‘cuPRinsut PREFATA LA EDITIA | PREFAPA LA EDIRIA La Car Prone ie chimic io te atin tnd, ore te i cree fee ae, Soca Pee i ey vee [costoea le razolvan ‘noe probleme cinerele ele cia) eo Ge ae 20 rie ole eee i Sxpurieta.propris confirma jpotersle aise anterior yi de ‘ety 8. Reumamne DE AZ is StRTEE GU Us ents, ee ae omen pen ‘al majoritaten domenipe aplicative a chim fice, Starick enovkitraye toe Sxstiton De ACH Sugeetie colegior “dia tavatémintl superior hime, gi melalui, slo soreettorior, pivistenkr yt igloo takes ogi din industria ehimiva gi metalurgica proenm gi ale altor cititort i reas o a ars Sa naan TE Aris 007 cmecpenel cau Win ca ea oaPRINCIPALELE NOTATIL UNLIZATE i rexel = Sata es eerie a gel SPO Tie psy nwt apo en sen tn ta ore de ain, ok semi ' Sitges ihe ee Thee abet dou xt eats ‘ pie Hers aes stent) Shop Sete or tat a eee Serpe uh de mse Ge? Tete tet ae ee : et a nis mm ‘Sey Teale ste Be vse ay ita tng site de tp, oes 2p 0 tae ee = 04 boy + om real fone Em) Gaps Sanle-haw Bok onl) cae purl date experimen, n= & Geld an, oo B+ eb + tt Be + {Ob + 7% — 40220 {Aa + 7840 + 4 6760— 20704 vind, se oboe: a = 98847: b= 6195 » = —OuBe = DAM + 1815-04? — 08: I Vlrile calcul st ne a [o> | om [a | mm | am | 0 [aww | a oa [sain faa [soa [a [aus [u | | irri ison il ed il O59‘yl 2 bucant de atuminin ce etnnsie IO @ tne tm proaiait AWE te iil nian taforaneira te Gonine Kp ead late Ne. Femporatie finath tn corinne ee de Shore Basha coe Pept wc condi per flr, sie rzine. Tomugtapleiss fvlorinr in focere tas th parte th, peptic te MC. BUR gf OEE oiosind gest date, hh tates sary mediated pet Hal capacitor abrive momice se alaminivini, fcr cheba ok ‘runacve. Se prosepune od Eatin calerihit ote poids Mest coon ale motion st resect: BBB; 5.89: SM, WERE eral Rescivers! 4 inclriron me geume de sultan de I tmperajure i chim st cildant goat yom as, In ean @ ito cildury position meio ty iateevaal de temiperaturt x ‘Pentew ez foose akin 4% my 050 (8, = Me 2 tn cre (A este diferenfa ines tempera Final 6 iitialé dt. calo mera 91 (ida dierent inte tempenatrn. de ec tenperrn Pratra Gyo-= Lond: gk se olkin uo tna (Ady 20095 ~20) ae ‘ ty = nano Ah, BH = 0215 ele ts, my (8g HKD — 20.5) aah 4 mod aseminste we odin pentrs for, zine angi sezltale: OMT eae He O08 ead ge RESO eg Capacitatonealotiekstomied mdi, € ete el Cnn. In cone eats masa atone «elem nh ‘Aplcind slain seis to Dyin aoe Guy 38, On 140, Cy, = B98 91 Ce PS AAL a ov eatentece tee) moranie mas pertra un proc de tote 4 nam te ap def. 25° ta "PC, ts prior conten de Late Coe ‘tone de dietaretrmicd abe’ teks, ae sal en 31 TOK Stl eC = 18 enl-mat!» K-, ah a caleteze @ gi AT. 0 cal-mol K Rezalvarc Iuerul myennie masion ef tua In prose canstant ate opal ev: Fa L=-AY, = Pay. Prin tigi Be) Vat — Pal At ~ 000228 ea: mal + an (eget {9a coe er Herotenre Prin tiites = ++ BY. Pentru vaporizana pentane ave an— apn, aU = AW Par, AU = all MV Up. Pie Va) = 84 1056 — 197) = 249 atm emg? = BAK onl ct x AU = 70 — BA = 67.5600) ah Considered dupa Prigogine si Detuy fumtille x — + gy BEA em by EYRE evant rh fla Ceri i dng ind 'eaprexe arena, oe peinepiat (sth invh et nate hinted). Rerolvare Dafoe totale oe po sori w(t th, ne (M4). ars (A f {oewind in econ prinipia Yn det Pte, dea dh oar. Schon r Petar eeas aca te (Fr), [Ge).—)P 3)mena f(A) —o]an vate LA Cit endif di probe 1.18 juno st obfinat relapes inte tee Hi tot, Mg gh AV ae a Resolvare Diterentind fanegin Gah ar tel Tnbraind ip expres tui 89h earaniat elesrtah aan *() Al. Ge), + "(Ga)" [ser (2) (65) + (Ge) Je enifioid ermeait din acer Mentitiind a 8 seugh eu oot Lorespunaiter din exper sooner] jer + U4 AH, pa, Sie 3) Oh Mire stat (8) a aren LtsMeattare ae ardore @ hepioaler normal, la volam consent, ate w= 14488 ‘real-mel 25°: + Calli) 4 A O4a) = TEO,fe) + 811,007) Si se eloneseeauara dearer Ia pestne constant, Aba, eonidirimd tr ideabtm pastor egiind garage eben ie eer Novolvaxe ina altima gcuatie din problem 1.04 Ji veal compartir ideale sine 2 obi Ally = Alon + AYRT, core ste sratn mumirai de mle emp surg iT od—o Noncis Ay = 11518 eal mot [hc.18605@ we eeedee etre de jormare standard a aciduta suture conform as Sto) + 20a) + Hale) — H,SOMd) Inlcindacsr $i 9 motota experimentatd de devrminare a ase Norolvare Deoarsce mu este posible pein imple amestocar a hidrozenuh ‘sigenulot fk nlf Intra walgrmotow 2g bine te salute det, Propane eles taris unor react ta se Pot realign Fanetie sb pene rary J hote determina ealarimoune eéidure, de Tenet Ni fost alee 1 ase sea reao(e (=) Reseia (1) ve poate naling Jin oxldwew sultului eu oxigen, iat acta (2) pe ele la wanlores bao ui de aull eu oxigen po eataliae se platinn I temperatany idicte fhilues de eeokie ge poate reeaeula pentra temperstura obigout Au fost Hive nea dou react eesnne (8) e (4), al ear ontap se pot deer 1) Sle) = Oale) = S04); (AM = — 70.95 ea. S040) + 1/20,fe) — SO4e); (Alle = 23,69 eal (Sh SOujeh + M04 — H,SO4H}; (AH, = 2186 koa (4) Hag) + 12046) = 04D ; (SHE ~~ 6572 keal Aplioind Inge Bai Tete 2 obine (AM (Aaa 190,91 Kea mo (Mi, (Ad h F AME1.17,A%é se determine caldura de reacts pontrw formavea wwtanntus din ee i a bred pte 9 ae aren ingens Waris pelinconerct ae ‘ath ate teeta eulnicht toi abecbate Qutoae Gtgraiy) + 2s) ~ CHa): (AM ‘eunosetn wemdorste elu de combate. : 95405 eal (1) Gig) + 2040) = COs) + 2019; (aSa)g = ~21280 Kea (2) a) + 1/206) = 1,005 (Adltee= 08.22 Kea CD Schutte acta eon vee merctami courts (8) Cees) + Oe) = COMay; (ath Tater anos Cota Rerolvare nian iets ee cele Asn eso Tea ee Soya prezioa maladacoficinlbor determin pentr elo I alfa s ee seriu eactile in form conventional ¥ © ™ o (1) — CHa) — 20,¢¢) + CO,{e) + 2H,0() = 0 5 (AMIE Seatie (2) — Hele) — 1/2042) + HOW) = 0 5 (ANB. * . ~ pater i | Poe grafit) — 2Hy(g) + CH(g) 5 (Oey, x Pen, tied venoul min pens subofle dn membrana elie. : ae ales ec ee (L) = AGHig) — BasOaleh + A QOgle) + HO = 05 (Set safe side aaa 2) — Palate) — 10,046) + tl, 010 (alba |S) ean $-2oe fF $3 (2) — Clery = 2,049 +3560) = 0 sata Ii q ji — Gigratit) — 2s) + CHYg) = 0 4 (Mai. Din tre ecuntil independent (Aeuarece patricen | vgs) are rang3) ceeelta: ty = 4, iy = 2 = Gildare de reayieeitata va t: 2 eee eee (Alle, = (Alan + MQM + 9AM, ex comin ea prin insumaven 3eachlor (1), (2) g (2) a ae obfink roucfa ‘Code ene determina ae aes Ce) +2040) = COga) + 280.) = Se dotormind eouticienli Py $y din ecuafit de dilan al admiral oe molt pentew diffu compaghfintte rosie 1, oat, ceea ce decurge din condi de that su MARIS cate canataten de catdunt deat la ardre am de mote, sprint inc ornate Gt at So unos ¢8ldurite de formare ale substenjelor Satta yao — io pers Ci: = 15 pepe ereest oe lang peateu Hy $5 2, ee : bilan} pentra C94 = 1 Rerolvare © Se diterming (ANB), Aploind gee bed He ,efldurn de mace vate (AMbob, = — (AMG + 28M £ (Atak = —17,89° kel ann i uae 2 (ali — uae eriad scar eoninimtitta wana acy oer re aia panes aaa eee 4h core prim tarmen este 0 samare tefirtoare lk produ do eae (2) Maral lle in rencan}i (4) stat sotielenittovehiometric a jasPentru renetia dad result: MM = 2SHfatca + (AMBaey — (AHR by, A917 Kon, Proureer 4. m* do melon, minunut in condi moimale. comtine na ri = I moi, eantiaten de ellduré deja andere I ox ee ml, cant Aldor dja Toi oat I> 0 Alby = EO (19175). — 8500 bea 3 De \ it ae celeulese cildara necevard reducoric oxitului ‘romée, Cryy Ps enc nt ened as we Sake eH co Rexalvare oncia de duce oxida erumie eae Gee) + 204) = ert) + 00 Chlduee de rar}, flood exile de formare eats egal en J Bie = Malanie — (attain, = 2m) 4 20m 90.5 eat | ROWSE se cites efctad sermie eb eco ACOs) + Se) (OHH + GION eaosinitse cadre de combustic tO. Sehecin hints oH Rezolvare Fedchilsvoespunzstony eumbastisi substanjcoe ints (My COfe) + 12 Oy) ~ CO}; (Ata © — 67,06 hea @ (2) Na) +472 Og) = O40; (S6Na§ — — 08320 hea (8) GAHLO0( +2044} — 26040) + aM, (Altes = 327 210 boa Folosint metoia costicienje nedetrmina}, dldurn de reset: mle: Alle = 2a = a,b kal Ciara de reacts se pote santa pe Ia eli MD. aunt Ds, (any Jn gam primal term sypteineh o sumars relestoare la reaotanl (Rar at dln ta prodit de ent tie (Px) 5, topretials eoetiengh sosebsoueat Uy > MAU + HA MB ~ (Sta cae Pr ar ~ x 194 ere dente se introduce ta determibarea edldati de forture wnat titanadat normal, ed cote de Comins stent 6 hetite ee minat meas de 2% Searle de beat a lon wht (ills) + 180M = SoD +580") ~ 5 carey = ~ 08 58 Kea not) + Oger = GO + (Allg" = — 94,515 eal 1 + #0) — 4 2 (AM = — 80474 la. Nexolra Nott de fomae« banal aontal ee: $Cpti) + lye) = Gs) sind alrite de andere ale aan e pti le ren mn ieTomare butaaael ee gai eas T&F : Mitte = GAD + Al, — FI, = —209 ho © ca de 0294 In determine fli de combusic 6 mane inca Kea ‘cour de 1 Keal pent eAldurs de formare asians repre 12 la ir renee mane bahay 1) Solent ent a stig Seino) Lane esi prcenal dacurae in od spontan lp tenspermtuse do 25°C, tnaetor. hare ee eu ite pea lek entra pte fi doterminatspranaibgeet ond floret, Canoga ist ealunle de mach ae Precelor i eo ‘© pons eeu cilduea de tinfonmar aloteop Stmonerlnie) + Sirmbic) Ale = (Alita), + (SMBe), = — O07 toa, In condi Meni, waren lotmpi os dotate cen magi tare nessa © chlo fe tenga mare penn span stan teat aldara ed resco impliok scons stary ve f mal mick, Saf rombie ete wat ee HQC dest mutt monet. Se cbeerva ed w |(AMee| aa PBs cen rnin itr traf bs BE opine sade Hie) = Bee); (Sito. = 287 ae, 2) 12g) = Be: (Aifhne = 5241 dew, 2) ABH) + 12059 = He); (ithe, = — 87 heal caysray(e) (Aly = 255 KeaInde de disacare a molecule’ de Hy $3 de sublimare « Cle] nd te acoleapi Clara de sporisr a bromatat ie) BRET Keak snok, ed ybtinae ites (Uj Mh al a ar altura te deface ala!" Te tea eal (AM ’ (0) NAM) = Hels (AiPbag = Ht oat mol 4S mcs rrr sdmiby Br ~ Be, 11, MB it) 9 ae 1) Se eat cmitaca standart foravce a otal ‘othe ? = i SE eee ga) dh, No oat | ellie de ewes ale ecor 4 comput la frmarea acsora din atom nig kgturor CH, CC, C=O gi C=6. Rezolvare 4) Conform tod! ta He 8 pica ta womdoral sic Bey SES rts + Be) BH), = SF} (AHP Pevire milan nears Sree (1) Biya = CHa); (Ait (©) Gi) = Gay + (AM (©) #2gla) = Heep (Sia (a) Alfie) = CHa: (Ate (Allog)n-ar = 1AM) = AM) = 2-287 — 7h — 88) oh In mod asemanite Fin sod eaaisiontilornesetaraninati nero (at?btons = (AEBads — (Alle — KA Mahe = — 30,9 ol ‘mol [ny wotan int €Jogituri GH. Atunel enersia wari legturi GH est Tat 2 tig te) _ (Alsen, sta fe) antes ee 1 SME, = My + (Athan Nong ponte otan uiliaind reais de frmam w asta, x eacia [AMM 2-238 — 149 = 96. Koa Gls) + Bligh = Cattle); (Aden, Pentex aft eniorginIydtueli H— Heap face urmtoases cinmhinay TAMEa)y-m = (SH), + (OFPde (Aaa = TB eal 1) Roaogn de tormoge aeitul i Vaile) + 1210) — MN) los eosfites ova (Ayaan = (APs — 2AMEate — 0147 ops sciderea valet Sorepunzitoars cele 6 logituri C—H, rex (Sifbalesc = — (AEB, ~ OOF = + 688 — 6> 98 78 heal. Pent tent 5 kealemal bide ont Penton epicet fei ta Ime so pt 2g) + AN = Gal (AME 2 12 Mya) = 0G) z 47 as) = (A2a)ao, = (AHBaly — QB nly MMs = — 84,6 Keal- molt 5) MH) = Miah + Ky iene [oe = (Aisles, — MAM. a = 3144-98 = 138 kewl mot _ (lla = (A fh, (Abas = 7: Real snl, Penn ostteds YD se crn tite joer nt pr rat UH tga ~ ths |Smgoy 120 heal (2) 249 Ri) Gay: ig = — 22 al mo (209 alla = eta) arta = 128 al a (0) BQ) + Hd = Glue (ay = 42 kl ma 20a) + 2) = CHa; (AMD (AMpdeag = (Atay — 24Medy — 2AM = — 288 Keal- molt (Alfbglewe = StAMaosh, — MAH bade = 388 — 2-66 = 182 kewl,Lab St ealeatece cithwrn de formate a daneuiné xi st se compare > “wart aden con oben pert: 90990 al stan sana tiainte standard de formar a slememttor in sare posse gc nercie de ot tne: Norolvind sistent de seus 1950850 6 obtin necunwseutel a 4, 6 LOVE 108s es Bs 8 eae = Ania ogee inloe Rate & tithe ee +) Convidertnd relatia(#) _ 6, pont tino) de. luorurd de anagnexia id (e ),- tne de fuori de mag ath ee hima mine st mone g cpa = (G8 neney tos Ps Lane yan (aise ta ats ame a (aM w-(Allyje AME 0 (8H Oar ana ote ms ate ieee ta ie rete a ale ten apa —196 645 cat Pore is enagneia ds a 900 ta 9M 7 ih Gag oft “1.019 = Hoch, 8 val molt Regolvar E Tata 1 1 Folin stele probleni, se pot were ccunfile San | Ghatatact Taam te 1675 = 0+ S102 b + (673.2% 17,90 = 0 + 673,26 +. (973.2) sires Wises 2 ition tas b= Ke ere aa ioe 10,22 = a + 77326 + (73,2) Hon | 25700 10-91 owes 30 8 hee PoRexolvare Kirclhott permite caleularu cilduri do seectie I 0 agen wi tempo. lemporttynt, AJ, tune tad so eupoage cde de reac lo tues, AH, i dapendenta eapeitatiy esloice de teriperaturs ami = a+ [acer ar, J care ACR sepeexints varia eeckiometeiod « capaci ealorce: SB =D wich, Dior Devan Sn intervaul de temperntina dat ary lov vaporizarss apei, lati devine asin, + (acpar ita = atta + ("acy a7 = Sitme +02: (Cbs — BCD — (CPoNT + 1 ay (io ED, — (Cada —— Ss Bs . 2 me ealeules fetal serie ol rect a temperatura de GC, winasinde-se dalle ATTaeta AA S04) + 12040) Sey) aR aee 7 anon. sore ceed SEG ion | 3S Nexolvare Conform log Iwi Kirebh ott an =am.+( separ AIT}, = AiTtg = — 94 630 + 20 960 — 20490 el, IC} = (CHa, — (Con — 1/2 (Co, = = 48 1,78 108 P + 1086-1047, hg ta + arpa = 20% CPi ener sri de entre 1080, pen rnp: lds) + Olen) = Drie) + 900 fo); Ady = 190 200 cal Se auton date din ted 1.3, ror) penis a8 Rerplvare ~ Conform eg at Kaveh hat Meg = Si 8E= Dy (Bh — Do tay Che = = Ott — 201. 10-974 5, Docie My = 189 214 cl Db et rigid nn urdu aries de isin Salo a mpeatre de 85,1708, 1153, HOH) peste 1900 Ke find foe Ge (Altay 200 eal. ae (3) Si0, (eanr} 6) = SiO, (ovistobalit 8); (AH yp = 1450 on, 44) Si0, (erstobatit 5) = Si0ys) (Adlton),= 2000 eal. Ss cunoageenaliasamtrd de eat i srais soethonari «capac Nijilor ealorice (tabelut 1.6, e i CH + CHa — Heer 7 PT (1) S10, (enaet a) = $10, (ouany 2) Sig = $i, Sched mart A, 5h = Hosst09 7 Aa nie (9) SiDg(o) + 20) = Sits) + 2¢044); AM, = 155.000 oatRerolvare . Rooin de reducers a bioxituli de silica tnt tmnperstrila 258 888. (©) SiO, (ovary 9) (9 + cts = Sly + 26018 (Ait = cP 90h a AP 52 20 ea. ‘La 885 K ar hae trasfornacee: (1 SiO,cuary 2) = SiO,leune} 6); (AMR), = 200 ea etch de reducere ly temperatura de 848 K care 40 poate objine din Aeron Sire tune (By) ts (0) Si0, feuart 31+ 269) — Site) + 26040) Devi conform bg li He (Ag = (Atal — (8 132200 ~ 200 = 154 910 en, (ata = (AM gh | Ahan sn AT A187 os Lat 11100 eal, Reuefa int 1700 K gi 1783 K (7) Si0, (eum 9) + 2616) = sity + 20010) 10. K are las lopir Siloti eu o varied eal exalt ca (Atay 0 ealculourdn mod analog eu earvl precedent {AM y = [Wl yly + (Maule = 148 790-4 100 — 159 490 can, 459 264 oa, Tiotnd cont ed 1743 K ane loetransarmaron (oriatobait 8) 5 (ALM nabs tonctia de redueere Inte 1749 K 5 1980 K ont: ( SiO, (oristobali 6) + 2646) — Sieg + 20012) Dei (SH nade = (84s — (AM nals Si0. (are 9) = Si 150 ca 89 264 = 1 $00 — 157 B14 eal (Béttgas = (AMR oa) iV" Shas AT = 196.27 cal, Deoarece la 1960 K hivxidul de silicéy se topete: (AMttaae (SARs — (Ale = 156227 — 2600 — 194.227 dt Pontra tempesntani musi mari dest 1000, eeacin esto 19) SiO 26) = SiN + 2601) (ait +f Sehnert = I= (ha = 106 $94 — 97-08-0978 4 40-100 1B, Sse calenece emperatire de andere (tempratiraflacarid) ta com usa sompletd a GO, la press constant de ats. 4) e0 0, pur; 9) canttat tested de ar. Se mint tee din tet 1.2 Fab 17 Oat ome oe bs Gh | ARO | mas pase ars aoc ene Rerolvare Pentrn ealeula tempenstara ile Bosh la presione constants (7) s6 ried of eof ar Ine fm doa ete (1) Rosotanti (Tp 2) —~ Prous (Ty Ps ABR, (2) Protsi Fy 2) — Prodas (a); aut — ("Fs, (08, a, r+ 39% (Chale sna produslor intro noni de moi wi cepaciie slice a prenone constant ale prudusilor de order (P+, ‘ent inte Paves! (0) Ronotont ty P) > Produ 2 B, iorind ef translormanea sate adinbatiot (9 neglifeush pierderile prin Testud), 5 poete are ait, (Encenar =o 4) Axderon eu O, pur are le conforn ew reach: 01) + 112 O48) = coxa) FO Aug = (iho, ~ (AH Allg = — 94650 {20410 = 67 636 cal,tine ois (CB AT = 1,85 (7, — 256) + 108» 10-4 72 — 208, 20-10% (7 — 2564), Cealut oi 7 din feral ie sate iil, Este reepmandabil rorulsanstrificas ever Tale tot FE. gbjidese dierte ler pena Ay Se repre Tn wie Aa fame de Pein, interpola, la A 2.68 heal se abjing | Fe = 40 KE Poniey etal tetio weet ea. 20) 2) Andee cu ennitat tonto te at, duce tn teen ined 138 tol Ny CO{g) + BA Ole) + 188N ie} — CO4e) +188 Neh Bos (C= mea Ch “2p 408102 7 — 204-109 7, 1 Fm lCBsy bine sal All E By (car, 67 634 =F (23.06 + 68: 19 72.04. WH AT, 8768 — 2805 (F.— 204-109 (TS — 296) + 204-1 Te — 2, Prin apelgi procedon grafic wenultd 7.2850 K. Aeste temporatunl fiat vile macam, Proc tr ele nse ati. detoet faptulis cd alt prow Atenrranrit 9 sombaetbi initia stor doors pe sua estan da aon. {Gulurmay, eure fv anders rons {SPB sabe mal mcd dec valoarea cal ‘ult (Ali. 1.88. Sé se calealezeweomperutnen mation toretcd do andere ta volume sore sani (temperatia te cxplose) la conbtia vomglsa a Redmsetas ca cant Ita orscg sor, wind dotted tbe ‘Se conviir somporar ideal ante AMA ee! amar wom Sanaa ‘iisad un roiomnest similar eel flit. coeol_ empertan a sods a preiune conwtanté problema 13) 9 obfige oll seals aun Econo vy AUB, roppeint varia do croesi tho Fife slr. roti de comune na produatlr ine minute mal espa isis calves Te-volum consiant ala profayilor de urders (Pr) Haig) + 050K) + 188 Nile) = HOI + 1.88 Nye Pee AOR, A1m,— A075 su ponte 7y= 208K, Slip = APe — 798-505-1987 -208 = 10 -{, omeit t Cons? om ba4 onary ta aos 14-menar, intend 575 — 5227, — 20) + 12-168 (73 — 208 188-45 (7, 208) 4188.07. 103 7S — 209, Died ste pel ott 947 + 138 T, — «Ld — 0, “ 7 = 208 ‘dona rink & oouatio te nogativ, neuron se Fa Yaloarea obfinatdeata mai mare deci cea peutic, din enuzn aproxinws filo intenduee fn enloe LBA, Sa se obfing » expres. penn cddnra dv roan eaant sentra veri 0 proporiewretantloe erta de tu stcchiometic wn erode fone (gh pris Umar sistas incr Se soir prsiona envy fei atm ren : 2Nexolvare. Pentn mtvaren probleme , fas, ae (2158) 18-10 eal-K se exprime cofiiontt Ji Le—T ha 9.0. (el $l copion (ut Eoukow Gigs pin dentate es venti fn fanefic de porametrt experimental msiabi Rerolvare In problema 2.5 st lint matin n= cyar sr 7(2) Jae Pewaiae meet wtcpe 2 = wane carl» Smile pornind da Ie osproin WU = dT + (4), eS ere se objian BA. 5 clear scorn ds tomporavri care apars penira 0, ‘en armare a une cart de prestane de Vai feet Sone T ho waiting otatir van dat Waals Rezolvare 3 Pentru un proves destégurat Ia nntalpie enastant (24) arecarao oe), Rorultd cara tamporatuni ew prsiones (4) eee) Po de alt parte: (cr), Ee) = ~(r) (ee) +P urna gm ven dex Waae2e) at = Gel -: [ira @).- wot (2) oA) Tntograla e6 poate rezolva aproximatiy penteu: So obi Vents Ops a= 146 Baten: mol; b = 00018 1 moh! $= 500 3.258 MIP 7 — 10.194 «107 7 Ponten O°: Ch = 80M 4 259 « LOS 9 — OTA 10 « 273 120 cal-mol-K-? = 0,284 1: atm mol! KL eta (ae asi one2: 279 oxo) 9 Bibs siostcot fois tn pratiok Ie liehaiove sarah 28, 9 so ara od ponuru vwriaia do enitopie la preivne constants Mortart) estes reli: 3-9,Rezolvare Nerolvare Volosind elafia dedust aiteric. Din oie diteronginles roofs do ona, are[P rer) Je | eaomon dH Fal total exact * obfine prin integrane Fohsind ora de nogrore pia pnt prin dere Bare 4C garg ote (Sef aura! ansiderind si vou do dons 1 al eae ete een este ports de Ie rela G— (55) 14 dorivind: In finat gusto st fe aleaice pr Drover ee nila! Rexolvare M4 sibibart expresite nea vlan, ta teperoied rantonl (ar) er) | 0 dupa rearanjare: Cy — ¢ sme ena) G afer Aolicind rlaia objimt tn probleme 2.16, 0 ebting: i 10-628. 88.8 1 =284 eal: mol. Gu) GBSucoral valor 4 din mumitoral fgetet a6 thee mY almtsmoltsK" hr pals mole Kee eee Rorolvare Se utitioaak fanejile: Dar: 4 (ar), = ler), ( hii Maxwell Comite rai (W=7G oe Put — 1); ey 4V = Wan), Inncuiad darivatele parle formulae initiate e obfin real cetate 2P) 4] + Per 1 av. AU 6, at ea ajar car Pur Nav =o, pal HV ay ar, 210, Conitorind forte 2 A.X, ¥) oars sto diferent int art pot serie rma eae derivate prt Gilt Cel. GS) ana 5 tae io ai dah 7 Gil Gra ind cee relat 9 relat de lxduard pen Alt, 0s sbpina expres Be pred Sauer, (Bix ii pen oe Im Poche Be paramettt tamer aos pert Roxalvare (emer (aen, ter) V aD se obi: 7 68 a7.‘Considerind yi relagia tai M a x we 11: 1 fing dupa tnlveun Proce gerne ete jatroduo tn defivata mieimile U, Hf, P waa G “dae wl apar dh constanto pont dove sn sgl mtn nau lininbtints U 6 nse tnd 2 de logit (de oxorpia AO Pass peg Stead it eonfia marimen care on ee se Cy = MeSiey, ell Tai ed pel nln, pat aie eran pei (aloe fence i arate Pe VT Oe (fled deroate ieenao Reroly apn umtal nine Iegatara . rm nas van: (22) or) *(9 ~ Se intidooe @ in deriva Ue\(a2) sth)" @sen,” (CPS), Ys +5 (en). |* og hap les ae es ce ; oe 6 ese iin propriate damcsanilar inabins (needa Shaw) Nia nd at ne on oa) at pode dy. Wind oak Fly) ete dat tn naa dost =) Ce), Ce)‘Pe baza acestei definitii remlti: . He 9) == He, w) <1; He, 2) = 05 ath, a Hs, = Hy. 2) = Wy, = 70, 2, Any) Hee) ote 9), ey Ay) ee 9) © = constant) 0 y= iacobianal Je, devine: Atuaei diferomion: ponte atig: ds — EV gy 26 2) aay ay, Introdueind dou vewabite ani sip, emt te a Je a He, Pde + Jom, Ady + Hy, 2) de 0, ‘are ste exprosin eer enh fd mis demiontn hint (ttn Sh 0) “20H, Genter proprietor doemninansilr saeobinhs (vei problena’ 2.8 a Ge Rexolvare APS) 2.9) Ate AV, 3) “EP. T) aw. 8) aen-ler) 0 is en ae av oclere anny a3)” nto ann ler), “anaes” bil (3) -(n) for). (09) 20), 29m eprint wut i 290 oe 0 fama. Dspondenn prsitnté vapor sahalé de temperate ete dal de ecualiz 1 Plan Tg) = 8.5856 — 1971.74 | 280), Si se caleeese carina de enropio a rece mai mul da ndaianal Beit 20 tm mbmional gta a pretane de O01 wim, fe aeons tomperaierd Voporit am eumnoniton un gas et tm domenca de presititdete, Noxolvare rag mont pit I dont ri ea 6 kate 2 pene crapotnret oteumd reversbilt « unui mol de r-butanal ly 25°C ») deatindera izpoem envi a-vaporilor de butanol oh presana ‘hia, tr prestanes da 0.001 atin, be 29°C Ponte pal prose they og S02 © 99 p6cal-mot}-K-} Bs aS, Zee 0) Pentea al doen proves so folbseste slain generat (ee),--(e), toe penten un gua il ein . 2 eo Rn = 2 p =apin— 7 _ say ie? Bere oS 3 TAB mm He = Py; P= O00 ates — O70 mm Hy, 2 5, — 1967-2808 Ig 2! — 4,65 enka K- AS AS, 4 AS, = A234 4445 = 38,69 pal: mo -Rot2.84. Ue mol de gas ideal Je 7°C se destinde de tx presitnea de 10 o a atm tn mod dropat. Conewiatndren proceed ianerm remastbl, #8 ‘oeadean uc merase tr, conti de s@ldard Q, i ceria lePunetlr ere inamice! AU, Sil, AS, Mi qi AG Rosolvare Ys Droamie snp nee unk go ideal neta fetal de varagn volum: SU = 0310 = SU — d= £373 cal- mob. " SH AU AUP = 0, saamee PY toute yori pra ideal teigorstnd cmastee 1 ==1978 eal: mor = = = 1.878 onl ‘mats seRcadue qected «,bensrnl slid pe demerit da-tomporanerd BOLO al valerate in ied at _ cootenxe | ona | om | oa4 | ox [ cae | eae | gts 5 se eleatce aria Te semperntera de — Rerolvare de enropi la tnelarea unt mol de bens solid UC Ta OC as aru ann, fn-care ate masa mol ee Douro, rma alge Ineo emoue a5 @ me? [em 4) ropromontind 4b? fane- asa | sem | 120 fe tr 2) ve | tae 2) repromntind i tunoti owes | to ae ie 7 gzoe | Vit Caleulelefectunts sinteupein- Bie | i son tall 22, 4) Prin mguranea avisi do ub curbi (fig, 2.4) euprined tate limitale 1H Tym obine vilpamee O78 ale gets AS = 0,888+78 = 28.29 enl- mol Ko! 2) 8 dous smotad duce Ia acs rutin Avia cuprined intr lg 7, slg 7, are valoazea 01580 AS = 2,008- 78-0,1500 — 28,88 vale mor uct: ty rh cl vl eto gra ae fa fe co ttm lt hae ae ae eit Bo fa a ae aa te aF 2 ae 5 og #F 2.208: consider 0 transformare adiahates de sare a nmi mol de p02 leah dla Sobel nad, Vs cence iid, ly te volun fina pV etn bre adahased) Sit wed dened expreie fi semaal fanchior ‘oditanice Ly @, AU, AH, AS. dact provsst ete realist 12) fx condi reversible (quasinuti); 3} eos, dstandre 1nd ©) ever, demindoe tm soni praie roi Rezolvare Procenul find adiabatic; sinkemul cate izolat, deci mu sohinbe ow medial exterior (80 — 9) Ponto condi roversibile apliind eounhin odiabatet 7, pidooarvce Vy > Vays tary > L roll Ty Py rent) Bxpoeil yi somal fane}ilor Lrmoinumive sit date 10 tabed Ta dowindores sn vi" = 0 gi deri tamporatarn final ste Init Tn oon powctice prodagal se va iton inte ale doa’ extant lira Lact nazuat va fii taste mbsuth msi mie dacit cal seroriil Vidor intennodiare atm eels dou Tinie) pivdiatd # varia Taaobilge SUA § AS,Menionion c& pentru caloul varie! de entmpie AS” si as" Actuals proce reversible pia cone an stro ial Ponies deniers ta eid rain rors sed eae destndeea ler April den Py ln Vp ema prone patie clan ever a ‘i i Tiel t= t0(F) a aes Soo ra! [eens met ee cee, wwocanatn — faestiit ro | aw ah ing in format dip vieaInoeors guaata de In Zy 1475, urate ian Htoorm di Hata Fp : Esta confit ate comin AS > 0 pentru sistem faust, In prove inevere : : ae 2.27 Aavtut 9: dstnde adichoic in confi de contagnesiene_conston de Wat de to store intats Vy = 20-1. Py = 100. atm a1 = 2G pl tao sure finola Py 1 xt, 54 be elas vrigind entople tm tps frees, constr edt azotul se comporta ca tn gaz ical, - Rerolvare Pera stare initial Pry 10-20 An, “Ope. F9a Poy = niPy 5158. Perera sare finda Pas ner form praepintas Cal tenmodinaniil su =—(" Pa pentru procesul adiabatic. La P= constant, pentsu un ou id Rona Nip MT = — Ped. ct Plea — 94h; wt, (Pe 7) = (oteu-un gez Bitton ie: Cy Beale ryal 2st np PORTE By 5: S12. 020 1220 yay De Ghat 1p 5-987 Pay M35 nak. ‘all 51,68: 0,080 Yarns de enteopia, pentzy mol do ait, ou temperature i preston commit vente reper de rai proba te Sol xara Sia 6 (par 2 6,89 cat-moF!-K=) X 2288 se caeaten carntin de exirppic pent ronsexmarea,@ 2 soli te-unatie lahil la tiporatna de 40°C im amoniae faa INP, ta posit ‘onan de 1 a, nose date din tabla 2, Scouser Seton Gal! Rezolvare Varian de entropis eu tmp ie puta ese data de rela ature la presine constant pentew n moli ait 7Deoarege In timpul proerulu ere gi 0 tranefonmare ls fai, vvigia enropie eite galt o Se ee ce we ee ool! ar! a (228.05 47 tore ar 10279 82 «59495 eal. R-4 SE 59485 eal, Goes9eere nl de wat te 2°0 te P= 4 aim, Dao vensornare Wi rath ae pry BP temas wf calm chan eae ROPIME!, TM Pe tind ait considertnd comportare ideal a gusutei. Z Hesalvare ‘Peotru un gua ideal entalpia este fonie doce de tempeenturts a Dos 7 Abunei: fig 2 eR 250, Si ae saicee vrigia anrciet Ware gia entetpei ides, ® rece ferred a olde ssc Se a prone Ge Wat ae ve a temperatura de 25°C. x ae ep Rerolvare F< Pasar; aan ~ sar von, entra procs item #7 0 dee =~ ar; ao ~ var, fe ate arms; a0 ar m2. Ber Ip cont taoterme ponte on gue ideal oxth. retin Bo y te » Py De AP 6 ta san no oe 2 U@Metaribnt de butt skid (GINO) are 9 desiate de OSE ta 20% Care exe wernt emul idee la comprimarsa form a Hit din aceasta estan staf ta fa 20 at 2 Rezolvare 6 var. a ~ sara var. Won a0: a 124 Dar = 18,5 em males s880r . Decks AG a 160,419 = 8.0475 om? atm mo! — 73,8 exds mot, 2.8205 ve canes Q. 1, AU, A, AS AF 51 AG ta comprinarce tyte mck de eigen lela Lit att, 30, 5 presupane cemporiars ra ideal, Rezolvare cal-mot AT In = np iy 2s x " A @> 1, pontea un proces Szeto, AU —05 Alf —0—deouree pentru on goa ies] A 9i AM sint ncyit mal de tamporatu 4087-2, oe Sar — par. = 1,774 e4h- molt K, as—— alone Droarece d= 0: d= ar=— a7 ("any nr ain p= 4,987-908. 2,208 Ig 778) = 2355.5 eal- mo auras, Sm AP Al ras —— 200% Ponti vasiie de ontalpie lites: aC Movi: AG = AP — 2.555 cal: molt 239@Un mot de api oapari ete comprinat socal ln apd Teil ta punted de fisbere, ADOC: Caldera ts vapor a epee fa TOG pk FON nis Hg este S007 cal! S90 catevece toerut pecan cantata We edn # Pinchitesiematinanoes SH, AU, SG, ME yi AS Rozolvace = = PAV me — PUY, — Vg) Pligg = RT oo an 7-18 = 9720 cal: 741 al-inarAU =A — PAV =~ 9720 476 ——8.079eaI-mol frar—o; ar =74L cel: ma? 220 a3 Gan —ras = 259 ale mol! CH 974 — 97320) 29150 we ealaecelrat de elem cariatia de enropi gt veriaia fentatie bed pena cask 28 mol de Cll, tpericeu ha eanctul no ab ror ta da et Corn: Se cunasts Try = 53K 53 Abhay — 7250 cal “rl ‘So consided comportare idetd a enperib. Rezolvare _ i (rear PV, Val — PV, — A= —702 cal: mal”. 285, Sa oo aabicaed exprsite de catoul pent funejils Ly Q, A AHL MS, 6. AF tm casul procerlai de deine ian boXtui fen e ne P+ 2)v— oy RT, (ros) deta volun iif Vy fa ota frat Va Rozolvare Usiiand relate Inert ie vol 1 { pu Tohouind P rat: Variafie de oxergis inter est see Protea gamut ven der Waals a Din rolaia principal 1 remus Q: o=ar eoteu caeull vaeaiai de entalpe se apied reefia de deine: AM = 00+ ALPY), sav dupa lnteginres an av + apn, Produnil PF so abtin in wewaia de stare ¥ ", ¥ at afar ponies ae Apes y= Rr Inogvind Is temperatura constanta gi rearanind ge obtine: soca 14 Kener el (ne ovina de entalpio este est: AH = oR ae Proven find ote 1. Prien ds eaporiw biaxidutné de carbon sordct te 58°. ete {givin Hg. iar cen a uni carton soli, ta teas temperatard este 1 24,0 mmm igDiferamt exist pentra Li 4, deaarsee Tverul da expansinnd tesa Care este ariatia de ental tier etnd 1 raph de Cy sir 0 eli x aceasth tempered? So prays 8 eaporth eh» simportare tate Rezolvare Procesul reversible soldificar a unui mot de GO, se:poate tal f= 05 400 cal, gf = 26500, Pap =~ ow tot prcotepartns, revevie ake slam ele nfs A al : pape 2} vavoraeea serail lexus gute eubrit Ie pre ton siesta constants By 3450 mm My gi Cs fe 1) detenta vepocilor de CO, la prosivnow Py = 4 204,8 mm Ua: i ohoeuind: ¥ = 22 400-2 ye ma *¥gomlensae reversibid & Yaporor In rosinne natant Py $b 0 2 oe 1 42 smo. 4, 14 05 en ea oa cng Hern RA awe re a force t= 4700 oat P2185 mm My P=826 See lg ie ete cnet ug me Ae, on “ M0 GER EER Oy ble MA te tly FRET : te 45000 — 479 — 268001 4710-6540) ~ 85 £09 ou ea Nom atuneis A= dy — gf 1, + B= 88500— 4700 — 5400 — Poa mm Wp P9260 lg os 1 seta K, Pentre proseeea parle, warialia dental liber esto Vontru Ae = Bos Bs, = 1815 eal KO, 4) AG, — 0 ©} MG)=D_ (proseae aeversibile Ja Z, P constant} hag = fours var ‘ va 1815 ons Ponieu Aly — Ags MA, — Ay — Aut PAY — Su, — by My = Ay = 19500 + 4700 = 20 500 Variaia de emtalpi liber ese easld ey Incraleretc produnin condi povesitie Ia Pal T ooetante 400 001 3206 4, 2,801 967-2149 1g 2088 35,43 oat ama ey 95, Pentra introgul proces: AC — AG, — —25,1 eal “mob ieee es [AG ~<0, devi proces este spontan in sensul considerat Doniru Of, = Bhs Me = Ae Drei f, — fg = 66 400 — 4700 = —70 100 et 23%, O react chimica cate relicnth revisit intro clalé de shetol 4a nrovlined ds 2 aun 3: fa temoiratan consinia de JOC. Huge ec ‘hint te denjarta m5 molt de bas ese 61400 val, Reacie respectiog Palisa eer ta asasttenberatnd $e prsian®. So wht wh lars Batu formed de energie ecros tr 494K eal ub forme deed sort aisajeea a 8 tl ga Siw auleates 2 am Ae, Au, Mh, A AF pentru cele dowd procene, co i abelol 2.5 ain sintetnats toate nonstate Aerindcompintare oi a sat a Rezolrare he ee Stirile inigiule gi finale sint aveleaei pentru enle dows prucese, = ins De tenet S| ose ‘ a hia a ey = teTess «ct enc ct mart Cf are ert (CYP=5-10979 (gents 0 7 <0 K) (ayt=6 (pone 304 1-<200 Ky (ay (pone 200< 1° 500 Ki) Tenpraira fe wire ett Tyg = 290K, tar entpia de opie So 400 cal mol e ) Si meat pe Uns rincpinos 10 al wma como abso att ela Bd Re 1) Se snes pri ert, vein de emrople Wi wif sieains leet ty wot do 100 Rte nererece wale eee toe re eedienctaens Aone eres 0) Be ban print I OCB ag ICN gy Alan (CB ap Bare ar Mae Bar Dyk inleeuiis $2y — £7.27 eal mol KC, 4b) Uidleind Ugca tad Kive hott (BM aghan = (AH ap + ie Achar, ACh = (Cy! — Ca¥ = galeria! 1 Atami: (SMa — 4080 1 (150 — 200) = 95¢ ea mal Sia (3a = (OSaske +" SAT = 1710 elena Varitia ls entalpie liber de tine ost: (AG ae — (A Halae ~ 150° (Aan (8G hie = 350 — 257 Seman Jai (AG.,)ie ant o. provera de tpire nu est spontan a cea temporal 8 eal- mat 2.98. Camamtnda sy dates din tablet 26, of ented somone | Se | a edbret | enonibrcs teal ioe 0 ee eee 1) Entropia moleré esunudut tehid ty P— 1 atm si T= 298 Ky °) Bnaropie motard mind « hevanalal coz ansiterind stares de gos oti ta Boe Vat ge Pe 8 a a ©) Eniatpia bart stodard de voporonr, SG. Nevalvare |) Deooreas ta 268 9h P= 1 atm ste lichid® 9h de vapook nv ant Iulibratobuve aleasie ale rovers penta celeul Bea ie an (eapsa ew) exan (23 Hsin (gas iat (Stehep = (Sho + AS; AS— AS + 85,445, 5,0 (variahia atopic ev presen In sare conensnt), ag, = (Alls) 7400 _ 94,84 ealmol?- KA 2 ane ee ec hes Pos AS, = 1987 2308 log 0.26 AS 0-4 2484 — 2.66 — 22,18 cul: mot !-K, =2, cal: mo? K- (Badong = 7085-4 2218 = 9279 eal-mo 1K 6} Penra ealeatil NGhy cle egporizare wo pont foes aceagh eel: AO} = AG, + a6, + AG, AG, = 0 (varngiaontalye kere co presianes in far condeneat) 0 ocr In 208K 45 Pha) of carn t a arine var Gt = RT Ia Pp Lua 208K Pie, <4, deci Sy 0 i fasn Hebi ent com stabil‘Valoarea Gk, ost ly = — 1,987 +2203 «258 log 426 — BD ou: mai Yo SA0@Siania safer da wempertua eon atoropeas tt ee ch Bea) ‘im sranrforma Scat) = Sa(eemayn ‘Sse desrmine temperature ransformari acd se cuyowdlatete din tabetet 2 Stim feamaierwer) oe ge] a | axenths. rc ee fot) T o { Boke | at | a 80) =n 139. ar aera [et ae] Pe aan tele: Ala = (Hun — (SMa, = — 520 eats AS = (Saher) ~ (plea 7125 = 4 8oul- mols K SCE = (CPscomen ~ (Chain ~ 85 A6t = — 520 4 629 = — 04 onl-molt 4, faper—rfasasf ay AF) 0 dup integra i redeanjare: BG = 604113 THO Tg ‘andomaren cee le anportora Ph sae 46} = Atanei: ee 600-419 T4023 Pg rg Renal pe 2180 i+ eT Rerolvaren s» poste face prin aprosimisi suecesve Im prima sproximere 9 negljeaeh 7 $90 is in a dous aproximare s@ Inbeuleyta aceasta valoare,ealelind » noul vloare 2430 22K ree ~ in « tin aprosimers se taloaiegte nous vahare, sulting Se ee Oem In a patra apmsinare Jn a eincoa aproximare iginoen valor constante peatru T'sodiod obliges. somata Ded tatfariare ar a = 4° vanes Cored ae ou cea gaa chpermentay top = BC Teautarye palo aon gi gatr. At po 1 sn valana AEP Sy face mpresatare AA f(T} ar pin arpa rnin AE} 0 se eine alae xtath ponte BAL, Si ce determine care din formels eloropice ale carbonate cca sult ta texaperatna obit [7 ='896 Kener oe Presiunesrafital {etiam st teed havea temperate? ‘eos date din tet 28 Soonie | AD, cimary | 18 a oy | a Se | Reralvare nema etabls va fi dotrminats de somal varias de entapie ber andar" proorauta, decatooe proves snk plete fe pane (lee) Sa pasanitral composite. Gratit “, Diamant; at = any —7asy Cildara Intent a transformant de stare se alelete din oaldurle nbaste MMS = (Adis — (AEs =~ O4050 + HABA — 44 en mat‘Vavinyin de enarope ete 3S tunis Seat Tinos 98 — 186 — 678 eal- mat? K-# Peano — (Sd Mg = 694 4 208: 078 = 688 ra mol MG > 0, deck forma stabil cet gratis Pentra ental presunié do eohilibrs se foloette cit: Gratit 8, Diameat ae nee ae eas T 7 (64 nope rlapin stu obfioutvalorle din tabelul 2.40, She = AG, + AG, + AG, ~ 106 cal ma vy Jn care Vor i Fe sat votumele mola ole grafitall gi daantuta Considcrind volumole constant (ncompresiittaten fazslor condone Rosati ty, dP = 656; (AG, = 0 I cotton, VptP.~ 1) 4 ¥elt — PB) = 8h onl: mol! = 27 40 em atm + mal! pte ea BL Rene ae cacao gp Rui eel wari fone nee rt «unt me aot 208 a5td gene 261 a3 (=i) _ yn (= Avis Py 1502 atm, See ed eee) 24. Pers rangirmerin sloop in cry pret ota PoC) rrnti rasa es Posi tmatormare Hop an ea a cola valoareg AG} =O le T= 088 K. Dn abel 29. sine re ‘abot emaiplilor (raportat ta saloer dita 8 K) st onropite baat outa Gin cpa cabled fe presane concanta (C3), determinate calerimerie. orl de emperaters Si se easels: fence de eneaie herd (GP ~ 29)/7,covespnsdoar ce dou forme etre, vrsaia ales Pact fern tempera, (04173) [rc taritia de tiatpie te 0 K(APR) 9 orf de entalpin ard side (a0,) temperate dave Pee lat tach in Anbu 240, Pentru a oalenla valoueea M3 Valorite gallate stat reds co apliod rola ac) _aGh— am, am, S aseg. $i loan vecatick tunel de eoerge Kent ANOS a exit SC Petra eae: eg emp te SA Sar TAREE jet hin ran se pte ka pete : ical iy dente tamper tind ne Corio + 2M mond Sly = 17,80 kel Sta lot date, 4¢asomenen, in tabrlat 2 moh 2 (5) = 164 (San, = 2,21 col pattie dri te (Ce = 267 +2,612-1047 — 110-107, (Chin, — 69987 — 0,190. 1087 4s 10 AE ATR 097 — 46s. 1047 248, Fn casu- una ise tachi in acide eat sa se tachis tn rs sir procen ies et “ ata Bitonptss de exropie (ler 21) devin Ting = Bb 8. Dupl Do Donde Boreal By = AME 0 tn car & ste arene reste’ chinir, Sd alee presi dfirenatlor Ptr yf i exp (Ca, finite tora deri psa a a hero} Rezolvare ‘pia in mia 2} — AM — TAS ‘a np ox i 3 in a scuar—s[asq + Attar), 10,28 eal mol K-! Tiny = Bay + Ad A0t = Allin + Pram pineal 1, Ye =A Pao; yy = ak — 9 ap, Dap tnlouiri we otyin deus din express core a= Tae Par — aay the Past oan A ied sat «fot is x tsa, Be uz atone sale eit yh Wem — ad Pav Adz, de — 57 sap — sae Pootra @ oboe rsa atm ai Po i nalts G dvivatele partial conde fancies 3d Psa fTets tT, Bo BS Pin She ee fe = ho 2S (ke — 20 5,120 WT 1 to 100, 8984 = (Shy — (8 AC = (Chen, $10 4 161.1057 1107 — 5,420: 10972 80+ tate +8 = Th opt ditecengens 20h ree se taosorryar—toof—toas +(e tat sae 40 7) ar] tpt etm AG pentru mati: NO{s) + 1/2 Og) NOge} noe funcide de energie Vera la 810 K i erelpile de formar semdand Wi Reale subnet abet 210 2 9 cle Mra () ert a= sou tn comditil standard: A°— — acy, xi) i standin: A¥— — 30, 8 : %Rosolvere resi de dehnijiy a onficionile’ JouleThomson Aplin lain: si en aets eli Ca 4 f (ai), --[- Ea), oA] 4. Un mol de gaz ide doetinds sevens dea tan nial de De ase'D dam Went entopte Sr earn isle de panels! Por Pe ) ~ 2, exist reat: 9 (a).4 Un trmoutt ov api ote menfinut Is» (ompemturh de °C, tempe Cereal mbuuet find do 22°C. Intron, aunt yy tvinstul slut Po eal prie oli on, Sis determine Varma eevee @ Apel ntrmoate gel ln comer SEM uateoseh due procera este reveribil at. Un mol dp gap Meal afl 400 Ke destinde never w gntarm, do 11 uo} iu30 Sa sraleuews Ieeul Mectoat de aura variain de esto $2 se eaplies tuple AS’ D, dog procet este revorsibil ‘9454 a0 cavuleze SS, Ad ge ALT pontea proces: svat Ti) (120°C, 4 alms) — 1 mal, 340) (gy 20°C, 1 atm) eunonen (CB 18s (ne = 80 wala, {Heal 108i a caleulere voriatia do ent resumen de 1 ata) de 2 Uatalain labclul 212, 172 keal- mat ic la toedliron unui mol do idl ei tomperatuen de IBC. Se cance! | sag | sx) | Saban | tw i Je WECO Asya caleulats pe bora principiutak 17 ste, nesntvt Tbatic es eager eonelunin rk aceusU reo este Smposibh? ” sn molar el upeé subetops Ip omperatara de 26°C In presi fiyinsy Sat O qa at esta dat de relia empiric Va 5 2P PA oni mol nail ib pent uo de sostents TORR 8 G0 atm i Be salou avian ta preinino bent ctrvdanl pentru se proces cts In 208 ih dentate : A cal = mol" Fine pose vrinia de enlape standard in cal mo ee teil forme Ally ap OT be ‘bjint 6 funehio do temporsturs pontru AGL a acestui proces ar, hon oazul uns gaz ideal exit penta exergin Tiber rela} MN, ‘i eompectiypanten eotapia Heese (i), i ata de funsio enone Hers [Pj skentalpe liber (6) se miata i unle Cag fencfia ae Maa sets det one . Sifingia We Pane det t : é Vener: * ‘Si a aralo ein engl arestr fone exist velyile eierentiae oe Bee ao =H ars Lav 9 dg—Har—Lap, Bars fav i ay Aar_fap Scoot pcenl dear ya ml hI pein enon HO (old) = HO (ena Sd oe stabileesss emul, voratei de entapie beri x” proceutut Fac. i tamperatrie ie 100, OC ye -FUG ae af ne St se ale ss Pentru un gat a cine ecustie de Gel aac cate Po = ht — ‘Sk se olotese 0, AU, ll, AG 3 AP pent 2) destinderen astern 800 K 1a weeutt, out moh de ux mono ‘Romie ideale ln 1D I a 2 2) eter izoerng roversbil te 300, 9 neehont gon, de 1" 3 ee Si ee ealeulems U1, 8, Cy Cai @ pontu un mol dy wyot Ia 50°C gi {isto preupunind este Wield Sly —5,Seal-mo? Ke a TOL T ealsimolsK-", Entatpis Le temperatura, de OG Fi proiuuns de} nto go consderd conventional egal ce ur, se demonstrts ci acuinjentroped uni flu wnntnd ecuaiaterinie ds Mage m hiya der Waals ane formas - TY =H — canta{2 Si se arte ct pentru un gus rare so comport conform eeuiek de ware Van der Waals, extiypa molara poate fexprimath pein relia: Salo TERI —B + Sy, In eate Sy vate 0 constant 2295) se onloulne varia ental inbard 2 Lmol@le bere a toi, a kid de fa la 4D R, Seung: Sty == O64 eal m0) ** Ky "Ea 1 On Boal: mols Ko), B= Lain. 25 se elev varia ontnpi} ere mato ape inten proces ca inn oH Mnf ste Boal 90K gh a Se ron sore at Et Coat aoeal- mak’ Rey Say 102 ealsmok rata 730 el 24856 caoulezs vari de entople e258 K pantry rae eo) MOata + Bf) — 240) + SCOL 4) AlOjs) + OTIC) = 2AIOYS) + 2,010; thea to cunose enti taadent peu substan Sonera [etna] seo] em [ee | ween | 040 | sin ed ogo Sart x) soe 25 Featra sei: anti | Che) = Hache tg = — 0,257 eal ty = — BOT eal Si ee calouli varinhia de ntmpie standand ares 2%. Pontea veueins 040) + towel = Cate) to cunose urmioasle valor pent fapeile deonesgie nerd 2 000 Leatdpie de formare ik OH (ab, 2.13). ‘Sk ealeulste varajia do ontalpin ised standant le 2 000° Kia) 22, Foeya eleetromotoamy a elemental evan: (-) Het Masel Hete-eai| Gh = P= 1) (49 an 29°Guete 1.0896 V. Cntviontal do temperatura piel este ~ 0.000065, Vik-*Sissealouboontalpi bar stondant Le foroave,entrop absolut entalpin siulned de fornvare a clorur meronronsn i east tempest ‘Gall entropile nbsolute ale moreurui ot clruluy 1a 25°, lat sepeet 1856 9) 983 eal emote 26, Un slement gulvanie in care se desiaund recta Auls) + 1/2 Mylo) = Autti) + Met Bly = 00455 ¥, Varna de entalpia «rani fave fort eleetromoto elo Aa = 1278 to caleulore penta wala dst NGBy, ASRq gi cotieentul de temperde ta alten aya z z3 sOLuT MARIM PARTIAL MOLARE a 18°C, 100 w de api dino 53 o wmf satrath, Densata slates este 13620 gy-en®, ‘se expring cannot ota tn procs ¢ mast, molartte, nota racic molars prcents ao 1) Doct g gest magele lor di composeni,egncentragia exprimal tn provonte do mas ete 0 = 886 Rta Se 2) Motortatea (gurvarul_ domo Aizlvali in 1.000. em de solu Glo: Ce % 100 = 88% clorwet do oalein: a 4n cares» ena VoTumaul de solufie: ny — numdeul do mol 188 apg 18 10,90 1 95808 G 428 mol 13, 1) Malan (oumsiral de soli do subsinots dizgtvate intron kg sateen) 1000 ng _, 1000 846 me 7 100-4800 4.85 mol keh 4 2) Frac motaré (nasal de mol de component mpostat Ix nomé tonal ce mo ds el he s.e46/110.09 yt me SRBOG/LIO.0 £1008 X= ps, 6) Proven mer ite: DAE - 100 = 803%, heros wn iain dl compas aif led na cmon io ml tat # tc any teat Pe ole nn i le no ‘serio: pt det aunts svat Asuna ot li oat Tabolul 3.1 prosinté traasformévile de concentratit nauale. Se propane «csoreiin suplinentae, sve salieuset toate ageate rola de tranformane : es 3.2.0 fmeis omogend [25 yy Zn) AP rah a este definite prin idetiiea Fibs, ky, Keak = fis 9, 2) Fine trmodinamin em hyo fy sink mei omazene de grad tn Iptind seroma htt Buller aotpre functor omosons, ef. se caprtnc nits do mas prix dre rial mare caresptnsdiare Rezolvare Devivind ieemtitotea dat in funotie de welt fos all fle, hab Ke) eB as eae + ait fn ys 2). ae 2 Dey = aft, y, 3) Acenstt este toreme BG Eu lo aspen fusotiloe omogene. Aplitnd Ayeneth mslatio fonetekomozone a unt nen tafe ccmponengi, penta fh ost het OT, Pi Hite) = AF, Py my tee‘se objino exprosin: (MEP saM AD ar Pinomeans imewe: j= Mae hi Ae Derivateleporiele at toca mine perjal moines ees nlocuin, rosmké expresia cera 17, Pry mang = Dem Simi otfin expr pets xh font aT, Pens my 18, 18 Un amet dap ec de rai malar ar densiatin “¢ = OS16 gem, 82 se duermine solunut partial malar ‘tool acd sonmat paral mor ope tte Vga = tf ent" m0 Sentites aotdae px 0.16 gem Reaolvare FFofin molar a alcoohulul es Volum molar sl acnestouloi eae Xy=1~ 048 = 0. Xa + XuPuce FoaPua, ‘Vohumulmolar al emestecuai se poste cluuls cu vlan Reza: Pa y He Sill Suoien, a BR EA OB 8 56 ot mot Ot Atunei: Fy = S84 =08- 18.7 55.7 ouet- mot, 2 Volomul aaaar a esol por ees fe ORB | amesiecul apaleop tiie apare dei o contrartis da vou, St = 78 ems mol 3.4. Fane patina st pny omogee de rad sro De exe eva ola pri mtr Fons naar me APE, knglng tn) = PAT, Pe, ayo tnd wage tai Bu Lei 98 blind 0 relat tre dere. pafate at fini EA, Bg ys} St 6 paar pn sek Par Rezolvare ourgee volun ssl sale @ fetid mare, pentru dorsal ale te ceding H exit ai : = Pontea un sistem binae cele dovd reli objinute devin (penta j =); ee Galea? eae BS aot oe ote realte obtnte at ome se suafut GibY Se HO) Pai coma fo dopa integrare: = hae 18. ‘oa determina! vetatia de enatpie (cabiara de dzalvare) ta der [eam = Bl Onin = — 108 Dine ng Se ait arora depen One) Sea. ae Veorie petra wl ora sot sedate ta Sabla 3.8 $8 se cane alrite AF, Ly 9) AB, = Ly pena mie ot ma Rares 09305; TES geval ally Fs pra’ po a, eaves ee ee ees Prin tiie; Akg Mn — f= mals + mle ~ rll, ~ nll Inve Hy yh ents pa ole asin toate (ye two ar ft stot snap mela ue rornpure ibe Bap eter, rlaja do anal gus door My = ne 1) nde 2) — mF mally ntuple perfil molar mative Ly Fase intends considered 0 standard ofr, saa io lngie Init, In orate ‘ SHE = by 16. Peniee enaipia molra reco aparemd @ anei subsanfe diztoate 2 solute Varmint sin sistem bivar), on gait o dependent te mollis firma: Lip 180 m, le iemprontunn de 259i prone 1 at Bas siaiteages expres cult pene Ly $4 l a= By lly — mlResolvare Conform definite oni mse molar sparente: Norolvare Din figura 3,6. eo eitepte elidura Integral do daalvare pentea 1 mol & 30 np = Bont Wigbeie Soe Ma Mh 5 te i five tu sedi uni mem Bead ate (Affe roel eg = lat ok jg re os Ciktura integral de dinolvare a Aer MDa a aa TaD ate Tat fete SAL = ghd? — EY 100 mt Deo oe fon = — M100 + 1969 = 39 tea 19, Save arate 00 in easel untd sistem trnar ideal entipta, Uberd de hiorare (err mal ames) are vadorea init dad” Xy = oy per X=, Sa se arm of tm arcs conti? envopta de nvstcart are 2 solvare Ponta sufi Moule teruares Coq BAT, Si we eakulse Alf pene actin Heh 10) 10+ NaOH 100 1,0 = NaCl-200 HO 4 1,0 (0) oor yi lpstora Xy = 1— Xa — Xp Maw = ATR IK, + Ninh + (LX AD ba — XY ~ dG) 9, (ila! 0, (data Cala Cae) js ) 216.0) | asd se unas enalie imegeate de dioTore (2) HC) + 100 1,0 = Hcl 400 1,0; (AM), = — £7,650 kel (2) Naowa) + 100 HO NaOU- 400 H,0; (Affe) = — 102 Keal (2) Nactee) + 200 1,0 — NaGl-200 10; (Alloy = 1018 kewl, entails etondard ds formars ale ston Sobstanta Hols) NaOwe) Nake HOW) (AM), kealsmal?— 22.058 — 101,66 — 98.202 — 68 174 Rozolyare Conform logit ad Hoe AM by = LAM oct + (AHF (AM — UAHIGd a + = (Athalon + (SM = =H eal 3.18. Sa wy caleiesredara deal ta formar oneé mtu ev am arid apricot de pk. Sie calntexe cara deg. ed Gielen BY at dap, Se lose diagrams in figure 8 [AMheianan = — 185,91 Keal mot? ind — Hx) =9, ofl — Xi XI =9 ea ésde wns w obfive Xs = Tam Be Se poate ata marion derivate de oni! 2 eae posi 1 ae = AM) ari Ponira entropin de nstocre obi = (A1ead REx my, Coosierind sinilr conf cormpusaitone do maxin. ae elfine pune co PROBLEME PROPUSE 6 slate de seid geste ce conting 8 e-4 20°C ane dens Ae“ D007. rear. Sa s0 exprme cohesitrafia ta; tolaitate, tht, feachie molar, procente Wo masa ss proceal molt 2, Uuliiad velape covespanatiaare pentew meine extensive sta tn eadral prinvipiaoi Ile obfini urmdtosrle expert aR ms 9 (28) ge) h ad evita potengiaulai chime al uuui comport tn solute UT Bt RT In Xp sh obfiok expreatie mail po role Sy Py i He D walt pees de CHOHL proconte arma arm. densa Fn Sa ge. Volant portal tool #1 CTLOH nse eee iis omt-mot, Si vo oateuleze volumal mole partial W) ape 5, Si xo arate cl ponte o solufie exis reli (@ = C= Cele in eare: Cp) gi (Cy)q sint capacitatile celorice partial molare ale compo- rector in soluya Get, tar (Cp ste capacrrato calorie paral mile 8 componentulai 2 Ia dilute fants, |. Pentru serie do sola apoase de KCI, de diferite molaititi ean deter rminat dermtaile ly P= atm gti = 35°: me wel-ket 0 ones 0 5 wt O9nTF soe sabe erat aT ET Se detemine volamul partial mol al KC fo sulin de molatate a mals het ‘ge calculze lucral minim neomar veparit uni mol de henge: pur ‘linkes olute {a} eebuapla dle benzon 4 lon de wohum fate mare: {8 Formate cin 1 mol benno 904 mol tien Se conalerk cprtere Le 25°C elldore integrals de diluare @ uayi compas eu api este data te reat Anes) = 2nd Ont Sn hie ia care m gate nomial de moth de TL tremine AFF pent 0 soi 10%, mole Alte intogals ie lear a CANO, vavinsk cw moleltaton le 25°C astlel: » 1 de compos. $8 we dox Se a8 Ti ams aK J ‘i ao ealeuleo po cele graft ealdara dp dinlvare perfil olan saul nae! into solute cute otra umesto de bongen i oluen tara integrlé molar do amestocars sepinde de trate molar a benaenului, Xy ete: ‘Si se calvuleze grafic ekldurle paral more dy wmestecam pentea mao - Cunossindu-se entalpily de smestacnr, ek we ealeuloxe entapin pari spoifiot do dizlvare apes ia glcerak st licrinel tn ap, pentru ratoaesle concentra ane te san, Si so ealcule 42, ponten roeyile 1,80; 5001.0 + KOH -2004,0 = KHSO,- 8000+ 1,0. KU1S0,-S0011,0 + KOH- 2001.0 ~ K80,- 100080 -} 1,040)tack we eonose entalpite standard de dnsivare: | aauso,ct0840 | 8010080 i cntapia do formare @ apeis (Ait) oy =~ at keal-mor Pentny prieearon ne asta care reat xk protic, 1 5A me Penn es peau de fat i tones SE eninareprliminarn Wyrulini Teeese eae ora orca enor dc ze dwar ecead tempera rock conto Parad conalernd © comprare ideal t gta Erect eaemyagamlor rm, Sie aster In aceloep col Cte raldur eo ve Bagh]s n proces db eparae deo 30°C P= {tm od dei (2) acta dei aa ba CP orins Sovind ow fac marek do component Shuma specie ml amestecuha ete Fann ee Setiey — Ofidad emt gS se enleulose volun Fecal ies Pe Pr tle compeneniair petra 2 — 0 05 #1 Volumul una} soli de molalitats mde aeid senting api 25°C La Volomul ee Uae Sona mf Stas, cn? penta maul Fee oa calculete expreide penta vowumede pastel molage Fe FP) Binaton une Fold acl weoUe de concentajic ¢= 2 moll Entalpia ds ditalvaro a NuCl nT conm\aate) k= 08 me rotaliaten soit dopa di a) She expresia pote 1) St bint expr pors Lf ) Scio OMG ey Sh ein presi pontra Uy gi = Someone uM 1, 1. 10 este dota de exprsia (Ia Tat 3784 mA — 728A mA 269 mi, cal, ume 2 ocala vaorle ects une cslowlgn valor arose tu 4 GAZE REALE. FUGAGTATE 4:1 Fi-un on chi be eo eal oft at Ch Ine iter se mmpermtrd tea rain dt pretsne delete deta de tetas att coprin tare he ee Conant wand ee W xa} penire Ce st 4 6 atm“ Bmok* gi bDOSGE Tsmal™ Sa se calles abut aaa Tr Si oe calentese baton Rezolvare Prosiunes conform epuatiel gana Weal esto: Pag m= AF . y ior pantry goml wal van dor Waals: at », tereasvltivd (a) erte: — 001 <2 su oonespneitor: Pye — By, < DP, §i Pay = Br > = O01 Pa 0.90 Be Telaguinal ape ponies ogee HUES ee Vi ¥=5 oes 7 1 09st r : 1648 cu P< 10K, itor Feeitot Siw: 0,99 + 0082 «T= 648 ow T > 1140 K 082 i Aor oma 2 = 0756 2666 get In 5) Marie mdse pentru mstan st ane V = ec es oy le nls zero go fe In ponditie normale s2hg7g Sse objne din dingeamt 2 = 0,89. Atunek: n= ee 46 moll RE i - 0080-328 se explieitaat P alll iloarea raleulas ford de ees exporimentlé en 12% mrt, Dla wine wry kth kc expiment et ate aR 1.909 0,082 me ay as Ms 732 > fe SK Uitisint diograme te somprsiiitete (oncza UIT) i we cocoa @) volamalocapat de 0 gan te OPC i abn 1) mantra de reo de meta sare gn pot inrodace ture ice de 2 sd peste ts 100 atm Samperatrd de °C provianon dino bute de 10 2, ex conve 1000 g propend de 7°GH se clogs o-valare pentru Z ocaleulanst P gi apot Py te determin in diagram 9 nauk valoare posta 2 Neo procedural le) valoare aprosimatiy- constant. a tal Z 10a tabelal 42 s)nt- date rozatiatele ealeul Conform oenmfiee van der Waals, presizmen gents esto data he reagins p= PAE a oe Jn came a gi stat constante individuals earactristin penta un gtx dat, Boga a4s 4s ary ee 235 — ™ onm9 7 Pot a caleuls prs fosind dingsama goneraliaté de campresblitte petodenah eain problema 8 paaetal So ine = 165 at, S: snes et condi date, prin ambele metode my ‘bfiut protic ‘okagh ental, ‘Abtoren ee of de dale experimerle ete de Se obine P 2 20 atm {0'Se procedons ang: Po A. 30 — ss explioieonn 7: 7 EA, ue aE In tabelal 4 aint preasntate calealele. berate: Eontla va er Wass acca competacn etl Jest ‘Conantle xslt vader Waals se pot sol dia dstee enter ow ene ttn 4 Yt bie ig see al pin eal eat reeset dn Se objine 7 = 462 K. Hp Me Ne ferent Sse ote Fe A a prostine de 5.atm go t= G0. # SH dermis mane nd ems Be rvbalo8 nse Satta eat emote nee gi = tng 6 Dee clas egos ee cot a ae dc faa (bo 448 Baim -aeol™ gi 9 — 0578 Tok Rezotvare Divatia Bart he Lot serie in formes Rr, realm Bp care 6 sin. consanteearstarintien subtanjln, resin o snd Picaro a eewafici van der Waals. " i Folin eonttautak 1 ih espeimala en ajutoral parametrilr iil Noolvare Foosind datele probleme se ealenluad o vaviabilé anbttars alt ceuntia van dee Watts at cu ajuloral facloratal gensral de compl Siuiat2. Vado eafeulae se emupand cu datele experimental 16 o-2 anny ¥ 3Jn care Ps pate volun) criti malar, we abine toma ven mai Secvent fl SHUM a eeuejiei Beet belo+ (eegliind dyps renrenjons armen a favs} apr, v= nitty 2 Plats 6 pawl earn) Jolt exe volta alent 1000 posye sy 2 RACE (, 5 48 soca BB fy 4 tt 7 Soe ar aaacaa ae) 40 sn Fa teatime Sete yates tne alr oars AS. Resettele obyinate to arma soda garofick denis tris aint oe present etind me dni tint eee eet iia al trimetilamines la temperaiara de 0 e Rexolvare austin virial de stare pentru gaze reas in Uermen ca pesiue are form PVT BP LEDS ; 1n care A, B, C sink rerpctir primul, al din gia treilencoeficioat vrs fnetie oma de tomporatard [A= 1a presiuni sedzue, ecuatia poate fh redusit n dat termenis PY = 4 + BP care poate fi sorist gi <4 + BP, ia care g onte densitate Areapta,. a aivt panko | coos Siri seen ravi] tabelut 4-4 aint date valor les iat figura 2, ding iin 41492 1-mol reali, re Tinat 44 St obeat din walkie oo atin ed, representing PsP ram [om fos [open] Bette meno Ua Din graic remilté 0h B= — 0.00007 1g to, va lo ame ea ve se gre oh asm ne {Stam vata (ics). tr de wa serio enol, ay eee YR ce ‘euteiches evn at see et 10, Sa se afle pe, as ccnajice 2,300 wy save'varn Her Waals ve oy (ie ooieentoe viral Tempe vied le re primal enfiotent © oars ral ete na eepuratura 0 vo, Ty) Roxelvare ck cana ae ete ser py a na(ts ¥ a ase eat isis Ay B,C oconsttai prin, al oils, a teil. cooicent viral ‘Eeugis van dee Waals (ae t= RT, se poste serie: Valoile eofiienilon visi sink — Bom cm le coeficienjio aot ¢ vanperaa By Le real din condi 5 ser peda, :410, Se dau salorile constanteer sovgiei, Beat ti -Bridgeme entre CO, (anitti: mel, |, atm, K, tabelul 45). Febsind coat Meares Total ¢2 Bridgeman sk xe calcul solemat conpat den, mot Pade Domo) Pe) Gb, a prentnnen do 460 a dete Sa timperotra de 350°C ones | im |ouor [owas [aa-io | Retolvare Fovopiy Beattie. Bri semen, atnoa pet cleus fomta existe pe un damning de petal alts — ea 5 1-8 yy an fm core 4, B gi e sat constants definite prin rene: aaalt }: Ba nl! Se oterrs cf eoustia Beattie-Bridgeman confine pe tt Cnstanin enna nek ete B eonsants Ag a; yb her To toeme at wolomal my poate explicit, find meena" opt meta narerve (vot Cap 1) Un call aproximetiv a6 ponte face dacd In expreite a yi se eye miriam P| pe basa ccuatsi fgnmulai iol. nei ay rap ie Fa rc re maranjeankeouatin tn forma: few a set Oy, ine In paranteza mare se mai face 0 aprosimare de gas ies) pentes nj, abgise inal dupa rosmajure: (Eyes tn enre: A= “(oar} a : In ld mn: A= 5,0; B05; «= 08, (22:53 oo) —opey BE 94 (222-22 + os) om «SA — on "cata lout pentr cael poten ese mal pain acts dec eta lt (nos Bite de eotem 9 = Di 411, 905 mote amesie gas cnfinind 15% Hy sé 25% Nz sint comprimat Se peteda pereeen ‘am Sia compare aceald Tutoare ik ee resulta in eal Pebiat t Ise eee = Tos ee ME ee erates ©) legen Bat Ama gat gf coe. |S tne) aa van der Waals; tema omse | Gums | 1) combinarea constantetsr eco |__| | I aie ven den Waals Sedaw rostontelsecuatei van der Waals din thelut s) Utibitnd ecaayia easata tea, roma UT 0082 ° 29 . 238 ae, 1) S exc peice dn cia van er Waals gh male husk pentru face conrttuont yrestnen parfinla, Apot we doleind ea fet te Dalton premunes tle” Aattals pet oe vom 8 i= 25.305 — 230 molis me, 25-208 ~ 70 moi 00 ‘ 10 Pag 2H .082- 23__mIOVE- OA “932 — 20-0.00001 OR, Pee 2080-024 _ P12 oy, 2 Pa Pu + Pi =32001m, ©) Se procoeest prin aprosimatitsnccriv anf! Ge: aloge ovale entra voleamal pasta! als, %o3 — se ealeulena ou gna bad Am a gat volumul pari a om = 2822 — ae oaloueaai prosianea toll po Bast op, 31 rapootiv ayy ou ewatia Iyendor Waals, Pye) 33 Paes): ‘> eantinui pnd 30 atiogo 2, 2 Py dal 47 st date evade one esta prosinmea total, InTale 2 Decks P= 69a, 1d) Corbina Conga vander Waaleate poncnion peat un med fear fractile more st 0 face allel p Pp = XPdie + Pe = (XT ean + XE, Apoi sp procedeazd ca tn problema “5, Se obfine ? — 225 atm. tru amit dat, de mieten 31 hidrogen: [XP = 95-45,8 + 0,65 128 4 8) = 2950 au 94-1903 + 065 984 + 8) = 9339 K. venE My nears 98, om efor I Donen iar my me 1, 418, 96 aerate pone gus rome xin rele 2 (Bab 8 6 ocd we conser ecaaja de store van der Wale, REE 025 Yaa b= 075- o”apst + 0.25-03015 ~ 0; at dep, ar wt Aplieind aeeste valor in etaia van dee Waals se objine: Rexelyare eee ae jn van dee Waals pontry 1 mol gur ose: Pp t BN — ms. DATE ARTF \r py —ary bo Ae ee ee ee ie ore Gear) vo Ws fle ik punital © (rh-"(Ge)-* Penteu gost van der W ants( 482. Tn oa om volume 1M er? contine wn mot de ameste dogs me #8 hire, im proporte de 23% (procenie Pounatrce) mean se trier aoe Folosind diggrama seeraliset de comuresibiliat, sf se calaleo sion sata tn ons, dard vaorle erie ns. meta set P= 15.8 oe SOG, tor als adepinants Py OB aim #i = S20. Rezolvare Culeutul pormetilor P-T-F ponte un anvstae de gaan eu jatar sramai gencralivae de armpresibltae, ste asemiaitor eu calealul pent {substeufa. pues. Difrenje cone in Tolsin ia Joel. marimilor entra aubstantae puro,» e-aumitelor mérint peendoreidsy nk amestey Setioite pein Ala: posit a ivear ae by) Se willoast relay: ermodinamicd enon) ler) Din covapin van der Waals se objine PVs AT = PbS T rogiind_Yermonal abjV% fm cares Pip, Ty gk Va sat variables de stare psoudoredune Ci aprosimajin PY = #7, 5» objine Pry Toe 3h Fy, sink mavinile panaoevitice cate ge pot exprina ta fun de vonsinatele eritiee ale substanjelor pure asifel: vals ? aE Py EXPL: Tea BAira sunicen ars (pp + a) (aor * Mt wr) eB : Cp 4b GPP. cu PY = AP si negiind trent tn ot feasiil mare sb conattuenyior amesteoua. 4 414, Polsind couse de tare van der Waals si Berthelot, dpa daesteoe ieeiaiales htone. sipibichaihecaberich:touines, a gisninek nianNerolvare 8) Conform. prinepitor £3 11 fie wrmadinonieit suk plait ueitonrea Nome guna puntra oficial dou tert hom sont ee Bae otem consant, entra matan tm conliile = 120°C gP ents penn” haan si = OG dP 1.8 abn, i Ea ee Rerolvare Conform principe T 53 1 ale trmodionmivit gm eeuayeitormodion sie sare 96 poute aot = fe aT) Aer), Din qveast relate, difrenta (Cp — Cy) eo poate eslona dimot din exjorimantale PT! sou cu ajaloral owt eeantit de sare, Ded at ‘gle cou’ van det Wale. pentry a calcula derivate pa saalitc flosind una ain ovpatile de stare ule gizulni veal. Reprezntarea afies a datelor dia taal 48 fn figura 2. pormite 2,25 cm Kt cs pone EY 578-295 — 1130 Te fae Ded it 9288 K- 9% 1) Point cpa van der Waste (p+ S)or—9 =a7, 3 pot erie urmistoarels rela psa LS Eos (er P tae dap par MP problems 4.18), ane 3) + 2-22-00 i Tnloouind Cy ~ Cy = $967 4 22 225-9599 ah mot t= KH s Yore-am-oons °° . Qa, dab Robind ceustie Boe the lot pastra x esknla, derivatele parila AE Bt aiid erent cu presial dn embrldeptYe atoll den = Substituind Sn eounia eos ponteu ti (ERIE, roma 4 bine 8 8 ro 2a an0P. c 2 Cee A(t - 1.989(1 OS So AT tere 16 5S 3a : tr fae = 2497 eal mol 278 Kata e) Sennitenficionalat Jou LeT bom Pons Gane de acumen): santo 200A aoe Lo im evunyile sure pentra yee Jprotee.= aedvaloaren. mumaratorsa wey 9.4. igrul se rioega tn tinpul expansiuai, valour negativa a mumarstoruly fonduce lee ioeilsve @ goaului. Lag. aumitd temperaluet valour Hinsritorelgi este som, Acaath temperniuel bate tempuraura de snare Prin gaovt van der Waals Valorie ealewats on colo doa went do stay slat practic nk 415, Valoorea caeficiatai Toule-Thomson penra an ta tomporatars ds 20° gt presicnn de ala eae de AST, Compare Tare enperimentla gO tu eon otceaa ies din des BT, Zi 6 abel 68 5) foosind souyia van walt ) cletaisenperanra de | Canucn elr molar peretara did exe §1,Nenl-molK- Consanih comtet vende e Wn pinta eannise Mar ises 4 Itc pca gt gh tee GTA ope 2710 K ‘Ro ~ 0,082. 0.9873Voloaren eosficientalui Jowle-T ho mso x ealbulats eu sjutorul cow finan dee Waals concordat fore putin co valoues olhinta ox Tinton Aces fapt ev Ustangte Inptalai'ctecouaia van der Wal Ii presan ideale r-di esata aatietettonre. L1G, Sa obgind expen ergot imarne U(T,¥ Yanni mo dg vmiagh coafie de sare Batti Bridgeman, EE fpeins mit PO) Gr Pa ezrin prin aie pl C= Gy t Oud a stare te refering eink U = 0, we alge Uda 2) ‘Gate ea Voth i Rezolvare olovind eesti tomodinamit awa cnars(1(Z) - +) av, ath ‘es obj prin integere, del staron do roforing la stares 7, ¥ (le (ccar el [re] — 2] nr.Y) te rT ~ To) + rs TH +07 TH +Cl(r) 7)" Fouatin do star Boa ttieliridgemon se srl ta toma yirls Ty , HA) pp p27 AD sh tar es tune ah Vive t ve rin f{) tiadae devivatele funetiDor f(T). iar 1) (25) -3 A Ae, crran ners + nae 140+ RIT) — ATH. nee 1 —ypatrecr— 14 ar=—4ea51n—1¢m0= ‘ (TPT) — 62D. Dur eeativien}ih vial stat (Sex! proms 4.3) te HAT) = BBE TE ys ALT) tunel derivatele corespunnitaare slot ft — na, 28 pry aie 1 an = 288 Nolaile cane apar tn integrals devin: AN) — THT) T= 1450) fy — 1412) In ioal s» biae dupi afectuarea tuturor ‘lecular: oe PT) hy Enh 7) 4 1144 RY ¥ (4) a ("4 Pe bn ceil de dfn 0 fusciic F:6 = GT) RT nf Vibe MELIGT ge cattle finda: and PY > PH p= Et cat pot onl gan, bw hand © Rig r 1 Re P lide cate pena vet Ean de defnijie so poate seis Informa: HT Scisind in ainbii mambsi expresia RT (In P/8 Pe Bee a a toear Dar fl a P Antegrnd de Ia P= 0 no prsiune 2 oarecare: art Aine Vi ’ Fle su, eel Gara) cso cep cas Bos cs Slupone de seuatl de stave de forma F = V(T, Ps Vey (P) a tempsratrs cotant i tinea nti pe call Se ata p= rv inpia{ 2100) a V5: conigite tia: em, Dy orn gi) mF nl ey eum m7( R27 Be ore PR) ar "are Cwsigur-£= (vet problems 417), dar unit sutrt prefer fommuern eo mai a, ‘Tiebaie mentions eevia de mai us rel ifn unm ye (vari de varied 4 mk scot ela ea Integenla din expres do la problana 4.17. octnati n exiretiaxplimantar. Limite emiateé objimte slot deternionte romai de cae se ev ust de ai Ane iajide Beattie Heldgestan sav Haditeh wong. servest la calculi! fogeetajit in fast da ‘yepori ne count BenediotcWebb:Hubin apbeabis ait Hehidoka ct qt vapecion Foue'th uae petea ealcabalfagaitilr In fam ie repel hn cok chide eer, as ne te llanbie ind i date experimental 4.19, Uuilistud eeuayia dedast fs prodlinn 418, 94 a objind expresia Pepa tn cactd owas de stare ven dew Waa Len frm Ar a ey bat ee Poovey fad i oe Rezolvare Rezolvare Fete vorba do fapt de o echimbury de variahila. Hearanjind relia de def up toler in eeuatia obpineté in probloms 4.18, rez tigi be oY 4 : toe LY RE Ge eet ae = (Galtaancan en aml} ‘sau in toma (27) aa. Conidertnd rolayn: 420, si se cleles fugacitea wa gos 25°C, fe preside 2,10, 15 : nell She Se aera Sopra se Roxolvare Min dao, a tompentrt comnantk: 7 nf— VAP ex condi i eteind saomou en mena olginer: ‘ee P Ivbeuind Vala euatia de sore: AP anf = Az — ops LP, ft Pal 2 (2e mAh (A) at lorlae ar) Nee seat gob n> 7 a arnt Jeet PRIRT = obsicem: Gr La ((ME rhaval oft pe cing = ain P— o9nseaP; din f= — oss ap, Pentru a obfine valorea fogasitalii a 0 prsivae Ps integreask i aed - onia[’ an,t byinnduaes tn Pp P= 0002 P. 'S objin tn uraus calowlelor datele din tabelul 4.8 tex fig 1 ar Gt pete Sen, find Sielsrihelodd SS sompane ren enh roe consortia Colas kas ah nin uo Ca ret ae Terateess Post ela w obey wlth ab In yates 41% aaa we-((Gr-a ind VAT din exp Ber hoo (. proloms 4.7) «Ot au Sbouind datete: Ip Devi 9 = 0785, iar fe ‘loan Ini ae poate determina ai eu ajatorul digas general Cinictnpilor de fugectace. Dentew seaesie es ealeuleaa pareetr Pewsey ea = Pa B= nt Ba 1, entry car din diagramé reaaltt et ¢ = 078 (Amera TY), Deci f 078-50 = 39am, Cole ond renaltate aint fourte aproplate. 422, La comprimarce isotem reversibi a wnat mat de Nyy te set abjinat pene facra de compra, tn func de prestunt, Slot tebe 0 7 wo | sn | 10 SB ae arose marine enn Si, witind pentru cofcientul de Pugcitate (=) si facoral de compres siaue"(2) dsuendente de presane, VF ee consanté ponte inet de Reneleare I conditit reversible, la trapsreturh constant, variafin de entalpie Fier ete gaa on Iueral ds comprosione! MGy— Considerind defiifin fagsvtai AG, = Ramp sw objine dupa ntegeare tutre dou Hite de presuns san doomeece te Abpea = RT inf Tncmduetnd costicfontal do fugnetate 9) L —inP Vand ante nla Ain tabelal 41 fe faguttace Seecese.Confores peobleniek 4.17, exist colagia | i Represent grafic ¢ ln tunel de P > objine « dneaptt (ig. 4.4). Bown sora deepte ate Wea ms-109 P, eave este dependent camuth pontea 9. Din panta aevate dropte nena z= = 29mnr(QE2) — — 2ana- a9. 298-27,8- 10-8 oP ‘ = 15 Ben mat deci o yaloure constants, Pontra gisin dependonfet Z= 2.2) oe ul saz laa: RY 2) aw Z Ar 2 mw Za 1 8 2 ey Indocuind s» obiny dependent Tink’ 2 = 1 6 10-4 P, beat Data sao feat ta 4.28, J abet 412. ote pre tm tude elemental amu a parka molar al bilegsnetat aneta : resin fa fompesaiura de °C, pe x faa de Heed Xin ie sulle fugartate Par fe hebrsennta tn anostent tt tn Lass ras Fearn de °C gt pcan de 400 a ‘nate Se eunase vanstaiee elie ole gem TS een, le PC, Rerolvare 4) eno im armas gues dt mak malt componente) v1 posted Sopnctaton parle po*bata rasiiors © mPOMA (1 se P i. ai ‘oucondiile limit: P+ 0,f,— Py sh = ® ‘on pasta, i 9, cosfisintal de fugacitate el camponontntui i din amoung (PNP Gi a FINE olsind'o Cale similar vest din problema 4.17, se obtino oxpresin ds cole gle ot ge (ar 3) Detnin o fanetn 3 porn a caranteran devin dea comportaven Meu: aay —P= 2 p, ? 201m cure Py one presi. in dere davis Pentra. a caleula integala, se Joterming valoern a lin seuafia de Aefinitie gs» repaint grafic 4, —=/(P). Ia tabelal 4.13 slat date valor bjuaule, iar tn figurn 45 dingrame! 3 712). Pria integra peice “bling alouwea —7 000 en-mol-* tinue limite de piesiane (460) ‘dupl eXteapolares eurbel experimentaly la P 0). su et: fy —5280 20m Secon a) & [eel] ee Pee 8).0 atts meted de cic const jobsiresroguit Le WissRan da Log f ws Randall cu sit asses compos star punt ampere Dar (2 Pefy tn tare of acto cotisientnl de fogucitate 1 compogentalat ur fe tonpetature 5 Presones sisemell, = Mnct: r= Bethy Chofshntal de fuguciate }composentalai pur (2) sm poate davenaiya Dy ujutoral ditgrametoncrnting ects nvell par (97) v0 poate determina,Bak: |v care HT, este entapia partial moburéi ia amesteval real, iar HB in cal ileal Poniry neat goealuload paremetsi edust Tou ajutoral est "AUTO! Decrees Ht" 1h fata molar sanponatee pa ete Cycles ferse ae pone Ee eal Ne LE RU AL Tl eg PS era GH). ar? ee aaa 0 159 cis P= =O a a02; 7, pone a+8 ‘PROBLEME PROPUSE Din iagemns, se sere, a fay Rat 18,0 = Jae? al, het mtt pi et a ia wie a a ALBA, Viitsind relatin de aufinivio o Pagastayt partite: f= WD) + RT Inf condita ind P+ 0, fem» Bok se sabi relia, eon penton feguctt de tempera Ya prasane fu compotie conan 1. Sian oleae presiunea exoreitah de 1 yo! de apa tt star de vapor, Intesin vol dy 10, 139°G fobxinds i 4) eyuotin de lane «uni eee eal” 8) ecagiia van der Waals, Saat ntl § =e GON Tc 3 Si oe caleulan pmiunes necesar, sf se omprime 2.86 m? de ammoniae laguna da Gm emperor 0 aun wl 17285 a6 tempmraturt de SD eat 00878 mol 4. Sia calouhre comarca vain der Waals pentma CO ye bata ‘alot misilarenflees T= 109 I Pete me 4-56 eal volumal molt ee molanatuai la 300°C 4i P= 290 atm ‘unoselad velo mivimilar entice! 42406 gr Py = 487 win % Canin ta oan dn no To les ena! mole rie $3 mporaara' Hoy 10 pentru Cally comcierind cena de uae ner Waale* se celewlne vulunal molar al Ne la P= 400 atm gi = (°C pe baa ‘ound gueal ulead gf a teuaied Vann ‘ew’ Wa 47. St se galoulizo densitaten aerulst entra eu vapor de’ op8 In 26°, tn soln’, Presined do vapor) Ie acenatd temporttu exe 23? mm He, Gompoagin eral unt Tire hisil de atbon ene $82 Ny Sg 31 00% Ae [proce do oun). aslo de compile, Z pontra bes de earbon le (°C 4i 100 atm esto 02007. St se ealeiete'volumul eeupat dy Gi inh decade Jb. 100 atm gh 0 ‘1) pent un ded; 6) folosind tactral de eompresibiate 9. Pectoral ds onmpresiiate, Z, ponte Ny ln 50°C 4 900 etm exe 15, ar In 400° 91 200 aim eato 0, Dac © wanthate meters de cup wn wala de 11 la 3° Gt 800 aims sare emee de Ne ups e eoeaytenntitate de att le 100°C 20) nt, 0. Cunoscnd pm on cated van der Waals: V-— 2h, Pp (RTs si'T. — Baf2Tbl, same calnloentactoral de evmnpreintats 1a punctal eri I}. S8 se determine covficintal Joule-Tomson pentru un gue a Rerolvare Uiiitndevlagin do dsfinitie in oem: 7) staf $i aplicind-o i In conf Py +0 reouli Fig wf NT) np, ToT in gare a eso valonren potenjialuhul chine 40 coniiiletimita, 2 ote envatan Dero pani cele dd ai couporife consanil x scree oie toe da thea ln Pi com ‘a, ane), gs tn caro Y; reprint tril ole le componesir ane Bin exb dou rll gh deonrooe (2 ln Pye Dye, 0, twa occa, (0), (0) Aplictnd relay Gi bbs-H elm ho Ltx ce objine 4 - mA AV B= Rr. H2. Si se caleulere fugucitaten metanului te 0° 91 200 tm cunosetnd vee love mavimior vice Zp 1003 st Py "5.8 atm, BT de, RTE : iT18, S¥ a0 sabiemcd o couse do cael penten coniisntal de fuze tn fanote de factor compress 2a Ft, ar Si se caletes, ind arse sono fayacta szatal le — In presi dp 1091 0 clam, dack so cuneve In moeata tensor 9, [aim (22) ar, (e676) an Pies ariel ans gb le rn #4 ocala cit, Sim aes tye ne tae fila pon fi a seaeezme a eS YntruCOvte 10°C 20 am bnen eager erences Dass eae rier Se hut ah Nanded "Ee oneomed ocean coceie Waren handing? 40, Sho objskmitin d pened enue pes pine un he Melis ee, my 21. Cunoseind expreia eapetiiteaborice Cy pentru CO Tn presinnen de Fateh eaiemort eo Oe : Cy= 876 40,608. 10°7 4 0413-10-47, [78 — 2.000 K), 1 4o ealeleae eapuitatncabried molar 4 CO ln 100% fe 80 atm, presupunind « vomortare 8 gu Helot Gomuawl sitive ale GO slats f Sk ML. Pentru un gaz eal a etabiit ccunfia do staro PV = RT +P, in eam Beste 0 conranth. Si sa stabilised 4) expres de caloul a fogeitiis BJ expresia do calcula voici be fing 16, To, intervalul do tumpernturi 30—00°C THe rman ecuatin dy BY = RT-+ BP, B find practic conitunt. # — 0419 I-mol ‘SK ae calelete valoils fugieitt, eotiientulot de tumncitate gi Clnintel Tonle Phoweon We P= 1 aun git= oC 16, La tompertana de °C oxigenal vemenntecuata de star» PVP OTT 104 Pe 1s. 10 Ps penta preioni cup {1000 ate, $8 se calealote fugacitatea i cafiiental def Sog'atm, Notatile PyV, te relent lq candle noe Hath i procionsa eonfarm ecw he r= i ORC g Pros 349 atm, ‘alealeze, fugoitaton CO Us 507C 95 100 atm a) prsiyaind wo ronortare a aul eonfom cugpet vay der 2) fokxind‘iogramn generalizatk couficiontulai de fogastate. Fle aneasie T 1 = 2%. In tabelal ve urmearé este dat comporigis una amestee do gem 53 centtantee Gite. SH we nleukns fagurtaten cdr camposent anes npr tla de atm emnjertn de 0 ilosind rogue Lewinlandai] sy diagrams, Genmralestt ace centults"defogacitate ferexa ty), ems ‘at ‘iiate le P adm i 0° 17. $8 90 demonstote o dependenta fugacitiji de tempernars, Ie pre Sonsanta, pentru un fluid pur eee dtl de roast BEY cancer ath” aT inde 21 este proprintaten de gaz idea! Ia acenast gi P. SE se calealede faguititen Nib, 225°C 31 P= 100 atm, cunt ‘alone Fingal Je acreag prestune si 200°G, 7 — 82,2 atm, Secon plieabit routia de siwe Ber tho lot, Datals esti sn jaw din anoxa 18, $i co arate of devingile propriatafile termodinamice ale wei aid Ale Yaorilecoroepuntiad taut gor iden, sint date expel wom G LER (ene = nr af |r —a(2) Jar, ae Si calbalem Tugaciiaton iaobutanuhif le 37245 K ql prosiunen do 40, %5, 0 atin, coscind ‘wrmétoarele dato exforimentae: Tae aeunas crate ou 8 eh. Se cunose aomibarele date: mesa clomid ee egal 2 UBL gomol, dena mcd so iO plata a a Ale, = 2 MO cal wot, la 7, = 1 88K, Ming = 1 880 051° mor, Ia Ty = 996 K, Rezolvare 5 ECHILIBRE DE FAZE IN SISTEME CU UN SINGUR COMPONENT. + folompte ria C1ausi0%C)ap ey roa In forma apeosimat efi Mln( 11) Bo RAT, Rents Ty = 1104 95 AT — 06 K, Volumil i mol de Cl rind dpentenys teppei, presi Iii sett ae: Toes "Pe basa atten relate soe cateléseealtaa de pire ashe ta 12, a il este egal eu 112. . SEE 13 om" mob! = 018 1-mor Nezolvare ap_ an, cron: Pe Votanaul unui m6l de Ga ich ste egal cn ar 1241 22 Conform eewapei Clow siv eClap ou Tobait 31g 2007 = 1405 em mat fete i Munei din rlaia AP Atta, ar” Tar, (ERO pemre un tic onogen sav deeming temioarcle resins de an 00K. is aK. ‘drive temperate eee 9) fncia Wy P= f(T): b) previanee de enpori ta PC ©) elidare de vaperizars; 1) punetit de Frbre normal a tichiutut. Hoya APU esata ea ‘fetinfgwea 94m cary sete ee ‘Rout gai cube P= My Ponte caret ote Rorolvare Din dhatole_prezentate In tabelal A. prin interpolre. a ob Lee Ae TH cm kg’ Tnlocbind in eeuaya Clans] Gispeytoat 9) Reprsentnd dese de wai sas imiro aiagrama ig P—~4 to obtine o nee pirodvind dou preci de ate os eing sens? OT Allg 00518, yyy, on 08 bear BC i0)-40° hrm apa a ee edt eo _ mgt {It Age see 268 = A226. 10 cane rezallls A B04 5} B se cae ce it ergs eaparatra i Perey cad 2370, @ so calcutess cu elt cregic (oie aruraide sotiaificarc daceSa ve catedes: a} pune pa; 3) <@itera molurd de sdlimare gi flare “Relogn ebtatd ene: Ig P= 86 — ‘nota ds tore iC, Resolvare 73K (°C) ete: 0,608: Pag = 0285 mm 14) Presianea de sopori ta 1) Tas pune rind ede tat fas eosin ecb, ine presignen de ‘vapor a'Mahidu gt soldala ete cess. Se poste acre dec oan 12000 ig Peg = 80 — cay se) Citdora de eaporiire s¢ cleat consiaerind rela Og? Meg, teh 2970, an aamer ar 50 cal: mol Sebati a B= TD a Dac Ty = 1 206390 ig P= 5000 — 128 Pe ORT sna mane is ay Di a deter aes 1) Gonfrm ccuayicd Clausiue-Glapeyron “Wee Ags dle 10 GF aguas "ar" Fae ox datrminas experimantal urmdivarcle date priv coil sishieeapors pentr if: Pets SME ae ear hg = Tel santnd salar cant de apo 1 4°, Png = 77 a cen nie mms are formeash On ware 0 Cals deat Se Rozolvare Ueiisind ccmjie inegata Clawaiue-Clapeyron (pentru ceonstant) Siecaidura de soporizre a apet eae 10,7 koa to de °C x 103 kesl- mola SMC, Consulrand ed tx» dependent liiard tir cithary de uporiare gt semperatya also, tse eheoed dopendenie pestande de ‘cporé de omperanord. La °C presinnen de eapors we ape ete $8 ra Hg Resolyara ‘Gildora de voporinsry fina dependent lines de temperatura absolut se pote erie! Sip — ATE 2 Cole dou constante; 4B, se pot determina din sisteaal de weuthi 1070244 B 10300 = 32h A 4 Bt Aaagi no nse Doci: AMyy = BT 12884 (oat mol Avoasti funele so iatreduso Su ralifia Claneiwa-Clapey ron: ln Mle, din Siler, oP 1 (ar + 100g af ar! at RP i iin: Sty = 609 ea-mah Bias ak tune: {in stare de vapori olen de sult eoresande formulsi: Sy enews one es ta entry ohinerex fwortst P— PUT) oe ialagressd aooaatt reli. intro Fimivle Poy $i P 4h respect 273 iT. rc . Pca Hg) = 6897 A ‘ of s J Pom He) reas mp2) St 28 gy 1s he ds 4g Po Ue) = 998048) $4 se siobieusct eouatia depomenfet eildurié de vaparizare de tmpe- a i nest oi Dp ftegrure yi tsoeren Ia ogsritn speimali rez 2) St se cleus calor de ooporinre a boncits ta tmperetire normale on 4: Rerkee (S040°0, gp = m8 — 401g 2%, (pm mn Her a Rezolvare si cateess presianon de vapor a ape’ ta O%G pe basa print ts label 32. 4) Transformind ceutia deté t forma difvenputd, we obfne: MF BOR yay 04m, sree EG Lanett & Prighespeigeh os eee Ca dine Ih ye 5 Ho | ws | acme | ssa Bent ABs | 88 aioli Svar trae ez dependent de tapscebok w cMurt de veporzay tne formn= Migcerehter . aie ek te Rerolvare HO) = H.00) Seek. a ieee Dec AM D) Le panent!marmat de ferbre: Moog 15 bia — 402 T+ 0675 T= re entra ealomal ui ACH 20 flisoyte whi NG} = AM — TAS, ow fold evirimilo steno: AG} = Alta + & acuar (ase ee a 7A bead mot 5M.) Prosiunes de pert o Ve ose de 497;2 mm Thy to DPC. de 05,6 tam ig la SIO. Sa se caewise eAlurh de vaporize, “onsierid Seharee meee onaentd nnd val de tapratrd cntidaran Ci ‘roars abulard si rated edb de vaportare acd pretend Ponlen ocilbeul de mai aus roaul: Alle = (Alain — (AMa)08 — W252 eal- mot ASta = (Sbaluou — (Sen4 = 2839 nl mod * AP = i0dmm tig ar 402K. Reralvare Viiiind rileie ClaweineClayesron intogrti punta Ath cy = 7487 4 237-109 T— 18016 = —10 809 4 27-1097 “Boe ibe nloeuiaa se oboe pantra 40% an a : Presuoea de aoe Feauld Mag pete AB 14260 eal- mal 4,48 mm Hg outro ealovha erent difrentnas relat oo mai soe) dunt ele pate urbe Py Pay Ty 8h Te ‘Valouren experimental rete 558mm a, i fe sar tear, tam ae SsW@Presane de capo a benceull et at co faci de mp 7 pe coment 10. join cea: (soe Noe, amar 20m T+ Asa Pe Jn Pam = — SN 16Diferonfialele se tnlocuinse prin diferenja si deoareve AT, —AT,= LAT sf AP) = AP. SAP 3 ponte sore 578 Ig ars i P. xe) ‘say dupé tnlonini: (Alyy) = E812eal- mol. I nll 5 leprae pl ale peta depo a sein epee edd tarnd mln or mat mic pe Phe ie ical CatlingactcDevis, penn mts lee. Rexolvare Conforms metodeicelor mai miei patente, pentra a ecuaye db forma yas tb Won cap. 10) gp EadnoBerey, ¥ waa lb Sat Cleans ae: eta rermat te fete Gat v5, ar Presta de too “ges arb 1G, - Piet normal. de fibre aupenuna ete BG be faikalce tae tonpdratod ties far penta fe pre Sinmea e100 mi Tg re ‘nea de eaport a actus a0. Rezolyare li RameayYoung, sapertal tenpersturior thal de i autare, In enon pana, ale onsen Conform a fiers a Ron {n car Tyr Ty int pete de frinrorospeoty ale unel substan oar ue a fabs dotlesinp no presione dat oe 7 7k —punele le irbere le sclragicubtanie ln ¢ pregae orbithant 2 : a Pont cislipenan 9 peotea se-poste serie: Ecresin | P, mio Be 28s" = — Ae, a+ 453 ~ aaa’ 7 Interstar de spac tate este dati valberea 1 — 12,66. 7324004 22 ‘Similar 25K c net 1 Task g= ee eee, Un tabekle co exprima depene samene | ets ger | pence | dente wmunil de vapor a roi.) oi tia | cielopentana do tener Valorie caleulte pentru x ain nt prerentate tn tabelal 5.4, 12,5000; Sryy, — OT ADOT AO, Ea MSE 108; (ay Ex = Mggang7281 10-5 n= 8 Beunfin Gallingeort-Davis pontry metal ore forma 670 20 esi,or sett 10%; P= 79000 iin luni se sicegle eh he t == O60, P= 10mm Hi cate abuts’ wie acoso presiunea da vapori a penta- lui 50°C, Literature proszta velgarea P— 9,9 mii Hg peotra pintaa, Ba 8 con rigs dagrama Co x-0 thm ar pe doménl d pe He punta hevan, Yeptan, benzon flier, eve spe abn de rerun pi fos dale dim lad 3.3 137Rerolyare fee eri iclcy one ales a acct mee a ins de min pre! enero, ne Poste sae tle P Alls, tig A Poin wtp ion ig» = Mlle ge anil iy P My 29 reprints i dep, eX conn ew rap im ravine eu temponstura: Aces presapanere esto satificu fe mjistan eluuayr ou esiep\n dctenisld yon pei stanyel Qe ectevinyt one): ea ci ee ee Gad Sates Prin unin" dah pects cu Ett. penta teeane means Hf ul8 es ‘cnt pits Bu Sd pe stable «reli de cae 0 fated acniis (nara de Pitzer gi Gurl) pe ba datebr otic (P, 7.) #0 a conan feuajet oi" oime penlow prisianca de vapor” Si ae cause et Inbnlan sind cd ToS Ky Py 2,8 atm, sap cones cea Antoine 4 = 6h, Bm i538, ¢— 240, Revolyare Prin defiikn factor) acentrie @ eve dat de exprosin: aes on. iy care (PL Jran topresintpresines de vapors sedush ls 7 Beuayia tu Anitwine poninn prosiun de vapoe eate MP4 ier (40 °C. Hovalia slid po sate uaa pot te aT a8, Pagneae cs te tncoe Ptsbuexprina nn Hg. Pesta hate wobjine dup lloui eee 5 i 4214, Dlageama presitnetempraiod per carn ote dad t figura 338 1 an Or a a dct ee: 4) Ge presume ete essa peer informa grail i» diamant In a), a formes af 4) La 0 vmperatird $6. presiune de fe ei mat ‘mare: gofitad a diamaneat? 7 Dat deat te eth a 8 tenporatard 98 resins sraftal $6 ‘arlonsl mpit ox accoes dense!" #800 Pe Rerolvace a) Pe coda do obits diamante ‘aft, ta emperaiom de 2 00 hie pretinen retard transfor ‘mara: P— 8) klabar 3) Pe cub de cairn amare ‘profits 40, 46 dar eG = Var—sar, Deeis ¥,4P — 5,4 000 ee a) Abies range ate eo hh ee ‘ar Panta evrbes, 97, cate positivd in diagen oor ae Deonmeee (Sy — Sj) <0, ronultd (Fa Vy) <0 at gu > a Faz eu densitatea tea’ mai mire este ddemantal

Sp he dust 9) AT 0; Ta Va>95 Va> Ye entra finele 2 yi 8 in mor! areménstor se deduce et Sethi Veo Py ta entry taste 3.911 Sy > 9) 1 Fa> Me Phin corelata relate ohtinate aaa Af Pwr o entation in do fore sity Osi coi si cu mapori, ea dermingt panels triple prosenaae im wbslal D6, Eeitoet net sat SE se masce diagrona de fa ao | 6 malt | Ee yormd ar dena on on ar ta epronimcie 100°C 4100 Rezolvare Diagrams co we obfine este prezentatt in figura 55. Deen fretioniie tension coratndfevoraeaek fore enim, Deel Fata uc ne pote Sabil presi mal Wi gee deat 1 wo daea fils tingl do. echiliba ee seg | chil SS tga ea posi Sorbet i ST. Studied opel te pres ints at a peel ei ” Romie pce pk | SRE eginc, ae Z ‘leata tA ghee UE stn! tn ech Brot ae. Ghaata eee nad dts sheaf TT, cre ste tenst dat ap Bebidas ett a) Sit se trast oproximanis désgrama de fasi provinne-teniperatirt pe do ‘menial —00"—0°G gt 0-3 D0 att, mand fitcare sre sare ean Pic cite 9 ot rl ae adel he la Dentne diagrams. 5) mova stir: shed Li gheald 1, geal 1 head 11, ghana 1 fl Magi TH sae stab care forma procs realbie rida mat! mare Rexolvare 4) Foloind dail din probomd va obi ingame dn igure 58, 35) Ray ee frit fe re Fares rai te pretense Sra ara entapie mole on tise, Del Hy > Hy My > Hyp Hay > Bae SAS, Demiie ormdarice ale si kn It ae Son ate th fw db tempat imitate Tenpercir tet widens te arbon se 10°C. St fe darmine columal crt a ea iia pr ota mora graf. (ini rr te fen oescatde madsra te Saye ser Rezolvare 4) Conform Wait Gailleter gi Machine f= ee tan in cores o, esta media avitenetios {tensa estar 2etare a tem eraturn ty gq, cantante, Foti date expesineotalo av fia pt ect, Adualndprinle pata ‘ecuatii gi urmatourele:patea, se objine un sistem de doud eouatii eaa8 determin’ « si go. S» objin fs = Osi — Ont, a tamperatara ested: p58 — OpON6G5- 31,0 = OBE gem VauimeRersic nl inaidul cation ee ek uw Me a ent mot ig ciate ; 2) In figure 5.7 ete repose bm Santen inte test ea Sa ‘tua (ahi i temper : Panelele ev ropreningh nei - cineticg 4 densa ela det a fae sat uae print inie pres ‘| aid, ne care as poate oii nae oi Ghmsitdtn Ya Semporaura et a = 1.085 ¥, = fo = 04055 Te = ote = 946m? mol ae ease tae et sit eee post wen eee Wed ‘iat afte reel ewes sad Gt ut se ek ‘ec h me i n gre Me e BEM ost PROBLEME PROPUSE /SK ae volevlere variayia (4PHIT) pentru op In temperatura de 4 ‘Gudurs de vaporiziy ape ests egal cu Si97 eal volute ol lubes cide note A808 em? mak gh vokinsl snolor al. spore BOND anor Ie ADC gh at Prsionen capoior, satura de eter ete Ia O° ete 185 0m Te ag {lira biota med de Sapte intr 0 9h 5°C eae 22 cal ge Si'mentevon preiuaeavapiriarsturft do ela temperate de 26° 3. La tamperntur: do 125°C axottal do amoniw aid sferé 0 trunfee Dre alsirop i prsiuen eT atm, sri temperature de Ice Aitca I presunen do 1000 atin. Varsha do votum co Insole formarea ate eas cu 010126 en? > qt Aa ro eleuhon fom. mol fhe ennatormare Tata 49° A, Preiunen do ve ae a ee ‘aan | maa | tah aie | ie | iz: | a, | a 8) catty eleré dl sublimare ¢)entalpn mols ‘te tani, 5. Prosumer vaporilor vaturafi de 22 te P (on Hy) = - aa 1470t Ie 4 s0 glomus 9 relokn do depundenpa w cBkdeit Stang, ld af Hichide 1 dente ante 28 Se aca fa) wunetal tipi: de topite a bom atamol este dat de ceuati 59,48, Iatente de vaporinge fle temperatura, Se caleuoap ealdura de vaporzare le IC. 6 Pogortaien epei ty sary lobids la 25°C alin tent fugactatna br 370 7. Ls temperatuza do 0°, eer Intent db opine etre tenia’ de vaperiuna 4 ape 96% sme de mm lemperaturk si sso compare cele ous Yala obliy 0 O01 gern, Cunedenind Paporeare gala eu 1480 alr mol-h sd yr etoeloe het onte 8D ox got tease oo era ft a 2) aa a ae Gai eee ee ea ene ‘dev ita nceont 8. In wecinitaten punetulai ipa 223, 0 substan ¢u iri modifica aloleope J, 2 sd peeinta SPSS STS a Ve SS traseze diagram ds ster presiane-tomperat trip. tn ja pune ‘9, Sf ae arte po baza sumault pants, o& inte diagram presione-tempo Sataed penta um sistem eu am component exe Posiil ale curbeloe de chili m dows faze tf 10. O snbstanl& axist8 tn stare do vapor, P, im tame lilt 191 ca" ot moditcahysteope * 13 4, Std ed ‘ntl prorat te ese ple arian ure S80 72Y 2a, T-P, at se completety tn tal Tole diagrams, fo tad Both moe 44, Tempera north do ferbory a aleolaol shite en 7830. Folornd rate Remaey Voounlg. sh se caloem temporatara Jo ft date frst 20 ci ig dre Soe mines de fer ape Ie 300 vam Hy ote are. A rt Opt entent orl plat aly ay caw12, Entropio polar standurd « metilciclopentannoi Hehid esta 5925 emo K-! Ginosetnd dependent de-tampartini n resus vor ‘ubotanjsi Hehile in interval 213-308 4186.00 » es # Toa st talovate ontronin mola stand » metileelopentana go Zens Rin Gino nemo 4a) comport de ge eal; 5) semortare de ee eal Contrm collet Beet he 10% Parametit critic sinks 2— S08 Ky Py Sak alin ‘Sim ealeulene enizoia mola standard « ortoslentai eatia ae sre Boyt hele i Se oun: eatapin ml Srosilnslat Weta 68,8 eal “mob, procanee Yayo ioneare 6 FECHILIBRE DE FAZE IN SISTEME CU MAI MULTI COMPONENFL ACTIVITATE TERMODINAMICK 18. G6, Pepi 9 eolaie rata Binard, poionfatbs chine ae slo doi compo= nent st fant de i vrai ig = wT, P,_XS) 4 ta tT, Py Sales wabllnsit cows earblor‘ehidrdnd ‘saps dr tn colton tih ‘por’ muitos oat tm antels fase, Sinan soe ebina cape soi ‘duns yi tichedudes tm echitibre wolidlichidl cu méocibiltate totale tr ets dowd fn. 6 80 bog 74 34,7774 si panei critic: T= 6121 Ky P= 36 atm. Rexolvare Ditereniel neon | ae, 2) are Sn ae of | ae “Ns Consider expresila pontra derivate partials gi euatis potenistlui entra conipenenfi stemulu ral, = HUT RT ag ef cui Anan pRétasy 1 ary map + Raina Bary 2 map + idk de coil Ia 7 yi Peonstante In ister bifarielchid-vaporicn 2 emponent eat: Mot 9 eo, sn pentru delesie po curbete de chibi «(2 of) (aAoloevind expresite diterentinlelor remit — ars Maps nang —— Bar ap nant, r 7 HY ary M8 gps ramet -— a7 + ap + rained ars Mays name ——ars Bans wana sav dopa rouranjre: A Ys ap obi AM _ (Atlas gp AV ay Mae \ pede (atta gp 2% AP Prin. ingens (eu limite soeritonee ls componental ur ai la ome se bine nthe aa = ee Vea gp ey T sre Ys (7 (AH coh P (AM ophy ty EE (Fond arf? Aa ap Path ae NaF Hatilaeurbelor Hehidelai si valorilor sn obtin la P= constant en 1 ‘onsant, Tn pra vx lage ma wus sil Aaa Oth ary ig BTR ler at sr ce ‘Tomporatorite 72 i TE sint punetale 05 tirbore ale componentior naive pot cbyins nua evespuneoare urbele ssi data inkios $5) 28 fll gp axe hy 8 4 tn care TY pi TY lat temperature de topine ale componentior pur. fle toll sint ccuahile Sehroider-van Laan Ponty sa ene sol ti (Ailey an dy ar GB) Preinwe a yopor 9 detent Ne SE ete 2848 mm He Prin sue i dr ise and der pra wiper a cat ard cu 8% min ie. Sm Cieals nose mar suckstanjet dizatoade, . Negolvare Conlon i foi Re ole a ee m con Exprimtnd mumaral do mali pria n= Jaf se bine ou MAP = ml PR— AP Bp Ba. fear Buta, Rémuls My = 127 g > mort Ponien idemificarea anci swdsante mcummeceis 1 sfocuato analica 9 Sementiar. iar ttn cbultomenre sx dtermiaat rtoree puncte de frtere'w staiet ot tn teratorira de carom. Folsind dati in tahela? GA S98 determine masa nord sbentt $8 forthe chad na | eam | exc | om | une | aero | sane na | exe | ; 0 | amo | amex fons | wim [eae [ase | oa oe | un | 3 Conta do taractarard de carton foestd eas de O88 g, sar contanta hahiospien jena tevacorara deri, 8. ‘Recall analse elemento ei: 10,39) ( 41 B87 Ch ezolvare ouotn generala pentru eehlibee lich vapor di problema 6.1 o¢ transom’ considerind somportam foal‘ fan lich se 1 i component (1) par in faan de vapor (of — of Y, z Atunei a abjine: : oa Soh ar Fotigrind pent (Aap) consiPPonteu solu fowete iluate v0 objine eenatix (deoweven In (tl — XQ) — pentru Xe ts (lag AT. RN APY é (Altes 2 TOO AMD, In care AT, reprint rican pnetull do fierhore a sali ‘Dn ecix ebulincrpios hata dint yoralt 000 A Reraltatalecaoullor eneespanaitoare ditelar din tabelul 0.1 My = 288; 24; 242; 240; 29591 200 mol. Bonn}in olositd ete apbieabilf slutilor dante, Valoaroa mali 9 My se pits afla prin nxtrapolamon Ik tora cue Ma = ea) (ig. Seiten diy — 257 ml Tn nnst can numa do atom de Cl esto: an- x. ints i mapeetiv do atomi de C: | ee 1098 ype 0-2 Fig O4. inte dooi vorba de CyCly, bexaclovetan, A, fn tote 02 este dad corsa panctotas de inchare al anei so eae aato im bnion,fenstie de encanta sla, 8 8 deeming ie asoier ol aridala ests in bona, daa salouroncanstaniv criaspice Aencentes ese 54 K kg -mo! Resalynre (Cu relaia simiby’ tok ebtinute pentru ebulioscopie {problema 63): 10008, : Odea = Ke re detormind man moan experinenlal (jae a nc aestie la enue, ‘naa mokek taortied, (Af, Hind cunoscui (ida rin roproentaros grtied a rportula i tinaidemelltate se «tine 0 conb specific pont eubstonilo Satie ig 2). Maan lard ‘apernontaisemple mpl i lsepa et tragtaron MOGLIRT: deter poe ‘ice emcee sree: Utsaal 9 porioe «cobs apmabe tne into asa nek sprint rae re lo rome Head pete oad fe neeet utecast Oh cent tect gad trelungoes€f pi ntereeia cua rdsstely, wolfe ene Fer Stee aeeete Die faces cai Bn : (a) Yeni er tae tune etnie ODL te std ae See Viet eae 24, Goel pare SE cine presinee We port sais te 250 ast pstancs de spore apt pw see 23,736.m We Contane “YBa 30 nomnpisd a ager ee 18 Khe e mol Fe an. Roroleare Decamyee clorura de arin dissiax tn ay, evunhia eviouopio limits gi pon at Ren uth devs " i ap AT. = ik. $=) Ph (awapm Dy eee siunea de vapori total 9 mola de? SS Gegr a ompoattie y= 040, P= 430m, ar He Ses 2) Pe deapl 3 se gisesto pesinnco parils 9 lui in fara de vapori inochi ew slain" eatin Ne "05, By 2 SO lan Hg on ols 3 pate ¢) Fobcind drapta 19: abtne eomponfinsolupvi la 6 prosiune totalt as bom fig ae opt oneal oil op u G17. $0.00 dtrmine manera de tlre tortce tm olen de rsifoare soe amesteal ction 4) ~ attr ae (ta pre tot Be 3 r ‘oloana cats atinenact on vm amvsteesehinwlar de acto 5 oleae. la shitter combos fads vegans ihe molar econ Fn bead 2 dae compere sor elon toperaiohe s een: (Pn ee & y ay] ie a | ets | y Rezolvare Numa tert dosh de dstvenesosor peatay vif un azysine dn componiie” dat foate af pre taf dguane Bo Bsn 9° tect sistema atonal ile ete atin gore A. Sai Teli dna din tbl 3" Fev teapot in arg og fn eatin de och wi gpl corpse noe tae a Tens a ida cooete Stier denteine Ses neal sa cre eb ae ape ald ens el pst Secirenet aerate aueee koe erin tes ae