2.

Alchilarea
CH2-CH3

a. + CH3-CH2-Br AlBr3> +HBr

CH3-CH-CH3

b. +CH3-CH2-CH2 AlCl3> +HCl

|
Cl
CH3-CH-CH3
|

c. +CH3-CH-CH3 AlCl3 > +HCl

|
Cl
(b si c- Acelasi produs deoarece clorura de propil sufera o izomerizare pe parcursul
reactiei)
CH2-CH3
|

d. +HCl2=HCl2 AlCl3> (=>In realitate,relaia decurge tot cu derivati

Urme de apa halogenati:AlCl3+3H2O->Al(OH)3+3HCl
CH2=CH2+HCl->CH3-CH2-Cl
CH2-CH3

+CH3-CH2-Cl AlCl3> )
 -HCl

a.b.c.d.=> Reactii Friedele-Crafts

3.Acilarea ( r. Friedele-Crafts)
/ C-CH3

+CH3-C =O AlCl3> \\ +HCl

\ Cl O (Acetofenona = fenil-metil-cetona)

Este o metoda eficienta de obtinere a acetonelor aromatice.

R-C =O PCl5---->R-C=O POCl5+HCl

\ OH \ Cl
(obtinere halogenilor acide)