Evaluarea globala a filierelor energetice

Filiera A: Arderea carbunelui in stare pulverizata+turbina cu abur in condensatie

Filiera B:Ciclul combinat gaze-abur
Filiera C:Arderea biomasei in stare pulverizata+turbina cu abur in condensatie

Compozitia elementara a carbunelui este:

C_i= 0.44
H_i= 0.036
N_i= 0.014
O_i= 0.011
S_i= 0.045
W_i= 0.19
A_i= 0.264

Compozitia elementara a biomasei este:

C_bi= 0.38
H_bi= 0.03
N_bi= 0.007
O_bi= 0.014
S_bi= 0.04
W_bi= 0.29
A_bi= 0.239

Compozitia naturala a gazului natural este:

CH4= 0.808
C2H6= 0.027
C3H8= 0.039
C4H10= 0.036
C5H12= 0.04
H2S= 0.0064
CO2= 0.0436

Distanta de transport pentru fiecare resursa energetica de la sursa de extractie la producator este:
Carbune: d_c= 450 km
Gaz natural d_g= 2200 km
Biomasa d_bi= 1 km
n= 20
ng= 10
1). Determinarea unitatii functionale pe bza cerintelor consumatorului

Nr_pers= 17500 om
E_pers/an= 4.5 MWh/an*om Energia consumata de o persoana pe o perioada de 1an
E_an= 78750 MWh/an Energia anuala ceruta de consumator
UF= 78750 MWh Unitatea functionala
d_af= 4250 h/an Durata anuala de functionare pentru instalatia energetica
P_bg= 18.52941 MW Pierderile de energie din retea
2). Determinarea necesarului de combustibil pentru fiecare filiera energetica si etapa

Etapa de producere a energiei : Etapa de transport a combustibilului:

A) ηc_c= 0.38 A) ηtp_c= 0.78
ηc_gn= 0.6 B) ηt p_gn
= 0.91
ηc_b= 0.36 C) ηtp_b
= 0.73

Etapa de extractie a combustibilului: Etapa de tratare a combustibilului:

A) ηex_c= 0.82 A) ηtr_c= 0.91
B) ηex_gn
= 0.95 B) ηtr_gn= 0.92
C) ηex_b
= 0.78

Determinarea puterii calorifice inferioare pentru carbune si biomasa tinand cont de compozitia acestora:
Hii_c= 18980.17 kJ/kg
Hii_b= 15907.07 kJ/kg

Determinarea puterii calorifice inferioare a gazului natural :

∑_(𝑠=1)^�▒(𝑋𝑗𝑖∗𝐻𝑖𝑖_𝑗
Hii_gn=) 45196.765 kJ/m3
Puterea calorifica inferioara a comp
Hii_CH4=
Densitatea gazului natural: Hii_C2H6=
ρ_gn= 1.006425 kg/m3 Hii_C3H8=
Hii_C4H10=
Determinarea puterii calorifice inferioare raportata la 1kg de gaz natural: Hii_C5H12=
Hii_gn1= 44908.25 [KJ/Kg] Hii_H2S=

Masa de combustibil in etapa de combustie pentru asigurarea necesarului de energi al consumatorului:

Filiera A M_c= 39306947.715 kg
Filiera B M_gn= 10521452.205 kg
Filiera C M_b= 49506301.411 kg

Masa de combustibil in etapa de transport pentru asigurarea necesarului de energie al consumatorului:

Filiera A M_tpc= 50393522.712 kg
Filiera B M_tpgn= 11562035.39 kg
Filiera C M_tpb= 67816851.248 kg

Masa de combustibil in etapa de tratare pentru asigurarea necesarului de energie al consumatorului:

Filiera A M_trc= 55377497.486 kg
Filiera B M_trgn= 12567429.771 kg
Filiera C M_trb= 0 kg
Masa de combustibil in etapa de extractie pentru asigurarea necesarului de energie al consumatorului:
Filiera A M_exc= 67533533.519 kg
Filiera B M_exgn= 13228873.444 kg
Filiera C M_exb= 86944681.087 kg
orifica inferioara a componenteleor gazului natural Masele molare pentru componentele gazului natural
35774 kJ/m3 M_CH4= 16 g/mol
63669 kJ/m3 M_C2H6= 30 g/mol
91138 kJ/m3 M_C3H8= 44 g/mol
118498 kJ/m3 M_C4H10= 58 g/mol
160000 kJ/m3 M_C5H12= 72 g/mol
55000 kJ/m3 M_CO2= 44 g/mol
M_H2S= 34 g/mol
Vm= 22.414 l/mol volum in condtii normale al gazelor
condtii normale al gazelor
3). Analiza de inventar pe ciclul de viata al resurselor energetice analizate

Filiera de carbune:
Extractie: Tratare: Transport:
NH3_exc= 0.0554 g/kg NH3_tr_c= 0.0305 g/kg NH3_tp_c=
CO2_ex_c= 5.243 g/kg CO2_tr_c= 5.34 g/kg CO2_tp_c=
CO_ex_c= 0.00781 g/kg CO_tr_c= 0.00722 g/kg CO_tp_c=
HCL_ex_c= 2.31E-09 g/kg HCL_tr_c= 4.05E-09 g/kg HCL_tp_c=
HF_ex_c= 0.000000003 g/kg HF_tr_c= 5.86E-09 g/kg HF_tp_c=
H2S_ex_c= 1.63E-09 g/kg H2S_tr_c= 1.72E-09 g/kg H2S_tp_c=
CH4_ex_c= 0.7591 g/kg CH4_tr_c= 0.00858 g/kg CH4_tp_c=
Nox_ex_c= 0.0331 g/kg Nox_tr_c= 0.0313 g/kg Nox_tp_c=
N2O_ex_c= 0.000592 g/kg N2O_tr_c= 0.000742 g/kg N2O_tp_c=
Pr_ex_c= 0.01689 g/kg Pr_tr_c= 0.00243 g/kg Pr_tp_c=
SO2_ex_c= 0.0812 g/kg SO2_tr_c= 0.0212 g/kg SO2_tp_c=

Filiera de gaz natural:

Extractie: Tratare: Transport:

C6H6ex_gn= 0.054 g/kg C6H6_tr_g 0.324 g/kg C6H6tp_gn
CO2_ex_gn= 78.12 g/kg CO2_tr_gn 30 g/kg CO2_tp_gn
CO_ex_gn= 0.1024 g/kg CO_tr_gn= 0.1318 g/kg CO_tp_gn=
CH4_ex_gn= 4.201 g/kg CH4_tr_gn 4.42 g/kg CH4_tp_gn
Nox_ex_gn= 0.512 g/kg Nox_tr_gn 0.311 g/kg Nox_tp_gn
NO2_ex_gn= 0.000985 g/kg NO2_tr_gn 0.00072 g/kg NO2_tp_g
Pr_ex_gn= 0.0601 g/kg Pr_tr_gn= 0.035 g/kg Pr_tp_gn=
SO2_ex_gn= 0.184 g/kg SO2_tr_gn 1.06 g/kg SO2_tp_gn

Filiera de biomasa:

Extractie:
NH3_ex_b= 0.022 g/kg Transport: Combustie:
CO2_ex_b= 138.93 g/kg CO2_tp_b= 1.909 g/kg*km CO2_c_b=
CO_ex_b= 0.071 g/kg CO_tp_b= 0.000257 g/kg*km CO_c_b=
HCL_ex_b= 0.000000208 g/kg HCL_tp_b= 7.6E-11 g/kg*km HCl_c_b=
HF_ex_b= 1.042E-07 g/kg HF_tp_b= 3.13E-10 g/kg*km HF_c_b=
H2S_ex_b= 6.28E-09 g/kg H2S_tp_b= 3E-11 g/kg*km H2S_c_b=
CH4_ex_b= 0.00324 g/kg CH4_tp_b= 5.49E-06 g/kg*km CH4_c_b=
Nox_ex_b= 0.08977 g/kg Nox_tp_b= 0.000678 g/kg*km Nox_c_b=
N2O_ex_b= 0.004426 g/kg N2O_tp_b 4.7E-06 g/kg*km NO2_c_b=
Pr_ex_b= 0.0197 g/kg Pr_tp_b= 0.000159 g/kg*km Pr_c_b=
SO2_ex_b= 0.0186 g/kg SO2_tp_b=0.000234 g/kg*km SO2_c_b=
Transport: Combustie:
0.00012645 g/kg*km NH3_c_c= 0.000281 g/kg
21.15 g/kg*km CO2_c_c= 1403.187 g/kg
3.249 g/kg*km CO_c_c= 0.2137 g/kg
1.0395E-07 g/kg*km Hg_c_c= 4.67E-05 g/kg
1.008E-08 g/kg*km HCl_c_c= 2.96E-06 g/kg
3.3615E-10 g/kg*km HF_c_c= 2.299E-07 g/kg
0.001458 g/kg*km H2S_c_c= 1.049E-08 g/kg
0.24885 g/kg*km CH4_c_c= 0.01063 g/kg
0.0003717 g/kg*km Nox_c_c= 4.4639 g/kg
0.02259 g/kg*km NO2_c_c= 0.00629 g/kg
0.14085 g/kg*km Pr_c_c= 19.198 g/kg
SO2_c_c= 13.2598 g/kg

Transport: Combustie:
0.007018 g/kg*km NH3_c_gn 0.217 g/kg
849.2 g/kg*km C6H6_c_gn 0.0596 g/kg
5.038 g/kg*km CO2_c_gn 2724.44 g/kg
19.448 g/kg*km CO_c_gn= 0.234 g/kg
8.47 g/kg*km CH2O_c_g 0.064 g/kg
0.01562 g/kg*km CH4_c_gn= 4.012 g/kg
0.118338 g/kg*km Nox_c_gn= 0.773 g/kg
1.4696 g/kg*km Pr_c_gn= 0.54 g/kg
SO2_c_gn= 0.0508 g/kg

Combustie:
910.32 g/kg
0.00435 g/kg
0.00000237 g/kg
1.77E-07 g/kg
7.06E-09 g/kg
0.000389 g/kg
0.479 g/kg
0.000299 g/kg
0.0203 g/kg
0.262 g/kg
4). Recalcularea emisiilor din analiza de inventar : extractie, tratare, transport si combustie :

M_exc= 67533533.519 kg M_trc= 55377497.49 kg

Carbune
Extractie: Tratare:
NH3_exc= 3741357.757 g/U.F NH3_tr_c= 1689013.673 g/U.F
CO2_ex_c= 354078316.24 g/U.F CO2_tr_c= 295715836.6 g/U.F
CO_ex_c= 527436.89679 g/U.F CO_tr_c= 399825.5318 g/U.F
HCL_ex_c= 0.1560024624 g/U.F HCL_tr_c= 0.224278865 g/U.F
HF_ex_c= 0.2046266066 g/U.F HF_tr_c= 0.324512135 g/U.F
H2S_ex_c= 0.1100796596 g/U.F H2S_tr_c= 0.095249296 g/U.F
CH4_ex_c= 51264705.295 g/U.F CH4_tr_c= 475138.9284 g/U.F
Nox_ex_c= 2235359.9595 g/U.F Nox_tr_c= 1733315.671 g/U.F
N2O_ex_c= 39979.851843 g/U.F N2O_tr_c= 41090.10313 g/U.F
Pr_ex_c= 1140641.3811 g/U.F Pr_tr_c= 134567.3189 g/U.F
SO2_ex_c= 5483722.9218 g/U.F SO2_tr_c= 1174002.947 g/U.F

M_exgn= 13228873.444 kg M_trgn= 12567429.77 kg

Gaz natural
Extractie: Tratare:
C6H6ex_gn= 714359.16595 g/U.F C6H6_tr_g 4071847.246 g/U.F
CO2_ex_gn= 1033439593.4 g/U.F CO2_tr_gn 377022893.1 g/U.F
CO_ex_gn= 1354636.6406 g/U.F CO_tr_gn= 1656387.244 g/U.F
CH4_ex_gn= 55574497.336 g/U.F CH4_tr_gn 55548039.59 g/U.F
Nox_ex_gn= 6773183.2031 g/U.F Nox_tr_gn 3908470.659 g/U.F
NO2_ex_gn= 13030.440342 g/U.F NO2_tr_gn 9048.549435 g/U.F
Pr_ex_gn= 795055.29395 g/U.F Pr_tr_gn= 439860.042 g/U.F
SO2_ex_gn= 2434112.7136 g/U.F SO2_tr_gn 13321475.56 g/U.F

Biomasa
M_tpb= 67816851.248 kg M_cb= 49506301.41 kg
Transport: Combustie:
CO2_tp_b= 129462369.03 g/U.F CO2_c_b= 45066576300 g/U.F
CO_tp_b= 17428.930771 g/U.F CO_c_b= 215352.4111 g/U.F
HCL_tp_b= 0.0051540807 g/U.F HCl_c_b= 117.3299343 g/U.F
HF_tp_b= 0.0212266744 g/U.F HF_c_b= 8.76261535 g/U.F
H2S_tp_b= 0.0020345055 g/U.F H2S_c_b= 0.349514488 g/U.F
CH4_tp_b= 372.31451335 g/U.F CH4_c_b= 19257.95125 g/U.F
Nox_tp_b= 45979.825146 g/U.F Nox_c_b= 23713518.38 g/U.F
N2O_tp_b= 318.46793346 g/U.F NO2_c_b= 14802.38412 g/U.F
Pr_tp_b= 10762.534293 g/U.F Pr_c_b= 1004977.919 g/U.F
SO2_tp_b= 15848.798137 g/U.F SO2_c_b= 12970650.97 g/U.F
e, transport si combustie :

M_tpc= 50393522.712125 kg M_c_c= 39306947.71546 kg

Transport: Combustie:
NH3_tp_c= 6372.2609469482 g/U.F NH3_c_c= 11045.25230804 g/U.F
CO2_tp_c= 1065823005.3615 g/U.F CO2_c_c= 55154998044.01 g/U.F
CO_tp_c= 163728555.2917 g/U.F CO_c_c= 8399894.726793 g/U.F
HCL_tp_c= 5.2384066859 g/U.F Hg_c_c= 1835.634458312 g/U.F
HF_tp_c= 0.5079667089 g/U.F HCl_c_c= 116.3485652378 g/U.F
H2S_tp_c= 0.0169397827 g/U.F HF_c_c= 9.0366672798 g/U.F
CH4_tp_c= 73473.756114278 g/U.F H2S_c_c= 0.4123298815 g/U.F
Nox_tp_c= 12540428.126912 g/U.F CH4_c_c= 417832.8542153 g/U.F
N2O_tp_c= 18731.272392097 g/U.F Nox_c_c= 175462283.907 g/U.F
Pr_tp_c= 1138389.6780669 g/U.F NO2_c_c= 247240.7011302 g/U.F
SO2_tp_c= 7097927.6740028 g/U.F Pr_c_c= 754614782.2414 g/U.F
SO2_c_c= 521202265.3174 g/U.F

M_tpgn= 11562035.389628 kg M_c_gn= 10521452.20456 kg

Transport: Combustie:
C6H6tp_gn= 81142.364364407 g/U.F NH3_c_gn 2283155.12839 g/U.F
CO2_tp_gn= 9818480452.8718 g/U.F C6H6_c_gn627078.5513918 g/U.F
CO_tp_gn= 58249534.292944 g/U.F CO2_c_gn 28665065244.19 g/U.F
CH4_tp_gn= 224858464.25748 g/U.F CO_c_gn= 2462019.815867 g/U.F
Nox_tp_gn= 97930439.750146 g/U.F CH2O_c_g 673372.9410919 g/U.F
NO2_tp_gn= 180598.99278598 g/U.F CH4_c_gn= 42212066.2447 g/U.F
Pr_tp_gn= 1368228.1439378 g/U.F Nox_c_gn=8133082.554126 g/U.F
SO2_tp_gn= 16991567.208597 g/U.F Pr_c_gn= 5681584.190463 g/U.F
SO2_c_gn=534489.7719917 g/U.F

M_exb= 86944681.087091 kg
Extractie:
NH3_ex_b= 1912782.983916 g/U.F
CO2_ex_b= 12079224543.43 g/U.F
CO_ex_b= 6173072.3571835 g/U.F
HCL_ex_b= 18.0844936661 g/U.F
HF_ex_b= 9.0596357693 g/U.F
H2S_ex_b= 0.5460125972 g/U.F
CH4_ex_b= 281700.76672218 g/U.F
Nox_ex_b= 7805024.0211882 g/U.F
N2O_ex_b= 384817.15849147 g/U.F
Pr_ex_b= 1712810.2174157 g/U.F
SO2_ex_b= 1617171.0682199 g/U.F
5). Determinarea emisiilor in etapa de combustie
Emisiile calculate sunt : CO2;praf;SO2;Nox

Determinarea emisiilor anuale CO2:

MCO2= (M_CO2*Ci*M_comb)/M_c unde

MCO2_c= 58226691.882 In cazul arderii carbunelui Ci=40,4%

MCO2_bi= 64077656.126 In cazul arderii biomasei Ci=35,3%

Gaz natural
Masa amestecului:
Mam= 22.558 g/mol

Participatiile gravimetrice:
GCH4= 0.5731004522
GC2H6= 0.0359074386
GC3H8= 0.0760705736
GC4H10= 0.0925613973
GC5H12= 0.1276708928
GH2S= 0.0096462452
GCO2= 0.0850430003 Gtotal= 1

Continutul de carbon:
C_gni= 0.7269793421

Continutul de hidrogen:
H_gni= 0.2020923841 1

Continutul de sulf:
S_gni= 0.009078819

Continutul de oxigen:
O_gni= 0.0618494547

Cantitatea anuala de carbon generata in mediul ambiant:

Carbune: CO2_c_cal= 7.70534E+13
Biomasa: CO2_bi_cal= 9.3317E+13
Gaz natural: CO2_gn_cal= 1.78766E+13

Determinarea emisiilor de Nox, in functie de tipul de combustibil:

Gaz natural:
coeficient dependent de natura combustibilului :β1=0,85 0.85
coeficient ce tine cont de gradul de recirculare al gazelor de ardere:β2=0,03
coeficient ce tine cont de tipul de arzator utilizat: β3=0,85 0.85
Gradul de recirculare al gazelor de ardere :r=0,25-0,005*n=
Se considera debitul nominal de abur:D=70-2*n= 30
Coeficient de sarcina: K=(3,5*D)/70tone/h)*(kg/J)= 1.5
Pierderile de caldura prin ardere incompleta chimic: q4=3,9 3.9
Mgaz=Mgn*1/an 10521452.2 Bgn=Mgaz/daf 0.687676615

Nox_cal_gn=(0,034*10^-6)*β1*K*Bgn*Hii_gn*(1-0,01*q4)*(1-β2*r)*β3
Nox_gn=Nox_cal_gn*daf 16.65614498 tone/an
Nox_c_gn_r=Nox_gn*an 16.65614498 (tone)

Carbune:
Pentru determinarea emisiilor de Nox in cazul arderii carbunelui/biomasei trebuie definite urmatoarele marimi:
Temperatuar teoretica : Tgt= 1900-2.5*n 1850
Temperatura gazelor de ardere la iesirea din focar : Tg0 = 1300-2.5*n
Temperatura flacarii se stabileste cu relatia:
Tfl= 0.925*(Tgt*Tg0)^0.5 = 1406.638835
Excesul de aer in focar : λf= 1.4
Excesul de Nox se determina cu relatia :
Nox_cal=Bc*Hii*Knox /1000
Knox=Knox_t+Knox_c = 0.652380805 (kg/GJ)
Emisia de Nox termic se determina cu relatia :
Knox_t=(0.45*10^16*exp(-64500/Tfl)*((λf-1)/λf)^0.5)/Tfl^0.5
Pentru determinarea emisiei raportate de Nox din combustibillul se va calcula in prealabil urmatorii parametrii:
a). Continutul de azot raportat Xn= N_i/Hii_c =
OBS. Continutul de azot se introduce in valoare absoluta iar puterea calorifica inferioara in GJ/Kg.
b). Coeficientul de influenta a excesului de aer (arzator turbionar)
ελ_c=(0.35*λf+0.4)^2 = 0.7921
c). Coeficientul de influenta a proportiei de aer primar:
proportia de aer primar in arzatoare este p= 0.2
εp_c=1.73*p+0.48 = 0.826
d). Coeficientul de influenta a gradului de recirculare r= 0.24
εr=1-0.016*r^0.5 0.992161633
e). Coeficientul de influenta a temperaturii flacarii :
εθ=0.11*(Tfl-1100)^(1/3) = 0.7417685297
Kw= 2.4
εw=0.4*Kw^2+0.32 2.624
Knox_c=0.7*Xn*ελ_c*εp_c*εr*εθ*εw = 0.652380024
Mcar=M_c/an= 39306.94772 (tone/an)
B_c=Mcar/daf= 2.56908155 (kg/s)
Nox_calc_c=B_c*Hii_c*Knox= 31.8111383334 (gr/s)
Nox_calc=Nox_calc_c*daf= 486.710416501 (tone/an)
Nox_c_c_r=Nox_calc*an= 486.710416501 (tone)
Biomasa:
Pentru determinarea emisiilor de Nox in cazul arderii carbunelui/biomasei trebuie definite urmatoarele marimi:
Temperatuar teoretica : Tgt= 1900-2.5*n 1850
Temperatura gazelor de ardere la iesirea din focar : Tg0 = 1300-2.5*n
Temperatura flacarii se stabileste cu relatia:
Tfl= 0.925*(Tgt*Tg0)^0.5 = 1406.638835
Excesul de aer in focar : λf,b= 1.35
Excesul de Nox se determina cu relatia :
Nox_cal=Bc*Hii*Knox /1000
Knox=Knox_t+Knox_c = 0.374052400 (kg/GJ)
Emisia de Nox termic se determina cu relatia :
Knox_t=(0.45*10^16*exp(-64500/Tfl)*((λf-1)/λf)^0.5)/Tfl^0.5
Pentru determinarea emisiei raportate de Nox din combustibillul se va calcula in prealabil urmatorii parametrii:
a). Continutul de azot raportat Xn= N_bi/Hii_bi =
OBS. Continutul de azot se introduce in valoare absoluta iar puterea calorifica inferioara in GJ/Kg.
b). Coeficientul de influenta a excesului de aer (arzator turbionar)
ελ_c=(0.35*λf+0.4)^2 = 0.76125625
c). Coeficientul de influenta a proportiei de aer primar:
proportia de aer primar in arzatoare este p= 0.2
εp_c=1.73*p+0.48 = 0.826
d). Coeficientul de influenta a gradului de recirculare r= 0.24
εr=1-0.016*r^0.5 0.992161633
e). Coeficientul de influenta a temperaturii flacarii :
εθ=0.11*(Tfl-1100)^(1/3) = 0.7417685297
Kw= 2.4
εw=0.4*Kw^2+0.32 2.624
Knox_c=0.7*Xn*ελ_c*εp_c*εr*εθ*εw = 0.374051655
Mcar=M_b/an= 49506.30141 (tone/an)
B_b=Mcar/daf= 3.235705975 (kg/s)
Nox_calc_b=B_c*Hii_b*Knox= 19.2526970572 (gr/s)
Nox_calc=Nox_calc_b*daf= 294.5662649753 (tone/an)
Nox_b_b_r=Nox_calc*an= 294.5662649753 (tone)

Determinarea emisiilor de SO2 :

Pentru determinarea emisiilor de oxizi de sulf se tine cont de continutul de sulf din combustibil, dar si de fractia de oxizi de sulf
respectiv absortia si evacuata in mediul ambiant odata cu cenusa zburatoare.
Valorile pentru fractiile de oxizi de sulf in cele doua cazuri sunt :
ηel= 0 se considera ca instalatia de desprafuire este reprezentata de un electrofiltru
ηev_c= 0.2
ηev_b= 0.15
ηev_gn= 0

Carbune :
SO2_calc_c=20*S_ci*B_c*(1-ηel)*(1-ηev_c)= 1.849738716
SO2_c=SO2_calc_c*daf= 28301.00236 (tone/an)
SO2_c_c_r=SO2_c*an= 28301.00236 (tone)
Biomasa:
SO2_calc_b=20*S_bi*B_b*(1-ηel)*(1-ηev_b)= 2.200280063
SO2_c=SO2_calc_c*daf= 33664.28496 (tone/an)
SO2_c_c_r=SO2_c*an= 33664.28496 (tone)

Gaze naturale:
SO2_calc_gn=20*S_gni*B_gn*(1-ηel)*(1-ηev_gn)= 0.124865831
Mcar=M_gn/an= 10521.4522 (tone/an)
B_gn=Mcar/daf= 0.687676615 (kg/s)
SO2_c=SO2_calc_c*daf= 1910.447213 (tone/an)
SO2_c_c_r=SO2_c*an= 1910.447213 (tone)

Determinarea emisiilor de praf : (fara gaze naturale)

Pentru determinarea cantitatii de particule generate in mediul ambiant se foloseste urmatoarea relatie :
a). Pierderea de caldura prin ardere incompleta : q4= 3.9
b). Gradul de retinere in instalatia de desprafuire : ηd= 0.995
c). Fractia de cenusa antrenata : aantr= 0.3

Carbune:
Pc=10*(1-ηd)*(A_i +q4*Hii_c/32700)*aantr*B_c= 0.097407636
Pcalc_c=Pc*daf= 1490.336826 (tone/an)
Pr_c_c_r=Pcalc_c*an= 1490.336826 (tone)

Biomasa:
Pc=10*(1-ηd)*(A_i +q4*Hii_b/32700)*aantr*B_b= 0.103680416
Pcalc_b=Pc*daf= 1586.310366 (tone/an)
Pr_b_b_r=Pcalc_b*an= 1586.310366 (tone)
M_CO2 este masa molara a CO2; Ci este continutul de carbon; M_comb este masa de combustibil;M_C este masa molara a car

MCO2_gn= 28045887.5 [Kg]

 0.03

0.15
tone/h
kg/J

(kg/s)

0.001088637 [g/s]

masei trebuie definite urmatoarele marimi:

K
1250 K

0.000000782 (Kg/GJ)
va calcula in prealabil urmatorii parametrii:
0.7376
calorifica inferioara in GJ/Kg.

(kg/GJ)
masei trebuie definite urmatoarele marimi:
K
1250 K

0.000000744 (Kg/GJ)
va calcula in prealabil urmatorii parametrii:
0.4401
calorifica inferioara in GJ/Kg.

(kg/GJ)

utul de sulf din combustibil, dar si de fractia de oxizi de sulf retinuta in instalatia de desprafuire

este reprezentata de un electrofiltru

(kg/s)
 (kg/s)

(kg/s)

ant se foloseste urmatoarea relatie :

(kg/s)

(kg/s)
bil;M_C este masa molara a carbonului
6). Analiza de impact
In prima faza se identifica clasele de impact pe baza emisiilor inventariate de.a lungul ciclului de viata , dupa care se calculeaza
aferenti fiecarei clase de impact.
Analizand emisiile inventariate de.a lungul ciclului de viata s.au identificat urmatoarele clase de impact :
consumul de resurse naturale
schimbari climatice
acidificare
eutrofizare
poluare fotochimica
toxicitate umana

Consumul de resurse naturale:

Pentru determinarea consumului de resurse naturale se utilizeaza metodologia produsa de catre CML-
Prin urmare acest indicator se calculeaza doar pentrui carbune si gaz natural biomasa considerandu-se inepuizabila
Contributia la epuizarea resurselor de gaz natural si carbune sunt prezentate mai jos :

ADP_gn= 0.0187 (kg_sb/m^3)

ADPgn= ADP_gn/ρ_gn = 0.018581 (kg_sb/kg)
ADPb= = 0 (kg_sb/kg)
ADPc= = 0.00671 (kg_sb/kg)

Pentru a detrmina contributia la epuizarea unei resurse se tine cont de cantitatea de energie primara extrasa :
Prin urmare, obtinem :
ADPc_gn= ADPgn*Mex_gn= 245800.8 (kg_sb)
ADPc_c= ADPc*Mex_c= 453150 (kg_sb)
ADPc_b= ADPb*Mex_b= 0 (kg_sb)

Schimbari climatice :
Indicatorul care sta la baza acestei clase de impact poarta denumirea de potentialul de incalzire globala,GWP
Contributia relativa a gazelor cu efect de sera este prezentata mai jos:

GWP_CO2= 1 (kg_co2/kg_co2)
GWP_N2O= 310 (kg_co2/kg_n2o)
GWP_CH4= 21 (kg_co2/kg_ch4)

Determnarea contributiei totale la clasa de schimbari climatice tine cont de masa de poluant generata in cadrul etapei ciclului d

Filiera de gaz natural:

Extractie gaz natural :

GWPc_CO2_ex_gn= CO2_ex_gn_r*GWP_CO2= 1033439.593407 (kg_CO2)
GWPc_N2O_ex_gn= N2O_ex_gn_r*GWP_N2O= 4039.436505976 (kg_CO2)
GWPc_CH4_ex_gn= CH4_ex_gn_r*GWP_CH4= 1167064.44406 (kg_CO2)
GWP_tot_ex_gn= GWPc_CO2_ex_gn + GWPc_N2O_ex_gn + GWPc_CH4_ex_gn= 2204543.474

Tratare gaz natural :

GWPc_CO2_tr_gn= CO2_tr_gn_r*GWP_CO2= 377022.89314 (kg_CO2)
GWPc_N2O_tr_gn= N2O_tr_gn_r*GWP_N2O= 2805.050324962 (kg_CO2)
GWPc_CH4_tr_gn= CH4_tr_gn_r*GWP_CH4= 1166508.831375 (kg_CO2)
GWP_tot_tr_gn= GWPc_CO2_tr_gn + GWPc_N2O_tr_gn + GWPc_CH4_tr_gn= 1546336.775

Transport gaz natural:

GWPc_CO2_tp_gn= CO2_tp_gn_r*GWP_CO2= 9818480.452872 (kg_CO2)
GWPc_N2O_tp_gn= N2O_tp_gn_r*GWP_N2O= 55985.68776366 (kg_CO2)
GWPc_CH4_tp_gn= CH4_tp_gn_r*GWP_CH4= 4722027.749407 (kg_CO2)
GWP_tot_tp_gn= GWPc_CO2_tp_gn + GWPc_N2O_tp_gn + GWPc_CH4_tp_gn= 14596493.89

Combustie gaz natural :

GWPc_CO2_c_gn= CO2_gn_cal*GWP_CO2= 28045887.47412 (kg_CO2)
GWPc_CH4_c_gn= CH4_c_gn_r*GWP_CH4= 886453.3911387 (kg_CO2)
GWP_tot_c_gn= GWPc_CO2_c_gn + GWPc_CH4_c_gn= 28932340.87

Rezultate globale filiera de gaz natural :

GWP_tot_gn = GWP_tot_ex_gn + GWP_tot_tr_gn + GWP_tot_tp_gn + GWP_tot_c_gn = 47279715

Filiera de carbune :

Extractie carbune :
GWPc_CO2_ex_c= CO2_ex_c_r*GWP_CO2= 354078.3162419 (kg_CO2)
GWPc_N2O_ex_c= N2O_ex_c_r*GWP_N2O= 12393.75407147 (kg_CO2)
GWPc_CH4_ex_c= CH4_ex_c_r*GWP_CH4= 1076558.811185 (kg_CO2)
GWP_tot_ex_c= GWPc_CO2_ex_c + GWPc_N2O_ex_c + GWPc_CH4_ex_c= 1443030.881

Tratare carbune :
GWPc_CO2_tr_c= CO2_tr_c_r*GWP_CO2= 295715.8365744 (kg_CO2)
GWPc_N2O_tr_c= N2O_tr_c_r*GWP_N2O= 12737.9319717 (kg_CO2)
GWPc_CH4_tr_c= CH4_tr_c_r*GWP_CH4= 9977.917497001 (kg_CO2)
GWP_tot_tr_c= GWPc_CO2_tr_c + GWPc_N2O_tr_c + GWPc_CH4_tr_c= 318431.686

Transport carbune:
GWPc_CO2_tp_c= CO2_tp_c_r*GWP_CO2= 1065823.005361 (kg_CO2)
GWPc_N2O_tp_c= N2O_tp_c_r*GWP_N2O= 5806.69444155 (kg_CO2)
GWPc_CH4_tp_c= CH4_tp_c_r*GWP_CH4= 1542.9488784 (kg_CO2)
GWP_tot_tp_c= GWPc_CO2_tp_c + GWPc_N2O_tp_c + GWPc_CH4_tp_c= 1073172.649

Combustie carbune :
GWPc_CO2_c_c= CO2_c_calc*GWP_CO2= 58226691.8825 (kg_CO2)
GWPc_N2O_c_c= N2O_c_c_r*GWP_N2O= 76644.61735037 (kg_CO2)
GWPc_CH4_c_c= CH4_c_c_r*GWP_CH4= 8774.489938522 (kg_CO2)
GWP_tot_c_c= GWPc_CO2_c_c + GWPc_CH4_c_c+ GWPc_N2O_c_c 58312110.99
Rezultate globale filiera de carbune :
GWP_tot_c = GWP_tot_ex_c + GWP_tot_tr_c + GWP_tot_tp_c + GWP_tot_c_c = 61146746.21

Filiera de biomasa :

Transport biomasa:
GWPc_CO2_tp_b= CO2_tp_b_r*GWP_CO2= 129462.3690323 (kg_CO2)
GWPc_N2O_tp_b= N2O_tp_b_r*GWP_N2O= 98.7250593727 (kg_CO2)
GWPc_CH4_tp_b= CH4_tp_b_r*GWP_CH4= 7.8186047804 (kg_CO2)
GWP_tot_tp_b= GWPc_CO2_tp_b + GWPc_N2O_tp_b + GWPc_CH4_tp_b= 129568.9127

Extractie biomasa:
GWPc_CO2_ex_b= CO2_ex_b_r*GWP_CO2= 12079224.54343 (kg_CO2)
GWPc_N2O_ex_b= N2O_ex_b_r*GWP_N2O= 119293.3191324 (kg_CO2)
GWPc_CH4_ex_b= CH4_ex_b_r*GWP_CH4= 5915.716101166 (kg_CO2)
GWP_tot_ex_b= GWPc_CO2_ex_b + GWPc_N2O_ex_b + GWPc_CH4_ex_b= 12204433.58

Combustie biomasa :
GWPc_CO2_c_b= CO2_c_b_calc*GWP_CO2= 64077656.12629 (kg_CO2)
GWPc_N2O_c_b= N2O_c_b_r*GWP_N2O= 4588.739077785 (kg_CO2)
GWPc_CH4_c_b= CH4_c_b_r*GWP_CH4= 404.4169762264 (kg_CO2)
GWP_tot_c_b= GWPc_CO2_c_b + GWPc_CH4_c_b+ GWPc_N2O_c_b 64082649.28

Rezultate globale filiera de biomasa :

GWP_tot_b = GWP_tot_tp_b + GWP_tot_ex_b + GWP_tot_c_b = 76416651.77

Toxicitate umana :

Indicatorul care sta la baza acestei clase de impact poarta denumirea de potentialul de toxicitate umana,HTP.
Mai jos se prezinta contributia relativa a poluantilor la aceasta clasa de impact :

HTP_hcl= 0.5 (kg dcb/kg hcl)

HTP_hf= 94 (kg dcb/kg hf)
HTP_h2s= 0.22 (kg dcb/kg h2s)
HTP_hg= 260 (kg dcb/kg hg)
HTP_nox= 1.2 (kg dcb/kg no2)
HTP_pr= 0.82 (kg dcb/kg pr)
HTP_sox= 0.096 (kg dcb/kg so2)
HTP_c6h6= 1900 (kg dcb/kg c6h6)
HTP_ch2o= 0.83 (kg dcb/kg ch2o)

Determinarea contributiei totale la clasa de toxicitate umana tine cont de masa de poluant generata
in cadrul etapei ciclului de viata : extractie, tratare, transport si combustie.

Filiera de gaz natural:

Extractie gaz natural :
HTPc_nox_ex_gn = Nox_ex_gn_r*HTP_Nox= 8127.819844 (kg dcb)
HTPc_pr_ex_gn = Pr_ex_gn_r*HTP_Pr= 651.945341 (kg dcb)
HTPc_sox_ex_gn = So2_ex_gn_r*HTP_Sox= 233.6748205 (kg dcb)
HTPc_c6h6_ex_gn = C6H6_ex_gn_r*HTP_C6H6= 1357282.415 (kg dcb)
HTPtot_ex_gn = HTPc_nox_ex_gn + HTPc_pr_ex_gn + HTPc_sox_ex_gn + HTPc_c6h6_ex_gn

Tratare gaz natural :

HTPc_nox_tr_gn = Nox_tr_gn_r*HTP_Nox= 4690.164791 (kg dcb)
HTPc_pr_tr_gn = Pr_tr_gn_r*HTP_Pr= 360.6852344 (kg dcb)
HTPc_sox_tr_gn = So2_tr_gn_r*HTP_Sox= 1278.861654 (kg dcb)
HTPc_c6h6_tr_gn = C6H6_tr_gn_r*HTP_C6H6= 7736509.767 (kg dcb)
HTPtot_tr_gn = HTPc_nox_tr_gn + HTPc_pr_tr_gn + HTPc_sox_tr_gn + HTPc_c6h6_tr_gn

Transport gaz natural :

HTPc_nox_tp_gn = Nox_tp_gn_r*HTP_Nox= 117516.5277 (kg dcb)
HTPc_pr_tp_gn = Pr_tp_gn_r*HTP_Pr= 1121.947078 (kg dcb)
HTPc_sox_tp_gn = So2_tp_gn_r*HTP_Sox= 1631.190452 (kg dcb)
HTPc_c6h6_tp_gn = C6H6_tp_gn_r*HTP_C6H6= 154170.4923 (kg dcb)
HTPtot_tp_gn = HTPc_nox_tp_gn + HTPc_pr_tp_gn + HTPc_sox_tp_gn + HTPc_c6h6_tp_gn

Combustie gaz natural :

HTPc_nox_c_gn = Nox_c_gn_calc*HTP_Nox= 19987.37398 (kg dcb)
HTPc_ch2o_c_gn = CH2O_c_gn_r*HTP_CH2O= 558.8995411 (kg dcb)
HTPc_pr_c_gn = Pr_c_gn_r*HTP_Pr= 4658.899036 (kg dcb)
HTPc_sox_c_gn = So2_c_gn_calc*HTP_Sox= 183402.9324 (kg dcb)
HTPc_c6h6_c_gn = C6H6_c_gn_r*HTP_C6H6= 1191449.248 (kg dcb)
HTPtot_c_gn = HTPc_nox_c_gn + HTPc_pr_c_gn + HTPc_sox_c_gn + HTPc_c6h6_c_gn+HTPc_ch2o_c_gn

Rezultate globale filiera de gaz natural :

HTP_tot_gn = HTP_tot_ex_gn + HTP_tot_tr_gn + HTP_tot_tp_gn + HTP_tot_c_gn = 10783632.84

Filiera de carbune:

Extractie carbune :
HTPc_pr_ex_c = Pr_ex_c_r*HTP_Pr= 935.3259325 (kg dcb)
HTPc_sox_ex_c = So2_ex_c_r*HTP_Sox= 526.4374005 (kg dcb)
HTPc_hcl_ex_c = HCl_ex_c_r*HTP_HCl= 7.800123E-05 (kg dcb)
HTPc_hf_ex_c = HF_ex_c_r*HTP_HF= 0.019234901 (kg dcb)
HTPc_h2s_ex_c = H2S_ex_c_r*HTP_H2S= 2.421753E-05 (kg dcb)
HTPtot_ex_c = HTPc_pr_ex_c + HTPc_sox_ex_c + HTPc_hcl_ex_c + HTPc_hf_ex_c + HTPc_h2s_ex_c

Tratare carbune :
HTPc_pr_tr_c = Pr_tr_c_r*HTP_Pr= 110.3452015 (kg dcb)
HTPc_sox_tr_c = So2_tr_c_r*HTP_Sox= 112.7042829 (kg dcb)
HTPc_hcl_tr_c = HCl_tr_c_r*HTP_HCl= 0.000112139 (kg dcb)
HTPc_hf_tr_c = HF_tr_c_r*HTP_HF= 0.030504141 (kg dcb)
HTPc_h2s_tr_c = H2S_tr_c_r*HTP_H2S= 2.095485E-05 (kg dcb)
HTPtot_tr_c = HTPc_pr_tr_c + HTPc_sox_tr_c + HTPc_hcl_tr_c + HTPc_hf_tr_c + HTPc_h2s_tr_c

Transport carbune :
HTPc_pr_tp_c = Pr_tp_c_r*HTP_Pr= 933.479536 (kg dcb)
HTPc_sox_tp_c = So2_tp_c_r*HTP_Sox= 681.4010567 (kg dcb)
HTPc_hcl_tp_c = HCl_tp_c_r*HTP_HCl= 0.002619203 (kg dcb)
HTPc_hf_tp_c = HF_tp_c_r*HTP_HF= 0.047748871 (kg dcb)
HTPc_h2s_tp_c = H2S_tp_c_r*HTP_H2S= 3.726752E-06 (kg dcb)
HTPtot_tp_c = HTPc_pr_tp_c + HTPc_sox_tp_c + HTPc_hcl_tp_c + HTPc_hf_tp_c + HTPc_h2s_tp_c

Combustie carbune :
HTPc_pr_c_c = Pr_c_c_calc*HTP_Pr= 1222076.198 (kg dcb)
HTPc_sox_c_c = So2_c_c_calc*HTP_Sox= 2716896.226 (kg dcb)
HTPc_hcl_c_c = HCl_c_c_r*HTP_HCl= 0.058174283 (kg dcb)
HTPc_hf_c_c = HF_c_c_r*HTP_HF= 0.849446724 (kg dcb)
HTPc_h2s_c_c = H2S_c_c_r*HTP_H2S= 9.071257E-05 (kg dcb)
HTPc_nox_c_c = Nox_c_c_calc*HTP_Nox 584052.4998 (kg dcb)
HTPtot_c_c = HTPc_nox_c_c + HTPc_pr_c_c + HTPc_sox_c_c + HTPc_hcl_c_c + HTPc_hf_c_c + HTPc_h2s_

Rezultate globale filiera de carbune :

HTP_tot_c = HTP_tot_ex_c + HTP_tot_tr_c + HTP_tot_tp_c + HTP_tot_c_c = 4526325.625

Filiera de biomasa :

Extractie biomasa :
HTPc_pr_ex_b = Pr_ex_b_r*HTP_Pr= 1404.504378 (kg dcb)
HTPc_sox_ex_b = So2_ex_b_r*HTP_Sox= 155.2484225 (kg dcb)
HTPc_hcl_ex_b = HCl_ex_b_r*HTP_HCl= 0.009042247 (kg dcb)
HTPc_hf_ex_b = HF_ex_b_r*HTP_HF= 0.851605762 (kg dcb)
HTPc_h2s_ex_b = H2S_ex_b_r*HTP_H2S= 0.000120123 (kg dcb)
HTPtot_ex_b = HTPc_pr_ex_b + HTPc_sox_ex_b + HTPc_hcl_ex_b + HTPc_hf_ex_b + HTPc_h2s_ex_b

Transport biomasa :
HTPc_pr_tp_b = Pr_tp_b_r*HTP_Pr= 8.82527812 (kg dcb)
HTPc_sox_tp_b = So2_tp_b_r*HTP_Sox= 1.521484621 (kg dcb)
HTPc_hcl_tp_b = HCl_tp_b_r*HTP_HCl= 0.000002577 (kg dcb)
HTPc_hf_tp_b = HF_tp_b_r*HTP_HF= 0.001995307 (kg dcb)
HTPc_h2s_tp_b = H2S_tp_b_r*HTP_H2S= 4.475912E-07 (kg dcb)
HTPtot_tp_b = HTPc_pr_tp_b + HTPc_sox_tp_b + HTPc_hcl_tp_b + HTPc_hf_tp_b + HTPc_h2s_tp_b

Combustie biomasa :
HTPc_pr_c_b = Pr_c_b_calc*HTP_Pr= 1300774.5 (kg dcb)
HTPc_sox_c_b = So2_c_b_calc*HTP_Sox= 3231771.356 (kg dcb)
HTPc_hcl_c_b = HCl_c_b_r*HTP_HCl= 0.058664967 (kg dcb)
HTPc_hf_c_b = HF_c_b_r*HTP_HF= 0.823685843 (kg dcb)
HTPc_h2s_c_b = H2S_c_b_r*HTP_H2S= 7.689319E-05 (kg dcb)
HTPc_nox_c_b = Nox_c_b_calc*HTP_Nox = 353479.518 (kg dcb)
HTPtot_c_b = HTPc_nox_c_b + HTPc_pr_c_b + HTPc_sox_c_b + HTPc_hcl_c_b + HTPc_hf_c_b + HTPc_h2s

Rezultate globale filiera de biomasa :

HTP_tot_b = HTP_tot_ex_b + HTP_tot_tr_b + HTP_tot_tp_b + HTP_tot_c_b = 4887597.219

Poluarea fotochimica :

Indicatorul care sta la baza acestei clase de impact poarta denumirea de potentialul de poluare fotochimica, POCP.
Mai jos se prezinta contributia relativa a poluantilor la aceasta clasa de impact :

POCP_co = 0.027 (kg_c2h4/kg_co)

POCP_ch2o = 0.519 (kg_c2h4/kg_ch2o)
POCP_ch4 = 0.006 (kg_c2h4/kg_ch4)
POCP_nox = 0.028 (kg_c2h4/kg_no2)
POCP_sox = 0.048 (kg_c2h4/kg_so2)

Determinarea contributiei totale la clasa de poluare fotochimica tine cont de masa de poluant generata in cadrul etapei ciclulu
extractie, tratare, transport si combustie;

Filiera de gaz natural:

Extractie gaz natural:

POCP_c_co_ex_gn = CO_ex_gn_r*POCP_co 36.5751893 (kg_c2h4)
POCP_c_ch4_ex_gn = CH4_ex_gn_r*POCP_ch4 333.446984 (kg_c2h4)
POCP_c_nox_ex_gn = NOx_ex_gn_r*POCP_nox 189.6491297 (kg_c2h4)
POCP_c_sox_ex_gn = SO2_ex_gn_r*POCP_sox 116.8374103 (kg_c2h4)
POCP_tot_ex_gn = POCP_c_co_ex_gn + POCP_c_ch4_ex_gn + POCP_c_nox_ex_gn + POCP_c_sox_ex_gn

Tratare gaz natural:

POCP_c_co_tr_gn = CO_tr_gn_r*POCP_co 44.72245558 (kg_c2h4)
POCP_c_ch4_tr_gn = CH4_tr_gn_r*POCP_ch4 333.2882375 (kg_c2h4)
POCP_c_nox_tr_gn = NOx_tr_gn_r*POCP_nox 109.4371784 (kg_c2h4)
POCP_c_sox_tr_gn = SO2_tr_gn_r*POCP_sox 639.4308268 (kg_c2h4)
POCP_tot_tr_gn = POCP_c_co_tr_gn + POCP_c_ch4_tr_gn + POCP_c_nox_tr_gn + POCP_c_sox_tr_gn

Transport gaz natural:

POCP_c_co_tp_gn = CO_tp_gn_r*POCP_co 1572.737426 (kg_c2h4)
POCP_c_ch4_tp_gn = CH4_tp_gn_r*POCP_ch4 1349.150786 (kg_c2h4)
POCP_c_nox_tp_gn = NOx_tp_gn_r*POCP_nox 2742.052313 (kg_c2h4)
POCP_c_sox_tp_gn = SO2_tp_gn_r*POCP_sox 815.595226 (kg_c2h4)
POCP_tot_tp_gn = POCP_c_co_tp_gn + POCP_c_ch4_tp_gn + POCP_c_nox_tp_gn + POCP_c_sox_tp_gn

Combustie gaz natural:

POCP_c_co_c_gn = CO_c_gn_r*POCP_co 66.47453503 (kg_c2h4)
POCP_c_ch2o_c_gn = CH2O_c_gn_r*POCP_ch2o 349.4805564 (kg_c2h4)
POCP_c_ch4_c_gn = CH4_c_gn_r*POCP_ch4 253.2723975 (kg_c2h4)
POCP_c_nox_c_gn = NOx_c_gn_calc*POCP_nox 466.3720594 (kg_c2h4)
POCP_c_sox_c_gn = SO2_c_gn_calc*POCP_sox 91701.46622 (kg_c2h4)
POCP_tot_c_gn = POCP_c_co_c_gn + POCP_c_ch4_c_gn+POCP_c_ch2o_c_gn + POCP_c_nox_c_gn + POCP_c_

Rezultate globale filiera de gaz natural :

POCP_tot_gn = POCP_tot_ex_gn + POCP_tot_tr_gn + POCP_tot_tp_gn + POCP_tot_c_gn =

Filiera de carbune:

Extractie carbune:
POCP_c_co_ex_c = CO_ex_c_r*POCP_co 14.24079621 (kg_c2h4)
POCP_c_ch4_ex_c = CH4_ex_c_r*POCP_ch4 307.5882318 (kg_c2h4)
POCP_c_sox_ex_c = SO2_ex_c_r*POCP_sox 263.2187002 (kg_c2h4)
POCP_tot_ex_c = POCP_c_co_ex_c + POCP_c_ch4_ex_c+ POCP_c_sox_ex_c 585.0477282

Tratare carbune:
POCP_c_co_tr_c = CO_tr_c_r*POCP_co 10.79528936 (kg_c2h4)
POCP_c_ch4_tr_c = CH4_tr_c_r*POCP_ch4 2.850833571 (kg_c2h4)
POCP_c_sox_tr_c = SO2_tr_c_r*POCP_sox 56.35214144 (kg_c2h4)
POCP_tot_tr_c = POCP_c_co_tr_c + POCP_c_ch4_tr_c + POCP_c_sox_tr_c 69.99826437

Transport carbune:
POCP_c_co_tp_c = CO_tp_c_r*POCP_co 4420.670993 (kg_c2h4)
POCP_c_ch4_tp_c = CH4_tp_c_r*POCP_ch4 0.440842537 (kg_c2h4)
POCP_c_sox_tp_c = SO2_tp_c_r*POCP_sox 340.7005284 (kg_c2h4)
POCP_tot_tp_c = POCP_c_co_tp_c + POCP_c_ch4_tp_c + POCP_c_sox_tp_c 4761.812364

Combustie carbune:
POCP_c_co_c_c = CO_c_c_r*POCP_co 226.7971576 (kg_c2h4)
POCP_c_ch4_c_c = CH4_c_c_r*POCP_ch4 2.506997125 (kg_c2h4)
POCP_c_nox_c_c = NOx_c_c_calc*POCP_nox 13627.89166 (kg_c2h4)
POCP_c_sox_c_c = SO2_c_c_calc*POCP_sox 1358448.113 (kg_c2h4)
POCP_tot_c_c = POCP_c_co_c_c + POCP_c_ch4_c_c + POCP_c_nox_c_c + POCP_c_sox_c_c

Rezultate globale filiera de carbune :

POCP_tot_c = POCP_tot_ex_c + POCP_tot_tr_c + POCP_tot_tp_c + POCP_tot_c_c =

Filiera de biomasa:
Extractie biomasa:
POCP_c_co_ex_b = CO_ex_b_r*POCP_co 166.6729536 (kg_c2h4)
POCP_c_ch4_ex_b = CH4_ex_b_r*POCP_ch4 1.6902046 (kg_c2h4)
POCP_c_sox_ex_b = SO2_ex_b_r*POCP_sox 77.62421127 (kg_c2h4)
POCP_tot_ex_b = POCP_c_co_ex_b + POCP_c_ch4_ex_b + POCP_c_sox_ex_b 245.9873695

Transport biomasa:
POCP_c_co_tp_b = CO_tp_b_r*POCP_co 0.470581131 (kg_c2h4)
POCP_c_ch4_tp_b = CH4_tp_b_r*POCP_ch4 0.002233887 (kg_c2h4)
POCP_c_sox_tp_b = SO2_tp_b_r*POCP_sox 0.760742311 (kg_c2h4)
POCP_tot_tp_b = POCP_c_co_tp_b + POCP_c_ch4_tp_b + POCP_c_sox_tp_b 1.233557328

Combustie biomasa:
POCP_c_co_c_b = CO_c_b_r*POCP_co 5.814515101 (kg_c2h4)
POCP_c_ch4_c_b = CH4_c_b_r*POCP_ch4 0.115547707 (kg_c2h4)
POCP_c_nox_c_b = NOx_c_b_calc*POCP_nox 8247.855419 (kg_c2h4)
POCP_c_sox_c_b = SO2_c_b_calc*POCP_sox 1615885.678 (kg_c2h4)
POCP_tot_c_b = POCP_c_co_c_b + POCP_c_ch4_c_b + POCP_c_nox_c_b + POCP_c_sox_c_b

Rezultate globale filiera de biomasa :

POCP_tot_b = POCP_tot_ex_b + POCP_tot_tr_b + POCP_tot_tp_b + POCP_tot_c_b =

Acidificare :
Indicatorul care sta la baza acestei clase de impact poarta denumirea de potential de acidificare,AP
Mai jos se prezinta contributia relativa a poluantilor la aceasta clasa de impact :

AP_nh3 1.6 (Kg_so2/Kg_nh3)

AP_nox 0.5 (Kg_so2/Kg_no2)
AP_sox 1.2 (Kg_so2/Kg_so2)

Determinarea contributiei totale la clasa de acidificare tine cont de masa de poluant generata in cadrul etapei ciclului de viata :

Filiera de gaz natural:

Extractie gaz natural:

AP_nox_ex_gn = NOx_ex_gn_r*AP_nox 3386.591602 (kg_so2)
AP_sox_ex_gn = SO2_ex_gn_r*AP_sox 2920.935256 (kg_so2)
AP_tot_ex_gn = AP_nox_ex_gn + AP_sox_ex_gn 6307.526858 (kg_so2)

Tratare gaz natural:

AP_nox_tr_gn = NOx_tr_gn_r*AP_nox 1954.235329 (kg_so2)
AP_sox_tr_gn = SO2_tr_gn_r*AP_sox 15985.77067 (kg_so2)
AP_tot_tr_gn = AP_nox_tr_gn + AP_sox_tr_gn 17940.006 (kg_so2)
Transport gaz natural:
AP_nox_tp_gn = NOx_tp_gn_r*AP_nox 48965.21988 (kg_so2)
AP_sox_tp_gn = SO2_tp_gn_r*AP_sox 20389.88065 (kg_so2)
AP_tot_tp_gn = AP_nox_tp_gn + AP_sox_tp_gn 69355.10053 (kg_so2)

Combustie gaz natural:

AP_nh3_c_gn = NH3_c_gn_r*AP_nh3 3653.048205 (kg_so2)
AP_nox_c_gn = NOx_c_gn_calc*AP_nox 8328.07249 (kg_so2)
AP_sox_c_gn = SOx_c_gn_calc*AP_sox 2292536.656 (kg_so2)
AP_tot_c_gn = AP_nox_c_gn + AP_sox_c_gn + AP_nh3_c_gn = 2304517.776

Rezultate globale filiera de gaz natural :

AP_tot_gn = AP_tot_ex_gn + AP_tot_tr_gn + AP_tot_tp_gn + AP_tot_c_gn =

Filiera de carbune :

Extractie carbune:
AP_nh3_ex_c = NH3_ex_c_r*AP_nh3 5986.172411 (kg_so2)
AP_sox_ex_c = SO2_ex_c_r*AP_sox 6580.467506 (kg_so2)
AP_tot_ex_c = AP_c_nh3_ex_c + AP_c_sox_ex_c 12566.63992 (kg_so2)

Tratare carbune:
AP_nh3_tr_c = NH3_tr_c_r*AP_nh3 2702.421877 (kg_so2)
AP_sox_tr_c = SO2_tr_c_r*AP_sox 1408.803536 (kg_so2)
AP_tot_tr_c = AP_c_nh3_tr_c + AP_c_sox_tr_c 4111.225413 (kg_so2)

Transport carbune:
AP_nh3_tp_c = NH3_tp_c_r*AP_nh3 10.19561752 (kg_so2)
AP_sox_tp_c = SO2_tp_c_r*AP_sox 8517.513209 (kg_so2)
AP_tot_tp_c = AP_c_nh3_tp_c + AP_c_sox_tp_c 8527.708826 (kg_so2)

Combustie carbune:
AP_nh3_c_c = NH3_c_c_r*AP_nh3 17.67240369 (kg_so2)
AP_nox_c_c = NOx_c_c_calc*AP_nox 243355.2083 (kg_so2)
AP_sox_c_c = SO2_c_c_calc*AP_sox 33961202.83 (kg_so2)
AP_tot_c_c = AP_c_nox_c_c + AP_c_sox_c_c + AP_c_nh3_c_c = 34204575.71

Rezultate globale filiera de carbune :

AP_tot_c = AP_tot_ex_c + AP_tot_tr_c + AP_tot_tp_c + AP_tot_c_c =

Filiera de biomasa :

Extractie biomasa:
AP_nh3_ex_b = NH3_ex_b_r*AP_nh3 3060.452774 (kg_so2)
AP_sox_ex_b = SO2_ex_b_r*AP_sox 1940.605282 (kg_so2)
AP_tot_ex_b = AP_c_nh3_ex_b + AP_c_sox_ex_b 5001.058056 (kg_so2)

Transport biomasa:
AP_sox_tp_b = SO2_tp_b_r*AP_sox 19.01855776 (kg_so2)
AP_tot_tp_b = AP_c_sox_tp_b 19.01855776 (kg_so2)

Combustie biomasa:
AP_nox_c_b = NOx_c_b_calc*AP_nox 147283.1325 (kg_so2)
AP_sox_c_b = SO2_c_b_calc*AP_sox 40397141.95 (kg_so2)
AP_tot_c_b = AP_c_nox_c_b + AP_c_sox_c_b 40544425.08

Rezultate globale filiera de biomasa :

AP_tot_b = AP_tot_ex_b + AP_tot_tr_b + AP_tot_tp_b + AP_tot_c_b =

Eutrofizare :
Indicatorul care sta la baza acestei clase de impact poarta denumirea de potential de eutrofizare,EP
Mai jos se prezinta contributia relativa a poluantilor la aceasta clasa de impact :

EP_nh3 0.35 (Kg_po43/Kg_nh3)

EP_nox 0.13 (Kg_po43/Kg_no2)
EP_no 0.2 (Kg_po43/Kg_no)

Determinarea contributiei totale la clasa de eutrofizare tine cont de masa de poluant generata in cadrul etapei ciclului de viata

Filiera de gaz natural:

Extractie gaz natural:

EPc_nox_ex_gn = NOx_ex_gn_r*EP_nox 880.5138164 (Kg_po43)
EPc_tot_ex_gn= EPc_nox_ex_gn 880.5138164 (Kg_po43)

Tratare gaz natural:

EPc_nox_tr_gn = NOx_tr_gn_r*EP_nox 508.1011856551 (Kg_po43)
EPc_tot_tr_gn= EPc_nox_tr_gn 508.1011856551 (Kg_po43)

Transport gaz natural:

EPc_nox_tp_gn = NOx_tp_gn_r*EP_nox 12730.95716752 (Kg_po43)
EPc_tot_tp_gn= EPc_nox_tp_gn 12730.95716752 (Kg_po43)

Combustie gaz natural:

EPc_nh3_c_gn = NH3_c_gn_r*EP_nh3 799.1042949 (Kg_po43)
EPc_nox_c_gn = NOx_c_gn_calc*EP_nox 2165.298847 (Kg_po43)
EPc_tot_c_gn = EPc_nox_c_gn + EP_nh3_c_gn = 2964.403142 (Kg_po43)

Rezultate globale filiera de gaz natural :

EPc_tot_gn = EPc_tot_ex_gn + EPc_tot_tr_gn + EPc_tot_tp_gn + EPc_tot_c_gn=
Filiera de carbune :

Extractie carbune:
EPc_nox_ex_c = NOx_ex_c_r*EP_nox 290.5967947337 (Kg_po43)
EPc_nh3_ex_c= NH3_ex_c_r*EP_nh3 1309.47521494 (Kg_po43)
EPc_tot_ex_c= EPc_nox_ex_c + EPc_nh3_ex_c 1600.072009674 (Kg_po43)

Tratare carbune:
EPc_nox_tr_c = NOx_tr_c_r*EP_nox 225.3310372699 (Kg_po43)
EPc_nh3_tr_c= NH3_tr_c_r*EP_nh3 591.1547856615 (Kg_po43)
EPc_tot_tr_c= EPc_nox_tr_c + EPc_nh3_tr_c 816.4858229314 (Kg_po43)

Transport carbune:
EPc_nox_tp_c = NOx_tp_c_r*EP_nox 1630.255656499 (Kg_po43)
EPc_nh3_tp_c= NH3_tp_c_r*EP_nh3 2.2302913314 (Kg_po43)
EPc_tot_tp_c= EPc_nox_tp_c + EPc_nh3_tp_c 1632.48594783 (Kg_po43)

Combustie carbune:
EPc_nox_c_c = NOx_tp_c_calc*EP_nox 63272.35414513 (Kg_po43)
EPc_nh3_c_c= NH3_tp_c_r*EP_nh3 3.8658383078 (Kg_po43)
EPc_tot_c_c= EPc_nox_tp_c + EPc_nh3_tp_c 63276.21998344 (Kg_po43)

Rezultate globale filiera de carbune:

EPc_tot_c = EPc_tot_ex_c + EPc_tot_tr_c + EPc_tot_tp_c + EPc_tot_c_c =

Filiera de biomasa :

Extractie biomasa:
EPc_nox_ex_b = NOx_ex_b_r*EP_nox 1014.653122754 (Kg_po43)
EPc_nh3_ex_b= NH3_ex_b_r*EP_nh3 669.4740443706 (Kg_po43)
EPc_tot_ex_b= EPc_nox_ex_b + EPc_nh3_ex_b 1684.127167125 (Kg_po43)

Transport biomasa:
EPc_nox_tp_b = NOx_tp_b_r*EP_nox 5.977377269 (Kg_po43)
EPc_tot_tp_b= EPc_nox_tp_b 5.977377269 (Kg_po43)

Combustie biomasa:
EPc_nox_c_b= NOx_c_b_calc*EP_nox 38293.61444679 (Kg_po43)
EPc_tot_c_b= EPc_nox_c_b 38293.61444679 (Kg_po43)

Rezultate globale filiera de biomasa:

EPc_tot_b = EPc_tot_ex_b + EPc_tot_tr_b + EPc_tot_tp_b + EPc_tot_c_b =
dupa care se calculeaza indicatorii de impact

inepuizabila

in cadrul etapei ciclului de viata : extractie, tratare, transport si combustie.

(kg_CO2)
(kg_CO2)

(kg_CO2)

(kg_CO2)

(kg_CO2)

(kg_CO2)

(kg_CO2)

(kg_CO2)

(kg_CO2)
(kg_CO2)

(kg_CO2)

(kg_CO2)

(kg_CO2)

(kg_CO2)
 1366295.86 (kg dcb)

7742839.48 (kg dcb)

274440.158 (kg dcb)

_gn+HTPc_ch2o_c_gn 1400057 (kg dcb)

(kg dcb)

+ HTPc_h2s_ex_c 1461.783 (kg dcb)

HTPc_h2s_tr_c 223.0801 (kg dcb)

+ HTPc_h2s_tp_c 1614.931 (kg dcb)

TPc_hf_c_c + HTPc_h2s_c_c 4523026 (kg dcb)

(kg dcb)

+ HTPc_h2s_ex_b 1560.614 (kg dcb)

+ HTPc_h2s_tp_b 10.34876 (kg dcb)

HTPc_hf_c_b + HTPc_h2s_c_b 4886026 (kg dcb)

(kg dcb)

mica, POCP.

a in cadrul etapei ciclului de viata :

OCP_c_sox_ex_gn 676.5087 (kg_c2h4)

CP_c_sox_tr_gn 1126.879 (kg_c2h4)

OCP_c_sox_tp_gn 6479.536 (kg_c2h4)

_c_nox_c_gn + POCP_c_sox_c_gn 92837.07 (kg_c2h4)

101119.989 (kg_c2h4)

(kg_c2h4)

(kg_c2h4)

(kg_c2h4)

1372305.31 (kg_c2h4)

1377722.17 (kg_c2h4)
 (kg_c2h4)

(kg_c2h4)

1624139.46 (kg_c2h4)

1624386.68 (kg_c2h4)

l etapei ciclului de viata : extractie, tratare, transport, combustie.

(kg_so2)

2398120.41 (kg_so2)

(kg_so2)

34229781.3 (kg_so2)
 (kg_so2)

40549445.2 (kg_so2)

ul etapei ciclului de viata : extractie, tratare, transport, combustie.

17083.9753 (Kg_po43)
67325.2638 (Kg_po43)

39983.719 (Kg_po43)
7). Analiza multicriteriala :

In cadrul acestei etape se urmareste determinarea filierei energetice cu impactul cel mai redus asupra mediului ambiant.
In acest sens se utilizeaza metoda ELECTRA I care presupune realizarea testului de concordanta si de non-discordanta.
Aplicarea metodei multicriteriale consta in :
a). Realizarea matricei de evaluare;
b). Verificarea testului de concordanta pentru cuplurile de actiuni;
c). Verificarea testului de non-discordanta pentru cuplurile de actiuni ;
d). Stabilirea cuplului de actiuni care verifica simultan cele doua teste;
Fiecarui cuplu de actiuni I se asociaza urmatoarea ipoteza de surclasare : actiunea ai S ak - actiunea ai surclaseara actiunea ak.
Matricea de evaluare este prezentata mai jos:

a). Realizarea matricei de evaluare;

ADPc_c ADPc_gn ADPc_b

GWP_tot_c GWP_tot_gn GWP_tot_b

HTP_tot_c HTP_tot_gn HTP_tot_b

POCP_tot_c POCP_tot_gn POCP_tot_b

AP_tot_c AP_tot_gn AP_tot_b

EP_tot_c EP_tot_gn EP_tot_b

1. Matricea evaluarilor
ADPc GWPtot HTPtot POCPtot
Carbune 453150.01 61146746.21 4526325.62 1377722.167219
Gaz Natural 245800.773 47279715 10783632.8 101119.9889323
Biomasa 0 76416651.77 4887597.22 1624139.463537
Ponderi 8 10 9 6

2. Matricea Normalizata
ADPc GWPtot HTPtot POCPtot
Carbune 0 0.1998243212 0.580259668 0.151721759
Gaz Natural 0.45757306 0.3812904137 0 0.9377393437
Biomasa 1 0 0.546757824 0
Ponderi 8 10 9 6

3. Testul de concordanta

Amplitudinile
ẟ 1 0.3812904137 0.580259668 0.9377393437
 Matricea de concordanta
Cik Carbune Gaz Natural Biomasa
Carbune - 0.2 0.71111111
Gaz Natural 0.8 - 0.62222222
Biomasa 0.28888889 0.377777778 -

Suma ponderilor
c,gn c,b gn,c gn,b
p+ 9 32 36 28
p= 0 0 0 0
p- 36 13 9 17
pT 45 45 45 45

4. Testul de non-discordanta

Matricea de non-discordanta
Dik Carbune Gaz Natural Biomasa
Carbune - 0.786017585 1
Gaz Natural 1 - 0.54675782
Biomasa 0.2123849 1 -

j-(c,gn) = {ADP,GWP,POCP,AP,EP} {c1,c2,c4,c5,c6}

j-(c,b) = {ADP,EP} {c1,c6}
j-(gn,c) = {HTP} {c3}
j-(gn,b) = {ADP,HTP} {c1,c3}
j-(b,c) = {GWP,HTP,POCP,AP} {c2,c3,c4,c5}
j-(b,gn) = {GWP,POCP,AP,EP} {c2,c4,c5,c6}

Pt. j-(c,gn) ẟmax = 1

gc1(gn)-gc1(c) 0.4575730615 Max{gj(ak)-gj( 0.7860175847
gc2(gn)-gc2(c) 0.1814660925 D(c,gn) = 0.7860175847
gc4(gn)-gc4(c) 0.7860175847
gc5(gn)-gc5(c) 0.7850085432
gc6(gn)-gc6(c) 0.7462471833

Pt. j-(c,b) ẟmax = 1

gc1(b)-gc1(c) 1 Max{gj(ak)-gj( 1
gc6(b)-gc6(c) 0.4061112166 D(c,b) = 1

Pt. j-(gn,c) ẟmax = 0.5802596685

gc3(c)-gc3(gn) 0.5802596685 Max{gj(ak)-gj( 0.5802596685
D(gn,c) = 1
 Pt. j-(gn,b) ẟmax = 1
gc1(b)-gc1(gn) 0.5424269385 Max{gj(ak)-gj( 0.5467578237
gc3(b)-gc3(gn) 0.5467578237 D(gn,c) = 0.5467578237

Pt. j-(b,c) ẟmax = 0.9408593533

gc2(c)-gc2(b) 0.1998243212 Max{gj(ak)-gj( 0.1998243212
gc3(c)-gc3(b) 0.0335018448 D(b,c) = 0.2123849016
gc4(c)-gc4(b) 0.151721759
gc5(c)-gc5(b) 0.1558508102

Pt. j-(b,gn) ẟmax = 0.9408593533

gc2(gn)-gc2(b) 0.3812904137 Max{gj(ak)-gj( 0.9408593533
gc4(gn)-gc4(b) 0.9377393437 D(b,gn) = 1
gc5(gn)-gc5(b) 0.9408593533
gc6(gn)-gc6(b) 0.3401359668

cik = pragul de concordanta

0.5ϵ [0,1] =
dik = pragul de n 0.5

Pt. Cik > cik ave C(c,b)

C(gn,c)
C(gn,b)
Pt. Dik < dik ave D(b,c)
s asupra mediului ambiant.
a si de non-discordanta.

unea ai surclaseara actiunea ak.

Ma

453150.009914714

61146746.2060096

= 4526325.62495092

1377722.16721935

34229781.2809665

67325.2637638742

APtot EPtot ADPmax = 453150.009914714

34229781.28097 67325.2637638742 GWPmax = 76416651.7737044
2398120.409625 17083.9753118784 HTPmax = 10783632.8443854
40549445.16047 39983.718991183 POCPmax = 1624139.46353682
7 5 APmax = 40549445.160469
EPmax = 67325.2637638742

APtot EPtot
0.1558508102 0
0.9408593533 0.7462471833
0 0.4061112166
7 5

0.9408593533 0.7462471833
or
b,c b,gn
13 17
0 0
32 28
45 45

0 ADPc GWPtot
Carbune 0 0.1998243212
Gaz Natural 0.4575730615 0.3812904137
Biomasa 1 0
 Matricea de evaluare :

245800.772545657 0

47279715.0041118 76416651.7737044

10783632.8443854 4887597.21878346 Kg

101119.988932348 1624139.46353682

2398120.40962545 40549445.160469

17083.9753118784 39983.718991183
HTPtot POCPtot APtot EPtot
0.5802596685 0.151721759 0.1558508102 0
0 0.9377393437 0.9408593533 0.7462471833
0.5467578237 0 0 0.4061112166