Proprieti electrice i magnetice

ale sistemelor de nanoparticule n

cmp de nalt frecven
I. Mlescu, C. N. Marin
Universitatea de Vest din Timioara, Facultatea de Fizic, Bd. V. Prvan no. 4,
300223 Timioara, Romania

Universitatea de Vest din Timioara

Facultatea de Fizic

Blvd. V. Prvan 4
Timioara 300223, Timi, Romania
Tel/fax +40-(0)256-592108
Email: secretary@physics.uvt.ro
www.physics.uvt.ro

Centre de cercetare
Facultatea de Fizica are o baza de cercetare foarte
solid format din 3 centre de cercetare:
1. Fizica materialelor cristaline (acreditat CNCSIS) Tip B
2. Centru de cercetri n Fizica Teoretic (acreditat CNCSIS)

3. Centru de cercetare pentru materiale

inteligente (acreditat CNCSIS)
4. Centrul National de Difractometrie cu Raze X-Laboratorul pentru
Determinari Cristalografice
5. Grupul de electronic cuantic
6. Platforma solar
7. Grupul de relativitate numeric

Centrul de cercetare pentru

Materiale Inteligente
Director: Prof. Dr. Ioan Bica
Director adj.: Prof. Dr. Iosif Mlescu
Membri:
Prof. dr. Agneta Balint
Conf. dr. Ctlin Nicolae Marin
Conf. dr. Aurel Ercuta
Conf. dr. Dorina Vangheli
Conf. dr. Costica Caizer
Lector dr. Adrian Neculae
Lector Nicoleta tefu
Drd. Radu Totoreanu
Drd. Cecilia Obead
Drd. Alexandru Savici
Secretar Diana Algayer

Direcii de cecetare:

Obinerea caracterizarea i aplicaiile fluidelor

magnetoreologice
(Prof. dr. Ioan Bica)
Procesarea materialelor n plasm
(Prof. dr. Ioan Bica)
Nanosisteme de particule n cmp electromagnetic
i aplicaii
(Prof. dr. I. Mlescu )
Modelarea i simularea proceselor fizice n sisteme
nano-microstructurate
(Lector. dr. A. Neculae)
Cercetarea sistemelor de tip spinel-magnetice,
nanocristaline obinute din combinaii complexe
hetero-nucleare i metoda sol-gel
(Conf. dr. C. Caizer)

 Obinerea, caracterizarea i aplicaiile

fluidelor magnetoreologice
Procesarea materialelor n plasm
(Prof. dr. Ioan Bica)
Rezultate:
30 articole de specialitate cotate ISI n ultimii 5 ani
4 contracte de cercetare internationale cu Dubna
1 Premiu al Academiei (2009)
colaborare internaionala cu Inha University din Coreea de Sud, prof. Choi,
n domeniul,
- realizrii de nano-microsisteme sub form de elastomeri
magneto-reologici i suspensii magnetoreologice.

Nanosisteme de particule n cmp

electromagnetic i aplicaii

Colectiv de cercetare:

Obiective:

Prof. Dr. Iosif Mlescu

Conf. dr. Ctlin Nicolae Marin
Conf. dr. Aurel Ercuta
Lector Nicoleta tefu
Doctoranzi:
Drd. Radu Totoreanu
Drd. Cecilia Obead
Drd. Alexandru Savici
Studeni master:
Dan Mlescu
Petronela Burov
Cosmina Stan

Studiul rezonanei feromagnetice i a proceselor

de relaxare n fluide magnetice;
Investigarea unor proprieti microscopice i
macroscopice ale fluidelor magnetice utiliznd
msurtorile de rezonan feromagnetic;
Studiul puterii specifice in nanofluide in
domeniul microundelor;
Fenomene de propagare a cmpului
electromagnetic in domeniul microundelor;
aplicaii.
Obinerea i caracterizarea de compozite
magneto-dielectrice nanostructurate cu indice de
refracie negativ;
Obinerea de anvelope inteligente cu absorbie
pronunat n domeniul microundelor pentru
protecia mpotriva polurii electromagnetice
Obinerea i caracterizarea coloizilor magnetoelectrici pentru aplicaii biomedicale.

UTILITI

Analizor de spectru, tip HM 5510 Hameg,

150 kHz - 1 GHz

RLC metru tip E4980A Agilent, 20 Hz - 2 MHz

Analizor de reea tip N9923A Agilent,

2 MHz - 4 GHz

Histeresisgraf, 50Hz, 0.5T

Generatoare de microunde
Linii de msur cu ghid de und
Celule de msur pentru msurarea
parametrilor dielectrici i magnetici n
domeniul 20 Hz 4 GHz

LISTA LUCRRILOR TIINIFICE

(2006-2011)
1. Articole publicate n reviste de specialitate cotate ISI
1) P. C. Fannin, C. N. Marin, I. Malaescu, N. Stefu, P. Vlzan, S. Novaconi, S. Popescu, Effect of the
concentration of precursors on the microwave absorbent properties of Zn/Fe oxide nanopowders, J.
Nanopart. Res. 13 (2011) 311319
2) P.C. Fannin, C.N. Marin, I. Malaescu, N. Stefu, P. Vlazan, S. Novaconi, P. Sfirloaga, S. Popescu, C.
Couper, Microwave absorbent properties of nanosized cobalt ferrite powders prepared by
coprecipitation and subjected to different thermal treatments, Materials and Design 32 (2011) 1600
1604
3) P. C.Fannin, I.Malaescu, C. N.Marin, N, Stefu, Microwave propagation parameters in magnetic
fluids, Eur. Phys. J. E 29, 299303 (2009)
4) P. C.Fannin, I.Malaescu, C. N.Marin, N, Stefu, Microwave specific loss power of magnetic fluids
subjected to a static magnetic field, Eur. Phys. J. E 27, 145148 (2008)
5) P. C.Fannin, C. N.Marin, I.Malaescu, N, Stefu, An investigation of the microscopic and macroscopic
properties of magnetic fluids, Physica B: Condensed Matter 388 (1-2), pp. 87-92, (2007)
6) P. C.Fannin, I. Malaescu, C. N.Marin, Determination of the Landau-Lifshitz damping parameter of
composite magnetic fluids, Physica B: Condensed Matter 388 (1-2), pp. 93-98, (2007)
7) P. C. Fannin, C. N. Marin, I. Malaescu, N. Stefu, Microwave dielectric properties of magnetite
colloidal particles in magnetic fluids, J. Phys.: Condensed Matter, 19 (2007) 036104-036111.
8) P.C.Fannin, C.Mac Oireachtaigh, I. Malaescu, C.N.Marin, Investigation of magnetic fluids exhibiting
field induced absorption peaks in the susceptibility spectra, Journal of Optoelectronics and
Advanced Materials 8 (1), pp. 46-49, (2006)

2. Articole indexate in baze de date internationale

1) P. C.Fannin, I.Malaescu, N, Stefu, C. N.Marin, Polarizing field and particle concentration dependence of the
magnetic loss power in ferrofluids, TIM-08, 28-29 November 2008, Timisoara, Romania, AIP Conference
Proceedings 1131, Melville New York (2009) 81-85, Editors M. Bunoiu, I. Malaescu
2) P. C.Fannin, N, Stefu, C. N.Marin, I.Malaescu, R. Totoreanu, Ferrofluid microwave devices with magnetically
controlled impedances, TIM-09, 27-28 November 2009, Timisoara, Romania, AIP Conference Proceedings 1262,
Melville New York (2010) 92-97, Editors M. Bunoiu, I. Malaescu
3) V. A.Serban, I.Malaescu, A. Ercuta, C. N.Marin, N, Stefu, C. Opris, C. Codrean, D. Utu, Magnetic properties of the
WC-Co cermet powders, TIM-09, 27-28 November 2009, Timisoara, Romania, AIP Conference Proceedings 1262,
Melville New York (2010) 113-117, Editors M. Bunoiu, I. Malaescu

3. Lucrari stiintifice comunicate

a) la conferine internaionale
1) I. Malaescu , C. N. Marin, P. C. Fannin, Investigation of the dynamic properties of magnetic fluids using the
ferromagnetic resonance, 7th International Balkan Workshop on Applied Physics, July 5-7, 2006, Constanta, Romania
(Invited lecture)
2) P. C. Fannin, C. N. Marin, C. Couper, I. Malaescu, N. Stefu, A Comparative Study of the Field Dependence of the
Properties of Colloidal Suspensions of Nanoparticles and of Magnetic Microspheres, PIERS Proceedings, Xi'an,
China, March 22-26, 2010

b) la conferine naionale
1). P.C.Fannin, I. Malaescu, C.N.Marin, N. Stefu, Power dissipation in magnetic fluids in microwave range, Physics
Conference Tim-06, Timisoara, November 24th- 25th, 2006.
2). P.C.Fannin, I. Malaescu, N. Stefu, C.N.Marin, Dependence on the frequency and magnetic polarizing field of the
complex dielectric permittivity of the magnetic fluids in microwave range, Physics Conference Tim-06, Timisoara,
November 24th- 25th, 2006.

3) P.C.Fannin, C.N.Marin, I. Malaescu, N. Stefu, The effect of the polarizing magnetic field and of the
partial immobilization of particles on the loss power in magnetic fluids, Physics Conference Tim-06,
Timisoara, November 24th- 25th, 2006.
4) I. Malaescu, P.C.Fannin, C.N.Marin, N.Stefu, Magnetic and dielectric behaviour of magnetic fluids in
electromagnetic field, National Conference on Applied Physics, December 8-9 2006, Iasi, Romania
(Invited lecture)
5) I.Malaescu, P.C.Fannin, C.N.Marin, N.Stefu, A study of magnetic fluid hyperthermia with application
to the cancer treatment, National Conference on Applied Physics, December 8-9 2006, Iasi, Romania
6) P.C. Fannin, I. Malaescu, C.N.Marin, N. Stefu, Specific loss in magnetic fluids in microwave range,
Physics Conference Tim-07, Timisoara, November 23th- 24th, 2007.
7) P.C. Fannin, I. Malaescu, C.N.Marin, N. Stefu, Frequency and field dependence of the
electromagnetic field propagation constant in magnetic fluids in microwave range, Physics
Conference Tim-07, Timisoara, November 23th- 24th, 2007.
8) P.C. Fannin, I. Malaescu, C.N.Marin, The spectroscopic splitting factor of nanoparticles in magnetic
fluids, Physics Conference Tim-07, Timisoara, November 23th- 24th, 2007.
4. Cri publicate n edituri recunoscute (cu ISSN sau ISBN):
1) I. Mlescu, Ferofluide n cmp de radiofrecven, Editura Mirton, Timioara, 1998, ISBN:
973-578-499-8.
2) I. Mlescu, Materiale i dispozitive electronice n cmp de nalt frecven, Editura
Eurobit, Timioara, 2008, ISBN: 978-973-620-391-6

Proiecte de cercetare pe baza de contract/grant

Programul/Proiectul

Funcia

Perioada

- Grant de cercetare CERCETARE DE EXCELENTA (CEEX) 2006, cu tema:

DEZVOLTAREA CUNOASTERII ASUPRA ELABORARII SI MICROPROCESARII
PRIN METALURGIA PULBERILOR A MATERIALELOR NANOSTRUCTURATE
PENTRU
COMPONENTE
MEMS,
acronim
:
PRONANOMAT
,
beneficiar : MATNANTECH ; coordonator: Universitatea din Craiova, Faculaltea
de Ingineria si Managementul Sistemelor Tehnologice din Drobeta Turnu Severin ;
director proiect : prof.dr.ing. Mangra Mihail ; durata finantarii: 2006 - 2008

Responsabil de
Proiect
(UVT)
Ioan Bica

Subontract CEEX, tip:P-CD, NANO4M nr.561/2005, cu tema: NANOCONTROL SI

MULTIFUNCTIONALITATE
IN
MATERIALE,
MICROSTRATURI
SI
ARHITECTURI CU MEMORIE A FORMEI director de proiect lector dr. Aurel
Ercuta, Universitatea de Vest din Timisoara

Responsabil de
Proiect
(UVT)
Aurel Ercuta

2005-2008

- Programul 4 Parteneriate in domeniile prioritare (PC), din programul PN2 cu

tema TEHNOLOGII INOVATIVE DE OBTINERE PRIN PULVERIZARE TERMICA
A MICROSTRATURILOR COMPOZITE DE TIP CERMET ANTICOROZIVE SI
ANTIUZARE, PC 2179
Universitatea POLITEHNICA Timisoara (UPT), Dir. Prof. Dr. Ing. Viorel-Aurel
Serban

Responsabil de
Proiect
(UVT)
Iosif Malaescu

2007-2010

Colaborare internationala cu prof. P.C. Fannin, de la Trinity College, Dublin, Irlanda,

in cadrul proiectului comun de cercetare cu tema:
THE INVESTIGATION, MEASUREMENT ANALYSIS AND APPLICATIONS OF
NANO-MICROPARTICLE SYSTEMS
Department of Electrical Engineering, Trinity College, Dublin 2, Ireland, Director
Prof. Dr. P. C. Fannin

Responsabil
stiintific
din partea UVT
Iosif Malaescu

2006-2010

Programul 4 Parteneriate in domeniile prioritare, tip PC 3456, Acronim SENBITE,

cu tema: SINTEZA DE SEMICONDUCTORI NANOSTRUCTURATI PE BAZA DE
Bi2Te3 SI Zn4Sb3 DOPATI CU APLICATII IN ENERGETICA CURATA
Coordonator: Institutul National de Cercetare Dezvoltare pentru Electrochimie si
Materie Condensata Timisoara, Director proiect, CP2 fiz. St. Novaconi

Responsabil de
Proiect
(UVT)
Iosif Malaescu

2008-2011
(in derulare )

Programul 4 Parteneriate in domeniile prioritare, tip PC 3516, Acronim AAEM, cu

tema: DEZVOLTAREA DE COMPOSITE MAGNETODIELECTRICE
NANOSTRUCTURATE PENTRU CREAREA DE ANVELOPE INTELIGENTE CU
ABSORBTIE PRONUNTATA A MICROUNDELOR
Coordonator: Institutul National de Cercetare Dezvoltare pentru Electrochimie si
Materie Condensata Timisoara, Director proiect, CP2 fiz. St. Novaconi

Responsabil de
Proiect
(UVT)
Catalin Marin

2008-2011
(in derulare )

2006-2008

Activitatea de cercetare
din ultimii cinci ani

Cercetare fundamental
Rezonana feromagnetic
Procese de relaxare
(dielectric i magnetic)

Cercetare aplicativ
Parametrii de propagare n
fluide magnetice i ferite
Absorbani electromagnetici

Principalele rezultate

1. Rezonanta feromagnetica
Fenomenul de rezonanta feromagnetica in fluidele magnetice, utilizand masuratorile de permeabilitate magnetica
complexa, a fost evideniat iniial de catre Fannin. Existenta fenomenului de rezonanta feromagnetica este indicata prin
tranzitia de la o valoare supaunitara la o valoare subunitara a partii reale a permeabilitatii magnetice complexe, (), la
frecventa de rezonanta fres.

'

1,5

'
''

MF1 - magnetite particles in kerosene

2

10

1,4
' 1,2

1
2

1,0

1,0
fres=5.46 GHz
fmax=5.45 GHz

fmax=1.22 GHz
1

0,5

''

6 7 8 9

10

f [GHz]

5 6

fmax=0.91 GHz

''

0,2
0,0
0,5

fmax=5.11 GHz

5
3

10

fres=5.12 GHz

fres=1.31 GHz

0,0
0,5

0,8

fres=1.81 GHz

'
''

MF2 - Mn0.6Fe0.4Fe2O3 particles in kerosene

7 8

10

f [GHz]

5 6

Fig. 1. The plots of the complex permeability of sample MF1 (a) and MF2 (b) as a function of frequency and polarizing field
(the polarizing field strengths are approximately: (1) 0 kA/m,(2) 15.23 kA/m, (3) 24.47 kA/m, (4) 35.28 kA/m, (5) 46.18
kA/m, (6) 57.07 kA/m, (7) 68.49 kA/m,(8) 79.33 kA/m, (9) 90.66 kA/m, (10) 102.40 kA/m. [6]
[6] P. C.Fannin, I. Malaescu, C. N.Marin, Determination of the Landau-Lifshitz damping parameter of
composite magnetic fluids, Physica B: Condensed Matter 388 (1-2), pp. 93-98, (2007)

Intr-un camp de polarizare puternic parametrul de atenuare

, din ecuatia Landau-Lifshitz satisface conditia (17) [6]
In Eq (1), fmax reprezinta frecventa corespunzatoare
maximului dependentei de frecventa a componentei imaginare,
().
1 ( f max / f res )
=
2
1 + ( f max / f res )
1.0

1.0

0.9

0.9

MF1 - magnetite in kerosene

0.8

0.7

0.6

fmax/fres

fmax/fres

0.8

0.6
20

40

60

80

100

H [kA/m]

(MF1) = 0.13

MF2 - Mn0.6Fe0.4Fe2O4 particles

in kerosene

HA=30.44 kA/m

0.7

HA= 48.14 kA/m

(17 )

(18)

120

20

40

60

80

100

H [kA/m]

( MF 2 ) = 0.127

(19)

120

Cunoasterea parametrului de atenuare , din ecuatia LandauLifshitz este importanta pentru medii de nregistrare magnetic.

Pe baza msurtorilor de rezonan feromagnetic, se pot determina o serie

de parametri macroscopici i microscopici ai fluidelor magnetice
investigate, aa cum am artat n lucrarea [5] i cum se observ n tabelul 1.

unde S1, S2 i S3 sunt fluide magnetice comerciale de tip Isopar M, cu

particule coloidale de magnetit (S1); de tip Ni0.5Zn0.5Fe2O4 (S2); si de tip
Mn0.66Zn0.33Fe2O4 (S3).

[5] P. C.Fannin, C. N.Marin, I.Malaescu, N, Stefu, An investigation of the microscopic and macroscopic
properties of magnetic fluids, Physica B: Condensed Matter 388 (1-2), pp. 87-92, (2007)

2. Comportarea dielectric n domeniul microundelor [7]

0,20

M F1 - m agne tite in kerosen e

''

'
3

MF1 - magnetite particles in kerosene

0,15
0,10

0,05

F IT
E X P E R IM E N T A L

1
0,1

1
f [G Hz]

0,00
0,1

FIT
EXPERIMENTAL

1
f [GHz]

a)
b)
Figure 2. Dependena de frecven a prii reale () i imaginare () a permitivitii dielectrice complexe a probei

[7] P. C. Fannin, C. N. Marin, I. Malaescu, N. Stefu, Microwave dielectric properties of magnetite colloidal
particles in magnetic fluids, J. Phys.: Condensed Matter, 19 (2007) 036104-036111.

Utiliznd teoria lui Sillars pentru dielectrici heterogeni (R. W. Sillars, Journal of
Institution of Electrical Engineers, 80 (1937) 378-394),
394 n aproximaia bifazic,
permitivitatea dielectric complex a fluidului magnetic calculat se potrivete cu
cea obinut experimental [7].

3. Puterea specific n domeniul microundelor [4]

unde

La o frecven, f(Hz), puterea de disipaie,

p, depinde de cmpul magnetic extern i
prezint un maxim. Rezultatul obinut
sugereaz posibilitatea controlrii
absorbiei de energie n microunde a
fluidelor magnetice prin intermediul unui
cmp magnetic extern aplicat.

[4] P. C.Fannin, I.Malaescu, C. N.Marin, N, Stefu, Microwave specific loss power of magnetic fluids
subjected to a static magnetic field, Eur. Phys. J. E 27, 145148 (2008)

4. Parametrii de propagare n nanosisteme de particule n

domeniul microundelor [1] [2] [3]
ntr-un mediu omogen i izotrop,
supus aciunii unui cmp
electromagnetic armonic, pornind de la
ecuaiile lui Maxwell rezult ecuaia
undelor:

Mrimea:
se numete constant de propagare fiind
o marime complex ce se poate scrie
sub forma:

Mrimea:

Mrimea

se numete impedana intrinsec a mediului, unde

Z0=377

se numete coeficientul de
reflexie la suprafata de
separarie dintre medii.

Cunoaterea parametrilor de propagare este important pentru

obinerea de absorbani electromagnetici pentru protecie
mpotriva polurii electromagnetice.
Astfel n lucrarea [1], s-a urmrit efectul concentraiei precursorilor asupra proprietilor de absorbant
electromagnetic n domeniul microundelor pentru nanopulberi de oxid de Fe-Zn.

x=Fe3+/Zn2+; x(A)=2.8/0.2; x(B)=2.5/0.5; x(C)=1.8/1.2; x(D)=1.5/1.5.

-----------------------------------------------------------------------------------[1] P. C. Fannin, C. N. Marin, I. Malaescu, N. Stefu, P. Vlzan, S. Novaconi, S. Popescu, Effect of the concentration of precursors on
the microwave absorbent properties of Zn/Fe oxide nanopowders, J. Nanopart. Res. 13 (2011) 311319
[2] P.C. Fannin, C.N. Marin, I. Malaescu, N. Stefu, P. Vlazan, S. Novaconi, P. Sfirloaga, S. Popescu, C. Couper, Microwave
absorbent properties of nanosized cobalt ferrite powders prepared by coprecipitation and subjected to different thermal treatments,
Materials and Design 32 (2011) 16001604
[3] P. C.Fannin, I.Malaescu, C. N.Marin, N, Stefu, Microwave propagation parameters in magnetic fluids, Eur. Phys. J. E 29, 299
303 (2009)

Rezultate in curs de diseminare

Intra-well relaxation process in magnetic fluids subjected to strong polarising fields

Teme propuse pentru doctoranzi

Studiul relaxarii magnetice si a efectului magneto-vascos in nanofluide magnetizabile
Nanosisteme de particule in camp electromagnetic

V MULUMESC!