II.

BILANT DE MATERIALE
1. Debitul de stiren produs de instalatie:
DST =

DSTanual 84 000 10 3
=
=10 500 kg /h
functionare
8000

2. Debitul de stiren produs de instalatie:

DST . pur =DST

p st
99,4
=10 500
=10437 kg /h
100
100

3. Debitul de etilbenzen care reactioneaza:

x

10437

C6H5-C2H5 C6H5-CH=CH2 + H2
106

104
=

D EB =

Cu
41
100= 100=85,41
Ct
48

D STtotal M EB
9443 106

=
=12453,91 kg/h
M ST

104 0, 8541

4. Debitul de etilbenzen care tine cont de conversie:

DEB . alim=

D EB 12453,91
=
=25945,64 kg /h
Ct
0, 48

5. Debitul de etilbenzen recirculat:

DEB . rec=D EB .alim D EB=13491,73 kg /h
6. Debitul de materie prima proaspata:
Dmp . proaspata=D EB + DB =DEB +

0, 1
DEB =124 78,81 kg/h
100

7. Debitul de materie prima recirculata:

Dmp =DEB . rec + DB . rec + DT . rec + DS T .rec =D EBrec+

rec

Dmp .rec =D EB. rec +

0,1 0,2 0,2

+
+
D
( 100
100 100 )

D
0,5
D mp. rec D mp .rec= EB . rec =13559 , 53 kg /h

100
10,005

mp .rec

DBrec =

0,1
13559,53=13, 56 kg /h
100
DTrec=

0,2
13559,53=2 7,11 kg /h
100

DSTrec =

0,2
13559,53=2 7,11 kg /h
100

Tabelul nr.1
COMPONENT

MP proaspata

MP recirculata

%gr.

kg/h

kmol/h

%gr.

kg/h

kmol/h

ETILBENZEN

99,8

12453,91

117,49

99,5

13491,73

127,28

BENZEN

0,2

24,91

0,32

0,1

13,56

0,17

TOLUEN

0,2

27,12

0,33

STIREN

0,2

27,12

0,26

TOTAL

100

12478,81

117,81

100

13559,53

128,05

Dabur =

abur
3 ,5
D EB .alim =
25945,64=90809,73 kg /h
mp
1

8. Calculul cantitatii de etilbenzen in reactii secundare:

C RS=C t Cu=0,4 80,4 1=0,0 7
1. D EBrs1=D EBalim C RS C S 1=544,86 kg
2. D EBrs2 =DEBalim C RS C S 2=817,29 kg /h
3. D EBrs3 =DEBalim C RS C S 3=454,05 kg/h
9. Calculul produsilor de reactie:
9.1.

Reactia principala
10437

C6H5-C2H5 C6H5-CH=CH2 + H2
104

H2
x = 200,7 kg/h
9.2.

Reactia secundara 1
544,86

C6H5-C2H5 C6H6
106

z
+ C2H4

78

28
y = 400,93 kg/h benzen
z = 143,92 kg/h etena

9.3.

Reactia secundara 2
817,29

C6H5-C2H5 + H2 C6H5-CH3 + CH4

106

92

16

x = 15,42 kg/h H2
y = 709,34 kg/h C5H6-CH3
z = 123,36 kg/h CH4
9.4.

Reactia secundara 3
454,05

C6H5-C2H5 + 16H2O 8CO2 + 21H2

106

16.18

8.44

2.2

x = 1233,64 kg/h H2O

y = 1507,78 kg/h CO2
z = 179,91 kg/h H2
DST =DST + DST =10437+27,12=10464,12 kg/h
total

rec

D H =D H + D H DH =200,7+123,36179,91=365,20 kg /h
2

2rs 1

2rs 2

2 rs 3

Dabur =D AB DH =90809,73 1507,78=89576,09 kg /h

alim

Tabelul nr.2 BILANT DE MATERIALE PE REACTOR

COMP.

Mi,
kg/kmol

INTRARI
kg/h

kmol/h

IESIRI
%mol

kg/h

kmol/h

%mol

EB

106

25945,64

244,77

4,62634

12453,91

117,49

2,17

78

38,47

0,49

0,00932

13,56

0,17

0,00

92

27,12

0,29

0,00557

27,12

0,29

0,01

St

104

27,12

0,26

0,00493

10464,12

100,62

1,85

C2H4

28

143,92

5,14

0,09

CH4

16

123,36

7,71

0,14

CO2

44

1507,78

34,27

0,63

H2

365,20

182,60

3,37

ABUR

18

90809,73

5044,99

95,35392

89576,09

4976,45

91,74

TOTAL

116848,08

5290,80

91562,2

5424,74

100,00

III. PROPRIETATI TERMICE

1.Calculul caldurilor specifice: (kcal/kmol.K)

Cp a b T c T 2 d T 3
T = 660 + 273 = 918 K
COMP.

Cp

CH4

4,75

0,012

3,03E-06

-2,63E-09

16,45

C2H4

0,944

0,03735

-1,99E-05

4,22E-09

21,87

CO2

6,85

0,008533

-2,48E-05

-6,73

H2

6,88

0,000066

2,79E-07

7,18

H2O

6,89

0,003283

-3,43E-07

9,65

-8,65

0,1158

-7,54E-05

1,85E-08

48,81

-8,213

0,1336

-8,23E-05

1,92E-08

60,39

EB

-8,4

0,1593

-0,0001

2,40E-08

72,63

St

-5,968

0,1435

-9,15E-05

2,20E-08

66,14

CO2
c)
a = 6,85

b = 0,008533
c = -2,475

10 5

d 0

Cp 6,85 0,0853 T 2,475 10 6 T 2

T(K)=918
Cp=12,58kcal/kmol*K

2.Calculul entalpiilor de formare:

Component

H kcal/kmol

EB
7,1
2

ST
35,2
2

B
19,8
2

T
CH4
11,95 -17,889

1.C6H5-C2H5 C6H5-CH=CH2
-8,4

-5,968

6,88

0,1593

0,1435

0,000066

10 4

9,15 10 5

2,7910 7

2,395 10 8
d

a=

2,2

pr

10 8

a pr r a r

T2
T3
H T H 0 a T b
c
2
3
H r298 H f pr H f r

CO2
-94,052

+ H2

C2H4
12,49
6

T4
d
4

a=9,312
b=-0,0158

0,878 10 5
c=

0,195 10 8
d=

H2O
-57,798

H2
0

298
298
H r298
H 298
fST DH fH 2 DH fEB 35, 22 0 7,12 28,10 kcal / mol 28100 kcal / kmol
1

2982
2983
28100 H10 9,312 298 0, 0158
0,878 10
5
2
3
0
H1 25952,96 Kcal / Kmol

0,195

108

2984

H T913 28532, 75kcal / kmol

2.C6H5-C2H5

C6H6

C2H4

-8,4

-8,65

0,944

a = 0,694

0,1593

0,1158

0,03735

b = -0,00615

10 4

7,54 10 5

1,993 10 7

c =

2,395 10 8
d

0,0467 10 5

1,854

10 8

4,22 10 9

1,19 10 9
d =

298
298
H rs2982 H 298
fB H fC2 H 4 H fEB 19,82 12, 496 7,12 25,196 kcal / mol 25196 kcal / kmol
3
4
2982
4 298
9 298
25196 H 0, 694 298 0, 00615
0, 0467 10

1,19
10

2
3
4
H10 25223, 41kcal / kmol
0
2

H T913 23205,56kcal / kmol

3. C6H5-C2H5

+ 16H2O

-8,4

0,1593

0,003283

0,08533

10 4

3,43 10 7

2,475 10 7

6,89

8CO2 + 21H2

2,395 10 8

6,88
0,000066

a = 97,44
b = -0,142

2,475 10 7

9,15 10 5
c =

2,395 10 8
d

6,85

d =

H rs2983 8 H 298
H 298

H 298

16 H298
fCO2 21
fH 2
fEB
fH 2 O

8 94, 0518 21 0 7,12

16 57,
7979 165,
265kcal / mol 165265

kcal / kmol
3
2982
5 298
165265 H 97, 44 298 0,142
9,15 10

2
3
0
H1 141781, 22 Kcal / Kmol
0
3

2984
2,395

10

4
9

H T913 190612,18kcal / kmol

4. C6H5-C2H5

H2

C6H5-CH3

+ CH4

-8,4

6,88

-8,213

4,75

0,1593

0,000066

0,1336

0,012

10 4

2,475 10 7

b = -0,0138

0,303 10 5

2,051 10 5
c =

2,395 10 8
d

8,23 10 5

a = -1,943

1,92 10 8

2,63 10 9

7,38 10 9
d =

298
298
298
H rs2982 H 298
fT H fCH 4 H fEB H fH 2

11,95 17,887 7,12 0 13, 059 kcal / mol 13059kcal / kmol

3
4
2982
5 298
9 298
13059 H 1,943 298 0, 0138
2, 05 10

7,38
10

2
3
4
H10 12033, 74kcal / kmol
0
4

H T913 15638, 27 kcal / kmol