TABEL

Transformare

Masa

Izobar
p = const

p V
m= 1 1
RT1

Izocor
V = const

p V
m= 1 1
RT1

Izoterm
T = const

Adiabat
Qrev = 0
(S = const)

m=

p1 V1
RT1

Ecuaii

TRANSFORMRI

U, H

p2 = p1
T1
T
= 2
V1 V2

V2 = V1
p1 p 2
=
T1 T2

U = m cv T

L12 = p1(V2-V1)

H = m cp T

Lt, 12 = 0

U = m cv T

L12 = 0

H = m cp T

Lt, 12 = V1(p1-p2)

T1

k 1
p1 k

T2

U = m cv T

p1V1n = p 2 V2n

Politrop

cv =

R
,
k 1

p V
m= 1 1
RT1

T1V1n 1

cp =

kR
,
k 1

T1

n 1
p1 n

= T2 V2n 1

T2

n 1
p 2n

R=

RM
,
M

H = m cp T

k 1
p 2k

Q12 = L12

V2
V1

Lt, 12 = L12
p V p 2 V2
T T2
L12 = 1 1
= mR 1
=
k 1
k 1

p1V1k = p 2 V2k
T1V1k 1 = T2 V2k 1

= U

V2
p
= p1V1 ln 1 =
V1
p2

= mRT1 ln

H = 0

Q12 = m cp(T2-T1)

Q12 = m cv(T2-T1)

U = 0

p1V1 = p2V2

Q12

= H

L12 = p1V1 ln

T2 = T1

p V
m= 1 1
RT1

L12, Lt, 12

U = m cv T

p1 V1
k 1

p 2

1
p
1

k 1
k

= - U
Lt, 12 = k L12
p V p 2 V2 mR ( T1 T2 )
L12 = 1 1
=
=
n 1
n 1
=

H = m cp T

p 2
p1 V1
1
p
n 1
1

n 1
n

Q12 = 0

Q12 = m cn (T2-T1),
cn =

n k
cv
n 1

Q12 = U + L12

Lt, 12 = n L12
RM = 8315 J/(kmol K)

T
V
T
p
S 2 S1 = mc v ln 2 + mR ln 2 = mc p ln 2 mR ln 2
T1
V1
T1
p1