Cea mai bună pompă de vid, generează vacuum la o presiune de 1 nano Torr la 25° C.

Presupunând că ae
a)Viteza medie a moleculelor C
b)timpul mediu între 2 ciocniri

a) C=sqrt((8*R*T)/π*M)) 8*R*T= 19811.04

C= 3.65324E+11 CORECT π*M= 0.08792

b) 1/t 0.0109447
Z= 3.65324E+11 K*T 3.9932E-21
p/Kb*T 3.33791E+13
Torr la 25° C. Presupunând că aerul conține numai azot cu un diametru de ciocnire 395 picometri. Calculați:

Flux de calcul
1nTorr= 10^(-9)Torr
C=sqrt((8*R*T)/π*M))
T (K) = 298
π= 3.14
M(kg/mol)28*(10^-3)
R(J/mol*k)= 8.31
Kь= 1.34E-23
p(N/m^2) 1.332895E-07
t= 91.36842105
Z= (1/t)*(p/(kb*T))
 Determinarea energiei de activare în laboratorul de cinetică
temperatutimp(s) 1/Dt 1/T ln(1/Δt) R
29 12.23 0.081766 0.003311 2.503892 0.9554
38 7.33 0.136426 0.003215 1.991976
48 1.8 0.555556 0.003115 0.587787
58 1.2 0.833333 0.003021 0.182322
Reprezentare liniara

ln(1/Δt)
3

2.5 f(x) = 8644.001143528x - 26.0484800258

R² = 0.9553898944
2

1.5

0.5

0
0.003 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335
sare(g) n1 H2o n2 sare delta T deltaH diz delta I H diz
1.06 33.26 0.0105 0.13 335.761 31977.24 Date experimentale
2.078 33.26 0.0205 0.21 543.278 26501.37
3.07 33.26 0.0304 0.36 932.828 27895.29
4.06 33.26 0.0402 0.44 1141.946 28406.62
5.02 33.26 0.0497 0.62 1611.596 32426.48

caz logaritmic
deltaH diz
1800
1600
1400
f(x) = 772.2102270526 ln(x) + 3716.6160048269
1200 R² = 0.8914010141

1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055

caz exponențial
deltaH diz
1800
1600 f(x) = 239.2330670985 exp( 39.5936530042 x )
R² = 0.9772600252
1400
1200
1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055

polinom deltaH diz

de 1800
gradul 2
1600
f(x) = 280359.022639506x^2 + 15203.254877542x + 142.3492135954
1400 R² = 0.9898702844
1200
1000
800
600
400
200
 f(x) = 280359.022639506x^2 + 15203.254877542x + 142.3492135954
1400 R² = 0.9898702844
1200
1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055

polinom
de deltaH diz
gradul 3 1800
1600
f(x) = 7536664.54698742x^3 - 400101.246451773x^2 + 33222.9800546931x + 11.0823067852
R² 1400
= 0.9905875397
1200
1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055

deltaH diz
1800
putere
1600
1400 f(x) = 30058.9413182577 x^1.0013333879
R² = 0.9812528304
1200
1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055
caz polinomial de gradul 4

deltaH diz
1800
1600
f(x) = 3658508449.81239x^4 - 433950943.500017x^3 + 18021941.523803x^2 - 274475.571834145x + 1688.7185133642
R² = 1
1400
1200
1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055

caz polinomial de gradul 5

deltaH diz
1800
1600
f(x) = 3658508449.81239x^4 - 433950943.500017x^3 + 18021941.523803x^2 - 274475.571834145x + 1688.7185133642
R² = 1
1400
1200
1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055

caz polinomial de gradul 6

deltaH diz
1800
1600
f(x) = 3658508449.81239x^4 - 433950943.500017x^3 + 18021941.523803x^2 - 274475.571834145x + 1688.7185133642
R² 1400
=1
 deltaH diz
1800
1600
f(x) = 3658508449.81239x^4 - 433950943.500017x^3 + 18021941.523803x^2 - 274475.571834145x + 1688.7185133642
R² 1400
=1

1200
1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055

deltaH diz
1800
1600
1400
1200
1000
800
600
400
200
0
0.005 0.01 0.015 0.02 0.025 0.03 0.035 0.04 0.045 0.05 0.055