiniu
Th
Toriu
Pa
Protactiniu
U
Uraniu
Np
Neptuniu
Pu Am Cm Bk
Plutoniu Americiu Curiu Berkeliu
Cf
Californiu
Es
Einsteiniu
Fm Md No
Fermiu Mendeleeviu Nobeliu
Lr
Lawrenciu
1,1 - 1,3 - 1,5 - 1,7 - 1,3 - 1,3 - 1,3 - - - - - - - - - - - - - - -
[Rn]6d17s2 [Rn]5f06d27s2 [Rn]5f26d17s2 [Rn]5f36d17s2 [Rn]5f46d17s2 [Rn]5f66d07s2 [Rn]5f76d07s2 [Rn]5f76d17s2 [Rn]5f96d07s2 [Rn]5f106d07s2 [Rn]5f116d07s2 [Rn]5f126d07s2 [Rn]5f136d07s2 [Rn]5f146d07s2 [Rn]5f146d17s2
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–
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–
&D VVSVSV H &DVVSVS
–
H Al+VVS
Al: V V S V S
–
6F VVSVSGV H 6F+VVSVS
–
Fe: VVSVSGV H FeVVSVSG
–
Fe: VVSVSGV H Fe+VVSVSG
H–
*D+VVSVSG
*D V V S V S G V S
–
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,RQLLSR]LWLYLVHREĠLQGLQDWRPLSULQFHGDUHGHHOHFWURQL
ÌQWUXQLRQSR]LWLYQXPăUXOGHHOHFWURQLGLQvQYHOLúXOGHHOHFWURQLHVWHPDLPLFGHFkWQXPăUXO
de protoni din nucleu.
–
([HPSOH 0JVVSV H
Mg+VVS
DWRPGH0JS+H– LRQGH0JS+H–
8úXULQĠDFXFDUHXQDWRPSRDWHVăFHGH]HHOHFWURQLHVWHPăVXUDWăSULQHQHUJLDGHLRQL]DUH
(QHUJLDGHLRQL]DUHUHSUH]LQWăFDQWLWDWHDGHHQHUJLHDEVRUELWăvQSURFHVXOGHvQGHSăUWDUHD
XQXLHOHFWURQGLQWUXQDWRPvQID]ăJD]RDVă
(QHUJLDGHLRQL]DUHSULPDUă,HVWHHQHUJLDQHFHVDUăvQGHSăUWăULLHOHFWURQXOXLFHOPDLVODE
OHJDWGLQDWRPXOQHXWUX
E(g) + Iĺ(+(g) + e–
(QHUJLD GH LRQL]DUH VHFXQGDUă , HVWH HQHUJLD QHFHVDUă vQGHSăUWăULL XQXL HOHFWURQ GLQ
cationul E+úLDúDPDLGHSDUWH
E+(g) + Iĺ((g) + e–
E(g) + Iĺ((g) + e–
(QHUJLLOHGHLRQL]DUHFUHFvQRUGLQHD,<I<IHWFSHQWUXFăDOGRLOHDHOHFWURQúLXUPăWRULL
YRU ¿ vQGHSăUWDĠL GLQWUXQ LRQ SR]LWLY vQ FDUH DWUDFĠLD HOHFWURVWDWLFă D QXFOHXOXL DVXSUD ¿HFăUXL
HOHFWURQHVWHPDLPDUH
35
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([HPSOXAl(g) + Iĺ$O+(g) + e– I .MPRO
+ –
Al (g) + Iĺ$O (g) + e I .MPRO
Al(g) + Iĺ$O(g) + e– I .MPRO
(QHUJLDGHLRQL]DUHVHPăVRDUăvQNMPROvQNFDOPROVDXvQH9HOHFWURQYROW NMPRO
(QHUJLDGHLRQL]DUHFUHúWHFXFUHúWHUHDVDUFLQLLQXFOHDUHHIHFWLYHúLHVWHRSURSULHWDWHFDUH
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*UD¿FXO
9DULDĠLDHQHUJLHLGH
LRQL]DUHSULPDUHFX
QXPăUXODWRPLF
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QXPăUXOXLGHSURWRQLGLQQXFOHXúLFXFUHúWHUHDDWUDFĠLHLQXFOHXOXL
(OHPHQWHOH FDUH DX vQ VWUDWXO H[WHULRU FRQ¿JXUDĠLL HOHFWURQLFH PDL VWDELOH DX HQHUJLL GH
LRQL]DUHPDLPDULFDGHH[HPSOXHOHPHQWHOHGLQJUXSDFDUHFHGHD]ăXQHOHFWURQGLQWUXQRUELWDOV
dielectronic (nsHOHPHQWHOHGLQJUXSDFDUHFHGHD]ăXQHOHFWURQGLQWUXQVXEVWUDWSVHPLRFXSDW
(nsnpHOHPHQWHOHGLQJUXSDFDUHDXRFRQ¿JXUDĠLHH[WHULRDUăFRPSOHWăQGns&HOH
PDLPDULHQHUJLLGHLRQL]DUHSULPDUăOHDXJD]HOHQRELOHFDUHDUWUHEXLVăSLDUGăXQHOHFWURQGLQWUR
FRQ¿JXUDĠLHVWDELOă
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VWUDWXULRFXSDWHFXHOHFWURQLúLFXPLFúRUDUHDDWUDFĠLHLQXFOHXOXLDVXSUDHOHFWURQLORUGHSHXOWLPXO
strat.
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WUDQVIRUPDvQLRQLSR]LWLYL
(OHPHQWHOHFXFDUDFWHUHOHFWURSR]LWLYDXXQFRPSRUWDPHQWFKLPLFGHPHWDOYH]LSDUDJUDIXO
&DUDFWHUXOPHWDOLFDOXQXLHOHPHQWHVWHGHWHUPLQDWGHXúXULQĠDFXFDUHDWRPLLVăLFHGHD]ă
36 FROHFĦLD
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FXVFăGHUHDHQHUJLHLGHLRQL]DUH
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VFDGHQXPăUXOGHHOHFWURQLFHGDĠLVFDGHHQHUJLDGHLRQL]DUH
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GHVWUDWXULRFXSDWHFXHOHFWURQLVFDGHDWUDFĠLDH[HUFLWDWăGHQXFOHXDVXSUDHOHFWURQLORUGHSHXOWLPXO
VWUDWVFDGHHQHUJLDGHLRQL]DUH
([HPSOX &DUDFWHUXO PHWDOLF DO HOHPHQWHORU %H 0J &D 6U %D GLQ JUXSD FUHúWH vQ RUGLQHD
%H0J&D6U%D
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FHGHD]ăXQQXPăUPDLPLFGHHOHFWURQLGHSHXQVWUDWPDLGHSăUWDWGHQXFOHX
([HPSOX Dintre potasiu (. VVSVSV úL PDJQH]LX 0J VVSV SRWDVLX
DUHFDUDFWHUXOHOHFWURSR]LWLYPDLDFFHQWXDWSHQWUXFăDWRPXOVăXFHGHD]ăXQHOHFWURQGHSH
VWUDWXOSHFkQGDWRPXOGHPDJQH]LXFHGHD]ăHOHFWURQLGHSHVWUDWXO
(OHPHQWHOH FX FDUDFWHU PHWDOLF DFFHQWXDW VXQW VLWXDWH vQ FROĠXO GLQ VWkQJD MRV DO WDEHOXOXL
SHULRGLF&HVLXOHVWHHOHPHQWXOFXFDUDFWHUXOHOHFWURSR]LWLYFHOPDLDFFHQWXDW
0HWDOHOH VXQW RUGRQDWH vQ VHQVXO GHVFUHVFăWRU DO FDUDFWHUXOXL PHWDOLF vQ VHULD UHDFWLYLWăĠLL
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FRQ¿JXUDĠLLVWDELOHGHJD]QRELO
–
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VS H– 2±VVS
2V
–
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HOHFWURQLGLQvQYHOLúXOGHHOHFWURQLHVWHPDLPDUHGHFkWQXPăUXOGHSURWRQLGLQQXFOHX
–
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$FFHSWDUHDXQXLHOHFWURQSRDWH¿XQSURFHVH[RWHUPVDXHQGRWHUP
$¿QLWDWHDSHQWUXHOHFWURQ$HUHSUH]LQWăFDQWLWDWHDGHHQHUJLHGHJDMDWăVDXDEVRUELWăvQ
SURFHVXOGHDFFHSWDUHDXQXLHOHFWURQGHFăWUHXQDWRPvQVWDUHJD]RDVă&DúLHQHUJLDGHLRQL]DUH
D¿QLWDWHDSHQWUXHOHFWURQVHPăVRDUăvQNMPRONFDOPROVDXH9YH]LDQH[D
/DQHPHWDOHDFFHSWDUHDSULPXOXLHOHFWURQHVWHXQSURFHVH[RWHUPLDUD¿QLWDWHDSHQWUXSULPXO
electron (Ae¿LQGRHQHUJLHSLHUGXWăGHVLVWHPDUHVHPQXOı´$FFHSWDUHDFHOXLGHDOGRLOHD
HOHFWURQHVWHXQSURFHVHQGRWHUPGHRDUHFHHVWHQHFHVDUXQFRQVXPGHHQHUJLHSHQWUXvQYLQJHUHD
UHSXOVLLORUHOHFWURVWDWLFHH[HUFLWDWHGHSULPXOHOHFWURQDFFHSWDWGHDWRP$¿QLWDWHDSHQWUXDOGRLOHD
electron (AeDUHVHPQXOÄ´
([HPSOH 2JH–ĺ2–(g) Ae NMPRO
2–(g) + e–ĺ2±(g) Ae NMPRO
37
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–
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SURSULHWăĠLDOHFRPSXúLORUFHDUWUHEXLVăFRQĠLQăDFHúWLLRQLQXSRW¿H[SOLFDWHSULQWUXQPRGHOSXU
ionic.
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DVHPHQHDQXOXăPvQFRQVLGHUDUHSRVLELOLWDWHDH[LVWHQĠHLXQRUFDWLRQLFXVDUFLQLHOHFWULFHUHODWLYH
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VHWUDQVIRUPDvQLRQLQHJDWLYL
(OHPHQWHOHFXFDUDFWHUHOHFWURQHJDWLYDXXQFRPSRUWDPHQWFKLPLFGHQHPHWDO&DUDFWHUXO
QHPHWDOLF DO XQXL HOHPHQW HVWH GHWHUPLQDW GH XúXULQĠD FX FDUH DWRPLL VăL DFFHSWă HOHFWURQL úL VH
WUDQVIRUPăvQLRQLQHJDWLYL
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ÌQDFHVWVHQVFUHúWHVDUFLQDQXFOHDUăFUHúWHDWUDFĠLDQXFOHXOXLDVXSUDHOHFWURQLORUGHSHXOWLPXO
VWUDWVFDGHQXPăUXOGHHOHFWURQLDFFHSWDĠL
([HPSOX &DUDFWHUXO QHPHWDOLF DO HOHPHQWHORU & 1 2 ) GLQ SHULRDGD FUHúWH vQ RUGLQHD
&12)
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([HPSOX&DUDFWHUXOQHPHWDOLFDOHOHPHQWHORU)&O%U,GLQJUXSDFUHúWHvQRUGLQHD,%U&O)
&DUDFWHUHOHHOHFWURQHJDWLYúLQHPHWDOLFDOHXQXLHOHPHQWVXQWPDLDFFHQWXDWHGDFăDWRPXO
VăXDFFHSWăXQQXPăUPDLPLFGHHOHFWURQLSHXQVWUDWPDLDSURSLDWGHQXFOHX
([HPSOX Dintre oxigen (2 VVS úL IRVIRU 3 VVSVS R[LJHQXO DUH
FDUDFWHUXOHOHFWURQHJDWLYPDLDFFHQWXDWSHQWUXFăDWRPXOVăXDFFHSWăHOHFWURQLSHVWUDWXO
SHFkQGDWRPXOGHIRVIRUDFFHSWăHOHFWURQLSHVWUDWXO
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(OHFWURQHJDWLYLWDWH
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¿DSUHFLDWSULQYDORDUHDHOHFWURQHJDWLYLWăĠLLOXL
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'DFă XQ DWRP DO XQXL HOHPHQW FKLPLF DUH R WHQGLQĠă DFFHQWXDWă GH D DWUDJH HOHFWURQL
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38 FROHFĦLD
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7DEHOXOSHULRGLF3URSULHWăĠLOHSHULRGLFHúLQHSHULRGLFHDOHHOHPHQWHORUFKLPLFH
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FKLPLFH
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FDUDFWHUXOXLQHPHWDOLF
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(OHPHQWXO 1D Mg Al 6L 3 6 &O
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&DUDFWHUXODFLGR 1D2 0J2 Al2 6L2 32 62 &O2
ED]LFDOR[L]LORU R[LGED]LF R[LGED]LF R[LGDPIRWHU oxid acid oxid acid oxid acid oxid acid
1D2+ 0J2+ $O2+
7ăULDED]HORU caracter - - - -
ED]ăWDUH ED]ăVODEă
DPIRWHU
H6 +&O
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SNa SNa ±
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R[L]LED]LFL
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0J2 0J2+
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39
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(OHPHQWXO QHJDWLYLWDWH
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H&2DFLGVODE
& &2 oxid acid -
SNa
6L 6L2 oxid acid - -
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6Q26Q2 6Q2+
6Q -
R[L]LDPIRWHUL FDUDFWHUDPIRWHU
3E23E2 3E2+
3E -
R[L]LDPIRWHUL FDUDFWHUDPIRWHU
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9DOHQĠD
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([HPSOH 6* DUHYDOHQĠD vQ1D6úL+6
1* DUHYDOHQĠD vQ&D1úL1+.
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([HPSOH &* DUHYDOHQĠHOHúL&2&2);
1* DUHYDOHQĠHOH1212121212);
3* DUHYDOHQĠHOH3232);
6* DUHYDOHQĠHOH6262);
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40 FROHFĦLD
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PHWDO
([HPSOX (OHFWURYDOHQĠDDOXPLQLXOXLHVWHXQDWRPGHDOXPLQLXFHGHD]ăHOHFWURQL
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DWRPGHQHPHWDO
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HOHFWURQLvQ62).
8QHRULYDOHQĠHOHHOHPHQWHORUVXQWH[SULPDWHúLvQFLIUHURPDQH
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(oxidare)
Fe(aq) (reducere) Fe(aq) + e–
$FHVWHOHFWURGVHUHSUH]LQWăDVWIHO3W(s)_)H(aq))H(aq).
(OHFWURGXO GH JD] DVHPăQăWRU FX HOHFWURGXO GH KLGURJHQ HVWH IRUPDW GLQWUR SODFă GH
PHWDOQRELOSODWLQăFDUHHVWHLQWURGXVăvQWURVROXĠLHFHFRQĠLQHLRQLLXQXLQHPHWDO+2– pentru
HOHFWURGXOGHR[LJHQ&O–SHQWUXHOHFWURGXOGHFORUHWFSULQFDUHVHEDUERWHD]ăQHPHWDOXOJD]RV
(FKLOLEUXOVHVWDELOHúWHvQWUHQHPHWDOXOJD]RVúLLRQLLGLQVROXĠLH
(oxidare)
&O– (reducere) &O + e–
$FHVWHOHFWURGVHUHSUH]LQWă3W(s)_&O–(aq)_&OJ.
(OHFWURGXOFRPSXVGLQWUXQPHWDORVDUHJUHXVROXELOăDDFHVWXLPHWDOúLXQHOHFWUROLW
VDUHVDXDFLGFDUHDXDQLRQXOFRPXQ8QDVWIHOGHHOHFWURGHVWHHOHFWURGXOGHFDORPHOIRUPDWGLQ
PHUFXUFORUXUăGHPHUFXU,+J&OVROLGăúLRVROXĠLHGHFORUXUăGHSRWDVLX.&OFDUHvQDFHVWH
FRQGLĠLLHVWHVDWXUDWăvQ+J&O&HOHGRXăVăUXULDXDQLRQXO&O–vQFRPXQ(FKLOLEUXOFRUHVSXQ]ăWRU
acestui electrod este:
(oxidare)
+J(s)&O–(aq) (reducere)
Hg&OVH–
208 FROHFĦLD
('8&$ĥ,21$/
Electrochimia
$FHVWHOHFWURGVHUHSUH]LQWăDVWIHO+J(l)_+J&OV_.&O(aq).
/DVXSUDIDĠDGHFRQWDFWGLQWUHFRQGXFWRUXOHOHFWURQLFúLVROXĠLDHOHFWUROLWXOXLGLQFDGUXOXQXL
HOHFWURGVHVWDELOHúWHRGLIHUHQĠăGHSRWHQĠLDOQXPLWăSRWHQĠLDOGHHOHFWURG.
$FHDVWă GLIHUHQĠă GH SRWHQĠLDO GLQWUH UHGXFăWRU úL R[LGDQW HVWH GDWRUDWă VFKLPEXOXL GH
HOHFWURQLGLQWUHDFHVWHVSHFLLFKLPLFH
9DORDUHDDEVROXWăDDFHVWXLSRWHQĠLDOQXVHSRDWHGHWHUPLQD3HQWUXGHWHUPLQDUHDYDORULORU
UHODWLYHDOHSRWHQĠLDOHORUGHHOHFWURGVDDOHVFDSRWHQĠLDOGHUHIHULQĠăSRWHQĠLDOXOHOHFWURGXOXLQRUPDO
GHKLGURJHQDFăUXLYDORDUHHVWHFRQVLGHUDWă]HUR
'LIHUHQĠD GH SRWHQĠLDO GLQWUH SRWHQĠLDOXO XQXL HOHFWURG VWDQGDUG úL SRWHQĠLDOXO
HOHFWURGXOXL QRUPDO GH KLGURJHQ HVWH QXPLWă SRWHQĠLDO VWDQGDUG GH HOHFWURG úL SRDWH ¿
GHWHUPLQDWăH[SHULPHQWDO6HQRWHD]ăFX(
'DFăVHFRQVLGHUăUHDFĠLDGHR[LGDUHSRWHQĠLDOXOVWDQGDUGGHHOHFWURGHVWHXQSRWHQĠLDOGH
R[LGDUH$YkQGvQYHGHUHFăUHDFĠLDGHR[LGDUHGHFXUJHFRQIRUPVFKHPHL
(oxidare)
5HGXFăWRU 2[LGDQWQH–
SRWHQĠLDOXOVWDQGDUGGHR[LGDUH(oxVHQRWHD]ă(5HG_2[.
3RWHQĠLDOXOVWDQGDUGGHR[LGDUHDOHOHFWURGXOXLXQXLPHWDOvQFD]XOFăUXLDUHDFĠLDGHR[LGDUH
este:
Me(s)5HGXFăWRUĺ0Hn+(aq)2[LGDQWQH–
VHQRWHD]ă(0H_0Hn+.
&RQVLGHUkQG UHDFĠLD GH UHGXFHUH SRWHQĠLDOXO VWDQGDUG GH HOHFWURG HVWH XQ SRWHQĠLDO GH
UHGXFHUH$YkQGvQYHGHUHFăUHDFĠLDGHUHGXFHUHGHFXUJHFRQIRUPVFKHPHL
(reducere)
2[LGDQWQH– 5HGXFăWRU
SRWHQĠLDOXOVWDQGDUGGHUHGXFHUH(UHGVHQRWHD]ă(2[_5HG.
3RWHQĠLDOXO VWDQGDUG GH UHGXFHUH DO HOHFWURGXOXL XQXL PHWDO vQ FD]XO FăUXLD UHDFĠLD GH
reducere este:
Men+(aq)2[LGDQWQH–ĺ0H(s)5HGXFăWRU
VHQRWHD]ă(Men+_0H.
3HQWUX VSHFLLOH FKLPLFH DWRPL LRQL FDUH DX WHQGLQĠD GH D VH R[LGD GH D FHGD
HOHFWURQLPDLPDUHGHFkWDKLGURJHQXOXLSRWHQĠLDOXOGHR[LGDUHHVWHFRQVLGHUDWSR]LWLYLDU
SRWHQĠLDOXOGHUHGXFHUHQHJDWLY
3HQWUX VSHFLLOH FKLPLFH DWRPL LRQL FDUH DX WHQGLQĠD GH D VH R[LGD GH D FHGD
HOHFWURQLPDLPLFăGHFkWDKLGURJHQXOXLSRWHQĠLDOXOGHR[LGDUHHVWHFRQVLGHUDWQHJDWLYLDU
SRWHQĠLDOXOGHUHGXFHUHSR]LWLY
6SHFLLOHFKLPLFHFXSRWHQĠLDOHGHR[LGDUHQHJDWLYHúLSULQXUPDUHDXSRWHQĠLDOHGHUHGXFHUH
SR]LWLYHDXWHQGLQĠDGHDVHUHGXFHGHDDFFHSWDHOHFWURQLPDLPDUHGHFkWFHDLRQLORU++.
3HQWUXXQFXSOXUHGXFăWRUR[LGDQWSRWHQĠLDOXOVWDQGDUGGHR[LGDUHHVWHHJDOFDPăULPHúL
GHVHPQRSXVFXSRWHQĠLDOXOVWDQGDUGGHUHGXFHUH(ox (red.
3RWHQĠLDOHOHVWDQGDUGGHHOHFWURGGHR[LGDUHVDXGHUHGXFHUHVXQWRPăVXUăDSXWHULLUHGXFăWRDUH
VDXR[LGDQWHDXQHLVSHFLLFKLPLFHDGLFăDWHQGLQĠHLDFHVWHLDGHDFHGDVDXGHDDFFHSWDHOHFWURQL
6H UHFRPDQGă Vă VH XWLOL]H]H QXPDL SRWHQĠLDOXO GH UHGXFHUH SHQWUX DSUHFLHUHD SXWHULL
UHGXFăWRDUHVDXR[LGDQWHDXQHLVSHFLLFKLPLFH
6SHFLLOH FKLPLFH FDUDFWHUL]DWH SULQ SRWHQĠLDOH GH UHGXFHUH PLFL VXQW DJHQĠL UHGXFăWRUL
SXWHUQLFLLDUVSHFLLOHFKLPLFHFDUDFWHUL]DWHSULQSRWHQĠLDOHGHUHGXFHUHPDULVXQWDJHQĠLLR[LGDQĠL
puternici.
209
FROHFĦLD
('8&$ĥ,21$/
RETINETI
, ,
'HH[HPSOXDOXPLQLXOFX(red 9HVWHXQUHGXFăWRUPDLSXWHUQLFGHFkWFXSUXOFX
(red 9GDUPDLVODEGHFkWPDJQH]LXOFX(Red 9&ORUXO&OFX(red 9
HVWHXQDJHQWR[LGDQWPDLSXWHUQLFGHFkWEURPXO%UFX(red 9GDUPDLVODEGHFkWÀXRUXO
(FFX(red 9
&XPXQFXSOXUHGR[HVWHIRUPDWGLQWUXQR[LGDQWúLXQUHGXFăWRUSULQYDORDUHDSRWHQĠLDOXOXL
UHGR[ GH UHGXFHUH VH SRDWH DSUHFLD DWkW SXWHUHD R[LGDQWă D DJHQWXOXL R[LGDQW FkW úL SXWHUHD
UHGXFăWRDUHDDJHQWXOXLUHGXFăWRU
&XFkWSRWHQĠLDOXOGHUHGXFHUHDOXQXLFXSOXUHGR[HVWHPDLPDUHFXDWkWR[LGDQWXO
GLQFXSOXHVWHPDLSXWHUQLFúLUHGXFăWRUXOGLQFXSOXHVWHPDLVODE
&XFkWSRWHQĠLDOXOGHUHGXFHUHDOXQXLFXSOXUHGR[HVWHPDLPLFFXDWkWR[LGDQWXO
GLQFXSOXHVWHPDLVODEúLUHGXFăWRUXOGLQFXSOXHVWHPDLSXWHUQLF
'HH[HPSOXFRQVLGHUkQGPHWDOHOH=QúL&X
=Q2[LGDQWH–ĺ=Q5HGXFăWRU (red 9
&X2[LGDQWH–ĺ&X5HGXFăWRU (red 9
GLQ YDORULOH SRWHQĠLDOHORU GH UHGXFHUH VH GHGXFH Fă ]LQFXO HVWH XQ UHGXFăWRU PDL SXWHUQLF GHFkW
FXSUXOúLFăLRQXO=QHVWHXQR[LGDQWPDLVODEGHFkWLRQXO&X.
9DORDUHDSRWHQĠLDOXOXLGHUHGXFHUHDOXQXLHOHFWURGYDULD]ăFXWHPSHUDWXUDúLFXFRQFHQWUDĠLD
LRQLORUGLQVROXĠLHFRQIRUPHFXDĠLHLOXL1HUQVW
ܴܶ ܿை௫ ͲǡͲͷͻ ܿை௫
ܧൌ ܧι ݈݊ ܧൌ ܧι ή ݈݊
݊ܿ ܨோௗ sau ݊ ܿோௗ
XQGH( SRWHQĠLDOVWDQGDUGGHUHGXFHUH95 -PROÂ.7 WHPSHUDWXUD.Q QXPăUXO
GH HOHFWURQL FHGDĠL VDX FDSWDĠL ) & F2[ FRQFHQWUDĠLD PRODUă D R[LGDQWXOXL FRed =
FRQFHQWUDĠLDPRODUăDUHGXFăWRUXOXL
'H H[HPSOX SRWHQĠLDOXO GH UHGXFHUH DO HOHFWURGXOXL UHGR[ 3W(s)_6Q(aq) 6Q(aq) IRUPDW
GLQWURVROXĠLHFHFRQĠLQH6Q&OúL6Q&OFXFRQFHQWUDĠLLOH0SHQWUXLRQLL6QúL0SHQWUX
LRQLL6QODWHPSHUDWXUDGH&.VHSRDWHFDOFXODGXSăHFXDĠLDOXL1HUQVW
(oxidare)
6Q (reducere) 6QH–
5H]XOWăFă6QHVWHDJHQWXOUHGXFăWRULDU6Q este agentul oxidant.
ܬ
ܴܶ ܿை௫ ͺǡ͵ͳ ή ͵ͳͲܭ Ͳǡͷ
ܧൌ ܧι ή ݈݃ ൌ Ͳǡͳͷ ݈݉ ήܭ ή ݈݊ ൌ
݊ܨ ܿோௗ ܥ ͳǡʹ
ʹ ή ͻͷͲͲ
݈݉
Ͳǡͷ
ൌ Ͳǡͳͷ ͲǡͲͳ͵͵݈݊ ൌ Ͳǡͳͷ െ ͲǡͲͲͺ ൌ ͲǡͳͶʹ͵ܸ
ͳǡʹ
3HQWUXHOHFWURGXOXQXLPHWDOFkQGVHFRQVLGHUăFred UHODĠLDGHPDLVXVGHYLQH
ͲǡͲͷͻ
ܧൌ ܧι ή ݈݃ܿை௫
݊
unde coxHVWHFRQFHQWUDĠLDPRODUăDLRQLORUPHWDOLFLGLQVROXĠLH
'HH[HPSXOSHQWUXRFRQFHQWUDĠLHGH0DVROXĠLHLGH=Q62SRWHQĠLDOXOGHUHGXFHUHDO
HOHFWURGXOXLGH]LQFHVWH
ͲǡͲͷͻ
ܧమశ Ȁ ൌ െͲǡ ή ݈݃ͳǡͷ ൌ െͲǡ ͲǡͲͲͷʹ ൌ െͲǡͷͶͺܸ
ʹ
3HQWUXRFRQFHQWUDĠLDGH0DVROXĠLHLGH=Q62SRWHQĠLDOXOGHUHGXFHUHDOHOHFWURGXOXL
210 FROHFĦLD
('8&$ĥ,21$/
Electrochimia
GH]LQFHVWH
ͲǡͲͷͻ
ܧమశ Ȁ ൌ െͲǡ ή ݈݃Ͳǡͷ ൌ െͲǡ െ ͲǡͲͲͺͻ ൌ െͲǡͺͻܸ
ʹ
$úDGDUSRWHQĠLDOXOGHHOHFWURGDOXQXLPHWDOGHSLQGHGHFRQFHQWUDĠLDLRQLORUVăLGLQVROXĠLH
/DFRQFHQWUDĠLLDOHLRQLORUPDLPDULGHPRO/SRWHQĠLDOHOHGHUHGXFHUHYRU¿PDLPDUL
GHFkWSRWHQĠLDOHOHVWDQGDUGGHUHGXFHUHúLPHWDOHOHYRUUHDFĠLRQDFDUHGXFăWRULPDLVODEL
/DFRQFHQWUDĠLLDOHLRQLORUPDLPLFLGHPRO/SRWHQĠLDOHOHGHUHGXFHUHYRU¿PDLPLFLGHFkW
SRWHQĠLDOHOHVWDQGDUGGHUHGXFHUHúLPHWDOHOHYRU¿UHGXFăWRULPDLSXWHUQLFL
6HULDSRWHQĠLDOHORUHOHFWURFKLPLFHDOHPHWDOHORU
0HWDOHOHVXQWHOHPHQWHFXFDUDFWHUHOHFWURSR]LWLYDWRPLLORUDYkQGSURSULHWDWHDGHDFHGD
(oxidare)
HOHFWURQLúLGHDVHWUDQVIRUPDvQLRQLSR]LWLYL0H Men+ + ne–.
$WRPLLPHWDOHORUVHR[LGHD]ăúLPHWDOHOHVXQWDJHQĠLUHGXFăWRUL
&DUDFWHUHOHHOHFWURSR]LWLYúLUHGXFăWRUYDULD]ăGHODXQPHWDOODDOWXOúLGHSLQGHGHFRQ¿JXUDĠLD
HOHFWURQLFă D DWRPXOXL GH PHWDO 2 PăVXUă D DFHVWRU SURSULHWăĠL SRDWH ¿ SRWHQĠLDOXO VWDQGDUG GH
electrod.
0HWDOHOHVXQWDúH]DWHvQRUGLQHDFUHVFăWRDUHDSRWHQĠLDOHORUORUVWDQGDUGGHUHGXFHUHvQWUR
VHULH QXPLWă VHULD UHDFWLYLWăĠLL PHWDOHORU VDX VHULD SRWHQĠLDOHORU HOHFWURFKLPLFH DOH PHWDOHORU VDX
VHULD%HNHWRY9ROWDYH]LDQH[D
/DvQFHSXWXOVHULHLVHDÀăPHWDOHOHFXFHOPDLDFFHQWXDWFDUDFWHUUHGXFăWRU$WRPLLDFHVWRU
PHWDOHFHGHD]ăIRDUWHXúRUHOHFWURQL$FHVWHHOHPHQWHDXFHOHPDLPLFLYDORULDOHHOHFWURQHJDWLYLWăĠLL
úLFDUDFWHUXOPHWDOLFFHOPDLDFFHQWXDW
/DVIkUúLWXOVHULHLVHDÀăPHWDOHOHFXFHOPDLVODEFDUDFWHUUHGXFăWRU$WRPLLDFHVWRUPHWDOH
FHGHD]ăJUHXHOHFWURQL$FHVWHPHWDOH$J3W$XDXFHOPDLVODEFDUDFWHUPHWDOLFúLVXQWQXPLWH
PHWDOH QRELOH 8UPăULQG VHULD SRWHQĠLDOHORU HOHFWURFKLPLFH vQ VHQV LQYHUV VFDGH WHQGLQĠD LRQLORU
PHWDOLFLGHDDFFHSWDHOHFWURQLDGLFăVFDGHFDUDFWHUXOORUR[LGDQW
5HDFWLYLWDWHDXQXLPHWDOSRDWH¿DSUHFLDWăGXSăSR]LĠLDOXLvQDFHDVWăVHULH
8Q PHWDO VFRDWH GLQ LRQLL ORU DÀDĠL vQ VROXĠLH PHWDOHOH FDUH XUPHD]ă GXSă HO vQ
VHULDSRWHQĠLDOHORUHOHFWURFKLPLFHDOHPHWDOHORU$FHVWHPHWDOHDXSURWHQĠLDOHVWDQGDUGGH
UHGXFHUHPDLPDULGHFkWSRWHQĠLDOXOVWDQGDUGGHUHGXFHUHDOPHWDOXOXLFRQVLGHUDW
8QPHWDOHVWHVFRVGLQLRQLLVăLDÀDĠLvQVROXĠLHGHPHWDOHOHFDUHvOSUHFHGvQVHULD
SRWHQĠLDOHORUHOHFWURFKLPLFHDOHPHWDOHORU$FHVWHPHWDOHDXSRWHQĠLDOHVWDQGDUGGHUHGXFHUH
PDLPLFLGHFkWSRWHQĠLDOXOVWDQGDUGGHUHGXFHUHDOPHWDOXOXLFRQVLGHUDW
0HWDOHOHFDUHSUHFHGKLGURJHQXOvQVHULDSRWHQĠLDOHORUHOHFWURFKLPLFHDOHPHWDOHORU
PHWDOHFXSRWHQĠLDOHVWDQGDUGGHUHGXFHUHQHJDWLYHVXEVWLWXLHKLGURJHQXOGLQDSăúLDFL]L
0HWDOHOH FDUH XUPHD]ă GXSă KLGURJHQ vQ VHULD SRWHQĠLDOHORU HOHFWURFKLPLFH DOH
PHWDOHORU PHWDOH FX SRWHQĠLDOH VWDQGDUG GH UHGXFHUH SR]LWLYH QX VXEVWLWXLH KLGURJHQXO
GLQDSăúLDFL]L
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SRDWH¿VFRVGLQLRQLL=QGHPDJQH]LXFX(red 96XQWSRVLELOHUHDFĠLLOH
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0J=Q&Oĺ0J&O=Q
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=Q+&Oĺ=Q&O + H
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211
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cuplurile redox sunt:
(oxidare)
=Q(s) (Red) –
(reducere) =Q (aq) 2[H
(reducere)
&X(aq)2[H– (oxidare) &X(s) (Red)
$YkQG vQ YHGHUH SRWHQĠLDOHOH VWDQGDUG GH UHGXFHUH (=Q=Q 9 úL (&X&X =
9VHGHGXFHFă]LQFXO5HGHVWHXQUHGXFăWRUPDLSXWHUQLFGHFkWFXSUXO5HGúLFăLRQXO
=Q2[HVWHXQR[LGDQWPDLVODEGHFkWLRQXO&X2[$QDOL]kQGVFKLPEXOGHHOHFWURQL
=Q5HG&X2[ĺ=Q2[&X5HG)
VH REVHUYă Fă UHGXFăWRUXO PDL SXWHUQLF =Q FHGHD]ă HOHFWURQL R[LGDQWXOXL PDL SXWHUQLF &X
FRQGXFkQGODR[LGDQWXOPDLVODE=QúLODUHGXFăWRUXOPDLVODE&X
ÌQWURUHDFĠLHUHGR[
5HG12[ĺ2[15HG
UHGXFăWRUXO5HG1PDLSXWHUQLFFHGHD]ăHOHFWURQLR[LGDQWXOXL2[PDLSXWHUQLFIRUPkQG
R[LGDQWXO2[1PDLVODEúLUHGXFăWRUXO5HGPDLVODE
0HWDOHOH SXWHUQLF UHGXFăWRDUH DX PDL PXOWH XWLOL]ăUL SUDFWLFH REĠLQHUHD DOWRU PHWDOH :
8 &U =Q REĠLQHUHD KLGURJHQXOXL vQ ODERUDWRU REĠLQHUHD ED]HORU WDUL vQ ODERUDWRU VXGDUHD SULQ
DOXPLQRWHUPLH DJHQĠL UHGXFăWRUL SXWHUQLFL vQ FKLPLD RUJDQLFă vQGHSăUWDUHD XUPHORU GH DSă GLQ
VROYHQĠLLRUJDQLFLúLJD]H
3LOHHOHFWURFKLPLFH
3LOHOHHOHFWURFKLPLFHQXPLWHúLFHOXOHHOHFWURFKLPLFHVDXSLOHJDOYDQLFHVXQWVLVWHPHFDUH
FRQYHUWHVFHQHUJLDFKLPLFăvQHQHUJLDHOHFWULFă
2SLOăHOHFWURFKLPLFăHVWHIRUPDWăGLQGRLHOHFWUR]LGRXăVHPLFHOXOHFDUHvQFD]XOSLOHL
]LQFFXSUXVXQWHOHFWURGXOGH]LQFúLHOHFWURGXOGHFXSUX&kQGHOHFWUR]LLQXVXQWFXSODĠLvQWUHHL
ODLQWHUIDĠDPHWDOVROXĠLHVHVWDELOHVFHFKLOLEUHOH
(oxidare) (oxidare)
=Q(s) (reducere) =Q(aq)H–úL&X(s) (reducere) &X(aq)H–
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YH]LVFKHPD
6FKHPD
(oxidare) (reducere)
=Q(s) =Q(aq)H–úL&X(aq)H– &X(s)
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212 FROHFĦLD
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Electrochimia
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GHR[LGDUHDDWRPLORUGH]LQFWUHFGHSHSODFDGH]LQFSULQFLUFXLWXOH[WHULRUVSUHSODFDGHFXSUXGH
XQGHVXQWSUHOXDĠLvQSURFHVXOGHUHGXFHUHDLRQLORU&X$VWIHOvQFLUFXLWXOH[WHULRUVHJHQHUHD]ă
XQFXUHQWHOHFWULFFRQWLQXX)XQFĠLRQDUHDSLOHLVHED]HD]ăSHGLIHUHQĠDGHFDUDFWHUHOHFWURSR]LWLYDO
FHORUGRXăPHWDOH
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R[LGDUH(OHFWURGXOGH]LQFUHSUH]LQWăDQRGXOúLERUQDQHJDWLYăDSLOHL
ÌQ VHPLFHOXOD FXSUXOXL HOHPHQW FX SRWHQĠLDO GH UHGXFHUH PDL PDUH DUH ORF SURFHVXO GH
UHGXFHUH(OHFWURGXOGHFXSUXUHSUH]LQWăFDWRGXOúLERUQDSR]LWLYăDSLOHL
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R[LGDUHVROXĠLDGLQMXUXO]LQFXOXLPHWDOLFQXPDLHVWHQHXWUă9RU¿vQVROXĠLHPDLPXOĠLLRQL=Q
GHFkWLRQL62±VLWXDĠLHFDUHvPSLHGLFăWUHFHUHDDQRLDWRPLGH]LQFvQLRQL=Q$VHPăQăWRU
vQVROXĠLDGLQVHPLFHOXODFXSUXOXLYRUH[LVWDPDLSXĠLQLLRQL&XGHFkWLRQL62±VLWXDĠLHFDUH
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3HQWUX DVLJXUDUHD FRQWLQXă D QHXWUDOLWăĠLL VROXĠLLORU GLQ FHOH GRXă VHPLFHOXOH VH LQWURGXFH
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ISBN 978-606-93525-7-1