Bilant termic pe compresor(2)

G23 1
4

G23 2.72255 10
5
100
95
100

initiator etilena
3

G23 1.361 10

initiator

G23

G23 2.586 10

etilena

3600 556.943
G23

pf 300

atm

pi 1

atm

3600

pf
pi
n

z 3

log

pi 5.192
pf

log ( 3)

fie n=6
6

300

300 2.587

300

300 3.129

j 1
j

pj pi z 3.129
j 2
j

pj pi z 9.791
j 3

pj pi z 30.639
j 4

pj pi z 95.873

0.014

7.563

j 5

pj pi z 300

calculam exponentul adiabatic

3

Xinitiator

Xc2h4

1.361 10
G23

2.586 104
G23

0.05

0.95

caldura specifica la presiune constanta

cp init 0.924
cp c2h4 1.643
cp mediu Xinitiator cp init Xc2h4 cp c2h4 1.607

caldura specifica la volum constant

cv init 0.664
cv c2h4 1.346
cv mediu Xinitiator cv init Xc2h4 cv c2h4 1.312

cp mediu

cv mediu

1.225

T1 293 ( 3.129)

361.288

T2 293 ( 9.791)

445.494

T3 293 ( 30.639)

549.333

T4 293 ( 95.873)

677.368

T5 293 ( 300)

835.246

t 1 T1 273 88.288
t 2 T2 273 172.494
t 3 T3 273 276.333
t 4 T4 273 404.368
t 5 T5 273 562.246

debitele de apa coresp celor 5 trepte

capa 4182
cgaze 1590
t i 10
t e 30

Gapa1
Gapa2
Gapa3
Gapa4
Gapa5

G23 cgaze t1 ti

capa te ti
G23 cgaze t2 ti

capa te t i
G23 cgaze t 3 t i

capa t e t i
G23 cgaze t 4 t i

capa t e t i
G23 cgaze t 5 t i

capa t e t i

4.052 10
4

8.41 10

1.378 10

2.041 10

2.858 10

Bilant termic pe compresor

pf 2500
pi 300

fie z=3 pf

log

pi

n
log ( 3)

1.93

deci n=2

pf

pf

pi

pi

2.887

j 1
j

pj pi z 866.025
j 2
j

pj pi z 2.5 10
1.225
Xinitiator 0.05
Xc2h4 0.95
cp mediu 1.607
cv mediu 1.312

calculam temperatura treptelor de comprimare

1

866.025
T1 293

300

355.98

T2 293

2500

300

432.499

t 1 T1 273 82.98
t 2 T2 273 159.499

calculam debitele de apa coresp celor 2 trepte de comprimare

t i 10
t e 30

Gapa1

G23 cgaze t1 ti

capa te ti

3.777 10

Gapa2

G23 cgaze t2 ti

7.737 10

capa te ti

95

debit masic monomer-

100

GM

3600
5

100

GI

debit masic sol initiator-

G23

G23

3600

kg

7.185

s
kg

0.378

cp i 0.924

kg

debit polimer-

kg

GP 1.07767

kJ

cpM 40 0.564 4180 2.358 10

kg K
kJ

cpM 260 0.681 4180 2.847 10

kg K
J

cp p 0.706 4180 2.951 10

cp L 1007.1

kg K

caldura specifica a ag termic(aer)

kg K

L - devit masic agent de racire

t i 20
t e 50

H 15 4180 6.27 10

Q L cp L t e t i

Q GM cpM 40 cp i GI GM 0.15 H GP cp p GM cpM 260 0.85 6.394 10

L

aer 1.293

kg

2.116

cp L t e t i

aer in conditii normale

kg
3

aer20 aer

273 6
7.228
293 1

L
Lv
0.293
aer20

densitatea aer la 20 grade , comprimat la 6 atm

m
s

aer comprimat de 6 atm

la temperatura medie
aer35 1.29

273 6
6.86
308 1
5

aer35 1.9 10
A

Q
200 194

kg
3

Pa s

1.648

Predimensionarea reactorului
t 0 35 s
G23
Dv
0.014
3600 556.94
3

capacitatea reactorului

V 0.25 m
d 0.317 m
h 3.17 m

( H ) V v r Dm Cp 110 Kt ST T Ta

volumul primei zone a reactorului

Vz 0.63 0.25 0.158

t 0z

Vz
0.014

11.25
3

kp 1.281

kmol s
3

kt 18.91

kmol s
1

kd 0.192

I0 0.01
t 0

I0 I
kd I

I 3.16 10
f 0.5
vrm kp

0.5

2 f kd
kt

0.5

7.256 10

m0 18.89

kmol
3

m 17.34
3

vrmm 7.256 10

m 0.126

( H ) V v r Dm Cp 110 Kt ST T Ta
15 1000 4180 0.25 0.1257
6

1.97 10 W 2.073 10

7.536 2501 110

rezulta ca reactorul functioneaza adiabat

Bilant termic pe racitor (12)

G29 6752
30
100

kg
h
kg

G29 2.026 10

5
100

G29 337.6

h
kg
h

PE

etilena

la 140 grd
cPE 1700
cET 1863

J
kg K
J
kg K

GPE cPE ( 260 20) GET cET ( 260 20)

Gapa capa ( 30 10)

30
3
GPE
G29 2.026 10
100
5
GET
G 337.6
100 29
3

capa 4.182 10

Gapa

GPE cPE ( 260 20) GET cET ( 260 20)

capa ( 30 10)

1.169 10

kg
h

Bilant termic pe racitor 18

G15 506.80648
GEt G15
3

capa 4.182 10
Gapa

GEt cET ( 260 20)

capa ( 30 10)

2.709 10

kg
h

apa