Fiqd tehnici de securitate azotat de amoniu

Secliunea 1 - IDENTIFIcAREA SUBSTANTET gt A SOCtETATtI

1,1 ldentificatorul produsului i

. Denumirea produsului : azotat de amoniu

. Denumire comerciale: azotat de amoniu
. Denumirea substantei : azotat de amoniu
. Numer CE : 229-347 -B
. Numer CAS : 6484 -52-2
. Numirul de inregistrare REACH 01-211949490981-27 -007 8 (azoiai de amonju)
01-21 194S1 164-38-0073 (azotat de magneziu)
. Formula chimici : H3N,HN03

o
. Formula structurale :
Nt"
.'^.."'.\-'-
rlrr t, t.tHi

'1.2 Utiliziri relevante identificate ale substanlelor sau amestecului 9i contraindrcatii

. utilizare recomandata : lngrasaminte
. Restricfii recomandate : A se utiliza nurnai ca ingragimant

1.3 Detalii privind furnizorul fi$ei tehnice de securitate :

. Dgtalii producetor : RustaviAzot

JSC Rustavi,
Georgia,
Telefon: +995 341 270901
Emajlr giakobashvili@rustaviazot.qe, info@rustaviazot.qe
. Reprezentant : PHARMEGIC HEALTHCARE LII\,IITED
etajul6, Konstitucijos av. 21A, 08'130 Vitnius,
Lituania

1.4 Telefon de urgenle I

Telefon: +995 341 270901

. Tetefonut de urgenti gi
persoana de contact:

Sectiunea 2 - IDENTIFICAREA PERICOLELOR

2'1c|asificareasubstan1eisauaamestecu|uiinconformitai@
Categoriigi coduri de pericole fizice: Substanle solide oxidante Categoria 1i H272

Categorii de pericol pentru sinitatea

umana 9i lritarea ochilor Categoria 2; H319
coduri:

2.2 Elichetare rn conformitare cu Regutamentut 1CE1-i--72i2008 1CLp1 .

Pictograma de pericol i Cuvent de atentionare : Avertisment

 Fiqi tehnici de securitate azotat de amoniu

Mentiuni de pericol : H272r Poate iniensiflca incendiul;
Mentiuni de precaulie
GHSOT
e) GHSO3
Semnul exc amdrii Flacerb peste cerc
oxidant. H319: Provoacd lriialii oculare
grave.
I P210i A se pdstra departe de cdldu16, suprafele flerbinli scantei, fldcdri
deschise sialte surse de apfindefe. Fumatuleste interzis.
P220. Pdsrrati/depoziali a d:sta-ld oe materia e corbusribile.
imbrecdminie. P370+P378i ln caz de incendlu: Folositi miiloace de
stingere adecvate pentru a stinge. P264: Spdlati-vd blne pe mainidupe
manLpulare.
P280: Purtati menugi de proteclie,/imbreceminte de p rotect e/p roteclje
penku ochl/protectie pentru fatd. P305+P351+P338: LA CONTACTUL CU
OCHllr Cldtili cu grijd cu apd tirnp de cateva minute. lndepertall lentilee
de_ coniact, dacd sunt prezente gi dacd este usor de ficut. Continuali
cralrea.

Contactul cu materlale combustibile va creste oerico ul de incendlu. Poate

exploda daci se lncelzegte in conditii de izolare, provocand o cre$tere a
preslunii sau daci este supus unor gocuri puternice. Azotatul de amon u
2.3 Alte pericole
solid, atuncicand este sensibilizat sau ln timpuldescompunedi. Doate
deven instabil si/sau exploz v. Atunci cand azoiatul de a.noniu este
incdlzii pane la descompunere, acesta poaie produce vapori care cont n
oxizide azot (NOx).

Sectiunea 3 - COMPOZITIAI NFORMATI PRIVIND IN GREDIENTELE

Tlplc
Constitu€nt NT.CE IntePalul de concentraite

229.347-A El€

7732-\8.5 231-791,2 >c),r:3 ai%lE/E) o,2 % lele)

azotal denasneziu 0a
tlanslbrrarea in MEO) 1309-48.4 2t5-\7I-9 o,3 % (slq) lerJ

SECI|UNEA 4 - MASURI DE PRIM AJUTOR

4.1 Descrierea m;surilor de prim ajutor'
. Mdsuri generale : Consultali un medic. Afrtati aceasti fisd tehnicd de secufitate medicului
prezent.
. Contactul cu ochiii Spdlaji imedlat ochii cu apd din abundenF timp de cel pulin 10-20 de
minute,
ridjcand ocazional pleoape e superioare gi inferioare. indepdrtali imed at
lentilele de contact, dacd pacienlii e poarte Solic tati irnediat ajutor
medlcal.
. Contactul cu pielea: Indepertati imbfecdmlntea giincelFmintea contaminate. Spdtali zona
afectaE cu multd apd, cont nuali sd spelall tirnp de cel pulin 10-20 de
minute.
Solicitati asistentd nredicald.
. lnhalare : Scoateli imediat pacjentul la aer curat, asigurali repaus absolut intr-o
pozitie
confortab a pentr.r respkalie. ln caz de asfixie - administrali oxige-. Daalt
0aientul.nu respird. aplicati respira!'a atificiatd Soticitati asistentz\$t

. Ingestie: In caz de lnghilire cldtili gufa cu apa (numaidacJ persoana estd/o:J'

congtiente). Nu provoca! voma. Obtineli asistenl6 redicald dadd,e!'ar
simptome. ljl; , d
1?.' 4$
'frffiri[
' \','.2Y
Pao)na
-.-7TI y
\ g?ADU!
-.;
 Figd tehnicd de securitate azotnt de amoniu

4,2 Cele mai atet acute cat si intarziate I

. In loaie cazurile ln care existd indoielisau cand simptomele persistA, consultati un medic.
. Contactulcu ochii: irrogirea ochilor
. lngesiiei dureriabdominale, buze sau unghiialbastfe, convulsii, diaree, ameteli, versdturj, sldbiciune.
. Inhalarei tuse, dureri de cap, dureri de gat.
. Alte e'eqe ac-te si intaziate nJ surt cunoscLte.

4.3 Indicarea oricerei atentii medicale imediate si a unui tratament

Sfaturi pentru medic : in caz de inhalare, poate aperea edem pulmonar. paclentul irebuie se fie linui sub
supraveghere medicali tmp de cel pulin 48 de ofe dupd expunere, deoarece se poate dezvolta un edem
pulmonar in€rz at. Substan!a conline nitrali, care pot fi redugi la niiri'ii de cetre bacteriile intestinale. Nitrllli
provoacd scadefea tensiunii arteriale gi methemoglobinemle. Efeciul expunerii atiJ'rge maxim!l 1n 3O de mlnuie.
Este necesar sb se lnstituie monitorizarea cardiace la pacientii

NEA 5 - MASURI DE COMBATERE A INCEN

5.1 l\4ijloace de stingere:
. Mijloace de stingere adecvate : Folos ti nurnai apa din abundent;.
. Incendiu mic: Necombustibil. Acest prodits poate sustjne cornbustia. Api
. lncendiu marei Necornbustibil. Acest produs poate sustine combustia. Apd

5.2 Pericole speciale care rezulta din substanti sau amestec:

. Poate fi exp oziv in contact cu substanle inflamabile sau organice gi la izolare in timpul unui incendiu.
. Produgii de combustie ai acestui r.aterialtrebuie se iie clasificali invariabil ca agenli toxici respiratori. in caz
de incendiu, pot fl eliberate urmdtoarele: Amoniac (NH3); oxizi de azot (Nbx); dioxid de carbon (CO2)l

5.3 Sfatlrri
. Nu sLlnt necesare mdsufispeciale. Purtalilmbricer.inte de protecile adecvatd. Se recomandA utilizarea unu
aparat de respifalie autonom.
. Informatiisuplimentare:
. Este lnterzis6 utillzarea foc!lu deschis in apfopierea spatiilor de depozltare a azotatului de amofiu.
contaciu uicu alte substanle inflamabile.

unea 6 - MASIJRI lN CAZ DE DEVERSARE ACCTDENTALA

.1 P de
Sfaturi pentru Evitali contactul cu ochiigi pielea prin utilizarea
personalul care ech ipamentului de proteclie. Nu rnencali, nu beti gi nu fumali
nu face parte din la loculde muncd.
personalul de
Sp;lali-vi iniotdeauna pe maini dut)i manipulare.
Spdlali hainele contaminate inainte de a le
urgenF:
reutitiza. Asigurali eTjminarea

Sfaturi Purtali echipament individual de proteclie (conform menliunii

pentru din secliunea 8.2.2). Aerisili zona.
responden!ii Evacuali personalul ln zone sigure.
in situafii de
urgen!e
:

6.2 Precautii de mediu :

TrebLrie preven tb scurgerea Lrnei cantltali mari_de apd in canalizare, ln apele de suprafald si in ape e subterane
oeoarece aceasta poale provoca eutrofizare. Trebuie sd se opfeasc; scurgerile de matefial solid gi de solulie
concentratd. Evital.contactul materialului vdrsat cu solul giimpiedicaji scu acestuia in cursuriie de apA de
In cazul 1n care sLtbstanta deversatd pdtrunde intr,un curs de apd, informaU autoritdtile loca e.
 Fisd tehnicd de securitate azotat de amoniu

6.3 Metode Si materiale pentru izolare Si cur:rtare:

Scurgeri 9i deversiri mici
Aspirali sau matufati maierialele gi puneli-le lntr-un recipient de deseuri clesemnat 9i eticheiat. curelali zona
afectatd cu o cantitate rnare de ape. Nu colectali materialul vdrsat in rumegus sau in alte maieriale
combustibile.
Scurgeri gi deversari mari
Aspirali s_a,u mdturali maierlalul si puneti-l ink-un recipient de degeuri desemnat si etichetat. Reciclaji, dacd
este posibil. curdlalizona afectatd cu o cantitate mare de apa. in cazul in care sLbstan!a deversatd pbtfunde
intr-un culs de ap5, informa!i autoritatea locald. Nu colectali rnaterialu varsai in rumegLig sau in alte materiaLe
cornbustib le

Sectiunea 7 - MANIPULARE Sl DEPOZITARE

7.1 Precautii pentru o manipulare sigura
. Sfaturi privind manipularea in
conditii de siguranti:
:
Asigurali o foarte bund ventilalle de adr.lsie/evacuare la locul de munce,
inclusiv la nivelul solului Pentr! umplere si transfer, utjlizatiechipamente
inchise cat mai bine posibil, cu vent latie prjn evacuare sau echllibrare a
vaporilor. Evitali caderea liberd si stropirea. Folosili pompe, fitinguri gi
supape cu protectie lmpotriva exploziilof. Nu alin'tentaiicu aer comprlmat.

. Sfaturi privind igiena: Spdlali-vd lntotdeauna pe mainidupe manipulare. Spdlati hainete

. Sfaturi privind protecfia
impotriva incendiilor gi
exploziilor
contaminate lnainte de a le reutitiza.
A se pastra depade de sursele de aprinderei nu fumali; nu sudati. Luati
mesuri impotfiva incercdrii electrostatice. Lucferile la recipiente si
conducte sunt permise nurnai dupe o purjare si o inertizare completd.
TrebJe sb fie disponioild o racire de u.ge-td in caz de i-cenoi- i.
aoropie-e Se pot forma a-iestecJri inflamabile de qaz gi ae. ir
recipientele goale.

7.2 Conditii pentru o depoz'tare siguri I

Pestali recipientul bine inchis. Pdstrafi recipientul iftr-o zond rrcoroasa si b ne ven|la€. A se separa de
acizi, baze, agentl reducdtori si combustibili.
Amplasali depozitul departe de posibile sufse de cdldurd, incendiisau explozii, curn ar fi depozjtele de petrol,
conductele de gaz, depozltele de cherestea lichidee inflamablle solidele inf amabile si matefialele
combustibile

Z3 Utilizeri finale specifice

DLrpS cura se ment oneazd in sectiunea 1.2.

Sectiunea I - CONTROLUL EXPUNERII/PROTECTIA PERSOANALA

8.1 Parametrii de control:
. Valori Iimite de exDunere:
Uniunea Europeana (Directiva 2000/39/CE)t azotatulde amoniu nu este
inclus in liste.
ACGIH - American Conference of Governmental Industrial Hygienists
(Conferinla americane a specialigtilor guvernamentali in igiena
industriala) : nu este inclus pe lista. ln confofrnitate cu reglementdrlie
locale,

8,2 Controlul expunerii :

8.2.1 Controale tehnice adecvate :
. Mdsuritehnologice: Folosili incinte de proces, ventilatie ocald prin evacuare sau alte
contfoale tehnice pentru a mentlne njvelurie din aef sub limitele de
expunefe recomandate. Dacd
operaliunile genereazd praf, furn sau ceald folositiventilalia pentru a
menline expunerea la contaminantii din aer sub llmita de expunere.
8,2,2 Mdsuri de protectie individuale;
1[/

,6 ile+
*"i;':9
(a

;d jj- - O

'r6trc)
 Fisd tehnici de securitate azotat de amoniu

. Protec$ia respiratorie : ln cazul in care concentralia de praf este ridicate $i/sau ventilatia este
inadecvatd, utilizali
mascd de proteclie adecvate impotriva prafului sau aparat de respirat cu
un filtru adecvat (EN 143, 149, nlkele P2, P3).
. Proteclia mainilor i Purtali menusi adecvate (de exemplu, din plastic, cauciuc sau piele)
atuncicand rnanipulati produsul oe perioade lunoi de timo.
. Protectia ochilor: Purlati ochelari de proiectie blne aiustati (EN 166)
. Proteclia pieliii Purtati mdnusi de proteclie adecvate pentru a preveni exounefea oielii.
. [4isuri de igieni: In limpul utiliz;rii, nu mancati, nu beligi nu furnati. Spelati-ve pe matni
dupe n]anipularea compusilor 9i inainte de a manca de a fuma de a
folosi toa eta si la sfarsitul zilei.
8.2,3 Conholul expuneriiin mediul
Scufgerile de produs trebuie curdtate imediat gi plasate intr-un rec pient cufai s,i et chetat pentru a fi eljm nate in
slgurantd. A nu se arnesteca cu rumegus sialte substanle combustibile sau organice. Se d ueaze cu ape sa! cu
materiale inerte, cum ar fi calcar/dolomit fosfat mineral gips, nisip. Aveli grijd se evitali contamjnarea cursurilor
de ap; Ei a canalelor de scurgere. Trebuie prevenitd scurgerea unei cantitdti mari de apd in canalizare, in apele
qe sup'a'ala s, in ape e sublerane, oeoarece aceasta poate p.ovoca eutrofiiare.

sectiunea 9 - PRoPRtETAT| FtZtcE $t C ltMlcE

9.1 informatii privind propriqhtile tizice si chimice de baza I

. Aspect: Cfistale higroscopice albe

. Miros: tnooor
. Praqul de miros: Nu este cazul.
pH (10% soln/ape): 5,0 -6,0
. Punct de topire / punct de 169'C
conqelare:
. Punctul inllial de fierbere 9i Apro{. 210 "C (se descompL.tne)
intervalul de fierbere I

. Punct de apaindere: Neinflamabil

. Rata de evaporare: Nu ex std date disponjbLle
Nu este combustibil, dar favorlzeaza arderea altor substante. Cand
. este indlz t ld 2lO "C se descompJne. Produs de desco-apunere
Inflamabilitate: peric-losioot
include amoniacul, oxizii de azot sl acidul nitric. Emite fumurl (sau
j94e) iritante sau ioxice ln caz dd incendiu.
. Limite de inflamabilitate sau
explodie superioari/inferioare Nu existd date disponib e

. Presiunea vaDorilorl Nu existd daie disponibile

Densitatea vaDorilor
. Densitate relativi:
Solubilitate I rnl (20 'C) 2S7
Coelicient de repartitiei n-
octanol/apa
:
: Nu existd date disponibile
1,690-1 725 g/cm3 (20 'C)
' Solubilitate in
apd: 118 g/100
ml(o'C) 150 g/100
s/100 ml(40 "c)
410 g/100 ml (60
'C) 576 g/100 ml
(80'c)
' Uqor solubil in metanol, acetond
Nu existd date disponibile

. Temperatura de autoaprindere: Nu e^ stb date disponlbie

Temperatura de descompunerei 210'C
 Fi;d tehnica de securitate azotat de amoniu

. Vascozitate l Nu exisie date d sponibile

. Proprietdliexplozive: Nu este exploziv
. Propriete$ oxidante: Agent de oxidare

9.2 Alte informalii : Fdfe

Sectiunea 10 - STABILITATE Sl REACTIVITATE

. Reactivitate:
. Stabilitate chimicS:
. Posibilitate de reactii
peflcLtloasel
. Conditii care trebuie evitate
Produgi de descompunere
periculogi:
. Agenli reducdtori, acizili baze puternice, pulberimetalice, mate ale
Materialeincompatibile:
Nu sunt disponibile date de testafe specjfice legate de feactivitate pentru
acesi produs sau pentru Ingredientele sale.
Stabll in condiliile de depozitare 9i man pulare recomandate (a se vedea
sectiunea Manipulare si depozjtare).
Dace este manipulat g depozitai in mod corespunzbtor, nu se cunosc
reacjlipericuloase.
I Incdlzirea la peste 170'C (se descompune in gaze) Apropiefea de
surse de celdura sau de foc Incdlzirea in condiliide izolare.
Contaminarea cu materiale incompatibie. Expunerea inutl 5 la
atrnosfera.
Cend este puternic incdlzit, se topegte gi se descompune elibefand
vaporitoxici (de ex.
oxizi de azot (NO, N02), amoniac). ln contact cu matefiale alcaline, cum
ar fi varul, poate deqaia oaz de amoniac.
combustibile, cromali, zinc, cupru gialiaje de cupru, clorati.

Sectiunea 'l l ' INFORMATII TOXICOLOGICE

11.1 Informatii privind efectele toxicologice ;

Tipul de Azotat de amoniu

toxicitat

Toxicitate orale acut; Nivelul de efect:

LD50 - 2950 mg/kg
corp Specii: Sobolan
Toxicitate acut5 prin inhalare Nivelulde efect:
LCo - > B8,B altele: mg/L
Speciii 9obolan
Expunere timp de 4 ore
Toxicitate cutanatd acute Nivelulde efect:
LD50->5000mg/kg
cofp Specii: 9obolan

11.2 lritatie /coroziune :

Ochi: Moderat iritant

Piele: Nu este iritant

11.3 Sensibilizare :

Piele: Nu este de asteptat sd fe senslbilzani.

11.4 Efecte CMR (carcinogenitate, mutagenitate gj toxicitate pentru reproducere) :

,4aJ
. Carcinogenitate: Nu este clasificar ca frind cancerigen.
iKv-,
1/S P.
;
t77
\&tna 1
hit-t611L//I
"l\Y

otcYt
 Fiqi tehnicd de securitate azotat de amoniu

. Efecte mutagene : Nu este clasificat ca mutagene.

. Efecte reprotoxicel Nu s-a dovedit a fi toxic oentru reoToducere.

'i 1.5 Alte efecte toxice asupra oamenilor :

. lnhalarel Nu existd date disponibile.

. Ochil Nu existd dale disponibile
. lngestie: Nu existd daie d spon bile.
. Toxicitate cronice: Nu exis€ date dispon bile.

11.6 Toxicitate specifici pentru organe-tintd I

. O singure expunere: Nu existd doveziexperimentale sau epidemiologice suficiente pentru

o toxicitate specrfrcb pentru orqanele tinti.
. Expunere repetate: Nu existd dovezi expefimentale sau epidemiologice suficiente peniru o
toxicitate specificd pentfu organele lintd.

11.7 Pericol de aspiralie : N- exrsta date oispor.bile.

Sectiunea 12 - INFORMATII ECOLOGICE

12.1 Ecotoxicitate:

Tipul de Toxicitate pe termen Toxicitate pe termen lung Toxicitate pentru algele

toxic;tate scurt pentru pesti pentru nevertebratele acvatice si cianobactefii
acvatice
Specii Cypr nus carp o Bullia dig talis Scenedesmus quadricauda
DuratS 48 ore 7 zile
Punct final LC50 EC50 EC50

12.2 Persistenli gi degradare:

. In conformitate cu anexa Xlll la Regulamentul (CE) nr. 1907/2006, nu a fost efectuatd nicio evaluare
PBT gi vPvB. Substanla este o substante organicd anorganicd.

'12.3 Potenlialul de bioacumulare :

Nu se aplicd evaluarea PBT.

12.4 Mobilitatea in sol :

. Nu sunt disponibile informa!li penlru produsul final.

12.5 Rezultatele evalLtArii PBT si vPvB .

Nu se ap lcb evaluarea PBT.

12.6 Alte efecte adverse :

 Figa tehnicl de securitate azotrt de amoniu

Nu se cunoaste.

Sectiunea 13 - CONSIDERATII PRIVIND ELIMINAREA

. Eliminarea produsului
. Eliminareaambalajelor:
: Degeurile trebuie eLjminate in conformitate cu reglementdrile nalionale
9i locale de mediu. Este posibile biodegradarea contro atd in tratarea
aoelor reziduale.
ln funclie de gradulii nat!ra contamindrii, se elimjnd ptin utilizarea ca
ingregdmant in ferma, ca materie primS pentru ingrdidmant iichid sau
la o instalatie de dese!fiautorizat5.
if
Nu golili in canalzafe; eliminali acest material 9i recipientul seu
condilii de siguranF giin conformitate cu toate reglemen€file locale gi
nalionale aplicabile. Catalogul eufopean al degeurilof (EWC) 06 03 14
sdrufi 9i solulii solide, altele decat cele menlionate la 06 03 11 9i 06
03 13.
Genefarea de deseufi a I trebul ev tatd sau red usb la minimum or de cate
o.i este poslb L Degeurile de ambalaje trebuie reciclaie. lncinerarea sau
depozitarea la groapa de gunol ar trebLti sd fie luate in considerare numa
aiuncicand reciclarea nu este fezabild.
Acest mateflal si recipientul s5! trebuie ellminate in conditii de
sigu'a'td Treb-ie sa se acorde ate"f- la manipLtarea recro e-leio
goale care nu au fost curSlaie sau clatite. Reclpientele goale sau
inveligufile goaie pot retine unele reziduLrride produs. Evitati
imprdgtierea materialului vd rsa1, scurgeTea si contactul cu so ul, cdlle
naviqabile, canalele de scurqere si canalele de canalizare.

Secliunea 14 - INFORMATII PRIVIND TRANSPORTUL

Clasificat ca periculos ln sensul reglementdrilor de transport din cauza compozitlei sale.

Transport terestru (ADR/RlD)

1942
. Numarul ONU:

. Denumirea 9i descderea azotat de amoniu

oficiale ONU pentru ingrdgen 6nt pe baze de azotat de amoni-
transpotti
. Denumire chimice: azotat de amoni!
. Limba: Englezd.
. Clasa de pericol pentru transport: 5.1

. Cod de clasificare: 02
. Grup de ambalarei l

. Etichete: 5.1

Numerulde identificare a pericolului :50

. Dispozi!ii speciale: Dispozilii speclale de transporit CW24, VW8
Cantitate limitaH: LQ12
Transport pe cdi navigabile interioare (ADN(R))
1942
. Numerul ONU:
2067
Denumirea gi descrierea azoiat de amoniu
oficiala ONU pentru ingrdgimant pe bazd de azotat de amoniu
transoort;
. Denumire chimice: azotat de amoniu
. Limba: Englezd. \'f lIi
/,_s"
,aq ,'': ,':
{l-tli. :o
l:c

B
 Fiqi tehnic[ de securitate azotat de amoniu

. Clasa de pericol pentru transport: 5.'1

. Cod de clasificare: 02
. Grup de ambalare: I

. Etichetei 5.t
Transpoft maritim (IMDG)
1942
. NumirulONl,J:

. Denumirea 9i descrierea azotat de amoniu

oliciala ONU pentru ingrSgdmant pe bazd de azotat de amon.-
transport:
. Denumire chimice: azotat de amoniu
. Clasa de pericol pentru transport: 5.1

. Grup de ambalare: l

. Etichete: 5.1
F-H
Numirul EmS:
S.Q
. Poluant marin: NU

Transport aerian ICAO/IATA

1942
. Numirul ONU:
2067
. Denumirea 9i descrierea azotat de amoniu
oficiald ONU pentru ingr59;ment pe baz6 de azoiat oe amoni-
transport:
. Denumire chlmicA: azotat de amoniu
. Clasa de pericol pentru transportl 5.1

. Grup de ambalare: l

. Etichete: Oxidant

. observalii Cantitate limitatd 0entru transoort.

Instructiuni de ambalare PAX 516. CAO 518.

Secliunea INFORMATIIDE
15 - REGLEMENTARE
Cl Alte ir{ormatil de r€gtementarc
. Aceastd figd tehnlce de securitate este conformd cu c€rintete Reguiamentutui (UE)2015/830.
. Reglementiri/legislatie privind siguranla, sanetatea gi mediul specifice substantei sau
amestecului :
Nu existd date disponibile.
. Starea inventarului :
componentele amestecului enumerate ln: suA (TscA), Europa (ErNEcs), Noua zeelandd (Nzloc), Firipine
(PICCS), Canada (DSL), China (IECSC), Austratia (AICS).
. Clasificarea HMIS (Slstemut O"

[",TXi:::"",1'"*''""' l4 i

Proteclie C
individuala
 Fiqi tehnici de securitate azotat de amoniu

Clasificarea NFPA
(National Fire Protection
Association):

15.2 Evaluarea securit;tii chimice:

. Furnizoful (LR) a efectuat o evaluafe a securitdtii chimice a substanteisau a amestecului - Da

Sectiunea 16 - ALTE INFORMATII

16.1 Consillere tehnice:
. Utilizali datele furnizate in aceaste figd tehnice de securitate ii faceli o liste de inventar a tuturor substanlelor
chimice utilizate in fabricdt
Creali un registrLr pentru substantele chimice de la loculde muncei
. Stabilili pr orite!le privind siguranla in cadful organizatiei;
Creali planuride urgenld pentru pericolele evaluatei
Organizatiasistenla medicale la loculde munca gianchete periodice, dupe caz:
. olganizali contacteJe cu autoritdliJe/labotatoarele pentru a crea un sistem de monitorizare a pericolelor chimice si
penifu a

. lncepeti sb colectati studii de caz privind lnfegiskarile accidentelor si ale imbolndvirilor din intreprindere pentru a
crea o baze pentru mesurile prioritafe in

. lmplicali lucr;torii in organizatiile de siguranli, cum ar fl sistemul de reprezentanti Si comitete de sigurantd;

. Efectuali inspeciii periodice folosind liste de verificare intocmite pentru anumite substante chimice si procese

. Marcaligietichetalitoaiesubstantelechimicei
. Pdstrali la indemand o listd de inventarjere a tuturor substanlelor chimice manipulate la locul de muncd, impreuni
cu o colectie de

. Pregdtili lucfdtoriisd citeasd gise inteleagd informatiile privind securitatea chimice, inclusiv pericolele

fpant\c
 Figi tehnici de securitate azottt de amoniu

expuneret instfuili-i sd manipuleze cu respect substanlele gi procesele chimice periculoase;

. Planificali, elaborali gi alegeli procedurile de lucru Tn conditiide sigufant;;
. Reduceli numerul de persoane care intrd in contact cu substante chirnice pedculoase;
r Reduceli durata gi/sau frecventa de expunere a lucrdiorilor la substante chimice periculoase;
o Insiruiti lucrdtorii se cunoasca gi sd Tnleleagd procedurile de urgenld;
. Echipali 9i instruili lucretoriisi utilizeze in mod corespunzetor echipamentul individual de proteclie dupe ce s-a
fdcut tot posibilul Dentru a
elimina pericolele prin intermediul altor metodei

'16,2 Lista mentiunllor R relevantei

Nu existi date disponibile

PHARN4EGIC HEALTHCARE LIMITED

stam p ila s i se m natu ra i nde sc ifra bi I a

TRADUCATOR
Subsemnatul ALEXANDRU TANASE, interpret si traducator autorizat pentru limba engleza in temeiul Autorizatiei
nr. 37315 din data de 14.01'2015, elibelata de Ministerul Justitiei din Romania, cedific exaatitatea traducerii. cu textul
inscrisului prezentat electlonic in limba engleza, vazut de mine si a carui fotocopie am anexat-o.
Traducator ALEXANDRU TANASE autorizat cu nr. 37315.

ffi-ffi tl!a
,o
F,//
 Safety Data Sheet
Ammonium nitrate
Section 1 - IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
1 ,1 Product identifier :

. Product name: ammonium nitfate

. Trade name; ammonium nilrate
. Substance Name i ammonium nilrate
EC Number 229-347 -8
. CAS Number : 6484 -52-2
. REACH Registration Number 01-21'l 9490981 -27-0078 (Amrnonium Nitrate)
01-21 1 9491 164-38-0073 (t\ilagnesium Nitrate)
. Chemical Formula: H3N,HNO3

il
StructuralFormula: li
t-ttt/ \o-
l'.1*

NH;

1.2 Relevant identified uses of the substances or mixture and used advised actrinat :
. Recommended use: Fert lizerc
Recommended restrictions : 0nly use as ferlilizer

1.3 Details of supplier of the safety data sheet i

. Manufacturer details
Only Representative details
: RuslaviAzot JSC
Rustavi, Georgia,
Phoner +995 34'1 270901
Email giakobashvili@rustaviazot.ge,
info@rustaviazoi.ge
: PHARI\4EGIC HEALTHCARE LII\4ITED
6th Floor, Konstjtucijos av. 21A, 08130
Vilnius, Lithuania

1,4 Emergency Telephone :

Phone: +995 341 270901

. Emergency telephone &
contact:

Section 2 - HAZARDS IDENT|FICATION

2.1 Classification of substance or mixture according to Regulation
1EC; t,to l2ZEOOa lELFfl
Physical hazard calegories and
coqes:
oxidising solids
Calegory jtH272

Human health hazard categories and

codes: Eyeirriiation Calegory 2;H3'19

2.2 Labeling according to Regulation (EC) No 1222|ZOOS (CLp):

Hazard Pictogram : Signat WoA : Warning
 Safety Data Sheet
Ammonium nitrate

GHSOT GHSO3
Exclamation mark Flame over circle
Hazard Statements : H272: Nilay ntensify fire; oxidiser,
H3'19: Causes serious eye irritalion.
Precautionary Statements : P210: Keep away from heat, hotsurfaces, spaRs, open flames and oiher
ignition soutces, No smoking.
P220: Keep/Store away from clolhing combustible materlals.
P370+P378:ln case offire: Use suitable extinguishes rnedia to exiinguish.
P264: Wash hands thoroughly after handling.
P280: Wear protective glovesiproteciive clothingieye pr0teclion/face protection.
P305+P351+P338 lF lN EYEST Rinse cautiously with water fof several
minutes. Rernovecontactlenses, if presentandeasylodo. Conlinue rinsinq.

Contactwith combustible maief ialwill increasefire hazard. l\4ay undergo

detonation if heated under confinement causing pressure buildup or if
subjected to strong shocks. Solid ammonium nilratewhen sensitized or dufing
2.3 Other hazards :
decomposition may become unslable and/ot explosive. When ammonium
nitrate is heated to decomposition, it may pf oducevaporswhich conta n
niifogen oxldes (NOx).

Section 3 - COMPOSITIO N/INFORM, \TION ON INGREDIENTS

Typical
CAS No. EC No, Concentration range

6484-s2.2 229-347-8 '95-< 99,9 e"(w/w) ees%@/w)

7732-18-5 23t-791.2 >o,1- < o,3 %(Vw) o,2 %lw/w) None

magnesium nitmte (on

conversion to MgO)
1J09.48,4 215-171-9 >o,25"<o,SS%(w/w) o,3 %(w lw)

Section 4 - FIRST AID MEASURES

4.1 Description of First Aid measures :

. General measures: Consuli aphysician. Showthissafetydala sheeltothedocior in attendance,

. Eye contaci: lmmediatelyflush eyeswith plenty ofwalerforat least 10-20 minutes,
occasionally lifting the upperand lowefeyelids.lmntediately removecontact
lenses, if the patients weafs them Gei medical aid irnmediatelv,
. Skin Contact: Remove contaminaied clothes and shoes. Flush an affected areawith 0leniv of
water, continue flushing for at least 10-20 rninutes.
Seek medical attenlion.
. lnhalation: lmmedialely remove the patientto fresh air, pr0vide absolute rest in a position
comfortable for breathing. In case ofasphyxia-apply oxygen. lfihe patient is not
breathirg, apply artificial respiratlof. Seek medical attention.
. Ingestion: 'swallowed, rinsemouth withwater(only iflhe pe|Son is conscious). Do not
rduce vomlting, Oblain medjcal attenlion if symptoms occur.

.?o
 Safety Data Sheet
Ammonium nitrate
4.2 Most important symptoms and effects, bolh acuteind dehyed :

. In allcases 0l doubt, 0rw"e" Syrnploms pe.sist, seek nedicaladvice.

. Eye conlact: redness ofeyes

'. lngeslion:abdominalpain, blue lips orfrngefnairs, convursions, drarhoea, crizziness, vomiiing, weakness.
Inhalalion: cough, headache, sorethroat.
. Other acuie and delayed effecls afe nol known.

4.3 Indication of any immediate medical attention anA spe-iit treatment needed i
' Advice to physician : ln case of ifhalation, pulmonary edema may develop. patient mustG t<ept unoer
medicar supervjsron for at reast 48 hours after exposufe, as delayed pulmonary edema may develop. substance
c0ntalns nihates, which may be reduced to nitriles by iniestinal bacteria. Nitfiles cause a fall in blood
pressure and methemog obinemia. Exposure effecl peaks wilhin 30 minules. lt,s necessary
to institute cardiac
monitoring in palienls
with pulmonary, coronary, adery diseases,

Section 5 - FIRE-FIcHTlNG MEASURES

5.l Extinguishing media :
. Suitable extinguishing media : Use plenty ofwater only,
. Smallfr|e: Non-combuslible.Thisproductcansustainc0mbustion.Water
. Largefiret N0n-combustible.Thisproductcansuslaincombustion,Waler
. Unsuitable extinguishing media : Do not use foam, C02, halogen and dry chemical.

5.2 Special hazards arising from the substance or mixture :

' [.4ay be exprosrve in contact wiih frammabre or orgar]ic substances and ai confinement
during fire.
' Combusiion pfoducls ofihis materialhave to be classed invariably as respiratory poison. ln the evenl
offife, lhe
following can be released:Arnmonia (NH3);Nltrogen oxides (NOx);carb0n dioxide (co2);cafbon
monoxide (co).

5.3 Advice for fire.fighters :

.NoSpecialmeasures|eqUi|ed'WearsuitableProtectivec|@
. Further information:
. lt is sirongly forbidden to use open flre ciose of amm on ium nitraie storage places.
. Protect against contact with othet flammable substances.
.
Section 6 - ACCIDENTAL RELEASE MEASURES

. Advice fornon- Avoid contaclwith eyesand skin by use 0fprotective equipnre_nt.

emergency Do not eal, drink, and smoke at workinq olace.
person nel: Always wash hands after handlinq.
Wash contaminatedclothinq before re-usinq.
Take care of proDer disooialoroducl
. Advice for Wear personalprolective equipment 1as mention inGction 8221.
emergency Ventilate the area.
responders: Evacuaie personnello safe afeas.

b.z Envtronmentat precautions :

@ eulrophysalion. Leakage 0f solid mak

, surface water and ground water must be prevented, because it can cause
ard colcentrated solLti0n nust be stopped. Avoid conract o, sp.ltmaler,al
w lh soriarq pfevenlrJnoft e-le ing{ 'rial
'urlace wateMays. lf spilled substance ente.s awaiefcourse, nfoin the local

\'..1-
t:l
c-
O

!AD\-\c
 Safety Data Sheet
Ammonium nitrate
authority.

6.3 Methocls and material for containment and cleaning :

. Small sDill and leak

. Vacuum orsweep up malerialand place in adesignaled,labelled waste container. Clean up aflected area with a large
amount ofwater. Do not collect spilled matefial in sawdust or olher combustible material.
. Large spill and leak
. Vacuum ofsweep up malerialand place in a designated, labelledwaste contalner. Recycle, ifpossible. Clean up
affected area wjth a large amountofwater. lfspilled substance enters a watercoufse, inform ihe localauthorily. Do not
collectspilled naterial r sawdusl of other co rbust'ble malerial.

Section 7 - HANDLING AND STORAGE

7.1
Advice on safe handling
. Advice on hygiene:
: Provide very good feed/exhaust ventilation at the workplace also n the floor
rcgjon. Forflling and lransfefiing use equipment closed as tightly as possible,
wilh exhaustventilati0n orvapoufbalancing, Avoid free falland splashing. Use
explosion-pr0tected pumps, fittings and valves, Do notfeed wilh compressed
air
Always wash hands after

Advice on protection
against fire and explosion
Keep away fom ignition sources; no smoking, no welding. Take measures
Workon containeBand pipelinesare permitted
aga inst electrostatic cha rge.
onlyafterihorough puqing and ineding. Emergency cooling muslbe available
in case oinearby frre, Flammable gas-aif mixtures may beformed in empty

7.2 Conditions for safe storage :

. Keepcontainertightlyclosed.Keepcontainerinacool well-venlllaled area. Separale from acids alkalles,r€ducing

agenls and combuslibles.
. Locaie storage away from possible sources 0lheat, flre orexplosion, s!ch as oilstorage, gas pipelines, timberyards,
flammable liquids, flammable solids and combustib!e rnaterials.

7.3 Specific end

As mention in section 1.2.

Section I- EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
European Union (Directive 2000/39/EC): ammonium nltrate is nol listed.
Exposure limits values: ACGIH-American Conference of covernmenial lndustdal Hv0ienisls : none
listed. In accordance with local

8.2 Exposure control :

8.2.1 Appropriate engineering controls :

. Engineeringmeasures: Use process enclosures, local exhaust ventilation or other engineeting

controlsto keep aiborne levels below recommended exposure llmils.lfuser
operalions generale dust, fume of mist, use ventilation to keep exposute t0
airb0rne contaminants below ihe ex0osure limit,
ndividual protection measures :
 Safety Data Sheet
Ammonium nitrate
Respiratory Protection : lf high dust concentrati0n is high and/or ventilation ls inadequale, use
suitable dusl mask or respiralorwilh an approprlate llltef (EN 143, 149, iltefs
P2, P3).
Hand Protection Wear suitable gloves (e.9, plastic, rubber or leaiher) when handling the
producl over long periods,
Eye protection : WeaI lightly filling safely goqgles \EN 166)
. Skin protection : Wear appropriate proteciive gloves to ptevenl skin exposure.
. Hygiene measures : When using do noieat, drink orsmoke. Wash hands afier handllng
compounds and before eating,smokingand using ihe lavatory and althe
end of the dav
8.2,3 Environmental exDosure controls :

. Leakage ofproductshould be cleaned up prompilyand placed in aclean labelled conlainerforsafe disposal. D0 not
mix wilh sawdust and other combusljble of organic substances. Dilute with water or ined materials such as
llmestone/dolornite, mineral ph0sphate, gypsum, sand. Take care to avoid ihe contamination of watercourses and
drains. Large amount oileakage into dlains, surface water and ground waiet must be prevenied, because il can cause
eutroDhvsaiion.

Section 9 - PHYSICAL & CHEMICAL PROPERTTES

9.1 Information on basic physical and chemical properties :

' Appearance; White hygroscopic crystals

. Odour Odorless
. Odour threshold : Not applicable,
. pH (10% soln/water): 5,0 -6,0
. Melting point/Freezing point: 169 'C
. Initial boiling point& boiling Approx. 210'C (decomposes)
range:
. Flash point: Non flammable
. Evaporation rate: Nol available
Not combustible butenhances combustion of olhersubstances. When
. Flammability: healed lo 210'C decomposes. Hazardous decomposiijon products can
includeammonia, oxides of n,troger and nificacid. Gives 0f rritating o.
toxic fumes (or gases) in a fire.
Upper/lower flammability or
Not available
explosive limits :
. Vapour pressure : Not available
Vapour density ; Noi available
. Relaiive density : 1,6S0-1 .725 g/crn3 (20 "C)
' Water solLrbilityl
1189/100rnl(0'C)
150 g/100 ml (20 "C)
. Solubility(ies) : 297 g/100 mt (40 "C)
410 g/100 mt(60"c)
5769/100 mt(80 "C)
. Slighlly soluble in melhanol, acelone
. Partition coefficient: n- Not available
octanol/water

. Auto-ignitiontemperature: Not available

. Decompositiontemperature: 21l',C
 Safety Data Sheet
Ammonium nitrate

9.2 Other information i None

Section 10 - STABILITY AND REACTIVITY

No specific lesl dala related to feactivity available for this prod!ct or its

Chemical stability: Stable underrecommended slorageand handling conditions (see section

Wren handled and stored approprialely no dangerous reaclions are

Conditions to avoid : Heating above 170'C (decomposesto gases). Closeness to sources ofheat
oI file Healing underconf inernent.
Contamination by incompatible maiefials. Unnecessaryexposuretothe

. Hazardousdecomposition strongly heated,lt melis and dec0mposes releasjng toxicfumes (e.9.

prooucls:
Incompatible materials
r itroger or'des (NO, \02), amnonia), Wne r in contactw l" al^ali'te
rnaterlal such as lime, mav qive off ammonia
Reducing agenis, strong acids and bases, metalpowders, comt
:
materials, chromates zinc, coppefand copper allovs chlorales.

Section 11 - TOXICOLOGICAL INFORMATION

11.1 lnformation on

Ammonium nitrate

LCo - > 88.8 other: mg/L

Speciesj Rat

LD50 -> 5000 mg/kg bw

Eye: lvloderately irritating

Skin: Not irritating

11.3 Sensitization :

. Skin: Not expected to besensitiz'rg.

11.4 CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction) I

rTrF/

,,3. &,cP (,r\

c I.-'.$9,,;P ct

11 . *,'S1 rP
5
sa-//
 Safety Data Sheet
Ammonium nitrate
. Mutagenic effects : Not classified as a mutagen.
. Reprotoxic effects: Noi found to be reprotoxic.

11.5 Other toxic elfects on humans .

. lnhalation: No data available.

. Eyes: No data available.
. Ingestion: No dala available.
. Chronic toxicity: No daia available.

11.6 Specific target organ toxicity :

No experimenlal orepidemiologicalsulficientevidence forspecillctarget

Single exposure:
organ toxiciiy.
Repeated exposure: Noexperimenlalorepidemiologicalsufficienlevidenceforspecifictargei
organ loxicity.

11.7 Aspiration hazard : No data available.

Section 12 - ECOLOGICAL INFORMATTON

12.1 Ecotoxicity :

Toxicity type Short-term toxicily io fish Long-term loxicjty to aqualic Toxicity to aquatic algae and
invertebrates cyanobactefia
Species Cypfinus carpio Bullia digitalis Scenedesmus quadricauda

Time scale 48h 7d

End point LC50 EC50 EC50
Effect level 447 nglL 555 mg/L 83 mg/L

12,2 Persistence and degradability :

According to Annex XlllofRegulation (EC) No 1907/2006, no pBT and vpvB assessmenthas been conducled.
The substance is an norganic organic substance.

1 2.3 Bioaccumulative Dotential

PBT assessment does notapply.

12.4 Mobility in soil :

Informaiion not available for finalproduct.

12.5 Results of PBT and vPvB assessment :

PBT assessment does noiapply,

12,6 Other adverse effects :

 Safety Data Sheet
Ammonium nitrate
Section 13 - DISPOSAL CONSIDERATIONS
. Disposal of product:
Disposal of packaging :
Section 14 - TRANSPORT INFORMATION
Classified as dangerous in the meaning of transpod regulations due to its c0mposition.
Land transport (
UN proper shipping
name and description:
. Special Provisions:
lnland waterway transport (ADN(R))
LJN proper shipping
name and description:
Waste mustbedisposedof ln accotdancewilh nationaland local
environmental teg!lations. Contfolled biodegradation inwastewater
trealment s possible.
Depending on degree and nature ofcontamination dispose ofby use as
fedilizeron farm, as raw matefial for liquid fertjlizer, orto an authorlzed
waste facilily.
Do nol empty inio drains;dispose ollhis malerialand its container in a safe
way and in accordancewith allappl cable local and nalional reguiatons.
European waste calalogue (EWC)06 03 14 solid salts and solulions othef
than those mentioned in 06 03 11 and 06 03 13.
The generation 0fwasle should be avoided or minimisedwhereverpossible.
Waste packaging should be fecycled, lncineration of landfill sh0uld only be
considered when recycling is not feasible.
This rnatefialand itscontainermusl bedisposed ofin a safeway. Care
should betakenwhen handlingemplied containersthathavenolbeen
cleaned orrinsed out. Emply containets ofliners may relain some prcducl
residues. Avoid dispersal of spilt material and runoff and c0ntactwiih soll,
waieMavs, drains and sewefs.
ammonium nltrate
ammonium nitrate based ferlilizef
Specialtranspoft pr0visions: CW24,VW8
1942
2467
ammonium nihate based ferlilizer
Tz,rsrittsr1
3')" *q.q'{$ )
fu_ffi9
eTm tdilcb)
 Safety Data Sheet
Ammonium nitrate
. Transport hazard class: 5.1
. Classification code: o2
. Packing group: l

Labels: 5,1

Marine transport (IMDG)

1942
. UN Number:
2067
UN proper shipping ammonium nikate
name and description: ammonium nilrate based fertilizer
Chemical name: ammonium nitrate
Transport hazard class: 5,1

Packing group: l

Labels: 5.1

. EmS number:
F-H
s-Q
. Marine pollutant: No
Air transport ICAO/IATA
1942
UN Number:
2067
. UN proper shipping arnmonium nihale
name and description: ammonium nitrale based fertilizer
. Chemical name: ammonium nitrate
. Transport hazard class: 5.1
Packing group: l
. Labels: Oxidizer

. Remarks Limiied quantity for transportation.

Package instructions PAX516, CAO 518.

Section REGULATORY
15 - INFORMATION
15.1 Other Regulatory informalion :

. This safely datasheet complies with the req uiremenis of Regulation (EU) 20'15/830.
. Safety, health and environmental regulations/legislation specific for the substance or
mlxture:
No data available.
. Inventory Status :
Components of mixture listed in:US (TSCA), Europe (EINECS), NewZealand (NZloC), philippines (plCCS), Canada
(DSL), China (IECSC), Australia (AtCg).
HMIS (Hazardous Materials
ldentif ication System)
classification:

Personal
Protection
 Safety Data Sheet
Ammonium nitrate

NFPA (National Fire

Protection Association)
classification:

1 = Nomally stable, bul can become unstable ai

glevated temperalures and 0ressures

. A chem icalsafety assessment has been carried oul forthe subslance otthe m ixture by lhe supplier (LR) - Yes

Section 16 - OTHER INFORMATION

. Use data given in th is Safety Data Sheel and make an inventory list of all chemica ls used in the factory;
. Create a Regisief for WoftplaceChemicals;
. Set priofities concerning lhe safety in the organization;
. Create emergency plans for the assessed hazards;
Organize occupational health care and regular surveys as necessaryi
. Organize contacts wilh authorities/laboraiories to create a monitoring system fof chemical hazards, and to reliabiy
measure and/or eslimate occupational exposures to chemicals when neededi
. Startcollecting case studies 0faccidentsand sickness rec0rds in the enterpriseto cfeate a basisforp oritymeasuresin
the contfol of hazards:
. Involve workers in safety organizations, s uch as the system of Safety Representaiives and Com mifiees;
. Do fegular inspection using checklists madeforthe particular chemicals and chem icalprocesses in use;
Mafk and label allchemicals;
. Keep at hand an inventory list ofallchem icals handled in the place ofworktogetherwith a collection ofChem icalS afety
Daia Sheeis for these chemicals:
. Train workers to read and undersland the Chemical Safety Information, jncluding the heallh hazards and routes
 Safetv Data Sheet
Ammonium nitrate
exposurel lrain them to handle dangerous chemicals and processes wllh respect;
Plan, develop and choose the safe working proceduresi
. Red uce the number of people coming inio contact with dangefous chem icals;

Reduce the length of time and/or frequency of exposure ofworkers io dangerous chemicals;
. Train wofters to know and understand the emefgency procedures;
. Equ ip and train workers io use personal protective equipmenl properly after everything poss ible has been done lo
eliminate hazards by means of other methods;

16.2 List of relevant R phrases;

Not available

Created 8yl
PHARMEGIC HEALTHCARE LIITI|TED

fl"-*s