Tabelul1

clasa component %masa gi Mi ni xi CO CO*xi

iC6 5.25 4593.75 86 53.42 0.061 73 4.458
nC6 7.35 6431.25 86 74.78 0.086 19 1.625
iC7 6.13 5359.375 100 53.59 0.061 65 3.983
P
nC7 8.58 7503.125 100 75.03 0.086 0 0.000
iC8 6.13 5359.375 114 47.01 0.054 100 5.375
nC8 8.58 7503.125 114 65.82 0.075 -19 -1.430
MCP 4.2 3675 84 43.75 0.050 91 4.552
DMCP 7.56 6615 98 67.50 0.077 95 7.332
ECP 4.2 3675 98 37.50 0.043 75 3.216
N CH 2.52 2205 84 26.25 0.030 87 2.611
MCH 8.4 7350 98 75.00 0.086 75 6.431
DMCH 5.04 4410 112 39.38 0.045 67 3.016
ECH 10.08 8820 112 78.75 0.090 46 4.142
B 0.8 700 78 8.97 0.010 99 1.016
T 1.92 1680 92 18.26 0.021 124 2.589
A
X 4.8 4200 106 39.62 0.045 145 6.569
EB 8.48 7420 106 70.00 0.080 124 9.924
TOTAL/medie 100 87500 874.63 1.000 65.408
Gi, kg/h 87500

%P C6 42
C7 42
C8 16
%N
%A
P 36750
36750
14000
d15^15 Gi/d15^15 Mi*xi Tcr Pcr ρi*xi
657.8 6.98 5.252 224 29.9 40.17
664 9.69 7.353 503.5 30.6 56.77
682.3 7.85 6.128 257.8 27.14 41.81
668.2 11.23 8.579 540 27 57.32
703.7 7.62 6.128 270.6 25 37.82
706.8 10.62 8.579 568 24.6 53.19
753.5 4.88 4.202 532.6 37.3 37.69
759.3 8.71 7.563 550 35 58.60
771 4.77 4.202 569 33.5 33.06
782.4 2.82 2.521 551 40.2 23.48
774 9.50 8.404 570 34.3 66.37
785.4 5.61 5.042 596 29.8 35.36
792 11.14 10.084 600 30.3 71.31
874.6 0.80 0.800 561 48.2 8.97
884.6 1.90 1.921 591 40 18.47
871.8 4.82 4.802 619 35 39.49
868.7 8.54 8.484 617 37 69.53
100.042 749.42
 Conversia globala
component conv. globala
C6 70
P
C7 84
C8 88
MCP 85
DMCP 88
ECP 88
N CH 95
MCH 97
DMCH 97
ECH 97
 Grad de conversie(transformare)
transformat netransformat
component Debit Conversia
Kg/h Kmol/h Kg/h Kmol/h
C8 12862.5 88 11319 99.29 1543.5 13.54
C7 12862.5 84 10804.5 108.05 2058.00 20.58
C6 11025 70 7717.5 89.74 3307.5 38.46
 Viteza relativa Parafine
Reactia C6 C7 C8
Dehidrociclizare 0.03 0.04 0.1
Izomerizare 0.08 0.13 0.2
Hidrocracare 0.04 0.04 0.08
 Vteza relativa r. de hidrocracare Vteza relativa naftene
Clasa parafine viteza relativa
nC6+H2→C1+C5 0.14
nC6+H2→C2+C4 0.2
2C6+H2→2C3 0.28
ACP
nC7+H2→C1+C6 0.14
nC7+H2→C2+C5 0.18
nC7+H2→C3+C4 0.27
nC8+H2→C1+C7 0.19
nC8+H2→C2+C6 0.25
nC8+H2→C3+C5 0.43
nC8+H2→2C1 0.35
ACH
 Vteza relativa naftene
Reactia Component vieza relativa
MCP 4.08
Dehidroizomerizare DMCP 9.03
ECP 9.03
MCP 1.48
hidrogenoliza DMCP 0.2
ECP 0.2
CH 4.02
MCH 9.03
Dehidrogenare
DMCH 21.5
ECH 21.5
CH 1.48
MCH 0.2
hidrogenoliza
DMCH 0.47
ECH 0.47
 fractia de viteza C8
C8 transformat
Reactia viteza relativa fractia de viteza
Kg/h Kmol/h
dehidrociclizare 0.1 0.26 2978.68 26.13
izomerizare 0.2 0.53 5957.37 52.26
hidrocracare 0.08 0.21 2382.95 20.90
Total 0.38 1.00 11319.00 99.29
 fractia de viteza C7
C7 transf
Reactia vit relativa fr de viteza
Kg/h Kmol/h
dehidrociclizare 0.04 0.19 2058.00 20.58
izomerizare 0.13 0.62 6688.50 66.89
hidrocracare 0.04 0.19 2058.00 20.58
Total 0.21 1.00 10804.50 108.05
 fractia de viteza C6
C6 transformt
Reactia vit relativa fr de viteza
Kg/h Kmol/h
dehidrociclizare 0.03 0.20 1543.50 17.95
izomerizare 0.08 0.53 4116.00 47.86
hidrocracare 0.04 0.27 2058.00 23.93
Total 0.15 1.00 7717.50 89.74
 Hidrocracare C6
C6 Transf. prin hc.
Reactia vit relativa fr. Viteza
Kg/h Kmol/h
nC6+H2→C1+C5 0.14 0.23 464.71 5.40
nC6+H2→C2+C4 0.20 0.32 663.87 7.72
2C6+H2→2C3 0.28 0.45 929.42 10.81
Total 0.62 1.00 2058.00 23.93
 Hidrocracare C7
C7 Transf. prin hc.
Reactia vit relativa fr. Viteza
Kg/h Kmol/h
nC7+H2→C1+C6 0.14 0.24 488.34 4.88
nC7+H2→C2+C5 0.18 0.31 627.86 6.28
nC7+H2→C3+C4 0.27 0.46 941.80 9.42
total 0.59 1.00 2058.00 20.58
 Hidrocracare C8
C8 Transf. prin hc.
Reactia vit relativa fr. Viteza
Kg/h Kmol/h
nC8+H2→C1+C7 0.19 0.16 371.11 3.26
nC8+H2→C2+C6 0.25 0.20 488.31 4.28
nC8+H2→C3+C5 0.43 0.35 839.89 7.37
nC8+H2→2C4 0.35 0.29 683.63 6.00
total 1.22 1.00 2382.95 20.90
 BM pe C8 BM pe C7
Comp Mi(kg/kmol) Gi(Kg/h) ni,kmol/h comp Mi, kg/kmol Gi, kg/h
C8 netransf 114 1543.50 13.54 C7 netransf 100 2058.00
EB 106 2769.65 26.13 T 92 1893.36
iC8 114 5957.37 52.26 iC7 100 6688.50
C1 16 52.09 3.26 C1 16 78.13
C2 30 128.50 4.28 C2 30 188.36
C3 44 324.17 7.37 C3 44 414.39
C4 58 695.63 11.99 C4 58 546.24
C5 72 530.46 7.37 C5 72 452.06
C6 86 368.37 4.28 C6 86 419.97
C7 100 325.54 3.26 H2 produs 2 164.64
H2 produs 2 209.03 104.52 H2 consumat 2 -41.16
H2 consumat 2 -41.81 -20.90 total - 12862.50
total - 12862.50 217.34
 BM pe C6 Grad de con
ni,kmol/h comp Mi, kg/kmol Gi, kg/h ni,kmol/h
component
20.58 C6 netransf 86 3307.50 38.46
20.58 B 78 1399.92 17.95 MCP
66.89 iC6 86 4116.00 47.86 DMCP
4.88 C1 16 86.46 5.40 ECP
6.28 C2 30 231.58 7.72 CH
9.42 C3 44 951.03 21.61 MCH
9.42 C4 58 447.73 7.72 DMCH
6.28 C5 72 389.06 5.40 ECH
4.88 H2 produs 2 143.58 71.79
82.32 H2 consumat 2 -47.86 -23.93
-20.58 total - 11025.00 199.99
210.95
 Grad de conversie(transformare)
transformat
Debit Conversia
Kg/h
3675 85 3123.75
6615 88 5821.20
3675 88 3234.00
2205 95 2094.75
7350 97 7129.50
4410 97 4277.70
8820 97 8555.40
 Reactie/HC nC6 nC7 nC8 MCP DMCP ECP CH

dehidrociclizare 1543.50 2058.00 2978.68 - - - -

izomerizare 4116.00 6688.50 5957.37 - - - -

hidrocracare 2058.00 2058.00 2382.95 - - - -
dehidroizomerizare - - - 2292.25 5695.06 2778.59 -
hidrogenoliza - - - 831.50 126.14 455.41 563.68
dehidrogenare - - - - - - 1531.07
Total 7717.50 10804.50 11319.00 3123.75 5821.20 3234.00 2094.75
 MCH DMCH ECH repartitia reactiilor pe reactoare

reactor/ dehidroge dehidroizo izomerizar dehidrocic

- - - Hc
reactie nare merizare e lizare

- - - 1 60 25 25 10 10
- - - 2 30 35 35 20 30
- - - 3 5 20 20 35 30
154.49 91.51 183.02 4 5 20 20 35 30
6975.01 4186.19 8372.38 total 100 100 100 100 100
7129.50 4277.70 8555.40
Vzr 41.68 m^3

d4^20 739.42
 repartitia catalizatorului pe reactoare

hidrodecic reactor Procent Vzr, m^3

lizare

10 1 10 4.17
20 2 20 8.34
35 3 35 14.59
35 4 35 14.59
100 Total 100 41.68
 Distributia componentilor pe reactii si reactoare

R1 R2 R3
Reactie Comp Gi, kg/h

% Gi, kg/h % Gi, kg/h %

CH 1531.07 60 918.64 30 459.32 5
MCH 6975.01 60 4185.01 30 2092.50 5
dehidrogenare
DMCH 4186.19 60 2511.71 30 1255.86 5
ECH 8372.38 60 5023.43 30 2511.71 5
MCP 2292.25 25 573.06 35 802.29 20
dehidroizomerizare DMCP 5695.06 25 1423.77 35 1993.27 20
ECP 2778.59 25 694.65 35 972.51 20
nC6 4116.00 25 1029.00 35 1440.60 20
izomerizare nC7 6688.50 25 1672.13 35 2340.98 20
nC8 5957.37 25 1489.34 35 2085.08 20
nC6 2058.00 10 205.80 20 411.60 35
Hc nC7 2058.00 10 205.80 20 411.60 35
nC8 2382.95 10 238.29 20 476.59 35
nC6 1543.50 10 154.35 30 463.05 30
dehidrociclizare nC7 2058.00 10 205.80 30 617.4 30
nC8 2978.68 10 297.87 30 893.60526 30
MCP 831.50 10 83.15 20 166.30 35
DMCP 126.14 10 12.61 20 25.23 35
ECP 455.41 10 45.54 20 91.08 35
hidrogenoliza CH 563.68 10 56.37 20 112.74 35
MCH 154.49 10 15.45 20 30.90 35
DMCH 91.51 10 9.15 20 18.30 35
ECH 183.02 10 18.30 20 36.60 35
total 64077.30 21069.22 19709.11
 Calculul gazelor de recirculare Calculul cp alimentare la t

R3 R4 debit molar Clasa

Gi, kg/h % Gi, kg/h m.p. 906.69

76.55 5 76.55 H2 6346.85
348.75 5 348.75 G.R. 7052.06
P
209.31 5 209.31 CH4 705.21
418.62 5 418.62
458.45 20 458.45
1139.01 20 1139.01
555.72 20 555.72
823.20 20 823.20
1337.70 20 1337.70 N
1191.47 20 1191.47
720.30 35 720.30
720.30 35 720.30
834.03 35 834.03
463.05 30 463.05
A
617.40 30 617.40
893.61 30 893.61
291.03 35 291.03 Total
44.15 35 44.15
159.39 35 159.39
197.29 35 197.29
54.07 35 54.07
32.03 35 32.03
64.06 35 64.06
11649.48 11649.48
Calculul cp alimentare la temp de reactie

cpm, xi*cpm,
Hc kcal/kmol⁰ xi kcal/kmol⁰
C C
iC6 69.55 0.061 4.25 cp mp, kcal/kmol⁰C 72.93
nC6 69.55 0.086 5.95 cp H2, kcal/kmol⁰C 7.09
iC7 80.51 0.061 4.93 cp CH4, kcal/kmol⁰C 25.26
nC7 80.51 0.086 6.91 cp alim, kcal/kmol⁰C 142.21
iC8 91.49 0.054 4.92
nC8 91.49 0.075 6.88
MCP 63.83 0.050 3.19
DMCP 75.04 0.077 5.79
ECP 100.83 0.043 4.32
CH 65.65 0.030 1.97
MCH 77.69 0.086 6.66
DMCH 8.93 0.045 0.40
ECH 76.24 0.090 6.86
B 44.73 0.010 0.46
T 55.21 0.021 1.15
X 65.93 0.045 2.99
EB 66.1 0.080 5.29
Total - 1.000 72.93
 Stabilirea caderii de temp pe reactorul I

Mi, Kg/ H, Ni*/H,

Reactie Comp Gi, kg/h Ni, kmol/h kcal/kmol
kmol Kcal/h

CH 84 918.64 10.94 49.9 545.72

MCH 98 4185.01 42.70 49.9 2130.94
dehidrogenare
DMCH 112 2511.71 22.43 51.3 1150.45
ECH 112 5023.43 44.85 52.3 2345.76
MCP 84 573.06 6.82 48.5 330.88
dehidroizomerizare DMCP 98 1423.77 14.53 47 682.83
ECP 98 694.65 7.09 47 333.15
nC6 86 1029.00 11.97 -2.3 -27.52
izomerizare nC7 100 1672.13 16.72 -2.3 -38.46
nC8 114 1489.34 13.06 -1.9 -24.82
nC6 86 205.80 2.39 62.9 150.52
Hc nC7 100 205.80 2.06 59.9 123.27
nC8 114 238.29 2.09 57.2 119.57
nC6 86 154.35 1.79 -23.4 -42.00
dehidrociclizare nC7 100 205.80 2.06 -23.4 -48.16
nC8 114 297.87 2.61 -23.4 -61.14
MCP 84 83.15 0.99 -16.9 -16.73
DMCP 98 12.61 0.13 -15.2 -1.96
ECP 98 45.54 0.46 -15.2 -7.06
hidrogenoliza CH 84 56.37 0.67 -10.6 -7.11
MCH 98 15.45 0.16 -10.7 -1.69
DMCH 112 9.15 0.08 -9.1 -0.74
ECH 112 18.30 0.16 -9.1 -1.49
total 21069.22 206.77 - 7634.20

Δt1, ⁰C 59.2
te1, ⁰C 440.8
 Stabilirea caderii de temp pe reactorul II

Mi, Kg/ H, Ni*/H,

Reactie Comp Gi, kg/h Ni, kmol/h kcal/kmol
kmol Kcal/h

CH 84 459.32 5.47 49.9 272.86

MCH 98 2092.50 21.35 49.9 1065.47
dehidrogenare
DMCH 112 1255.86 11.21 51.3 575.23
ECH 112 2511.71 22.43 52.3 1172.88
MCP 84 802.29 9.55 48.5 463.23
dehidroizomerizare DMCP 98 1993.27 20.34 47 955.96
ECP 98 972.51 9.92 47 466.41
nC6 86 1440.60 16.75 -2.3 -38.53
izomerizare nC7 100 2340.98 23.41 -2.3 -53.84
nC8 114 2085.08 18.29 -1.9 -34.75
nC6 86 411.60 4.79 62.9 301.04
Hc nC7 100 411.60 4.12 59.9 246.55
nC8 114 476.59 4.18 57.2 239.13
nC6 86 463.05 5.38 -23.4 -125.99
dehidrociclizare nC7 100 617.40 6.17 -23.4 -144.47
nC8 114 893.61 7.84 -23.4 -183.42
MCP 84 166.30 1.98 -16.9 -33.46
DMCP 98 25.23 0.26 -15.2 -3.91
ECP 98 91.08 0.93 -15.2 -14.13
hidrogenoliza CH 84 112.74 1.34 -10.6 -14.23
MCH 98 30.90 0.32 -10.7 -3.37
DMCH 112 18.30 0.16 -9.1 -1.49
ECH 112 36.60 0.33 -9.1 -2.97
total 19709.11 196.52 - 5104.18

Δt2, ⁰C 39.6
te2, ⁰C 460.4
 Stabilirea caderii de temp pe reactorul III

Mi, Kg/ H, Ni*/H,

Reactie Comp Gi, kg/h Ni, kmol/h kcal/kmol
kmol Kcal/h

CH 84 76.55 0.91 49.9 45.48

MCH 98 348.75 3.56 49.9 177.58
dehidrogenare
DMCH 112 209.31 1.87 51.3 95.87
ECH 112 418.62 3.74 52.3 195.48
MCP 84 458.45 5.46 48.5 264.70
dehidroizomerizare DMCP 98 1139.01 11.62 47 546.26
ECP 98 555.72 5.67 47 266.52
nC6 86 823.20 9.57 -2.3 -22.02
izomerizare nC7 100 1337.70 13.38 -2.3 -30.77
nC8 114 1191.47 10.45 -1.9 -19.86
nC6 86 720.30 8.38 62.9 526.82
Hc nC7 100 720.30 7.20 59.9 431.46
nC8 114 834.03 7.32 57.2 418.48
nC6 86 463.05 5.38 -23.4 -125.99
dehidrociclizare nC7 100 617.40 6.17 -23.4 -144.47
nC8 114 893.61 7.84 -23.4 -183.42
MCP 84 291.03 3.46 -16.9 -58.55
DMCP 98 44.15 0.45 -15.2 -6.85
ECP 98 159.39 1.63 -15.2 -24.72
hidrogenoliza CH 84 197.29 2.35 -10.6 -24.90
MCH 98 54.07 0.55 -10.7 -5.90
DMCH 112 32.03 0.29 -9.1 -2.60
ECH 112 64.06 0.57 -9.1 -5.20
total 11649.48 117.82 - 2313.39

Δt3, ⁰C 17.9
te3, ⁰C 482.1
 Stabilirea caderii de temp pe reactorul IV

Mi, Kg/ H, Ni*/H,

Reactie Comp Gi, kg/h Ni, kmol/h kcal/kmol
kmol Kcal/h

CH 84 76.55 0.91 49.9 45.48

MCH 98 348.75 3.56 49.9 177.58
dehidrogenare
DMCH 112 209.31 1.87 51.3 95.87
ECH 112 418.62 3.74 52.3 195.48
MCP 84 458.45 5.46 48.5 264.70
dehidroizomerizare DMCP 98 1139.01 11.62 47 546.26
ECP 98 555.72 5.67 47 266.52
nC6 86 823.20 9.57 -2.3 -22.02
izomerizare nC7 100 1337.70 13.38 -2.3 -30.77
nC8 114 1191.47 10.45 -1.9 -19.86
nC6 86 720.30 8.38 62.9 526.82
Hc nC7 100 720.30 7.20 59.9 431.46
nC8 114 834.03 7.32 57.2 418.48
nC6 86 463.05 5.38 -23.4 -125.99
dehidrociclizare nC7 100 617.40 6.17 -23.4 -144.47
nC8 114 893.61 7.84 -23.4 -183.42
MCP 84 291.03 3.46 -16.9 -58.55
DMCP 98 44.15 0.45 -15.2 -6.85
ECP 98 159.39 1.63 -15.2 -24.72
hidrogenoliza CH 84 197.29 2.35 -10.6 -24.90
MCH 98 54.07 0.55 -10.7 -5.90
DMCH 112 32.03 0.29 -9.1 -2.60
ECH 112 64.06 0.57 -9.1 -5.20
total 11649.48 117.82 - 2313.39

Δt3, ⁰C 17.9
te3, ⁰C 482.1
 Diametrul si inaltimea reactoarelor

D1, m H1, m 0.00

D2, m H2, m 0.00

D3, m H3, m 0.00
D4, m H4, m 0.00

Reactorul D, m ω, h^(-1) Ni, kmol/h Ne, kmol/h Vmediu, m^3/s τ, s ε

1 1.29 28.01 7258.83 7730.11 3.67 0.73 0.646
2 1.62 14.01 7730.11 8129.06 3.93 1.37
3 1.95 8.00 4064.53 4231.30 2.09 4.51
4 1.95 8.00 4064.53 4231.30 2.09 4.51
11.13
ϒv, kg/ m^3 850
ϒr, kg/ m^3 2400

h
 Calculul variatiei
numarului de mol pe R1 R2 R3
reactoare

Reactie Comp Ni, kmol/h Δni Ni, kmol/h Δni Ni, kmol/h

dehidrogenare CH 10.94 32.81 5.47 16.40 0.91

MCH 42.70 128.11 21.35 64.06 3.56
DMCH 22.43 67.28 11.21 33.64 1.87
ECH 44.85 134.56 22.43 67.28 3.74
dehidroizomerizare MCP 6.82 20.47 9.55 28.65 5.46
DMCP 14.53 43.58 20.34 61.02 11.62
ECP 7.09 21.26 9.92 29.77 5.67
izomerizare nC6 11.97 - 16.75 - 9.57
nC7 16.72 - 23.41 - 13.38
nC8 13.06 - 18.29 - 10.45
Hc nC6 2.39 - 4.79 - 8.38
nC7 2.06 - 4.12 - 7.20
nC8 2.09 - 4.18 - 7.32
dehidrociclizare nC6 1.79 7.18 5.38 28.72 5.38
nC7 2.06 8.23 6.17 32.93 6.17
nC8 2.61 10.45 7.84 41.81 7.84
hidrogenoliza MCP 0.99 -0.99 1.98 -1.98 3.46
DMCP 0.13 -0.13 0.26 -0.26 0.45
ECP 0.46 -0.46 0.93 -0.93 1.63
CH 0.67 -0.67 1.34 -1.34 2.35
MCH 0.16 -0.16 0.32 -0.32 0.55
DMCH 0.08 -0.08 0.16 -0.16 0.29
ECH 0.16 -0.16 0.33 -0.33 0.57
total 206.77 471.28 196.52 398.96 117.82

R1:
 R4

Δni Ni, kmol/h Δni

2.73 0.91 2.73

10.68 3.56 10.68
5.61 1.87 5.61
11.21 3.74 11.21
16.37 5.46 16.37
34.87 11.62 34.87
17.01 5.67 17.01
- 9.57 -
- 13.38 -
- 10.45 -
- 8.38 -
- 7.20 -
- 7.32 -
21.54 5.38 21.54
24.70 6.17 24.70
31.35 7.84 31.35
-3.46 3.46 -3.46
-0.45 0.45 -0.45
-1.63 1.63 -1.63
-2.35 2.35 -2.35
-0.55 0.55 -0.55
-0.29 0.29 -0.29
-0.57 0.57 -0.57
166.77 117.82 166.77